CN107266959A - Scratch resistance electronic beam curing ironwork surface printing ink and preparation method thereof - Google Patents
Scratch resistance electronic beam curing ironwork surface printing ink and preparation method thereof Download PDFInfo
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- CN107266959A CN107266959A CN201710429388.0A CN201710429388A CN107266959A CN 107266959 A CN107266959 A CN 107266959A CN 201710429388 A CN201710429388 A CN 201710429388A CN 107266959 A CN107266959 A CN 107266959A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/108—Hydrocarbon resins
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of scratch resistance electronic beam curing ironwork surface printing ink, the ink includes the component of following parts by weight：10~20 parts of high density polyethylene (HDPE), 1~10 part of trimethylolpropane trimethacrylate, 10~20 parts of polyetheramine, 20~60 parts of n-BMA, 10~25 parts of diluent, 10~20 parts of titanium dioxide, 0.1~2 part of dispersant, 1~30 part of corrosion-inhibiting pigment.The ink of the present invention is in high density polyethylene (HDPE), trimethylolpropane trimethacrylate, polyetheramine, under the mutual synergy of each components such as n-BMA, ink is enabled to form high molecular weight steric converging network that is strong and interacting under extremely short hardening time, the problem of solving the high energy consumption high VOC emission of traditional solvent-borne baking ink, solve traditional UV cured printing inks adhesive force, the problem of deep cure and recoatability, cause ink film that there is higher hardness simultaneously simultaneously, adhesive force, chemical resistance, rub resistance, heat resistance and boiling resistance energy, its is economic and environment-friendly, development for EB curing technologies in ink provides a kind of new application.
Description
Technical field
The invention belongs to ink area, and in particular to a kind of scratch resistance electronic beam curing ironwork surface printing ink and its
Preparation method.
Background technology
The ink referred to as electron beam curing ink solidified using beam energy（That is EB ink）.Ink after common ink printing
Link stuff in the drying of film layer, usually ink is absorbed and volatilized by stock, and solid matter is then retained in stock surface,
Form a thin layer of layer of ink.And electronic beam curing is then to do the irradiation energy by electron beam, enter with active liquid chemical formulation
The process of row radiation chemical reaction, at normal temperatures rapid dry solidification.
Because electron beam is a kind of radiation, so electron beam irradiation can also be attributed to the class of radiation curing one.Radiation curing
It is the new technology grown up on the basis of existing science and technology, it is mainly accelerated using a kind of electronics of sweep type
The electron beam of electron accelerator is scanned to substrate surface so as to realize solidification processing in device, radiation curing, and its basic meaning is exactly
It is the energy using ultraviolet light or electron beam, triggering has chemically active liquid formulations, and fast reaction is realized in matrix surface
Solidification process.Ultraviolet light solidifies and Electron beam curing technology is different from conventional art（Such as heat cure）Great advantage be spoke
Solidification is penetrated using the ultraviolet light or electron beam of high efficient energy sources as initiation means, curing of coatings is quickly realized.Wherein electron beam spoke
Penetrate, be made up of a collection of electron stream by acceleration, in the presence of high-power electron beam, produce free radical or ion radical,
Free radical or ion radical are cross-linked into network polymers with other materials again, and compared with ultraviolet light, particle energy is significantly larger than ultraviolet
Light, can make air ionization, and electronic beam curing is typically not required to light trigger, can directly trigger chemical reaction, to material
Penetration power is also wideer than ultraviolet.
The resin that both electronic beam curing and photocuring are used（Prepolymer）It is similar with monomer, therefore it polymerize
Journey and product also have certain similitude and comparativity.But, both difference are also apparent, and these difference determine it
Different advantages and the market demand.Compared with photocuring, the advantage of electronic beam curing includes：
1）Electronic beam curing is very high because of the energy of electronics, can directly make the organic matters such as resin or monomer dissociate, produce free radical and
Ion is required for light trigger so as to initiated polymerization in electronic beam curing formula.This can bring many benefits.
First, light trigger can not be decomposed completely in photocuring, and they are typically all the compound containing carbonyl, and this is to photocuring
The ageing-resistant performance of material is totally unfavorable；Secondly, cured product can be made purer without light trigger, will not be due to residual
The volatilization of light trigger and its photolysis products and cause unpleasant stink, this to certain this apply（Such as biology, medical science, food
Deng）It is vital；Finally, due to light trigger price is general all somewhat expensive, therefore without light trigger workinprocess cost
Aspect is also advantageous；
2）The penetration capacity of electron beam is relevant only with the density of material, is not present for coloring materials such as ink as photocuring
Light the problem of be difficult to pass through, it is to avoid in photocuring must usage amount is big and the shortcoming of the light trigger of high price；
3）The penetration depth of electron beam is bigger than the penetration depth of light, and therefore, electronic beam curing cannot be only used for thin face coat,
Thickness be can also be used for up to the solidification and two-sided solidification of several millimeters or even several centimeters of composite, this is to be relatively difficult in photocuring
Accomplish.
