CN107189325A - A kind of ABS laser edge bondings bar and preparation method thereof - Google Patents
A kind of ABS laser edge bondings bar and preparation method thereof Download PDFInfo
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- CN107189325A CN107189325A CN201710357195.9A CN201710357195A CN107189325A CN 107189325 A CN107189325 A CN 107189325A CN 201710357195 A CN201710357195 A CN 201710357195A CN 107189325 A CN107189325 A CN 107189325A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
- C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/304—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being heat-activatable, i.e. not tacky at temperatures inferior to 30°C
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2455/00—Presence of ABS
- C09J2455/006—Presence of ABS in the substrate
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- Chemical Kinetics & Catalysis (AREA)
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Abstract
The present invention relates to edge band technical field, specifically related to a kind of ABS laser edge bondings bar and preparation method thereof, the ABS laser edge bondings bar includes ABS substrate layer and is coated on the laser hot melt adhesive layer at the ABS substrate layer back side, and the ABS substrate layer includes the raw material of following parts by weight：75 100 parts of ABS resin, 10 30 parts of active nano-calcium carbonate, 2 10 parts of modified additive, 0.2 1.2 parts of processing aid, 0.3 1.2 parts of antioxidant, 0.5 1.5 parts of antistatic additive.The ABS laser edge bondings bar of the present invention is heated using laser, and PUR is melted, edge band combines together with plate well by moment, and finishing back edge is seamless；And it is Nian Jie with various sheet materials have a splendid adhesive effect, adhesion strength is high, and peel strength is big；Compared with traditional heating edge sealing, waited without heating, quick to bond, not influenced by ambient temperature, time-saving and efficiency, convenient operation.
Description
Technical field
The present invention relates to edge band technical field, and in particular to a kind of ABS laser edge bondings bar and preparation method thereof.
Background technology
Edge band is one of accessory for commonly using in furniture decoration, is used for carrying out sealing to the section of Furniture panel, so that
Protect sheet material to be adversely affected from Environmental Water, illumination etc., and the formaldehyde inside sheet material can be prevented to volatilize, moreover it is possible to play decoration
And the effect of beautification.
The edge band commonly used in home decoration typically divides log edge band and traditional polyvinyl chloride（PVC）Edge band, log
Edge band makes simple but costly, and its raw material is mainly derived from the raw wooden skin of trees；In recent years, various countries are gloomy in order to protect
Woods resource, limits the felling of forest so that the raw material sources of log edge band are restricted；Therefore, it is thought that being replaced with PVC
Raw wooden skin is used as the main material for making edge band；But PVC heat resistance is poor, the chlorine element in PVC has certain to environment
Harm, can not meet high-grade furniture to heat resistance, environmental protection, safety requirement.
Publication No. CN101798434A Chinese invention patent discloses a kind of ABS resin furniture edge banding, the present invention
Product is by 2000~2500 parts of ABS resin, 500~600 parts of CCR nano activated calcium carbonates, 25~300 parts of MBS resins, interior profit
80~120 parts of lubrication prescription, 6~8 parts of antioxidant, 8~11 parts of ultraviolet absorber, 4~6 parts of dispersant, 10~30 parts of compositions of toner.
Existing ABS resin household edge band need to heat wait using heating edge sealing, and adhesive speed is slow, and heats by ring
Border temperature influence is larger, and efficiency is low.
The content of the invention
In order to overcome shortcoming and defect present in prior art, it is an object of the invention to provide a kind of ABS laser envelope
Edge strip, the ABS laser edge bondings bar is heated using laser, and PUR is melted, is well fused to edge band with plate by moment
One, finishing back edge is seamless；Compared with traditional heating edge sealing, waited without heating, it is quick to bond, not by environment temperature shadow
Ring, time-saving and efficiency, convenient operation.
Another object of the present invention is to provide a kind of preparation method of ABS laser edge bondings bar, preparation method step letter
Single, convenient operation and control, steady quality, production efficiency is high, and production cost is low, can large-scale industrial production.
