CN106987187A - A kind of cement paint and preparation method thereof - Google Patents
A kind of cement paint and preparation method thereof Download PDFInfo
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- CN106987187A CN106987187A CN201710159559.2A CN201710159559A CN106987187A CN 106987187 A CN106987187 A CN 106987187A CN 201710159559 A CN201710159559 A CN 201710159559A CN 106987187 A CN106987187 A CN 106987187A
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- parts
- cement
- sodium
- cement paint
- rosin
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- 239000004568 cement Substances 0.000 title claims abstract description 94
- 239000003973 paint Substances 0.000 title claims abstract description 71
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000011734 sodium Substances 0.000 claims abstract description 45
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 45
- -1 sodium alkyl benzene Chemical class 0.000 claims abstract description 39
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 24
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 24
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 24
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 24
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229920001353 Dextrin Polymers 0.000 claims abstract description 22
- 239000004375 Dextrin Substances 0.000 claims abstract description 22
- QBLDFAIABQKINO-UHFFFAOYSA-N barium borate Chemical compound [Ba+2].[O-]B=O.[O-]B=O QBLDFAIABQKINO-UHFFFAOYSA-N 0.000 claims abstract description 22
- 235000019425 dextrin Nutrition 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims abstract description 21
- 229940077388 benzenesulfonate Drugs 0.000 claims abstract description 21
- HCJLVWUMMKIQIM-UHFFFAOYSA-M sodium;2,3,4,5,6-pentachlorophenolate Chemical compound [Na+].[O-]C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl HCJLVWUMMKIQIM-UHFFFAOYSA-M 0.000 claims abstract description 21
- 239000000344 soap Substances 0.000 claims abstract description 20
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000006185 dispersion Substances 0.000 claims abstract description 17
- 239000008103 glucose Substances 0.000 claims abstract description 16
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 16
- 239000002994 raw material Substances 0.000 claims abstract description 12
- 238000001514 detection method Methods 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 6
- OPTDDWCXQQYKGU-UHFFFAOYSA-N diphenyldichloromethane Chemical class C=1C=CC=CC=1C(Cl)(Cl)C1=CC=CC=C1 OPTDDWCXQQYKGU-UHFFFAOYSA-N 0.000 claims abstract 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 34
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 7
- 238000000227 grinding Methods 0.000 claims description 5
- 238000003860 storage Methods 0.000 claims description 5
- 238000007873 sieving Methods 0.000 claims description 3
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- VBCGWXRNJSINCA-UHFFFAOYSA-N (1-chloro-1-phenylethyl)benzene Chemical compound C=1C=CC=CC=1C(Cl)(C)C1=CC=CC=C1 VBCGWXRNJSINCA-UHFFFAOYSA-N 0.000 claims 1
- 229920002125 Sokalan® Polymers 0.000 claims 1
- 239000000839 emulsion Substances 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 239000004584 polyacrylic acid Substances 0.000 claims 1
- 238000007710 freezing Methods 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000003756 stirring Methods 0.000 abstract 1
- MDNWOSOZYLHTCG-UHFFFAOYSA-N Dichlorophen Chemical compound OC1=CC=C(Cl)C=C1CC1=CC(Cl)=CC=C1O MDNWOSOZYLHTCG-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 241000894006 Bacteria Species 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 244000005700 microbiome Species 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 229910001424 calcium ion Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- IZUPBVBPLAPZRR-UHFFFAOYSA-N pentachlorophenol Chemical compound OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl IZUPBVBPLAPZRR-UHFFFAOYSA-N 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 1
- 241000219095 Vitis Species 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 230000002308 calcification Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 125000000609 carbazolyl group Chemical class C1(=CC=CC=2C3=CC=CC=C3NC12)* 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to cement paint technical field, and in particular to a kind of cement paint and preparation method thereof, is mainly made up of following raw material：80 100 parts of cement, 90 110 parts of polyacrylate dispersion, 46 parts of nano titanium oxide, 24 parts of barium metaborate, 23 parts of sodium pentachlorophenol, 2,2' dihydroxy 5,45 55 parts of 24 parts of 5' dichloro-diphenyl methanes, 35 parts of sodium soap, 46 parts of rosin, 0.2 0.3 parts of sodium alkyl benzene sulfonate, 0.5 1.0 parts of dextrin, 0.5 1.0 parts of glucose, 47 parts of NPE and water, it, which is prepared, includes the steps such as raw material mixing, stirring, detection.The cement paint has excellent mould proof, moistureproof and anti-freezing property, effectively the service life of extension cement paint, and preparation method is simple, easily production.
