CN107227612A - A kind of spinning oil of resistance to volatile-type - Google Patents
A kind of spinning oil of resistance to volatile-type Download PDFInfo
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- CN107227612A CN107227612A CN201710509924.8A CN201710509924A CN107227612A CN 107227612 A CN107227612 A CN 107227612A CN 201710509924 A CN201710509924 A CN 201710509924A CN 107227612 A CN107227612 A CN 107227612A
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- agent
- volatile
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- spinning oil
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- 238000009987 spinning Methods 0.000 title claims abstract description 34
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 63
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 20
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 19
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 19
- 230000000740 bleeding effect Effects 0.000 claims abstract description 18
- 239000000080 wetting agent Substances 0.000 claims abstract description 14
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000654 additive Substances 0.000 claims abstract description 8
- 230000000996 additive effect Effects 0.000 claims abstract description 8
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims abstract description 7
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims abstract description 7
- 235000010234 sodium benzoate Nutrition 0.000 claims abstract description 7
- 239000004299 sodium benzoate Substances 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims abstract description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 24
- 239000000706 filtrate Substances 0.000 claims description 18
- 239000008236 heating water Substances 0.000 claims description 18
- 240000000560 Citrus x paradisi Species 0.000 claims description 17
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 15
- 244000276331 Citrus maxima Species 0.000 claims description 14
- 235000001759 Citrus maxima Nutrition 0.000 claims description 14
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 14
- -1 epoxide modified oleic acid Chemical class 0.000 claims description 14
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 13
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 13
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 13
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 13
- 239000005642 Oleic acid Substances 0.000 claims description 13
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 13
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 10
- QHGNHLZPVBIIPX-UHFFFAOYSA-N tin(ii) oxide Chemical compound [Sn]=O QHGNHLZPVBIIPX-UHFFFAOYSA-N 0.000 claims description 10
- 229960002163 hydrogen peroxide Drugs 0.000 claims description 7
- 238000005292 vacuum distillation Methods 0.000 claims description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 125000001931 aliphatic group Chemical group 0.000 claims description 6
- 239000000395 magnesium oxide Substances 0.000 claims description 6
- 238000002137 ultrasound extraction Methods 0.000 claims description 6
- 238000009777 vacuum freeze-drying Methods 0.000 claims description 6
- VETPHHXZEJAYOB-UHFFFAOYSA-N 1-n,4-n-dinaphthalen-2-ylbenzene-1,4-diamine Chemical compound C1=CC=CC2=CC(NC=3C=CC(NC=4C=C5C=CC=CC5=CC=4)=CC=3)=CC=C21 VETPHHXZEJAYOB-UHFFFAOYSA-N 0.000 claims description 3
- PRWJPWSKLXYEPD-UHFFFAOYSA-N 4-[4,4-bis(5-tert-butyl-4-hydroxy-2-methylphenyl)butan-2-yl]-2-tert-butyl-5-methylphenol Chemical compound C=1C(C(C)(C)C)=C(O)C=C(C)C=1C(C)CC(C=1C(=CC(O)=C(C=1)C(C)(C)C)C)C1=CC(C(C)(C)C)=C(O)C=C1C PRWJPWSKLXYEPD-UHFFFAOYSA-N 0.000 claims description 3
- 230000004048 modification Effects 0.000 claims description 3
- 238000012986 modification Methods 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 238000013517 stratification Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 238000007654 immersion Methods 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 230000006837 decompression Effects 0.000 claims 1
- 238000001704 evaporation Methods 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 238000007380 fibre production Methods 0.000 abstract description 2
- 230000009286 beneficial effect Effects 0.000 abstract 1
- 239000004753 textile Substances 0.000 abstract 1
- 239000000835 fiber Substances 0.000 description 14
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 8
- 239000007788 liquid Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 230000000149 penetrating effect Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000000470 constituent Substances 0.000 description 3
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 3
- 229940049964 oleate Drugs 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000004129 EU approved improving agent Substances 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000006735 epoxidation reaction Methods 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000011895 specific detection Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/1845—Aromatic mono- or polycarboxylic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of spinning oil of resistance to volatile-type, belong to macromolecular fibre production technical field.The textile finish oil of resistance to volatile-type of the invention includes following parts by weight material：45~50 parts of modified smooth agents, 15~20 parts of antistatic additive SN, 10~15 parts of emulsifying agents, 0.5~1.0 part of wetting agent, 0.2~0.3 part of obvolvent agent, 0.5~1.0 part of antioxidant, 0.3~0.5 part of bleeding agent, 0.6~0.8 part of polyoxyethylene polyoxypropylene pentaerythrite ether, 0.5~1.0 part of sodium benzoate.The beneficial effects of the invention are as follows：The spinning oil of resistance to volatile-type of the invention is not volatile, while having preferable wettability and heat resistance.
