CN106988111A - Carbon fiber blending fabric coating and preparation method thereof and coating method - Google Patents
Carbon fiber blending fabric coating and preparation method thereof and coating method Download PDFInfo
- Publication number
- CN106988111A CN106988111A CN201710265212.6A CN201710265212A CN106988111A CN 106988111 A CN106988111 A CN 106988111A CN 201710265212 A CN201710265212 A CN 201710265212A CN 106988111 A CN106988111 A CN 106988111A
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- CN
- China
- Prior art keywords
- carbon fiber
- fiber blending
- expanded perlite
- titanium dioxide
- blending fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 238000000576 coating method Methods 0.000 title claims abstract description 53
- 239000004744 fabric Substances 0.000 title claims abstract description 50
- 239000011248 coating agent Substances 0.000 title claims abstract description 41
- 229920000049 Carbon (fiber) Polymers 0.000 title claims abstract description 36
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 239000004917 carbon fiber Substances 0.000 title claims abstract description 35
- 238000002156 mixing Methods 0.000 title claims abstract description 34
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 239000010451 perlite Substances 0.000 claims abstract description 48
- 235000019362 perlite Nutrition 0.000 claims abstract description 48
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 40
- 239000000843 powder Substances 0.000 claims abstract description 40
- 239000008187 granular material Substances 0.000 claims abstract description 39
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000002270 dispersing agent Substances 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000013530 defoamer Substances 0.000 claims abstract description 20
- 235000011187 glycerol Nutrition 0.000 claims abstract description 20
- 239000000839 emulsion Substances 0.000 claims abstract description 19
- 239000000080 wetting agent Substances 0.000 claims abstract description 19
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- 230000003750 conditioning effect Effects 0.000 claims abstract description 13
- 239000008367 deionised water Substances 0.000 claims abstract description 9
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 9
- 238000002203 pretreatment Methods 0.000 claims abstract description 5
- 238000012856 packing Methods 0.000 claims abstract description 4
- 238000004804 winding Methods 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 31
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 claims description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- 238000009835 boiling Methods 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 3
- 238000005096 rolling process Methods 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims 2
- 239000000203 mixture Substances 0.000 claims 1
- 238000005406 washing Methods 0.000 abstract description 5
- 238000011031 large-scale manufacturing process Methods 0.000 abstract description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 52
- 230000015556 catabolic process Effects 0.000 description 8
- 238000006731 degradation reaction Methods 0.000 description 8
- 239000004753 textile Substances 0.000 description 7
- 238000010521 absorption reaction Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229910010413 TiO 2 Inorganic materials 0.000 description 4
- 238000002242 deionisation method Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 230000001699 photocatalysis Effects 0.000 description 4
- 238000011160 research Methods 0.000 description 4
- 229930040373 Paraformaldehyde Natural products 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229920002866 paraformaldehyde Polymers 0.000 description 3
- 238000007146 photocatalysis Methods 0.000 description 3
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 2
- 235000017491 Bambusa tulda Nutrition 0.000 description 2
- 241001330002 Bambuseae Species 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 2
- 239000011425 bamboo Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 206010064571 Gene mutation Diseases 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- HGWOWDFNMKCVLG-UHFFFAOYSA-N [O--].[O--].[Ti+4].[Ti+4] Chemical compound [O--].[O--].[Ti+4].[Ti+4] HGWOWDFNMKCVLG-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000000994 depressogenic effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 210000000867 larynx Anatomy 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000004792 oxidative damage Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000000505 pernicious effect Effects 0.000 description 1
- 238000007539 photo-oxidation reaction Methods 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000004224 protection Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 239000003053 toxin Substances 0.000 description 1
- 231100000765 toxin Toxicity 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/02—Processes in which the treating agent is releasably affixed or incorporated into a dispensing means
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/40—Fibres of carbon
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2201/00—Chemical constitution of the fibres, threads or yarns
- D06N2201/08—Inorganic fibres
- D06N2201/087—Carbon fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2205/00—Condition, form or state of the materials
- D06N2205/10—Particulate form, e.g. powder, granule
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/14—Properties of the materials having chemical properties
- D06N2209/142—Hydrophobic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/14—Properties of the materials having chemical properties
- D06N2209/143—Inert, i.e. inert to chemical degradation, corrosion resistant
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
A kind of carbon fiber blending fabric coating, it includes following components (per 100ml)：5~15ml of glycerine, 0.5~2ml of wetting agent, 2.5~4ml of defoamer, 3~4ml of dispersant, 3~5ml of coalescents, 30~40g of expanded perlite granule, 40~50g of nano titanium dioxide powder, 70~95g of emulsion, remaining is deionized water；And PH is more than 6.5 and is less than 8.5, is adjusted using PH conditioning agents；The granularity of the expanded perlite granule is at least 300 mesh, and nano titanium dioxide powder is 10~50 nanometers.The preparation method of carbon fiber blending fabric coating, it is comprised the steps of：1) expanded perlite granule is made；2) component expanded perlite granule and nano titanium dioxide powder are pressed；3) component surplus stock is then pressed；4) PH is adjusted；5) dispense and pack.The coating method of carbon fiber blending fabric coating, it is comprised the steps of：1) fabric pre-treatment；2) coatings；3) pack：Winding, packing.Compared with prior art, the characteristics of present invention has large-scale production, product fastness to washing preferably and produces relatively easy.