Description
Technical field
The present invention relates to cement paint technical field, and in particular to a kind of cement paint and preparation method thereof.
Background technology
Cement paint is a kind of main coating by cement composition, is widely used in the basement, wall, ground of large area
Deng.Cement paint causes hydraulic performance decline because of the influence of the factors such as light, heat, bacterium, causes the short life of cement paint.As cement is applied
Material is destroyed by a variety of organisms such as mould, is caused film discoloration, tacky, perforation, destruction and is peeled off, loses adhesive force, shadow
The protective value of film and the clean and tidy and outward appearance of material are rung, mechanical property is reduced, reduction of service life, danger is caused to environmental sanitation
Evil.Rainy weather goes back to Nan Tian, and wall is very moist, cement paint film water outlet so that indoor environment is moist, uncomfortable.But
It is that the performances such as cement paint mildew resistance, moisture resistance, frost resistance in the market are undesirable, service life is short, and application is small,
The demand of people far can not be met.
The content of the invention
The goal of the invention of the present invention is：For above-mentioned problem there is provided a kind of cement paint and preparation method thereof,
Service life with excellent mould proof, moistureproof and anti-freezing property, effectively extension cement paint, its preparation method is simple, Yi Sheng
Production.
To achieve these goals, the technical solution adopted by the present invention is as follows：
A kind of cement paint, is mainly made up of following raw material：80-100 parts of cement, polyacrylate dispersion 90-
110 parts, 4-6 parts of nano titanium oxide, 2-4 parts of barium metaborate, 2-3 parts of sodium pentachlorophenol, 2,2'- dihydroxy -5,5'- dichloro two
2-4 parts of phenylmethane, 3-5 parts of sodium soap, 4-6 parts of rosin, 0.2-0.3 parts of sodium alkyl benzene sulfonate, alkyl phenol polyoxyethylene
45-55 parts of 0.2-0.3 parts of ether, 0.5-1.0 parts of dextrin, 0.5-1.0 parts of glucose and water.
Preferably, mainly it is made up of following raw material：90 parts of cement, 100 parts of polyacrylate dispersion, nano-silica
Change 5 parts of titanium, 3 parts of barium metaborate, 2.5 parts of sodium pentachlorophenol, 2.5 parts of 2,2'- dihydroxy -5,5'- dichloro-diphenyl methane, fat
Sour 4 parts of sodium, 5 parts of rosin, 0.25 part of sodium alkyl benzene sulfonate, 0.25 part of polyoxyethylene alkylphenol ether, 0.7 part of dextrin, glucose
0.7 part and 50 parts of water.
The preparation method of cement paint as described above, specifically includes following steps：
(1) accurately weigh by weight respectively nano titanium oxide, barium metaborate, sodium pentachlorophenol, 2,2'- dihydroxy-
5,5'- dichloro-diphenyl methanes, sodium soap, rosin, sodium alkyl benzene sulfonate, polyoxyethylene alkylphenol ether, dextrin and grape
Sugar, adds and is ground in grinder, sieved for subsequent use；
(2) by the nano titanium oxide of grinding, barium metaborate, sodium pentachlorophenol, 2,2'- dihydroxy -5 in step (1),
5'- dichloro-diphenyl methanes, sodium soap, rosin, sodium alkyl benzene sulfonate, polyoxyethylene alkylphenol ether, dextrin, glucose and
Cement adds in mixer be uniformly mixed together, obtains mixture, standby；
(3) polyacrylate dispersion and water are accurately weighed by weight, are added in the mixture, high-speed stirred mixing,
Sieving, obtains the cement paint；
(4) cement paint is subjected to performance detection, and packed, be put in storage.
Preferably, the mesh number sieved described in step (1) and step (3) is 60-80 mesh.