Description
Technical field
The present invention relates to a kind of spinning oil of resistance to volatile-type, belong to macromolecular fibre production technical field.
Background technology
Spinning oil chemical fibre or synthetic fibers are before spinned fiber, the liquid substance added into spinning solution.
During experimental branch line and post-processing, in order to there is preferable spinnability, it is necessary to eliminate the electrostatic of precursor, coefficient of friction is adjusted, is assigned
Give fiber smoothly and flexibility, fiber is passed through the processes such as spinning, drawing-off, winding, twisting, winder, weaving, it is therefore necessary to
Add appropriate spinning oil.
The component of conventional preparation medium can be divided into two major classes：First major class include component be smooth agent, antistatic additive,
Emulsifying agent, the second major class is accessory constituent, including wetting agent, softening agent, obvolvent agent, antioxidant, point fine agent, bleeding agent, pH are adjusted
Save agent, viscosity-improving agents, stabilizer, defoamer, antimicrobial, preservative and balanced adjustment agent etc..Conventional finish be by
More than 90% major constituent and less than 10% accessory constituent composition, the common frictional behaviour for being used for adjusting chemical fibre, prevent or eliminate
Accumulation of static electricity, assigns the performance such as smooth fiber, boundling, antistatic, soft.But there is problems with：The heat resistance of finish is poor,
In high temperature and high speed spinning process, most of finish is volatile, decompose, and fibre strength reduction, flatness is deteriorated, and then produces hair
Silk and broken end；During high speed spinning, finish wetability is poor, it is impossible to be quickly and evenly attached to fiber surface, make fiber it
Between obvolvent poor performance, fiber strength reduction, and then influence drawing-off and deformation；Finish on fiber can splash under the action of the centrifugal force
Onto hot-rolling, the heated formation for being easily caused coke-like thing for a long time, coking residual is big.
It would therefore be highly desirable to develop a kind of good spinning oil of not volatile, wetability.
The content of the invention
The technical problems to be solved by the invention：For the drawbacks of conventional spinning finish is volatile, wetability is poor there is provided
A kind of spinning oil of resistance to volatile-type.
In order to solve the above technical problems, the present invention is using technical scheme as described below：
A kind of spinning oil of resistance to volatile-type, including following parts by weight material：
45~50 parts of modified smooth agents, 15~20 parts of antistatic additive SN, 10~15 parts of emulsifying agents, 0.5~1.0 part of wetting agent, 0.2
~0.3 part of obvolvent agent, 0.5~1.0 part of antioxidant, 0.3~0.5 part of bleeding agent, 0.6~0.8 part of polyoxyethylene polyoxypropylene
Pentaerythrite ether, 0.5~1.0 part of sodium benzoate；The described specific preparation process of modification smooth agent is：
（1）Take and mill and sieve after fresh grapefruit skin, vacuum freeze drying, obtain pomelo peel powder, in mass ratio 1:8, by shaddock
Skin powder is mixed with n-hexane, ultrasonic extraction after immersion, is filtered to get filtrate, and in mass ratio 1:5, filtrate is mixed with n-hexane,
Centrifuge to obtain shaddock ped oleic acid；
（2）By volume 1:5, hydrogenperoxide steam generator is added dropwise in shaddock ped oleic acid, after heating water bath stratification and collect on
Layer oil phase, obtains epoxide modified oleic acid；
（3）Count by weight, 45~50 parts of epoxide modified oleic acid, 35~40 parts of pentaerythrites, 5~8 parts of diformazans are weighed respectively
Benzene and 0.5~1.0 part of stannous oxide Hybrid Heating must be modified mixed liquor, then in mass ratio 1:10, magnesia is added to and is modified
In mixed liquor, heated after ultrasonic disperse, then vacuum distillation, standing cooling, filter to get filtrate, be prepared into modified smooth agent.