Description
Technical field
The invention belongs to multifunctional textile lining field, and in particular to a kind of carbon fiber blending fabric coating and its preparation
Method and coating method.
Background technology
Formaldehyde (formaldehyde, HCHO) is commonly called as formaldehyde, is waved in recent years as a kind of most commonly seen in room air
Organic matter is sent out, is also a key factor of indoor pollution.Formaldehyde is a kind of primary toxin, formaldehyde in air can to eye, nose,
Larynx, skin etc. produce obvious stimulation, can induce the oxidative damage of each histoorgan, induced tumor, gene mutation etc.
Various diseases.Therefore Long Term Contact can make one One's spirits are drooping depressed failure of memory, how effectively remove in room air
Formaldehyde turns into the focus of current research.Metal oxide semiconductor material is frequently utilized for being harmful to because susceptibility high price is cheap
Gas-monitoring field, wherein TiO2 are because safety non-toxic, performance are stable, the low many merits of cost and receive much concern.Yang etc.
It was found that TiO2 under uv illumination in room temperature environment can effectively degradation of formaldehyde molecule so as to proving that TiO2 base optic catalytic materials exist
The feasibility of this kind of pernicious gas technically and application prospect economically are handled at room temperature.Li etc. has found what is be combined with Y2O3
TiO2 as the sensor that is made of detection material have the higher susceptibility of good stability and the faster speed of response because
And it is adapted to continue to monitor the formaldehyde pollution situation in air.Chen etc. is thin using the porous TiO2 and ZnO of UV-activated
Film sensors detect formaldehyde gas.Very promising TiO2 nanotubes also can degradation of formaldehyde gas at room temperature in addition.
These fruitful researchs show there is important application using the formaldehyde gas in TiO2 base catalyst degradation indoor environments
Prospect.
Nano material is increasingly paid close attention in exploitation multifunctional textile product field by people, wherein having certain representational
It is the application of nano TiO 2.The Teng Dao of Tokyo Univ Japan in 1967 has found TiO2 single crystals electrodes by light in an experiment
Photooxidation and reduction reaction can be produced after irradiation and hydrogen and oxygen is split water into.This excellent light that nano TiO 2 has is urged
Change various pollutants of the performance not only in decomposable asymmetric choice net water and air, the particularly formaldehyde in room air, it may also be used for sterilization disappears
Poison, absorbs ultraviolet etc..Having turned into the fields such as biology, medical science, chemical industry, material has the catalysis material of applications well prospect
One of.
Research at present both at home and abroad to formaldehyde degradation by photocatalytic oxidation process household textiles is also less.South China Science ＆ Engineering University king happiness China etc.
People has carried out absorption and the research of degradation property to a variety of coating papers using nano TiO 2 modification bamboo charcoal as pigment.Coating paper can have
Effect ground absorption degradation formaldehyde, when modification bamboo charcoal consumption (accounting for pigment) is 30%, in 0.8mgm-3 formaldehyde initial mass concentration
Under, ultraviolet lighting 3h, the absorption degradation rate of PARA FORMALDEHYDE PRILLS(91,95) is up to 93.75%.The nano TiO 2 of preparation is arranged and arrived by history member member et al.