Preferably, the speed of high-speed stirred is 400-500r/min described in step (3).
The application method of cement paint as described above, described 2 films of cement paint point, treats first time film coated surface
After drying, continue second of film, film gross thickness is 1.0-1.5mm.
In summary, by adopting the above-described technical solution, the beneficial effects of the invention are as follows：
The cement paint of the present invention is by cement, polyacrylate dispersion, nano titanium oxide, barium metaborate, pentachlorophenol
Sodium, 2,2'- dihydroxy -5,5'- dichloro-diphenyl methane, sodium soap, rosin, sodium alkyl benzene sulfonate, alkylphenol polyoxy second
Alkene ether, dextrin, glucose and water mechanical agitation are mixed.Wherein, nano titanium oxide, barium metaborate, sodium pentachlorophenol and
2,2'- dihydroxy -5,5'- dichloro-diphenyl methanes belong to mould inhibitor, and the antibacterial range of nano titanium oxide is extensive, in the work of light
A series of active oxidation material is produced with third contact of a total solar or lunar eclipse catalytic action is issued, there is these active oxidation materials very strong oxidation to live
Property, the organic component of energy degrading microorganism, so that microorganism is killed, and nano titanium oxide particle diameter is small, is scattered in cement paint
In, the effectively tensile strength of enhancing cement paint, barium metaborate chance water decomposition, metal ion and bacterium haptoreaction cause bacterium
Proper constituent is destroyed, and is caused bacterial death, is not reacted with other materials, therefore can prolonged mould proof, pentachlorophenol
Solubility is big in sodium water, more containing chlorine atom, and its chlorination degree is high, therefore with very strong sterilization capability, 2,2'- dihydroxies
Base -5,5'- dichloro-diphenyl methane contains hydrophilic radical hydroxyl and chlorine atom, and energy rapid dispersion is in cement paint, with micro- life
Thing Rapid contact enters the breeding of Carbazole alkaloid microorganism, and extensively, a variety of mould inhibitors of the above are used in mixed way bactericidal range, phase interaction
With considerably increasing mould proof scope, the antimildew function of the cement paint effectively facilitated；Sodium soap and rosin are anti-blushing agents, are waved
Send out speed slowly, therefore required volatilization heat is reduced, surface temperature declines not enough, and the steam in air fails to condense, rosin
In contain conjugated double bond and carboxyl, with stronger reactivity, can with the calcium ion reaction generation calcification rosin in cement, with fat
Sodium ion reaction generation rosin sodium soap in fat acid sodium, these products are water insoluble, enter with water in cement hole, so as to have
Effect promotes the moisture resistance of cement paint；Sodium alkyl benzene sulfonate and polyoxyethylene alkylphenol ether are air entraining agents, contained hydrophilic group and
The absorption property of lipophilic group preferably, the effective interfacial free energy of reduction cement paint so that cement paint in whipping process more
Plus be readily incorporated air and form uniform and stable bubble, bubble can be adsorbed in the calcium ion formation calcium precipitation in cement
Film is formed on film, bubble-break can be effectively prevented, promotes the frost resistance of cement paint.These materials are added to cement paint
In, learn from other's strong points to offset one's weaknesses, complement each other, significantly improve the combination property of cement paint, make it have excellent mildew resistance, moisture resistance
And frost resistance, effectively extend the service life of cement paint.
Embodiment
Technical scheme is clearly and completely described below by specific embodiment.
Embodiment 1
A kind of cement paint, is mainly made up of following raw material：80 parts of cement, 90 parts of polyacrylate dispersion, receive
4 parts of titanium dioxide of rice, 2 parts of barium metaborate, 2 parts of sodium pentachlorophenol, 2 parts of 2,2'- dihydroxy -5,5'- dichloro-diphenyl methane, fat
3 parts of sodium of fat acid, 4 parts of rosin, 0.2 part of sodium alkyl benzene sulfonate, 0.2 part of polyoxyethylene alkylphenol ether, 0.5 part of dextrin, glucose
0.5 part and 45 parts of water.