Described emulsifying agent is in mass ratio 1:1, aliphatic acid polyethenoxy ether LAE-9 and emulsifying agent NP-2 stirrings are mixed
It is prepared from.
Described wetting agent is any one in OP-4, OP-6 and OP-10.
Described obvolvent agent is any one in obvolvent agent SJ-B and obvolvent agent LAE-9.
Described antioxidant is times in antioxidant 1076, antioxidant CA, antioxidant 164, antioxidant DNP
Meaning is a kind of.
Described bleeding agent is any one in penetrating agent JFC-E and bleeding agent OEP-70.
Step（2）Described hydrogenperoxide steam generator drop rate is 2mL/min.
Step（3）Described vacuum distillation condition is that 200~250 DEG C of temperature, pressure are 85~90kPa.
The present invention is compared with other method, and advantageous effects are：
（1）The present invention is used as raw material by pomelo oil, carries out epoxidation modification to it, makes it as the matrix of smooth agent material
Oil, after epoxide modified, being passed to grafted epoxy group improves material smooth agent heat resistance, and smooth agent is used as spinning oil
The main body of agent, can be effectively improved the heat resistance of material, reduction finish volatilization intensity；
（2）The present invention is compounded by hydrophilic and oleophilic emulsifier, and hydrophilic group is attracted by water, and hydrophobic group is repelled by water,
Not only the motion for having attracted but also having repelled promotes surfactant to form Interfacial Adsorption on the interface of liquids and gases, liquid and solid
Layer, when Interfacial Adsorption reaches saturation, unadsorbed molecule just initially forms micella in liquid internal, so as to enter to fibrous material
Row effectively cladding, improves finish wettability, can quickly be coated in fiber surface formation, improve fiber mechanicses intensity.
Embodiment
Take after fresh grapefruit skin, 6~8h of vacuum freeze drying, milled and cross 75~80 mesh sieves, obtain pomelo peel powder,
In mass ratio 1:8, pomelo peel powder is mixed with n-hexane, soaked at 45~50 DEG C after 25~30min, then 200~
10~15min of ultrasonic extraction under 300W, standing is cooled to room temperature, filters to get filtrate, and in mass ratio 1:5, by filtrate and n-hexane
Mixing, then 10~15min is centrifuged under 2500~3000r/min, obtain shaddock ped oleic acid；By volume 1:5, by mass fraction
15% hydrogenperoxide steam generator is added dropwise in shaddock ped oleic acid, and it is 2mL/min to control drop rate, after being added dropwise to complete, then 55~
25~30min of heating water bath at 60 DEG C, then stands and is cooled to room temperature, stratification simultaneously collects upper oil phase, obtains epoxide modified
Oleic acid；Count by weight, 45~50 parts of epoxide modified oleic acid, 35~40 parts of pentaerythrites, 5~8 parts of dimethylbenzene are weighed respectively
It is placed in three-necked flask, must be modified after 45~60min of heating water bath is mixed at 75~80 DEG C mixed with 0.5~1.0 part of stannous oxide
Close liquid, then in mass ratio 1:10, magnesia is added in modified mixed liquor, 10~15min of ultrasonic disperse under 200~300W
Afterwards, 45~60min of heating water bath then at 75~85 DEG C, after the completion for the treatment of heating water bath, then in 200~250 DEG C, 85~90kPa
Under the conditions of 45~60min of vacuum distillation, then stand be cooled to room temperature, filter to get filtrate, be prepared into modified Ji Shi tetrols oleic acid
Ester；Count by weight, 45~50 parts of modified Ji Shi tetrols oleates, 15~20 parts of antistatic additive SN, 10~15 are weighed respectively
Part emulsifying agent, 0.5~1.0 part of wetting agent, 0.2~0.3 part of obvolvent agent, 0.5~1.0 part of antioxidant, 0.3~0.5 part of infiltration
Agent, 0.6~0.8 part of polyoxyethylene polyoxypropylene pentaerythrite ether, 0.5~1.0 part of sodium benzoate stirring mixing, you can be prepared into
A kind of spinning oil of resistance to volatile-type.Described emulsifying agent is in mass ratio 1:1, by aliphatic acid polyethenoxy ether LAE-9 and emulsification
Agent NP-2 stirrings, which are mixed with, to be formed.Described wetting agent is any one in OP-4, OP-6 and OP-10.Described obvolvent
Agent is any one in obvolvent agent SJ-B and obvolvent agent LAE-9.Described antioxidant is antioxidant 1076, antioxidant
Any one in CA, antioxidant 164, antioxidant DNP.Described bleeding agent is penetrating agent JFC-E and bleeding agent OEP-
Any one in 70.