The purpose of the present invention is achieved through the following technical solutions：A kind of ABS laser edge bondings bar, the ABS laser edge bondings bar
Including ABS substrate layer and the laser hot melt adhesive layer for being coated on the ABS substrate layer back side, the ABS substrate layer includes following parts by weight
Raw material：
75-100 parts of ABS resin
10-30 parts of active nano-calcium carbonate
2-10 parts of modified additive
0.2-1.2 parts of processing aid
0.3-1.2 parts of antioxidant
0.5-1.5 parts of antistatic additive.
The present invention ABS laser edge bonding bars be using ABS resin as raw material, add processing aid, through batch mixing, granulation, extrusion,
Printing, the edge band being made is formed through precoating laser thermosol again.The ABS laser edge bonding bars of the present invention are nontoxic, tasteless, it is easy to plus
Work, product size are stable, lustrous surface is good；Simultaneously have impact resistance, heat resistance, lower temperature resistance, chemical proofing and
Excellent electrical properties.
The ABS laser edge bonding bars of the present invention are the laser beam heats using high-energy-density, temperature is increased rapidly, non-
Precoating thermosol glue-line is melted in the often short time, the purpose of edge sealing is reached；It is that the section of Furniture panel is protected, filled
Decorations, beautification effect, its major function be to sheet material section carry out sealing, during reaching from environment and use it is unfavorable because
Element（Predominantly moisture）Destruction to sheet material, and prevent the formaldehyde volatilization inside sheet material and avoid environmental pollution, while reaching makes
Furniture shows the effect of clear, the riotous with colour decoration of wood grain.
It is preferred that, the ABS resin be acrylonitrile unit content 15%-25%, butadiene unit content 25%-35%,
Acrylonitrile-butadiene-styrene copolymer of the styrene units content in 40%-60%.
The present invention ABS resin refer to acrylonitrile-butadiene-styrene copolymer, its be a kind of intensity height, good toughness,
Thermoplastics type's high polymer material easily processed into type.Replace PVC to be applied in household edge band using ABS resin, effectively carry
The temperature capacity and edge-neatening efffct of high household edge band, so that the service life of furniture is improved, meanwhile, ABS resin is free of
Chlorine element, its degraded will not produce harmful effect to environment, with safe and environment-friendly performance.
It is preferred that, the nm-class active calcium carbonate is particle diameter in 10-100nm and handled and poly- through silane coupler modified
The treated nm-class active calcium carbonate of propylene graft.
The nm-class active calcium carbonate is prepared by following steps：Nm-class active calcium carbonate is carried out using silane coupler
After surface modification treatment, by the propylene monomer graft polymerization to nano-calcium carbonate surface under the conditions of gamma Rays.First
Make organic molecule absorption on the surface of nm-class active calcium carbonate by coupling agent treatment, further radiation effects can be poly- third
Alkene monomer occurs polymerization and is grafted on the organic molecule of nano-calcium carbonate, while radiation effects can also make calcium carbonate surface
The hydroxyl structure that hydrolysis is produced produces free radical, and then triggers the polymerization of propylene monomer, improves the grafting rate of Paris white.
The particle diameter of filler is smaller, and the tensile strength and impact strength to packing material are more beneficial, and the present invention is by selecting
Nm-class active calcium carbonate is as filler and controls its particle diameter in 10-100nm, and its crystal structure and Electronic Structure there occurs
Change, generates quantum size effect, small-size effect, skin effect and macroscopic quantum effect that ordinary calcium carbonate does not have
Should, therefore with good toughened and reinforced effect, it, which is added, can improve bending strength and bending bullet in the edge band of the present invention
The stability of property modulus and heat distortion temperature and size；Filler is to play its effect and control with the good compatibility of resin
The key of addition, the present invention is using through silane coupler modified processing and polypropylene grafted treated nano active carbonic acid
Calcium, can improve the compatibility of nm-class active calcium carbonate and ABS resin, so as to improve the intensity of material.
It is preferred that, the modified additive is that methyl methacrylate units content exists in 30%-50%, butadiene unit content
The MBS terpolymer of 25%-35%, styrene units content in 25%-35%.