The expectation of said ratio is prepared into cement paint using following methods, following steps are specifically included：
(1) accurately weigh by weight respectively nano titanium oxide, barium metaborate, sodium pentachlorophenol, 2,2'- dihydroxy-
5,5'- dichloro-diphenyl methanes, sodium soap, rosin, sodium alkyl benzene sulfonate, polyoxyethylene alkylphenol ether, dextrin and grape
Sugar, adds and is ground in grinder, crosses 60 mesh sieves, standby；
(2) by the nano titanium oxide of grinding, barium metaborate, sodium pentachlorophenol, 2,2'- dihydroxy -5 in step (1),
5'- dichloro-diphenyl methanes, sodium soap, rosin, sodium alkyl benzene sulfonate, polyoxyethylene alkylphenol ether, dextrin, glucose and
Cement adds in mixer be uniformly mixed together, obtains mixture, standby；
(3) polyacrylate dispersion and water are accurately weighed by weight, are added in the mixture, with 400r/min speed
High-speed stirred mixing is spent, 60 mesh sieves is crossed, obtains the cement paint；
(4) cement paint is subjected to performance detection, and packed, be put in storage.
Application method：Using 2 films of cement paint time-division obtained above, after first time film coated surface is dried, after
Continue second of film, film gross thickness is 1.0mm.
Embodiment 2
A kind of cement paint, is mainly made up of following raw material：90 parts of cement, 100 parts of polyacrylate dispersion, receive
5 parts of titanium dioxide of rice, 3 parts of barium metaborate, 2.5 parts of sodium pentachlorophenol, 2,2'- dihydroxy -5,5'- dichloro-diphenyl methane 2.5
Part, 4 parts of sodium soap, 5 parts of rosin, 0.25 part of sodium alkyl benzene sulfonate, 0.25 part of polyoxyethylene alkylphenol ether, 0.7 part of dextrin,
50 parts of 0.7 part of glucose and water.
The expectation of said ratio is prepared into cement paint using following methods, following steps are specifically included：
(1) accurately weigh by weight respectively nano titanium oxide, barium metaborate, sodium pentachlorophenol, 2,2'- dihydroxy-
5,5'- dichloro-diphenyl methanes, sodium soap, rosin, sodium alkyl benzene sulfonate, polyoxyethylene alkylphenol ether, dextrin and grape
Sugar, adds and is ground in grinder, crosses 70 mesh sieves, standby；
(2) by the nano titanium oxide of grinding, barium metaborate, sodium pentachlorophenol, 2,2'- dihydroxy -5 in step (1),
5'- dichloro-diphenyl methanes, sodium soap, rosin, sodium alkyl benzene sulfonate, polyoxyethylene alkylphenol ether, dextrin, glucose and
Cement adds in mixer be uniformly mixed together, obtains mixture, standby；
(3) polyacrylate dispersion and water are accurately weighed by weight, are added in the mixture, with 450r/min speed
High-speed stirred mixing is spent, 70 mesh sieves is crossed, obtains the cement paint；
(4) cement paint is subjected to performance detection, and packed, be put in storage.
Application method：Using 2 films of cement paint time-division obtained above, after first time film coated surface is dried, after
Continue second of film, film gross thickness is 1.3mm.
Embodiment 3
A kind of cement paint, is mainly made up of following raw material：100 parts of cement, 110 parts of polyacrylate dispersion,
6 parts of nano titanium oxide, 4 parts of barium metaborate, 3 parts of sodium pentachlorophenol, 4 parts of 2,2'- dihydroxy -5,5'- dichloro-diphenyl methane,
5 parts of sodium soap, 6 parts of rosin, 0.3 part of sodium alkyl benzene sulfonate, 0.3 part of polyoxyethylene alkylphenol ether, 1.0 parts of dextrin, grape
Sugared 1.0 parts and 55 parts of water.