Example 1
Take after fresh grapefruit skin, vacuum freeze drying 6h, milled and cross 75 mesh sieves, obtain pomelo peel powder, in mass ratio 1:
8, pomelo peel powder is mixed with n-hexane, soaked at 45 DEG C after 25min, then the ultrasonic extraction 10min under 200W, stand cold
But to room temperature, filter to get filtrate, in mass ratio 1:5, filtrate is mixed with n-hexane, then is centrifuged under 2500r/min
10min, obtains shaddock ped oleic acid；By volume 1:5, the hydrogenperoxide steam generator of mass fraction 15% is added dropwise in shaddock ped oleic acid, controlled
Drop rate is 2mL/min, after being added dropwise to complete, then the heating water bath 25min at 55 DEG C, then stands and is cooled to room temperature, quiet
Put and be layered and collect upper oil phase, obtain epoxide modified oleic acid；Count by weight, 45 parts of epoxide modified oleic acid, 35 are weighed respectively
Part pentaerythrite, 5 parts of dimethylbenzene and 0.5 part of stannous oxide are placed in three-necked flask, after heating water bath 45min is mixed at 75 DEG C
Modified mixed liquor, then in mass ratio 1:10, magnesia is added in modified mixed liquor, under 200W after ultrasonic disperse 10min,
The heating water bath 45min at 75 DEG C again, after the completion for the treatment of heating water bath, then the vacuum distillation 45min under the conditions of 200 DEG C, 85kPa,
Then stand and be cooled to room temperature, filter to get filtrate, be prepared into modified Ji Shi tetrols oleate；Count, weigh respectively by weight
45 parts of modified Ji Shi tetrols oleates, 15 parts of antistatic additive SN, 10 parts of emulsifying agents, 0.5 part of wetting agent, 0.2 part of obvolvent agent, 0.5
Part antioxidant, 0.3 part of bleeding agent, 0.6 part of polyoxyethylene polyoxypropylene pentaerythrite ether, 0.5 part of sodium benzoate stirring mixing,
A kind of spinning oil of resistance to volatile-type can be prepared into.Described emulsifying agent is in mass ratio 1:1, by aliphatic acid polyethenoxy ether
LAE-9 and emulsifying agent NP-2 stirrings, which are mixed with, to be formed.Described wetting agent is OP-4.Described obvolvent agent is obvolvent agent SJ-
B.Described antioxidant is antioxidant 1076.Described bleeding agent is penetrating agent JFC-E.