MBS terpolymer（MBS）For impact modified auxiliary agent, MBS resins it is resistance to
Time property is worst, but its low temperature toughening effect is optimal, and because structure is close with ABS, therefore, phase minimum to ABS Color influences
To transparent highest, and processing effect is not also poor；The present invention by using methyl methacrylate units content in 30%-
50%th, butadiene unit content 25%-35%, styrene units content 25%-35% methyl methacrylate-butadiene-benzene
Ethylene-dien terpolymer, realizes the high performance-price ratio of PVC edge bands.
It is preferred that, the processing aid is slipping agent, and the slipping agent is erucyl amide, oleamide, calcium stearate, hard
At least one of resin acid acid amides, oleamide, pentaerythritol tetrastearate and N, N'- ethylene bis stearamide.It is more excellent
Choosing, the slipping agent is with weight to compare 2-4 by erucyl amide, stearic amide and pentaerythritol tetrastearate:1.5-
2.5:The mixture of 1 composition.The present invention strictly controls its weight proportion by using above-mentioned three kinds of slipping agent compounding uses,
Mechanical resistant stirring capacity and fingerprinting stress, finished product good forming effect, any surface finish can be strengthened, moreover it is possible to strengthen the extensibility of finished product,
It is easy-to-draw not easily broken.
It is preferred that, the antioxidant is antioxidant 1010, antioxidant 1076, irgasfos 168, antioxidant 164, antioxygen
In agent CA, antioxidant DNP, anti-oxidant DLTP, antioxidant TNP, antioxidant TPP, antioxidant MB and antioxidant 264
It is at least one.The present invention is by using above-mentioned antioxidant, and its antioxidant effect is good.It is more highly preferred to, the antioxidant is by resisting
Oxygen agent 1010, antioxidant 1076 and irgasfos 168 compare 1-2 with weight:0.8-1.2:The mixture of 1 composition.The present invention is by adopting
With above-mentioned three kinds of antioxidant compounding uses, and its weight proportion is strictly controlled, can delay or suppress entering for material oxidation process
OK, so as to prevent the aging of material and extend its service life.
It is preferred that, the antistatic additive is stearic acid-base trimethyl ammonium chloride, hexadecyltrimethylammonium chloride, dodecane
Base trimethyl ammonium chloride, OTAC, stearoylketene dimethyl-penten ammonium chloride, trimethyl bromination
Ammonium, TTAB, cetyl trimethylammonium bromide, trihydroxyethyl methyl quaternary amine Methylsulfate and fat
At least one of alcohol polyoxyethylene ether phosphate.It is more highly preferred to, the antistatic additive is by cetyl trimethyl chlorination
Ammonium, cetyl trimethylammonium bromide and trihydroxyethyl methyl quaternary amine Methylsulfate are with weight ratio 1:0.5-1.5:1.6-2.4
The mixture of composition.The present invention strictly controls its weight proportion by using above-mentioned three kinds of antistatic additive compounding uses, has
Preferable electric action, thus electrostatic can be made to leak in time.
It is preferred that, the ABS substrate layer also includes 0.5-1.5 parts of toner, and the toner is ultramarine toner, phthalocyanine blue and titanium
At least one of white powder.The present invention is by using above-mentioned toner, and obtained ABS laser edge bondings bar color and luster is good.
Another object of the present invention is achieved through the following technical solutions：A kind of preparation method of ABS laser edge bondings bar, including
Following steps：
（1）Above-mentioned raw materials mixing is weighed by the parts by weight of constitutive material, is stirred；
（2）Raw material after stirring is granulated, then base material is made in extrusion；
（3）In the surface printing pattern of base material, pattern is finally crossed into UV coating protections, then swashed in one layer of the backside coating of base material
Photo-thermal melten gel, is made ABS laser edge bonding bars.
The beneficial effects of the present invention are：The ABS laser edge bondings bar of the present invention is heated using laser, and moment melts PUR
Melt, edge band combines together with plate well, finishing back edge is seamless；And bonding with various sheet materials have splendid
Adhesive effect, adhesion strength is high, and peel strength is big, and universal tensile tests peel strength up to more than 60PMa；With traditional heating
Edge sealing is compared, and is waited without heating, quick to bond, not influenced by ambient temperature, time-saving and efficiency, convenient operation.
