CN107087635A - A kind of oil field Compositional type bactericide and preparation method thereof - Google Patents
A kind of oil field Compositional type bactericide and preparation method thereof Download PDFInfo
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- CN107087635A CN107087635A CN201710364505.XA CN201710364505A CN107087635A CN 107087635 A CN107087635 A CN 107087635A CN 201710364505 A CN201710364505 A CN 201710364505A CN 107087635 A CN107087635 A CN 107087635A
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- compositional type
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
- A01N35/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing aliphatically bound aldehyde or keto groups, or thio analogues thereof; Derivatives thereof, e.g. acetals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
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- General Health & Medical Sciences (AREA)
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- Pest Control & Pesticides (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to field of oilfield chemistry, it is related to a kind of oil field Compositional type bactericide and preparation method thereof.Oil field of the present invention Compositional type bactericide, including following components：The wt % of 2,2 dibromo malonamide 10wt% 15；The wt % of 15 wt % of tetra methylol phosphonium bromide 20；The wt % of 10 wt % of glutaraldehyde 15；Surplus is water.Above-mentioned four kinds of materials are stirred and produce the Compositional type bactericide of the present invention.The oil field of the present invention is sterilized with Compositional type has stronger bactericidal properties to sulfate reducing bacteria, iron bacteria, saprophytic bacteria, and bactericidal effect substantially, has a wide range of application, raw material is easy to get, and low with cost, the advantages of usage amount is small.
Description
Technical field
The invention belongs to field of oilfield chemistry, and in particular to a kind of oil field Compositional type bactericide and preparation method thereof.
Background technology
In today's society, fossil fuel is still the main force of energy field, and crude oil in national product field still
Play the role of very important.There is much harmful bacterium, such as sulfate reducing bacteria in the production process of crude oil
(SRB), iron bacteria (TGB), saprophytic bacteria (FB) etc., wherein harmfulness maximum are sulfate reducing bacterias, sulfate reducing bacteria
Raised growth can cause the blocking and the reduction of oil reservoir void permeabilities of pipeline.In addition, the hydrogen sulfide that SRB is produced can cause drilling to set
The corrosion of standby, pipeline and equipment, these, which corrode, adds high cost to crude oil production.
With the development of two tertiary oil recovery technologies, most oil fields come into high water-cut stage, and oil field mining liquid is aqueous
The raising of rate, and suitable breeding farm condition in one's power is provided to bacterium, this undoubtedly adds extent of corrosion again.International oil price is low
Fan, in order to pull through their difficulties, CNOOC has also been proposed the measure of cost efficiency, therefore develops a kind of efficient and economic bactericide just
Seem particularly necessary.
The content of the invention
The purpose of the present invention is that there is provided a kind of oil field Compositional type bactericide and its preparation side in view of the shortcomings of the prior art
Method.The present invention has stronger bactericidal properties to sulfate reducing bacteria, iron bacteria, saprophytic bacteria, and bactericidal effect is obvious, application
Extensively, raw material is easy to get, and low with cost, the advantages of usage amount is small.
For achieving the above object, the present invention is adopted the following technical scheme that：
A kind of oil field Compositional type bactericide, the Compositional type bactericide includes following components, according to mass fraction meter：
The bromo- malonamide 10wt%-15wt% of 2,2- bis-；
Tetra methylol phosphonium bromide 15wt%-20wt%；
Glutaraldehyde 10wt%-15wt%；
Surplus is water.
The structural formula of the bromo- malonamides of 2,2- bis- is as follows：
It is preferred that, using pH value regulator, the pH value of Compositional type bactericide is adjusted to 7-9.
It is used as preferred technical scheme：
Present invention also offers a kind of preparation method of oil field with Compositional type bactericide, by the bromo- malonamides of 2,2- bis-, four
Methylol phosphonium bromide and glutaraldehyde, which are sequentially added in water, to stir, and then adjusts pH value to 7-9 with alkaline hydrated oxide.
It is preferred that, the alkaline hydrated oxide is sodium hydroxide or potassium hydroxide.
It is preferred that, mechanical agitation is used during stirring, churned mechanically speed is 2000-2500rpm.
Inventive principle:
The action principle of bactericide generally comprises following two：1st, the generation of energy in bacterial reproduction is suppressed.2nd, bacterium is disturbed
The synthesis of body living matter.The bromo- malonamides of 2,2- bis-, tetra methylol phosphonium bromide and glutaraldehyde in this Compositional type bactericide,
Every kind of material is respectively provided with certain bactericidal action, and triplicity has the effect mutually cooperateed with, so as to be imitated with more excellent sterilization
Really.
The reason for present invention regulation pH to 7-9 is that within this range, the damage to oil field equipment is minimum.When pH be less than 7 or
When person pH is more than 9, certain corrosion can be produced to oil field equipment, these corrosion products can be deposited in equipment, the extra large pipe of increase
Pressure, shortens the service life of equipment, and then increases the cost of production of hydrocarbons, has run counter to the original intention of extra large oily cost efficiency.