Example 2
Take after fresh grapefruit skin, vacuum freeze drying 7h, milled and cross 78 mesh sieves, obtain pomelo peel powder, in mass ratio 1:
8, pomelo peel powder is mixed with n-hexane, soaked at 48 DEG C after 28min, then the ultrasonic extraction 13min under 250W, stand cold
But to room temperature, filter to get filtrate, in mass ratio 1:5, filtrate is mixed with n-hexane, then is centrifuged under 2700r/min
13min, obtains shaddock ped oleic acid；By volume 1:5, the hydrogenperoxide steam generator of mass fraction 15% is added dropwise in shaddock ped oleic acid, controlled
Drop rate is 2mL/min, after being added dropwise to complete, then the heating water bath 27min at 58 DEG C, then stands and is cooled to room temperature, quiet
Put and be layered and collect upper oil phase, obtain epoxide modified oleic acid；Count by weight, 48 parts of epoxide modified oleic acid, 38 are weighed respectively
Part pentaerythrite, 7 parts of dimethylbenzene and 0.8 part of stannous oxide are placed in three-necked flask, after heating water bath 52min is mixed at 78 DEG C
Modified mixed liquor, then in mass ratio 1:10, magnesia is added in modified mixed liquor, under 250W after ultrasonic disperse 13min,
The heating water bath 52min at 80 DEG C again, after the completion for the treatment of heating water bath, then the vacuum distillation 52min under the conditions of 230 DEG C, 88kPa,
Then stand and be cooled to room temperature, filter to get filtrate, be prepared into modified Ji Shi tetrols oleate；Count, weigh respectively by weight
48 parts of modified Ji Shi tetrols oleates, 18 parts of antistatic additive SN, 13 parts of emulsifying agents, 0.8 part of wetting agent, 0.2 part of obvolvent agent, 0.8
Part antioxidant, 0.4 part of bleeding agent, 0.7 part of polyoxyethylene polyoxypropylene pentaerythrite ether, 0.8 part of sodium benzoate stirring mixing,
A kind of spinning oil of resistance to volatile-type can be prepared into.Described emulsifying agent is in mass ratio 1:1, by aliphatic acid polyethenoxy ether
LAE-9 and emulsifying agent NP-2 stirrings, which are mixed with, to be formed.Described wetting agent is OP-6.Described obvolvent agent is obvolvent agent LAE-
9.Described antioxidant is antioxidant CA.Described bleeding agent is bleeding agent OEP-70.
Example 3
Take after fresh grapefruit skin, vacuum freeze drying 8h, milled and cross 80 mesh sieves, obtain pomelo peel powder, in mass ratio 1:
8, pomelo peel powder is mixed with n-hexane, soaked at 50 DEG C after 30min, then the ultrasonic extraction 15min under 300W, stand cold
But to room temperature, filter to get filtrate, in mass ratio 1:5, filtrate is mixed with n-hexane, then is centrifuged under 3000r/min
15min, obtains shaddock ped oleic acid；By volume 1:5, the hydrogenperoxide steam generator of mass fraction 15% is added dropwise in shaddock ped oleic acid, controlled
Drop rate is 2mL/min, after being added dropwise to complete, then the heating water bath 30min at 60 DEG C, then stands and is cooled to room temperature, quiet
Put and be layered and collect upper oil phase, obtain epoxide modified oleic acid；Count by weight, 50 parts of epoxide modified oleic acid, 40 are weighed respectively
Part pentaerythrite, 8 parts of dimethylbenzene and 1.0 parts of stannous oxides are placed in three-necked flask, after heating water bath 60min is mixed at 80 DEG C
Modified mixed liquor, then in mass ratio 1:10, magnesia is added in modified mixed liquor, under 300W after ultrasonic disperse 15min,
The heating water bath 60min at 85 DEG C again, after the completion for the treatment of heating water bath, then the vacuum distillation 60min under the conditions of 250 DEG C, 90kPa,
Then stand and be cooled to room temperature, filter to get filtrate, be prepared into modified Ji Shi tetrols oleate；Count, weigh respectively by weight
50 parts of modified Ji Shi tetrols oleates, 20 parts of antistatic additive SN, 15 parts of emulsifying agents, 1.0 parts of wetting agents, 0.3 part of obvolvent agent, 1.0
Antioxidant, 0.5 part of bleeding agent, 0.8 polyoxyethylene polyoxypropylene pentaerythrite ether, 1.0 parts of sodium benzoate stirring mixing, you can
It is prepared into a kind of spinning oil of resistance to volatile-type.Described emulsifying agent is in mass ratio 1:1, by aliphatic acid polyethenoxy ether LAE-9
It is mixed with and forms with emulsifying agent NP-2 stirrings.Described wetting agent is OP-10.Described obvolvent agent is obvolvent agent SJ-B.Institute
The antioxidant stated is antioxidant 164.Described bleeding agent is penetrating agent JFC-E.
Reference examples：The spinning oil of Jiangsu company production.
The spinning oil of the spinning oil of resistance to volatile-type obtained by above-described embodiment and reference examples is detected, specific detection is such as
Under：
1st, wettability：Determined using natural sedimentation；
2nd, volatile performance：Under the conditions of 150 DEG C, spinning oil is poured into glass dish, every 0.5h spinning oil of survey
Quality, calculates its residual mass percentage, judges the height of volatility；
3rd, fracture strength, elongation at break：By GB 9997-88《The survey of chemical fibre broken filament strength and extension at break
It is fixed》It is measured.