Preferably finishing technique is bath raio 1 on fabric：10, crosslinking agent 40g/L, photochemical catalyst 2g/L, fabric after arranging on this condition
Ultraviolet protection index UPF values exceeded 15 reached Australia sun-proof apparel standards, fabric is in ultraviolet light after arrangement
The photocatalysis Decomposition efficiency of PARA FORMALDEHYDE PRILLS(91,95) can reach that the strength of fabric and whiteness become after more than 90, arrangement in 200min according under the conditions of
Change little.But because the catalytic degradation performance of the formaldehyde adsorption limited efficacy of textile, therefore PARA FORMALDEHYDE PRILLS(91,95) also have received textile
The limitation of absorption property, and the fastness to washing of household textiles is not good, also limit photocatalysis adsorption-decomposition function formaldehyde textile
Using.Therefore there is presently no the coating and method that can mass produce photocatalysis adsorption-decomposition function formaldehyde weaving face fabric.
The content of the invention
It is an object of the invention to provide a kind of large-scale production, product fastness to washing is preferable and produces relatively easy carbon
Fabric lining coating.
Technical scheme：
The present invention is to provide a kind of carbon fiber blending fabric coating, it includes following components (per 100ml)：Glycerine 5~
15ml, 0.5~2ml of wetting agent, 2.5~4ml of defoamer, 3~4ml of dispersant, 3~5ml of coalescents, expanded perlite granule
30~40g, 40~50g of nano titanium dioxide powder, 70~95g of emulsion, remaining is deionized water；And PH is less than more than 6.5
8.5, adjusted using PH conditioning agents；The granularity of the expanded perlite granule is at least 300 mesh, and nano titanium dioxide powder is
10~50 nanometers.
5~the 10ml of glycerine, 0.5~2ml of wetting agent, 3~4ml of defoamer, 3~4ml of dispersant, coalescents 3
~4ml, 30~40g of expanded perlite granule, 45~50g of nano titanium dioxide powder, 75~90g of emulsion, remaining is deionization
Water.
The granularity of the expanded perlite granule is at least 300 mesh, and nano titanium dioxide powder is 10~30 nanometers.
The PH is 7.5.
The coalescents are Texanol.
Another object of the present invention is to provide the preparation method of the carbon fiber blending fabric coating described in claim 1, its feature
It is：It is comprised the steps of：
1) perlite is crushed, is ground to granularity and is at least 300 mesh, and frying is into expanded perlite granule；
2) component (per 100ml) is then pressed by 40~50g of 30~40g of expanded perlite granule and nano titanium dioxide powder
It is put into mixer, 1.5~2ml of dispersant is added after 2~5min of stirring, continues to stir 10~20min；
3) 5~15ml of glycerine, 0.5~2ml of wetting agent, 2.5~4ml of defoamer then are added by component (per 100ml),
Remaining dispersant, 3~5ml of coalescents, 70~95g of emulsion and ionized water, continue to stir 5~10min；
4) it is adjusted using PH conditioning agents so that PH is more than 6.5 and is less than 8.5；
5) dispense and pack.
5~the 10ml of glycerine, 0.5~2ml of wetting agent, 3~4ml of defoamer, 3~4ml of dispersant, coalescents 3
~4ml, 30~40g of expanded perlite granule, 45~50g of nano titanium dioxide powder, 75~90g of emulsion, remaining is deionization
Water.
The granularity of the expanded perlite granule is at least 300 mesh, and nano titanium dioxide powder is 10~30 nanometers.
The PH is 7.5；The coalescents are Texanol.
Another object of the present invention is to provide the coating method of the carbon fiber blending fabric coating described in Claims 1 to 5, and it is special
Levy and be：It is comprised the steps of：
1) fabric pre-treatment：By carbon fiber blending fabric first by the acetone soln tank of boiling, it is stirred continuously in tank, water
The width of groove is 2m, and temperature control is at 72 ± 1 DEG C；After air knife, enter back into 9~10%NaOH solution tanks, tank not
Disconnected stirring, the width of tank is also 2m, then spends deionized water spray cleaning, then drying, rolling speed be 1m/10~
20min；
2) coatings：By step 1) carbon fiber blending fabric is coated with carbon described in Claims 1 to 5 on coating machine after processing
Fabric lining coating；
3) pack：Winding, packing.