The ABS laser edge bondings bar of the present invention is processed and scientific formula through special process, will not be gone out after the solidification of product edge sealing interior
Stress cracking phenomenon, low temperature resistant, high-temp resisting high-humidity resisting performance is splendid；There is high impact resistance simultaneously, pliability is good, comprehensive physical
Excellent performance.The ABS laser edge bonding bars of the present invention are nontoxic, tasteless, environmental protection, without heavy metal, without phthalate, meet
European Union REACH requirements.
The preparation method step of the present invention is simple, convenient operation and control, steady quality, and production efficiency is high, and production cost is low,
Can large-scale industrial production.
Embodiment
For the ease of the understanding of those skilled in the art, with reference to embodiment, the present invention is further illustrated, real
The content that the mode of applying is referred to not limitation of the invention.
Embodiment 1
A kind of ABS laser edge bondings bar, the ABS laser edge bondings bar includes ABS substrate layer and is coated on swashing for the ABS substrate layer back side
Photo-thermal melt layer, the ABS substrate layer includes the raw material of following parts by weight：
75 parts of ABS resin
10 parts of active nano-calcium carbonate
2 parts of modified additive
0.2 part of processing aid
0.3 part of antioxidant
0.5 part of antistatic additive.
The ABS resin is that acrylonitrile unit content exists in 15%, butadiene unit content in 25%, styrene units content
60% acrylonitrile-butadiene-styrene copolymer.
The nm-class active calcium carbonate is particle diameter in 10nm and through silane coupler modified processing and polypropylene grafted processing
The nm-class active calcium carbonate crossed.
The modified additive is for methyl methacrylate units content in 30%, butadiene unit content in 35%, styrene
MBS terpolymer of the unit content 35%.
The processing aid is slipping agent, and the slipping agent is erucyl amide or oleamide.
The antioxidant is antioxidant 1010 or antioxidant 1076.
The antistatic additive is stearic acid-base trimethyl ammonium chloride or hexadecyltrimethylammonium chloride.
Embodiment 2
The difference of the present embodiment and above-described embodiment 1 is：
The ABS substrate layer includes the raw material of following parts by weight：
80 parts of ABS resin
15 parts of active nano-calcium carbonate
4 parts of modified additive
0.5 part of processing aid
0.5 part of antioxidant
0.8 part of antistatic additive.
The ABS resin is that acrylonitrile unit content exists in 20%, butadiene unit content in 30%, styrene units content
50% acrylonitrile-butadiene-styrene copolymer.
The nm-class active calcium carbonate is particle diameter in 30nm and through silane coupler modified processing and polypropylene grafted processing
The nm-class active calcium carbonate crossed.
The modified additive is for methyl methacrylate units content in 40%, butadiene unit content in 30%, styrene
MBS terpolymer of the unit content 30%.
The processing aid is slipping agent, and the slipping agent is calcium stearate or stearic amide.
The antioxidant is irgasfos 168 or antioxidant 164.
The antistatic additive is DTAC or OTAC.
Embodiment 3
The difference of the present embodiment and above-described embodiment 1 is：
The ABS substrate layer includes the raw material of following parts by weight：
85 parts of ABS resin
20 parts of active nano-calcium carbonate
6 parts of modified additive
0.7 part of processing aid
0.8 part of antioxidant
1.0 parts of antistatic additive.
The ABS resin is that acrylonitrile unit content exists in 20%, butadiene unit content in 30%, styrene units content
50% acrylonitrile-butadiene-styrene copolymer.
The nm-class active calcium carbonate is particle diameter in 50nm and through silane coupler modified processing and polypropylene grafted processing
The nm-class active calcium carbonate crossed.
The modified additive is for methyl methacrylate units content in 40%, butadiene unit content in 30%, styrene
MBS terpolymer of the unit content 30%.
The processing aid is slipping agent, and the slipping agent is oleamide.
The antioxidant is antioxidant CA, antioxidant DNP or anti-oxidant DLTP.
The antistatic additive is stearoylketene dimethyl-penten ammonium chloride or DTAB.
Embodiment 4
The difference of the present embodiment and above-described embodiment 1 is：
The ABS substrate layer includes the raw material of following parts by weight：
90 parts of ABS resin
25 parts of active nano-calcium carbonate
8 parts of modified additive
1.0 parts of processing aid
1.0 parts of antioxidant
1.2 parts of antistatic additive.