As a result as shown in Table 1.
Table one：
| Detection project | Example 1 | Example 2 | Example 3 | Reference examples |
| Wetting time/s | 35.21 | 31.03 | 28.56 | 42.11 |
| Surface tension/（mN/m） | 38.6 | 42.3 | 45.8 | 33.5 |
| Volatile performance | 2h, volatility is 2.16% | 2h, volatility is 1.75% | 2h, volatility is 1.32% | 2h, volatility is 2.95% |
| Fracture strength/（cN/dtex） | 3.86 | 4.53 | 5.22 | 3.22 |
| Elongation at break/% | 26.3 | 31.5 | 36.8 | 23.2 |
As seen from the above table, the spinning oil of resistance to volatile-type of the invention is not volatile, while having preferable wetability and heat resistance.
Claims (8)
1. a kind of spinning oil of resistance to volatile-type, it is characterised in that including following parts by weight material：
45~50 parts of modified smooth agents, 15~20 parts of antistatic additive SN, 10~15 parts of emulsifying agents, 0.5~1.0 part of wetting agent, 0.2
~0.3 part of obvolvent agent, 0.5~1.0 part of antioxidant, 0.3~0.5 part of bleeding agent, 0.6~0.8 part of polyoxyethylene polyoxypropylene
Pentaerythrite ether, 0.5~1.0 part of sodium benzoate；The described specific preparation process of modification smooth agent is：
（1）Take and mill and sieve after fresh grapefruit skin, vacuum freeze drying, obtain pomelo peel powder, in mass ratio 1:8, by shaddock
Skin powder is mixed with n-hexane, ultrasonic extraction after immersion, is filtered to get filtrate, and in mass ratio 1:5, filtrate is mixed with n-hexane,
Centrifuge to obtain shaddock ped oleic acid；
（2）By volume 1:5, hydrogenperoxide steam generator is added dropwise in shaddock ped oleic acid, after heating water bath stratification and collect on
Layer oil phase, obtains epoxide modified oleic acid；
（3）Count by weight, 45~50 parts of epoxide modified oleic acid, 35~40 parts of pentaerythrites, 5~8 parts of diformazans are weighed respectively
Benzene and 0.5~1.0 part of stannous oxide Hybrid Heating must be modified mixed liquor, then in mass ratio 1:10, magnesia is added to and is modified
In mixed liquor, heated after ultrasonic disperse, then vacuum distillation, standing cooling, filter to get filtrate, be prepared into modified smooth agent.
2. a kind of spinning oil of resistance to volatile-type according to claim 1, it is characterised in that：Described emulsifying agent is by quality
Than 1:1, aliphatic acid polyethenoxy ether LAE-9 and emulsifying agent NP-2 stirrings are mixed with and formed.
3. a kind of spinning oil of resistance to volatile-type according to claim 1, it is characterised in that：Described wetting agent be OP-4,
Any one in OP-6 and OP-10.
4. a kind of spinning oil of resistance to volatile-type according to claim 1, it is characterised in that：Described obvolvent agent is obvolvent agent
Any one in SJ-B and obvolvent agent LAE-9.
5. a kind of spinning oil of resistance to volatile-type according to claim 1, it is characterised in that：Described antioxidant is antioxygen
Any one in agent 1076, antioxidant CA, antioxidant 164, antioxidant DNP.
6. a kind of spinning oil of resistance to volatile-type according to claim 1, it is characterised in that：Described bleeding agent is bleeding agent
Any one in JFC-E and bleeding agent OEP-70.
7. a kind of spinning oil of resistance to volatile-type according to claim 1, it is characterised in that：Step（2）Described peroxidating
Hydrogen solution drop rate is 2mL/min.