After the present invention is using above-mentioned coating and preparation and coating method, beneficial effects of the present invention are as follows：
The carrier of absorption nano titanium dioxide powder, and above-mentioned pH value and nano-silica are used as using expanded perlite granule
When changing the granularity of titanium powder, catalyst surface is negatively charged, and absorption of the reactant on surface is more effective so that nanometer titanium dioxide
Titanium powder is more abundant with air contact, can not only improve the light-catalysed efficiency of nano titanium dioxide powder, and purification efficiency is also
It is higher, while being also easier to be coated on carbon fiber blending fabric, and then greatly improve fastness to washing；And preparation process can be effective
Ground prevents nano titanium dioxide powder from situation about reuniting occur, so as to ensure the using effect of nano titanium dioxide powder；Furthermore
Due to have passed through pre-treatment so that the combination of coating and fabric is even closer, so as to greatly improve the fastness to washing height of fabric,
Fabric after preparation have environmental protection, corrosion resistance it is good, with functional characteristics such as water repellencies.
Embodiment
Chemicals used below except glycerine for chemistry it is pure in addition to remaining be technical pure grade,
The present invention is to provide a kind of carbon fiber blending fabric coating, it includes following components (per 100ml)：Glycerine 5~
15ml, 0.5~2ml of wetting agent, 2.5~4ml of defoamer, 3~4ml of dispersant, 3~5ml of coalescents, expanded perlite granule
30~40g, 40~50g of nano titanium dioxide powder, 70~95g of emulsion, remaining is deionized water；And PH is less than more than 6.5
8.5, adjusted using PH conditioning agents；The granularity of the expanded perlite granule is at least 300 mesh, nano titanium dioxide powder
Granularity is 10~50 nanometers.Defoamer is the model THIX-318 that Yantai Thinking Finechem Technology Co., Ltd. produces；Wetting
Agent, defoamer, PH conditioning agents and dispersant are the chemical Science and Technology Ltd.'s productions of Shandong Sheng Yuan；Glycerine is Weifang stars at dawn
The 98% of work Science and Technology Ltd. production；Expanded perlite granule Puyang are bright up to the production of development in science and technology Co., Ltd；Nanometer two
Titanium dioxide powder is purchased from Dongguan City titanic chemical industry Import and Export Co., Ltd.；Emulsion is Guangzhou Wei Pu chemical analysis Technology Co., Ltd.
The model wp5235 of production water-proof emulsion.
5~the 10ml of glycerine, 0.5~2ml of wetting agent, 3~4ml of defoamer, 3~4ml of dispersant, coalescents 3
~4ml, 30~40g of expanded perlite granule, 45~50g of nano titanium dioxide powder, 75~90g of emulsion, remaining is deionization
Water.
The granularity of the expanded perlite granule is at least 300 mesh, and nano titanium dioxide powder is 10~30 nanometers.
The PH is 7.5.
The coalescents are Texanol, are the Texanol of Eastman Chemical's production.
The preparation method of carbon fiber blending fabric coating described in claim 1, it is comprised the steps of：
1) perlite is crushed, is ground to granularity and is at least 300 mesh, and frying is into expanded perlite granule；
2) component (per 100ml) is then pressed by 40~50g of 30~40g of expanded perlite granule and nano titanium dioxide powder
It is put into mixer, 1.5~2ml of dispersant is added after 2~5min of stirring, continues to stir 10~20min；
3) 5~15ml of glycerine, 0.5~2ml of wetting agent, 2.5~4ml of defoamer then are added by component (per 100ml),
Remaining dispersant, 3~5ml of coalescents, 70~95g of emulsion and ionized water, continue to stir 5~10min；
4) it is adjusted using PH conditioning agents so that PH is more than 6.5 and is less than 8.5；
5) dispense and pack.
5~the 10ml of glycerine, 0.5~2ml of wetting agent, 3~4ml of defoamer, 3~4ml of dispersant, coalescents 3
~4ml, 30~40g of expanded perlite granule, 45~50g of nano titanium dioxide powder, 75~90g of emulsion, remaining is deionization
Water.
The granularity of the expanded perlite granule is at least 300 mesh, and nano titanium dioxide powder is 10~30 nanometers.
The PH is 7.5；The coalescents are Texanol.