The expectation of said ratio is prepared into cement paint using following methods, following steps are specifically included：
(1) accurately weigh by weight respectively nano titanium oxide, barium metaborate, sodium pentachlorophenol, 2,2'- dihydroxy-
5,5'- dichloro-diphenyl methanes, sodium soap, rosin, sodium alkyl benzene sulfonate, polyoxyethylene alkylphenol ether, dextrin and grape
Sugar, adds and is ground in grinder, crosses 80 mesh sieves, standby；
(2) by the nano titanium oxide of grinding, barium metaborate, sodium pentachlorophenol, 2,2'- dihydroxy -5 in step (1),
5'- dichloro-diphenyl methanes, sodium soap, rosin, sodium alkyl benzene sulfonate, polyoxyethylene alkylphenol ether, dextrin, glucose and
Cement adds in mixer be uniformly mixed together, obtains mixture, standby；
(3) polyacrylate dispersion and water are accurately weighed by weight, are added in the mixture, with 500r/min speed
High-speed stirred mixing is spent, 80 mesh sieves is crossed, obtains the cement paint；
(4) cement paint is subjected to performance detection, and packed, be put in storage.
Application method：Using 2 films of cement paint time-division obtained above, after first time film coated surface is dried, after
Continue second of film, film gross thickness is 1.5mm.
In order to further illustrate the excellent performance of cement paint of the present invention, many experiments have been carried out, and according to national performance
Examination criteria carries out the performance detection of a variety of mildew resistances, moisture resistance and frost resistance to cement paint, and experimental result is as shown in table 1.
Control group：The cement paint sold on the market.
1st group：The raw material that cement paint is used for cement, polyacrylate dispersion, nano titanium oxide, barium metaborate,
Sodium pentachlorophenol, 2,2'- dihydroxy -5,5'- dichloro-diphenyl methane, dextrin, glucose and water, other are implemented according to the present invention
Example 1 prepares cement paint.
2nd group：The raw material that cement paint is used is cement, polyacrylate dispersion, sodium soap, rosin, dextrin, grape
Sugar and water, other prepare cement paint according to the embodiment of the present invention 1.
3rd group：The raw material that cement paint is used gathers for cement, polyacrylate dispersion, sodium alkyl benzene sulfonate, alkylphenol
Oxygen vinethene, dextrin, glucose and water, other prepare cement paint according to the embodiment of the present invention 1.
4th group：The embodiment of the present invention 1.
5th group：The embodiment of the present invention 2.
6th group：The embodiment of the present invention 3.
The performance detection of the cement paint of table 1
| Group | Tensile strength/MPa | Mildew resistance/d | Moisture resistance/d | Frost resistance/d |
| Control group | 0.7 | 13 | 14 | 13 |
| 1st group | 1.3 | 23 | 11 | 12 |
| 2nd group | 1.0 | 10 | 25 | 11 |
| 3rd group | 0.9 | 11 | 12 | 25 |
| 4th group | 1.6 | 28 | 30 | 29 |
| 5th group | 1.8 | 30 | 32 | 31 |
| 6th group | 2.1 | 32 | 34 | 33 |
As known from Table 1, the data of 1-3 groups are compared with control group, the 1st group of addition mould inhibitor, obtained cement paint
Fungicidal properties and tensile strength it is optimal, the 2nd group of addition anti-blushing agent, the humidity resistance of obtained cement paint is optimal, the 3rd group
Air entraining agent is added, the anti-freezing property of obtained cement paint is optimal, but 1-3 groups obtained cement paint and control group
Combination property it is poorer than the embodiment of the present invention 1,4-6 group data displays, the combination property of cement paint of the present invention is with original
Expect the increase of consumption and increase, with excellent mildew resistance, anti-blushing agent and frost resistance.
Described above is the detailed description for the present invention preferably possible embodiments, but embodiment is not limited to this hair
The equal change or modification change completed under bright patent claim, the technical spirit suggested by all present invention, all should belong to
Cover the scope of the claims in the present invention.
Claims (6)
1. a kind of cement paint, it is characterised in that be mainly made up of following raw material：80-100 parts of cement, polyacrylic acid
90-110 parts of ester emulsion, 4-6 parts of nano titanium oxide, 2-4 parts of barium metaborate, 2-3 parts of sodium pentachlorophenol, 2,2'- dihydroxy -5,
2-4 parts of 5'- dichloro-diphenyl methanes, 3-5 parts of sodium soap, 4-6 parts of rosin, 0.2-0.3 parts of sodium alkyl benzene sulfonate, alkylphenol
45-55 parts of 0.2-0.3 parts of APEO, 0.5-1.0 parts of dextrin, 0.5-1.0 parts of glucose and water.