Electron beam curing ink is the same with UV ink, is also one of most promising " green " ink in wire mark.
Due to the limitation of electron beam curing ink not ink receptive layer thickness, operate also more safer than ultraviolet photo-curing ink.
Certainly, as the developing new curing technology of one kind, there is also some shortcomings for EB curing technologies.As in recent years
Although EB curing apparatus has in price significantly to be reduced, disposably input is still larger for its equipment；EB ink
Price of the price still than common ink is high；, typically all must be using inert gas shielding to solve the problems, such as the suppression of oxygen in air
Method, not only increase the complexity of device, and add production cost；The coating that EB solidifications are only applicable to plane is consolidated
Change, thus the geometry of cured article is restricted；One key property of EB ink is exactly that it has good resistance, but
This then turns into deinking hardly possible when discarded printed matter is reclaimed, hinders the factor reclaimed, therefore must also in terms of printing recovery
Do new research.
The content of the invention
The purpose of the present invention is that there is provided a kind of scratch resistance electronic beam curing ironwork surface print on the basis of existing technology
Brush ink.
It is a further object of the present invention to provide a kind of system of above-mentioned scratch resistance electronic beam curing ironwork surface printing ink
Preparation Method.
The purpose of the present invention can be reached by following measures：
A kind of scratch resistance electronic beam curing ironwork surface printing ink, the ink includes the component of following parts by weight：High density
10~20 parts of polyethylene, 1~10 part of trimethylolpropane trimethacrylate, 10~20 parts of polyetheramine, n-BMA
20~60 parts, 10~25 parts of diluent, 10~20 parts of titanium dioxide, 0.1~2 part of dispersant, 1~30 part of corrosion-inhibiting pigment.
The electron beam curing ink of the present invention only can be formulated by above each component, can also not influence globality
Other components, such as wetting agent etc. are added on the basis of energy.
In a kind of scheme, scratch resistance electronic beam curing ironwork surface printing ink of the invention includes following parts by weight
Component：10~20 parts of high density polyethylene (HDPE), 2~8 parts of trimethylolpropane trimethacrylate, 10~20 parts of polyetheramine, methyl
30~50 parts of n-butyl acrylate, 15~25 parts of diluent, 10~20 parts of titanium dioxide, 0.1~1 part of dispersant, anticorrosion face
5~30 parts of material.
In another scheme, scratch resistance electronic beam curing ironwork surface printing ink of the invention includes following weight
The component of part：12~17 parts of high density polyethylene (HDPE), 3~8 parts of trimethylolpropane trimethacrylate, 12~18 parts of polyetheramine, first
35~45 parts of base n-butyl acrylate, 15~20 parts of diluent, 12~20 parts of titanium dioxide, 0.1~0.5 part of dispersant, anti-corrosion
Lose 15~30 parts of pigment.
In a kind of preferred scheme, scratch resistance electronic beam curing ironwork surface printing ink of the invention includes following weight
Measure the component of part：16 parts of high density polyethylene (HDPE), 6 parts of trimethylolpropane trimethacrylate, 15 parts of polyetheramine, methacrylic acid is just
40 parts of butyl ester, 18 parts of diluent, 15 parts of titanium dioxide, 0.2 part of dispersant, 20 parts of corrosion-inhibiting pigment.
Diluent in the present invention is selected from hexamethylene.
Dispersant in the present invention is selected from excellent card UNIQJET9510 or Si Luoke Silok7195W dispersants.
, first will be highly dense the invention provides a kind of preparation method of scratch resistance electronic beam curing ironwork surface printing ink
Spend polyethylene, trimethylolpropane trimethacrylate, polyetheramine, n-BMA and diluent high at 20~80 DEG C
Speed, which is dispersed to, obtains finely dispersed solution, adds titanium dioxide, dispersant and corrosion-inhibiting pigment, then uses hydraulic pressure three-roller machine
It is ground, until pigment is completely dispersed to less than 5 microns, finally filters and packages.
It is preferred that, the temperature when high speed is scattered is 40~60 DEG C.
The EB ink of the present invention has many advantages, such as follows：
（1）Without volatile materials VOC, without smell or the only smell of very little, the harm to workers ' health is reduced, it is acyclic
Pollute in border；
（2）Resistance is good, and the chemical substance in ink forms high molecular weight steric network polymers, ink film tool by cross-linking reaction
There are preferable chemical resistance and rub resistance；
（3）Hardening time is short, only needs thoroughly dry for 0.1 second or so, and a few minutes even several days ability is needed with traditional printing
Thoroughly drying is compared, and substantially increases production efficiency, is conducive to carrying out large-scale production；
（4）The dense bottom of pigment is high, and the product appearance of printing is beautiful, with very strong gloss height and third dimension；
（5）Reduce the scavenging period of printing machine, even if EB ink in ink fountain deposits an evening, be also not in skinning,
Hardening phenomenon, reduces waste；
（6）Be not in cause the heat-flash amount of printing composition deformation during solidification.