The coating method of carbon fiber blending fabric coating described in Claims 1 to 5, it is comprised the steps of：
1) fabric pre-treatment：By carbon fiber blending fabric first by the acetone soln tank of boiling, it is stirred continuously in tank, water
The width of groove is 2m, and temperature control is at 72 ± 1 DEG C；After air knife, enter back into 9~10%NaOH solution tanks, tank not
Disconnected stirring, the width of tank is also 2m, then spends deionized water spray cleaning, then drying, rolling speed be 1m/10~
20min；
2) coatings：By step 1) carbon fiber blending fabric is coated with carbon described in Claims 1 to 5 on coating machine after processing
Fabric lining coating；
3) pack：Winding, packing.
Embodiment one
The preparation method of carbon fiber blending fabric coating, it is comprised the steps of：
1) perlite is crushed, is ground to granularity for 300 mesh, and frying is into expanded perlite granule；
2) expanded perlite granule 30g and nano titanium dioxide powder 40g are then put into stirring by component (per 100ml)
In machine, dispersant 1.5ml is added after stirring 2min, continues to stir 10min；Nano titanium dioxide powder is 10~50 nanometers；
3) then glycerine 5ml is added by component (per 100ml), wetting agent 0.5ml, defoamer 2.5ml are remaining scattered
Agent 1.5ml, coalescents 3ml, emulsion 70g and ionized water, continue to stir 5min；
4) it is adjusted using PH conditioning agents so that PH is more than 6.5 and is less than 7.0；
5) dispense and pack.
Embodiment two
The preparation method of carbon fiber blending fabric coating, it is comprised the steps of：
1) perlite is crushed, is ground to granularity for 500 mesh, and frying is into expanded perlite granule；
2) expanded perlite granule 40g and nano titanium dioxide powder 50g are then put into stirring by component (per 100ml)
In machine, dispersant 2ml is added after stirring 5min, continues to stir 20min；Nano titanium dioxide powder is 10~50 nanometers；
3) glycerine 15ml, wetting agent 2ml, defoamer 4ml, remaining dispersant then are added by component (per 100ml)
2ml, coalescents 5ml, 95g and ionized water, continue to stir 10min；
4) it is adjusted using PH conditioning agents so that PH is more than or equal to 7.0 and is less than 7.5；
5) dispense and pack.
Embodiment three
The preparation method of carbon fiber blending fabric coating, it is comprised the steps of：
1) perlite is crushed, is ground to granularity for 400 mesh, and frying is into expanded perlite granule；
2) expanded perlite granule 35g and nano titanium dioxide powder 45g are then put into stirring by component (per 100ml)
In machine, dispersant 1.7ml is added after stirring 3min, continues to stir 15min；Nano titanium dioxide powder is 10~50 nanometers；
3) glycerine 10ml, wetting agent 4ml, defoamer 3ml, remaining dispersant then are added by component (per 100ml)
1.7ml, coalescents 4ml, emulsion 80g and ionized water, continue to stir 8min；
4) it is adjusted using PH conditioning agents so that PH is more than or equal to 7.5 and is less than 8.5；
5) dispense and pack.
Example IV
The preparation method of carbon fiber blending fabric coating, it is comprised the steps of：
1) perlite is crushed, is ground to granularity for 300 mesh, and frying is into expanded perlite granule；
2) expanded perlite granule 35g and nano titanium dioxide powder 45g are then put into stirring by component (per 100ml)
In machine, dispersant 1.7ml is added after stirring 2.5min, continues to stir 16min；Nano titanium dioxide powder is 10~50 nanometers；
3) glycerine 10ml, wetting agent 1ml, defoamer 3ml, remaining dispersant then are added by component (per 100ml)
1.8ml, coalescents 4ml, emulsion 75g and ionized water, continue to stir 7min；
4) it is adjusted using PH conditioning agents so that PH is more than or equal to 7.5 and is less than 8.5；
5) dispense and pack.
Embodiment five
The preparation method of carbon fiber blending fabric coating, it is comprised the steps of：
1) perlite is crushed, is ground to granularity for 400 mesh, and frying is into expanded perlite granule；
2) expanded perlite granule 37g and nano titanium dioxide powder 48g are then put into stirring by component (per 100ml)
In machine, dispersant 2ml is added after stirring 5min, continues to stir 20min；Nano titanium dioxide powder is 10~50 nanometers；
3) 5~15ml of glycerine, 0.5~2ml of wetting agent, 2.5~4ml of defoamer then are added by component (per 100ml),
Remaining dispersant 1.5ml, coalescents ml, emulsion 90g and ionized water, continue to stir 9min；
4) it is adjusted using PH conditioning agents so that PH is more than or equal to 7.5 and is less than 8.5；
5) dispense and pack.