8. a kind of spinning oil of resistance to volatile-type according to claim 1, it is characterised in that：Step（3）Described decompression is steamed
The condition of evaporating is that 200~250 DEG C of temperature, pressure are 85~90kPa.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108252098A (en) * | 2017-12-18 | 2018-07-06 | 江苏新瑞贝科技股份有限公司 | A kind of polyester fiber spinning oil and preparation method thereof |
| CN108560067A (en) * | 2018-05-03 | 2018-09-21 | 常熟涤纶有限公司 | A kind of preparation process of low melting point nylon fibre |
| CN108589300A (en) * | 2018-05-18 | 2018-09-28 | 薛向东 | A kind of emulsifying spinning oil and preparation method thereof |
| CN108611862A (en) * | 2018-05-04 | 2018-10-02 | 沈阳浩博实业有限公司 | A kind of continuous spinning viscose filament yarn antistatic high-performance oil |
| CN113308765A (en) * | 2021-05-31 | 2021-08-27 | 福建合利新材料科技有限公司 | Spinning oil for polyester staple fibers and preparation method thereof |
| CN119243376A (en) * | 2024-10-29 | 2025-01-03 | 南通恒润新材料科技有限公司 | Environmentally friendly high temperature resistant polyester polypropylene spinning oil and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1258775A (en) * | 1999-12-21 | 2000-07-05 | 浙江皇马化工集团有限公司 | Oiling agent for nylon common textile cord and manufacturing method thereof |
| CN1272568A (en) * | 1999-12-21 | 2000-11-08 | 浙江皇马化工集团有限公司 | Conventional polyester spinning oil and preparation method thereof |
| CN105239375A (en) * | 2015-09-16 | 2016-01-13 | 宋新祥 | Terylene spinning oil |
| CN105803766A (en) * | 2016-04-13 | 2016-07-27 | 北京服装学院 | Superfine filament spinning oil agent and preparation method |
-
2017
- 2017-06-28 CN CN201710509924.8A patent/CN107227612A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1258775A (en) * | 1999-12-21 | 2000-07-05 | 浙江皇马化工集团有限公司 | Oiling agent for nylon common textile cord and manufacturing method thereof |
| CN1272568A (en) * | 1999-12-21 | 2000-11-08 | 浙江皇马化工集团有限公司 | Conventional polyester spinning oil and preparation method thereof |
| CN105239375A (en) * | 2015-09-16 | 2016-01-13 | 宋新祥 | Terylene spinning oil |
| CN105803766A (en) * | 2016-04-13 | 2016-07-27 | 北京服装学院 | Superfine filament spinning oil agent and preparation method |
Non-Patent Citations (3)
| Title |
|---|
| 刘鹏雷等: "纺丝油剂中脂肪酸酯类平滑剂的抗氧化及热稳定性", 《纺织学报》 * |
| 周存等: "耐高温化纤油剂季戊四醇油酸酯的合成", 《合成纤维工业》 * |
| 张慧蓉等: "环氧油酸季戊四醇酯的合成及在PVC加工中的应用", 《塑料工业》 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108252098A (en) * | 2017-12-18 | 2018-07-06 | 江苏新瑞贝科技股份有限公司 | A kind of polyester fiber spinning oil and preparation method thereof |
| CN108560067A (en) * | 2018-05-03 | 2018-09-21 | 常熟涤纶有限公司 | A kind of preparation process of low melting point nylon fibre |
| WO2019210650A1 (en) * | 2018-05-03 | 2019-11-07 | 常熟涤纶有限公司 | Preparation technique for low-melting-point polyamide fiber |
| CN108611862A (en) * | 2018-05-04 | 2018-10-02 | 沈阳浩博实业有限公司 | A kind of continuous spinning viscose filament yarn antistatic high-performance oil |
| CN108589300A (en) * | 2018-05-18 | 2018-09-28 | 薛向东 | A kind of emulsifying spinning oil and preparation method thereof |
| CN113308765A (en) * | 2021-05-31 | 2021-08-27 | 福建合利新材料科技有限公司 | Spinning oil for polyester staple fibers and preparation method thereof |
| CN113308765B (en) * | 2021-05-31 | 2023-02-21 | 福建合利新材料科技有限公司 | Spinning oil for polyester staple fibers and preparation method thereof |
| CN119243376A (en) * | 2024-10-29 | 2025-01-03 | 南通恒润新材料科技有限公司 | Environmentally friendly high temperature resistant polyester polypropylene spinning oil and preparation method thereof |
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