The ABS resin is that acrylonitrile unit content exists in 20%, butadiene unit content in 30%, styrene units content
50% acrylonitrile-butadiene-styrene copolymer.
The nm-class active calcium carbonate is particle diameter in 80nm and through silane coupler modified processing and polypropylene grafted processing
The nm-class active calcium carbonate crossed.
The modified additive is for methyl methacrylate units content in 40%, butadiene unit content in 30%, styrene
MBS terpolymer of the unit content 30%.
The processing aid is slipping agent, and the slipping agent is pentaerythritol tetrastearate.
The antioxidant is antioxidant TNP or antioxidant TPP.
The antistatic additive is TTAB or cetyl trimethylammonium bromide.
Embodiment 5
The difference of the present embodiment and above-described embodiment 1 is：
The ABS substrate layer includes the raw material of following parts by weight：
100 parts of ABS resin
30 parts of active nano-calcium carbonate
10 parts of modified additive
1.2 parts of processing aid
1.2 parts of antioxidant
1.5 parts of antistatic additive.
The ABS resin is that acrylonitrile unit content exists in 25%, butadiene unit content in 35%, styrene units content
40% acrylonitrile-butadiene-styrene copolymer.
The nm-class active calcium carbonate is particle diameter in 100nm and through silane coupler modified processing and polypropylene grafted place
The nm-class active calcium carbonate managed.
The modified additive is for methyl methacrylate units content in 50%, butadiene unit content in 25%, styrene
MBS terpolymer of the unit content 25%.
The processing aid is slipping agent, and the slipping agent is N, N'- ethylene bis stearamides.
The antioxidant is antioxidant MB or antioxidant 264.
The antistatic additive is trihydroxyethyl methyl quaternary amine Methylsulfate or AEO phosphate.
Embodiment 6
The difference of the present embodiment and above-described embodiment 1 is：
The ABS substrate layer also includes 0.5 part of toner, and the toner is ultramarine toner.
The slipping agent is with weight ratio 2 by erucyl amide, stearic amide and pentaerythritol tetrastearate:1.5:1
The mixture of composition.
The antioxidant is with weight ratio 1 by antioxidant 1010, antioxidant 1076 and irgasfos 168:0.8:1 composition it is mixed
Compound.
The antistatic additive is by hexadecyltrimethylammonium chloride, cetyl trimethylammonium bromide and trihydroxyethyl first
Base quaternary amine Methylsulfate compares 1 with weight:0.5:The mixture of 1.6 compositions.
Embodiment 7
The difference of the present embodiment and above-described embodiment 2 is：
The ABS substrate layer also includes 0.8 part of toner, and the toner is phthalocyanine blue.
The slipping agent is with weight ratio 2.5 by erucyl amide, stearic amide and pentaerythritol tetrastearate:1.8:
The mixture of 1 composition.
The antioxidant is with weight ratio 1.2 by antioxidant 1010, antioxidant 1076 and irgasfos 168:0.9:1 composition
Mixture.
The antistatic additive is by hexadecyltrimethylammonium chloride, cetyl trimethylammonium bromide and trihydroxyethyl first
Base quaternary amine Methylsulfate compares 1 with weight:0.8:The mixture of 1.8 compositions.
Embodiment 8
The difference of the present embodiment and above-described embodiment 3 is：
The ABS substrate layer also includes 1 part of toner, and the toner is titanium dioxide.
The slipping agent is with weight ratio 3 by erucyl amide, stearic amide and pentaerythritol tetrastearate:2:1 group
Into mixture.
The antioxidant is with weight ratio 1.5 by antioxidant 1010, antioxidant 1076 and irgasfos 168:1:1 composition it is mixed
Compound.
The antistatic additive is by hexadecyltrimethylammonium chloride, cetyl trimethylammonium bromide and trihydroxyethyl first
Base quaternary amine Methylsulfate compares 1 with weight:1:The mixture of 2 compositions.
Embodiment 9
The difference of the present embodiment and above-described embodiment 4 is：
The ABS substrate layer also includes 1.2 parts of toner, and the toner is ultramarine toner.