The scratch resistance electronic beam curing ironwork surface printing ink of the present invention is under the synergy of each component, particularly
High density polyethylene (HDPE), trimethylolpropane trimethacrylate, polyetheramine, n-BMA mutual synergy
Under so that ink can form high molecular weight steric converging network that is strong and interacting under extremely short hardening time, solution
The problem of high energy consumption high VOC emission of traditional solvent-borne of having determined baking ink, solve traditional UV cured printing inks adhesive force, deep layer
Solidification and the problem of recoatability, while so that ink film have simultaneously higher hardness, adhesive force, chemical resistance, rub resistance,
Heat resistance and boiling resistance energy, its is economic and environment-friendly, and can meet various mode of printings includes silk-screen, wire mark, digital printing and spray
Ink print, the development for EB curing technologies in ink provides a kind of new application.
Embodiment
The present invention will be further described with reference to embodiments, but protection scope of the present invention be not limited to it is following
Embodiment.
Embodiment 1
The parts by weight of each component are constituted：16 parts of high density polyethylene (HDPE), 6 parts of trimethylolpropane trimethacrylate, polyetheramine 15
Part, 40 parts of n-BMA, 10 parts of diluent hexamethylene, 8 parts of diluent hexamethylene, 15 parts of titanium dioxide, UNIQJET
9510 0.2 part of dispersants, 20 parts of corrosion-inhibiting pigment.
Preparation method, by high density polyethylene (HDPE), trimethylolpropane trimethacrylate, polyetheramine, methacrylic acid just first
Butyl ester and diluent are dispersed at a high speed at 20~80 DEG C obtains finely dispersed solution, add titanium dioxide, dispersant and
Corrosion-inhibiting pigment, is then ground with hydraulic pressure three-roller machine, until pigment is completely dispersed to less than 5 microns, is finally filtered and packaged
.
Embodiment 2
The parts by weight of each component are constituted：18 parts of high density polyethylene (HDPE), 7 parts of trimethylolpropane trimethacrylate, polyetheramine 11
Part, 35 parts of n-BMA, 16 parts of diluent hexamethylene, 13 parts of titanium dioxide, 0.2 part of Silok7195W dispersants,
15 parts of corrosion-inhibiting pigment.
Preparation method, by high density polyethylene (HDPE), trimethylolpropane trimethacrylate, polyetheramine, methacrylic acid just first
Butyl ester and diluent are dispersed at a high speed at 20~80 DEG C obtains finely dispersed solution, add titanium dioxide, dispersant and
Corrosion-inhibiting pigment, is then ground with hydraulic pressure three-roller machine, until pigment is completely dispersed to less than 5 microns, is finally filtered and packaged
.
Embodiment 3
The parts by weight of each component are constituted：10 parts of high density polyethylene (HDPE), 5 parts of trimethylolpropane trimethacrylate, polyetheramine 11
Part, 38 parts of n-BMA, 15 parts of diluent hexamethylene, 11 parts of titanium dioxide, the dispersants 0.2 of UNIQJET 9510
Part, 20 parts of corrosion-inhibiting pigment.
Preparation method, by high density polyethylene (HDPE), trimethylolpropane trimethacrylate, polyetheramine, methacrylic acid just first
Butyl ester and diluent are dispersed at a high speed at 20~80 DEG C obtains finely dispersed solution, add titanium dioxide, dispersant and
Corrosion-inhibiting pigment, is then ground with hydraulic pressure three-roller machine, until pigment is completely dispersed to less than 5 microns, is finally filtered and packaged
.
Comparative example 1
High density polyethylene (HDPE) in embodiment 1 is removed, other components and preparation be the same as Example 1.
Comparative example 2
Trimethylolpropane trimethacrylate in embodiment 1 is removed, other components and preparation be the same as Example 1.
Comparative example 3
Polyetheramine in embodiment 1 is removed, other components and preparation be the same as Example 1.
Test case
Ink obtained by each embodiment and comparative example is applied on tinplate substrate surface, inserts and electricity is carried out in electron-beam accelerator
Beamlet is irradiated, after 0.1s irradiation doses 1kgy, ink film solidification.Ink film properties test result is as follows after solidification：1st, adhere to
Power, scratch resistance, the method for expressing of wearability：1 is worst, and 5 be optimal, and specific performance see the table below.
2nd, water resistance（GB/T1733-93 first methods）, embodiment 1-3 is above 3500h, and comparative example 1 and 2 is less than 400h.