2. cement paint according to claim 1, it is characterised in that be mainly made up of following raw material：Cement 90
Part, 100 parts of polyacrylate dispersion, 5 parts of nano titanium oxide, 3 parts of barium metaborate, 2.5 parts of sodium pentachlorophenol, 2,2'- dihydroxies
2.5 parts of base -5,5'- dichloro-diphenyl methane, 4 parts of sodium soap, 5 parts of rosin, 0.25 part of sodium alkyl benzene sulfonate, alkylphenol gather
50 parts of 0.25 part of oxygen vinethene, 0.7 part of dextrin, 0.7 part of glucose and water.
3. the preparation method of the cement paint according to any one of claim 1-2, it is characterised in that specifically include following
Step：
(1) nano titanium oxide, barium metaborate, sodium pentachlorophenol, 2,2'- dihydroxy -5,5'- are accurately weighed by weight respectively
Dichloro-diphenyl methane, sodium soap, rosin, sodium alkyl benzene sulfonate, polyoxyethylene alkylphenol ether, dextrin and glucose, plus
Enter in grinder and be ground, sieve for subsequent use；
(2) by the nano titanium oxide of grinding, barium metaborate, sodium pentachlorophenol, 2,2'- dihydroxy -5,5'- bis- in step (1)
Chlorodiphenyl methylmethane, sodium soap, rosin, sodium alkyl benzene sulfonate, polyoxyethylene alkylphenol ether, dextrin, glucose and cement
Add and be uniformly mixed in mixer together, obtain mixture, it is standby；
(3) polyacrylate dispersion and water are accurately weighed by weight, are added in the mixture, high-speed stirred mixing, sieving,
Obtain the cement paint；
(4) cement paint is subjected to performance detection, and packed, be put in storage.
4. the preparation method of cement paint according to claim 3, it is characterised in that：Described in step (1) and step (3)
The mesh number of sieving is 60-80 mesh.
5. the preparation method of cement paint according to claim 3, it is characterised in that：High-speed stirred described in step (3)
Speed be 400-500r/min.
6. the application method of the cement paint according to any one of claim 1-5, it is characterised in that：Described cement is applied
2 films of material point, after after the drying of first time film coated surface, continuing second of film, film gross thickness is 1.0-1.5mm.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1109488A (en) * | 1994-11-29 | 1995-10-04 | 蔡晋才 | Water-based cement paint and preparation method thereof |
| CN1663940A (en) * | 2004-03-04 | 2005-09-07 | 赵国忠 | 2,2 '-dihydroxy-5, 5' -dichloro diphenylmethane and its preparation method |
| CN102173683A (en) * | 2011-01-28 | 2011-09-07 | 长沙理工大学 | Polymer cement waterproof material and preparation method thereof |
| CN105971131A (en) * | 2016-06-01 | 2016-09-28 | 上海尤卉防水工程有限公司 | Environment-friendly waterproof construction method |
| CN106186855A (en) * | 2016-07-04 | 2016-12-07 | 青岛百千川海洋生态科技有限公司 | A kind of cement mortar of improvement |
-
2017
- 2017-03-17 CN CN201710159559.2A patent/CN106987187A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1109488A (en) * | 1994-11-29 | 1995-10-04 | 蔡晋才 | Water-based cement paint and preparation method thereof |
| CN1663940A (en) * | 2004-03-04 | 2005-09-07 | 赵国忠 | 2,2 '-dihydroxy-5, 5' -dichloro diphenylmethane and its preparation method |
| CN102173683A (en) * | 2011-01-28 | 2011-09-07 | 长沙理工大学 | Polymer cement waterproof material and preparation method thereof |
| CN105971131A (en) * | 2016-06-01 | 2016-09-28 | 上海尤卉防水工程有限公司 | Environment-friendly waterproof construction method |
| CN106186855A (en) * | 2016-07-04 | 2016-12-07 | 青岛百千川海洋生态科技有限公司 | A kind of cement mortar of improvement |
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