The slipping agent is with weight ratio 3.5 by erucyl amide, stearic amide and pentaerythritol tetrastearate:2.2:
The mixture of 1 composition.
The antioxidant is with weight ratio 1.8 by antioxidant 1010, antioxidant 1076 and irgasfos 168:1.1:1 composition
Mixture.
The antistatic additive is by hexadecyltrimethylammonium chloride, cetyl trimethylammonium bromide and trihydroxyethyl first
Base quaternary amine Methylsulfate compares 1 with weight:1.2:The mixture of 2.2 compositions.
Embodiment 10
The difference of the present embodiment and above-described embodiment 5 is：
The ABS substrate layer also includes 1.5 parts of toner, and the toner is phthalocyanine blue.
The slipping agent is with weight ratio 4 by erucyl amide, stearic amide and pentaerythritol tetrastearate:2.5:1
The mixture of composition.
The antioxidant is with weight ratio 2 by antioxidant 1010, antioxidant 1076 and irgasfos 168:1.2:1 composition it is mixed
Compound.
The antistatic additive is by hexadecyltrimethylammonium chloride, cetyl trimethylammonium bromide and trihydroxyethyl first
Base quaternary amine Methylsulfate compares 1 with weight:1.5:The mixture of 2.4 compositions.
The technical parameter of ABS laser edge bondings bar produced by the present invention is as shown in the table：
The performance indications of ABS laser edge bondings bar produced by the present invention are as shown in the table：
The environmental protection index of ABS laser edge bondings bar produced by the present invention is as shown in the table：
The ABS laser edge bondings bar that can be seen that the present invention from above three table is processed and scientific formula through special process, product envelope
Internal stress cracking phenomena will not be gone out after the solidification of side, low temperature resistant, high-temp resisting high-humidity resisting performance is splendid；There is high impact resistance simultaneously,
Pliability is good, comprehensive physical excellent performance.The ABS laser edge bonding bars of the present invention are nontoxic, tasteless, environmental protection, without heavy metal, are free of
Phthalate, meets European Union REACH requirements.
The ABS laser edge bondings bar of the present invention is heated using laser, and moment melts PUR, well by edge band and plate
Part combines together, and finishing back edge is seamless；And Nian Jie with various sheet materials have splendid adhesive effect, adhesion strength
Height, peel strength is big, and universal tensile tests peel strength up to more than 60PMa；Compared with traditional heating edge sealing, without heating etc.
Treat, quick to bond, not influenced by ambient temperature, time-saving and efficiency, convenient operation.
Above-described embodiment is the present invention preferably implementation, and in addition, the present invention can be realized with other manner,
Any obvious replacement is within protection scope of the present invention on the premise of not departing from present inventive concept.
Claims (9)
1. a kind of ABS laser edge bondings bar, it is characterised in that：The ABS laser edge bondings bar includes ABS substrate layer and is coated on ABS
The laser hot melt adhesive layer at the substrate layer back side, the ABS substrate layer includes the raw material of following parts by weight：
75-100 parts of ABS resin
10-30 parts of active nano-calcium carbonate
2-10 parts of modified additive
0.2-1.2 parts of processing aid
0.3-1.2 parts of antioxidant
0.5-1.5 parts of antistatic additive.
2. a kind of ABS laser edge bondings bar according to claim 1, it is characterised in that：The ABS resin is acrylonitrile unit
Content 15%-25%, butadiene unit content 25%-35%, styrene units content 40%-60% acrylonitrile-butadiene-
Styrol copolymer.
3. a kind of ABS laser edge bondings bar according to claim 1, it is characterised in that：The nm-class active calcium carbonate is grain
Footpath is in 10-100nm and through silane coupler modified processing and polypropylene grafted treated nm-class active calcium carbonate.
4. a kind of ABS laser edge bondings bar according to claim 1, it is characterised in that：The modified additive is metering system
Sour methyl esters unit content 30%-50%, butadiene unit content 25%-35%, styrene units content 25%-35% methyl
Methylacrylate-butadiene-styrene copolymer.