Beneficial effect：
The oil field of the present invention is sterilized with Compositional type has stronger bactericidal properties to sulfate reducing bacteria, iron bacteria, saprophytic bacteria,
Bactericidal effect substantially, has a wide range of application, raw material is easy to get, and low with cost, the advantages of usage amount is small.
Embodiment
The invention will be further elucidated with reference to specific embodiments.It should be understood that these embodiments are merely to illustrate this hair
Bright rather than limitation the scope of the present invention.In addition, it is to be understood that after the content of the invention lectured has been read, art technology
Personnel can make various changes or modifications to the present invention, and these equivalent form of values equally fall within the application appended claims and limited
Fixed scope.
Embodiment 1
A kind of efficient Compositional type bactericide BK-00 in oil field preparation and application.
The constituent of Compositional type bactericide is according to mass ratio：The mass fraction of 2,2- bis- bromo- malonamides is 10%,
The mass fraction of tetra methylol phosphonium bromide is 15%, and the mass fraction of glutaraldehyde is 10%, and the mass fraction of water is 65%.
Preparation method：Four kinds of materials are more uniform than mechanical agitation according to above-mentioned quality, then adjust pH with alkaline hydrated oxide
It is worth to 7, wherein, churned mechanically speed is 2000rpm, and pH value regulator selects potassium hydroxide.
Objective for implementation：South Sea oil produced water cabin water sample.
Test method:According to method specified in SY/T5329-2012 standards, 100mL water samples are taken, the present invention is added and prepares
Compositional type bactericide, diluted according to dilution-to-extinction method, and in insulating box (65 ± 5 DEG C) culture, sulfate reducing bacteria culture 2
Week, saprophytic bacteria and iron bacteria are cultivated 7 days, determine total number of bacteria, and calculating obtains sterilizing rate.It the results are shown in Table 1.
The various concentrations BK-00 bactericidal effects of table 1 are contrasted
Embodiment 2
A kind of efficient Compositional type bactericide BK-01 in oil field preparation and application.
The constituent of Compositional type bactericide is according to mass ratio：The mass fraction of 2,2- bis- bromo- malonamides is 12%,
The mass fraction of tetra methylol phosphonium bromide is 17%, and the mass fraction of glutaraldehyde is 13%, and the mass fraction of water is 58%.
Preparation method：Four kinds of materials are more uniform than mechanical agitation according to above-mentioned quality, then adjust pH with alkaline hydrated oxide
It is worth to 7.8, wherein, churned mechanically speed is 2400rpm, and pH value regulator selects sodium hydroxide.
Objective for implementation：South Sea oil produced water cabin water sample.
Test method:According to method specified in SY/T5329-2012 standards, 100mL water samples are taken, the present invention is added and prepares
Compositional type bactericide, diluted according to dilution-to-extinction method, and in insulating box (65 ± 5 DEG C) culture, sulfate reducing bacteria culture 2
Week, saprophytic bacteria and iron bacteria are cultivated 7 days, determine total number of bacteria, and calculating obtains sterilizing rate.It the results are shown in Table 2.
The various concentrations BK-01 of table 2 bactericidal effect
Embodiment 3
A kind of efficient Compositional type bactericide BK-02 in oil field preparation and application.
The constituent of Compositional type bactericide is according to mass ratio：The mass fraction of 2,2- bis- bromo- malonamides is 15%,
The mass fraction of tetra methylol phosphonium bromide is 20%, and the mass fraction of glutaraldehyde is 15%, and the mass fraction of water is 50%.
Preparation method：Four kinds of materials are more uniform than mechanical agitation according to above-mentioned quality, then adjust pH with alkaline hydrated oxide
It is worth to 8, wherein, churned mechanically speed is 2300rpm, and pH value regulator selects sodium hydroxide.
Objective for implementation：South Sea oil produced water cabin water sample.
Test method:According to method specified in SY/T5329-2012 standards, 100mL water samples are taken, the present invention is added and prepares
Compositional type bactericide, diluted according to dilution-to-extinction method, and in insulating box (65 ± 5 DEG C) culture, sulfate reducing bacteria culture 2
Week, saprophytic bacteria and iron bacteria are cultivated 7 days, determine total number of bacteria, and calculating obtains sterilizing rate.It the results are shown in Table 3.
The various concentrations bactericide BK-02 of table 3 bactericidal effect
Comparative example 1
A kind of efficient Compositional type bactericide BK-02 in oil field preparation and application, mainly BK-02 and other bactericide
Bactericidal effect contrast.
Objective for implementation：South Sea oil produced water cabin water sample.
Test method:According to method specified in SY/T5329-2012 standards, 100mL water samples are taken, the present invention is added and prepares
Compositional type bactericide and other bactericide, diluted according to dilution-to-extinction method, and in insulating box (65 ± 5 DEG C) culture, sulfuric acid
Salt reducing bacteria culture 2 weeks, saprophytic bacteria and iron bacteria are cultivated 7 days, determine total number of bacteria, and calculating obtains sterilizing rate
Wherein CW-01 to CW-03 is the medicament that certain Oil Field is used, and CW-01 main component is organosulfur compound
The aqueous solution of (isothiocyanate), CW-02 main component is the water-soluble of benzimidazole (2- substituted benzimidazoles) compound
Liquid, CW-03 main component is the aqueous solution of inorganic salts (calcirm-fluoride).It the results are shown in Table 4.Wherein, CW-01 is sterilized into CW-03
Main component account for the 50% of bactericide gross weight.