3rd, acid resistance（5 wt % hydrochloric acid solutions soak 300h）, embodiment 1-3 ink films are without exception, and comparative example 1-3 is in 48h
Inside there is the dissolving of ink film partial exfoliation.
4th, alkali resistance（5 wt %NaOH solution soak 300h）, embodiment 1-3 ink films are without exception, and comparative example 1-3 is in 40h
There is ink film to have dissolution phenomena.
5th, pencil hardness, embodiment 1-3 is 3H-4H, and comparative example 1-3 is H.
6th, glossiness（GB/T9754-2007）, embodiment 1-3 is more than 88%, and comparative example 1-3 is less than 55%.
Claims (8)
1. a kind of scratch resistance electronic beam curing ironwork surface printing ink, it is characterised in that the ink includes following parts by weight
Component：10~20 parts of high density polyethylene (HDPE), 1~10 part of trimethylolpropane trimethacrylate, 10~20 parts of polyetheramine, methyl-prop
20~60 parts of olefin(e) acid N-butyl, 10~25 parts of diluent, 10~20 parts of titanium dioxide, 0.1~2 part of dispersant, corrosion-inhibiting pigment 1
~30 parts.
2. scratch resistance electronic beam curing ironwork surface printing ink according to claim 1, it is characterised in that the ink
Include the component of following parts by weight：10~20 parts of high density polyethylene (HDPE), 2~8 parts of trimethylolpropane trimethacrylate, polyetheramine
10~20 parts, 30~50 parts of n-BMA, 15~25 parts of diluent, 10~20 parts of titanium dioxide, dispersant 0.1~
1 part, 5~30 parts of corrosion-inhibiting pigment.
3. scratch resistance electronic beam curing ironwork surface printing ink according to claim 2, it is characterised in that the ink
Include the component of following parts by weight：12~17 parts of high density polyethylene (HDPE), 3~8 parts of trimethylolpropane trimethacrylate, polyetheramine
12~18 parts, 35~45 parts of n-BMA, 15~20 parts of diluent, 12~20 parts of titanium dioxide, dispersant 0.1~
0.5 part, 15~30 parts of corrosion-inhibiting pigment.
4. scratch resistance electronic beam curing ironwork surface printing ink according to claim 3, it is characterised in that the ink
Include the component of following parts by weight：16 parts of high density polyethylene (HDPE), 6 parts of trimethylolpropane trimethacrylate, 15 parts of polyetheramine, first
40 parts of base n-butyl acrylate, 18 parts of diluent, 15 parts of titanium dioxide, 0.2 part of dispersant, 20 parts of corrosion-inhibiting pigment.
5. the scratch resistance electronic beam curing ironwork surface printing ink according to claim 1,2,3 or 4, it is characterised in that
The diluent is selected from hexamethylene.
6. the scratch resistance electronic beam curing ironwork surface printing ink according to claim 1,2,3 or 4, it is characterised in that
The dispersant is selected from excellent card UNIQJET9510 or Si Luoke Silok7195W dispersants.
7. a kind of preparation method of the scratch resistance electronic beam curing ironwork surface printing ink described in claim 1, its feature
It is first high density polyethylene (HDPE), trimethylolpropane trimethacrylate, polyetheramine, n-BMA and diluent exist
It is dispersed at a high speed at 20~80 DEG C and obtains finely dispersed solution, adds titanium dioxide, dispersant and corrosion-inhibiting pigment, then
It is ground, until pigment is completely dispersed to less than 5 microns, is finally filtered and packaged with hydraulic pressure three-roller machine.
8. the preparation method of scratch resistance electronic beam curing ironwork surface printing ink according to claim 7, its feature
It is 40~60 DEG C to be the temperature when high speed is scattered.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710429388.0A CN107266959A (en) | 2017-06-08 | 2017-06-08 | Scratch resistance electronic beam curing ironwork surface printing ink and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710429388.0A CN107266959A (en) | 2017-06-08 | 2017-06-08 | Scratch resistance electronic beam curing ironwork surface printing ink and preparation method thereof |
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| CN107266959A true CN107266959A (en) | 2017-10-20 |
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| CN201710429388.0A Withdrawn CN107266959A (en) | 2017-06-08 | 2017-06-08 | Scratch resistance electronic beam curing ironwork surface printing ink and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113861775A (en) * | 2021-09-25 | 2021-12-31 | 上海吉祥家美幕墙材料有限公司 | Corrosion-resistant printing alloy plate and production process thereof |
-
2017
- 2017-06-08 CN CN201710429388.0A patent/CN107266959A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113861775A (en) * | 2021-09-25 | 2021-12-31 | 上海吉祥家美幕墙材料有限公司 | Corrosion-resistant printing alloy plate and production process thereof |
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