5. a kind of ABS laser edge bondings bar according to claim 1, it is characterised in that：The processing aid is slipping agent, institute
State slipping agent for erucyl amide, oleamide, calcium stearate, stearic amide, oleamide, pentaerythritol tetrastearate and
At least one of N, N'- ethylene bis stearamide.
6. a kind of ABS laser edge bondings bar according to claim 1, it is characterised in that：The antioxidant is antioxidant
1010th, antioxidant 1076, irgasfos 168, antioxidant 164, antioxidant CA, antioxidant DNP, anti-oxidant DLTP, antioxidant
At least one of TNP, antioxidant TPP, antioxidant MB and antioxidant 264.
7. a kind of ABS laser edge bondings bar according to claim 1, it is characterised in that：The antistatic additive is stearic acid-base
Trimethyl ammonium chloride, hexadecyltrimethylammonium chloride, DTAC, OTAC,
Stearoylketene dimethyl-penten ammonium chloride, DTAB, TTAB, cetyl front three
At least one of base ammonium bromide, trihydroxyethyl methyl quaternary amine Methylsulfate and AEO phosphate.
8. a kind of ABS laser edge bondings bar according to claim 1, it is characterised in that：The ABS substrate layer also includes toner
0.5-1.5 parts, the toner is at least one of ultramarine toner, phthalocyanine blue and titanium dioxide.
9. a kind of preparation method of ABS laser edge bondings bar as described in claim any one of 1-8, it is characterised in that：Including such as
Lower step：
（1）Above-mentioned raw materials mixing is weighed by the parts by weight of constitutive material, is stirred；
（2）Raw material after stirring is granulated, then base material is made in extrusion；
（3）In the surface printing pattern of base material, pattern is finally crossed into UV coating protections, then swashed in one layer of the backside coating of base material
Photo-thermal melten gel, is made ABS laser edge bonding bars.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710357195.9A CN107189325A (en) | 2017-05-19 | 2017-05-19 | A kind of ABS laser edge bondings bar and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710357195.9A CN107189325A (en) | 2017-05-19 | 2017-05-19 | A kind of ABS laser edge bondings bar and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109401181A (en) * | 2018-11-29 | 2019-03-01 | 东莞欧德雅装饰材料有限公司 | Arc edge band ABS composite material and preparation method thereof and arc edge band therefrom |
| WO2020112050A3 (en) * | 2018-08-11 | 2020-07-30 | Tece Dekor Kağit Baski Ve Emprenye Sanayi̇ Ve Ti̇caret Anoni̇m Şi̇rketi̇ | Self-adhesive edgebanding for furnitures and a coextrusion method for the production of the same |
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| CN103183900A (en) * | 2013-04-10 | 2013-07-03 | 东莞欧德雅装饰材料有限公司 | ABS resin edge banding for furniture and manufacturing technology thereof |
| CN104015324A (en) * | 2014-05-27 | 2014-09-03 | 东莞市华立实业股份有限公司 | A preparation process of co-extruded edge banding |
| CN104207508A (en) * | 2014-09-01 | 2014-12-17 | 东莞市华立实业股份有限公司 | A paper-plastic edge banding with hot melt adhesive and its preparation process |
| CN204351391U (en) * | 2014-05-27 | 2015-05-27 | 东莞市华立实业股份有限公司 | A kind of coextrusion mold edge band and edge sealing sheet material |
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| CN103183900A (en) * | 2013-04-10 | 2013-07-03 | 东莞欧德雅装饰材料有限公司 | ABS resin edge banding for furniture and manufacturing technology thereof |
| CN104015324A (en) * | 2014-05-27 | 2014-09-03 | 东莞市华立实业股份有限公司 | A preparation process of co-extruded edge banding |
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| WO2020112050A3 (en) * | 2018-08-11 | 2020-07-30 | Tece Dekor Kağit Baski Ve Emprenye Sanayi̇ Ve Ti̇caret Anoni̇m Şi̇rketi̇ | Self-adhesive edgebanding for furnitures and a coextrusion method for the production of the same |
| CN109401181A (en) * | 2018-11-29 | 2019-03-01 | 东莞欧德雅装饰材料有限公司 | Arc edge band ABS composite material and preparation method thereof and arc edge band therefrom |
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Application publication date: 20170922 |