Hung with six onesize and concentration of formaldehyde closed containers and scribble common coating and above-described embodiment coating
Cloth, places 6 hours at (morning in afternoon) at 9 points at 15 points under sunshine condition, as a result such as following table：
Claims (10)
1. a kind of carbon fiber blending fabric coating, it is characterised in that：It includes following components (per 100ml)：5~15ml of glycerine,
0.5~2ml of wetting agent, 2.5~4ml of defoamer, 3~4ml of dispersant, 3~5ml of coalescents, expanded perlite granule 30~
40g, 40~50g of nano titanium dioxide powder, 70~95g of emulsion, remaining is deionized water；And PH is more than 6.5 and is less than 8.5, makes
Adjusted with PH conditioning agents；The granularity of the expanded perlite granule is at least 300 mesh, and nano titanium dioxide powder is 10~50
Nanometer.
2. carbon fiber blending fabric coating according to claim 1, it is characterised in that：5~the 10ml of glycerine, wetting agent
0.5~2ml, 3~4ml of defoamer, 3~4ml of dispersant, 3~4ml of coalescents, 30~40g of expanded perlite granule, nanometer
45~50g of titania powder, 75~90g of emulsion, remaining is deionized water.
3. carbon fiber blending fabric coating according to claim 1, it is characterised in that：The particle of the expanded perlite granule
It is at least 300 mesh to spend, and nano titanium dioxide powder is 10~30 nanometers.
4. carbon fiber blending fabric coating according to claim 1, it is characterised in that：The PH is 7.5.
5. carbon fiber blending fabric coating according to claim 2, it is characterised in that：The coalescents are Texanol.
6. the preparation method of carbon fiber blending fabric coating described in claim 1, it is characterised in that：It is comprised the steps of：
1) perlite is crushed, is ground to granularity and is at least 300 mesh, and frying is into expanded perlite granule；
2) then 30~40g of expanded perlite granule and 40~50g of nano titanium dioxide powder are put into by component (per 100ml)
In mixer, 1.5~2ml of dispersant is added after 2~5min of stirring, continues to stir 10~20min；
3) 5~15ml of glycerine, 0.5~2ml of wetting agent, 2.5~4ml of defoamer then are added by component (per 100ml), it is remaining
Dispersant, 3~5ml of coalescents, 70~95g of emulsion and ionized water continue to stir 5~10min；
4) it is adjusted using PH conditioning agents so that PH is more than 6.5 and is less than 8.5；
5) dispense and pack.
7. the preparation method of carbon fiber blending fabric coating according to claim 6, it is characterised in that：The glycerine 5~
10ml, 0.5~2ml of wetting agent, 3~4ml of defoamer, 3~4ml of dispersant, 3~4ml of coalescents, expanded perlite granule 30
~40g, 45~50g of nano titanium dioxide powder, 75~90g of emulsion, remaining is deionized water.
8. the preparation method of carbon fiber blending fabric coating according to claim 6, it is characterised in that：The expanded perlite
The granularity of particle is at least 300 mesh, and nano titanium dioxide powder is 10~30 nanometers.
9. the preparation method of carbon fiber blending fabric coating according to claim 6, it is characterised in that：The PH is 7.5；Institute
Coalescents are stated for Texanol.
10. the coating method of the carbon fiber blending fabric coating described in Claims 1 to 5, it is characterised in that：It includes following step
Suddenly：
1) fabric pre-treatment：By carbon fiber blending fabric first by the acetone soln tank of boiling, it is stirred continuously in tank, tank
Width is 2m, and temperature control is at 72 ± 1 DEG C；After air knife, enter back into and constantly stirred in 9~10%NaOH solution tanks, tank
Mix, the width of tank is also 2m, then spends deionized water spray cleaning, then drying, and rolling speed is 1m/10~20min；
2) coatings：By step 1) carbon fiber blending fabric is coated with carbon fiber described in Claims 1 to 5 on coating machine after processing
Fabric coating；
3) pack：Winding, packing.
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