The bactericidal effect contrast of the different bactericide of table 4
It can be seen that from comparative example 1：In this 4 kinds of bactericide, efficient germicide BK-02 sterilizing rate highest is compared
Other three kinds of pharmacy effects are obvious.
Comparative example 2
The efficient Compositional type bactericide BK-02 in a kind of oil field preparation and application, in order to prove in Compositional type bactericide
The bactericidal effect of the synergy of each component, mainly BK-02 and its interior one-component bactericide is contrasted.
Objective for implementation：South Sea oil produced water cabin water sample.
Test method:According to method specified in SY/T5329-2012 standards, 100mL water samples are taken, the present invention is added and prepares
Compositional type bactericide and other bactericide, diluted according to dilution-to-extinction method, and in insulating box (65 ± 5 DEG C) culture, sulfuric acid
Salt reducing bacteria culture 2 weeks, saprophytic bacteria and iron bacteria are cultivated 7 days, determine total number of bacteria, and calculating obtains sterilizing rate.It the results are shown in Table 5.
Wherein：
K-01：The mass fraction of 2,2- bis- bromo- malonamides is 15%, and surplus is water, pH value to 8；
K-02：The mass fraction of tetra methylol phosphonium bromide is 20%, and surplus is water, pH value to 8；
K-03：The mass fraction of glutaraldehyde is 15%, and surplus is water, pH value to 8；
K-12：The mass fraction of 2,2- bis- bromo- malonamides is 15%, and the mass fraction of tetra methylol phosphonium bromide is
20%, surplus is water, pH value to 8；
K-13：The mass fraction of 2,2- bis- bromo- malonamides is 15%, and the mass fraction of glutaraldehyde is 15%, and surplus is
Water, pH value to 8；
K-23：The mass fraction of tetra methylol phosphonium bromide is 20%, and the mass fraction of glutaraldehyde is 15%, and surplus is water,
PH value is to 8；
The bactericidal effect contrast that table 5BK-02 bactericide is combined with its interior component
It can be seen that from comparative example 2：The bromo- malonamides of 2,2- bis- in this Compositional type bactericide, tetra methylol bromination
Phosphorus and glutaraldehyde, every kind of material are respectively provided with certain bactericidal action, but only triplicity has the effect mutually cooperateed with, from
And with more excellent bactericidal effect.
Claims (5)
1. a kind of oil field Compositional type bactericide, it is characterized in that, the Compositional type bactericide includes following components：
The bromo- wt%-15 wt % of malonamide 10 of 2,2- bis-；
The wt %-20 wt % of tetra methylol phosphonium bromide 15；
The wt %-15 wt % of glutaraldehyde 10；
Surplus is water.
2. oil field according to claim 1 Compositional type bactericide, it is characterised in that adjust the pH value of Compositional type bactericide
Whole is 7-9.
3. after claim 12 it is any as described in oil field Compositional type bactericide preparation method, it is characterised in that by 2,2-
Two bromo- malonamides, tetra methylol phosphonium bromide and glutaraldehyde are sequentially added in water and stirred, and are then adjusted with alkaline hydrated oxide
PH value is saved to 7-9.
4. the oil field as claimed in claim 3 preparation method of Compositional type bactericide, it is characterised in that the alkaline hydroxide
Thing is sodium hydroxide or potassium hydroxide.
5. the oil field according to claim 3 preparation method of Compositional type bactericide, it is characterised in that machine is used during stirring
Tool is stirred, and churned mechanically speed is 2000-2500rpm.
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| CN201710364505.XA CN107087635A (en) | 2017-05-22 | 2017-05-22 | A kind of oil field Compositional type bactericide and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108174868A (en) * | 2017-12-31 | 2018-06-19 | 仙桃市中楚化工有限责任公司 | A kind of strong fungicide |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102307722A (en) * | 2009-02-12 | 2012-01-04 | 罗地亚管理公司 | Methods for controlling depolymerization of polymer compositions |
| CN102548403A (en) * | 2009-09-28 | 2012-07-04 | 陶氏环球技术有限责任公司 | Compositions of dibromomalonamide and their use as biocides |
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2017
- 2017-05-22 CN CN201710364505.XA patent/CN107087635A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102307722A (en) * | 2009-02-12 | 2012-01-04 | 罗地亚管理公司 | Methods for controlling depolymerization of polymer compositions |
| CN102548403A (en) * | 2009-09-28 | 2012-07-04 | 陶氏环球技术有限责任公司 | Compositions of dibromomalonamide and their use as biocides |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108174868A (en) * | 2017-12-31 | 2018-06-19 | 仙桃市中楚化工有限责任公司 | A kind of strong fungicide |
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Application publication date: 20170825 |