CN106957532B - Batik resist printing wax and preparation method thereof suitable for burlap - Google Patents
Batik resist printing wax and preparation method thereof suitable for burlap Download PDFInfo
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- CN106957532B CN106957532B CN201710240361.7A CN201710240361A CN106957532B CN 106957532 B CN106957532 B CN 106957532B CN 201710240361 A CN201710240361 A CN 201710240361A CN 106957532 B CN106957532 B CN 106957532B
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- 238000010019 resist printing Methods 0.000 title claims abstract description 53
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 235000013871 bee wax Nutrition 0.000 claims abstract description 87
- 239000012166 beeswax Substances 0.000 claims abstract description 86
- 239000001993 wax Substances 0.000 claims abstract description 79
- 239000000203 mixture Substances 0.000 claims abstract description 64
- 239000012188 paraffin wax Substances 0.000 claims abstract description 48
- 238000001816 cooling Methods 0.000 claims abstract description 33
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 24
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 24
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000008117 stearic acid Substances 0.000 claims abstract description 24
- 240000000972 Agathis dammara Species 0.000 claims abstract description 23
- 229920002871 Dammar gum Polymers 0.000 claims abstract description 23
- 241001494479 Pecora Species 0.000 claims abstract description 23
- 239000004203 carnauba wax Substances 0.000 claims abstract description 23
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims abstract description 21
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims abstract description 21
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 15
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000155 melt Substances 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 claims description 17
- 238000010257 thawing Methods 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 4
- 238000011403 purification operation Methods 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 claims 2
- 230000001376 precipitating effect Effects 0.000 claims 1
- 238000004043 dyeing Methods 0.000 abstract description 13
- 238000004018 waxing Methods 0.000 abstract description 10
- 230000003204 osmotic effect Effects 0.000 abstract description 8
- 239000000853 adhesive Substances 0.000 abstract description 6
- 230000001070 adhesive effect Effects 0.000 abstract description 6
- 230000000694 effects Effects 0.000 description 21
- 239000004744 fabric Substances 0.000 description 15
- 238000000746 purification Methods 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 14
- 239000000049 pigment Substances 0.000 description 9
- 239000002994 raw material Substances 0.000 description 9
- 238000005336 cracking Methods 0.000 description 7
- 241000256844 Apis mellifera Species 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000012535 impurity Substances 0.000 description 5
- 239000000835 fiber Substances 0.000 description 4
- 238000007639 printing Methods 0.000 description 4
- 239000000975 dye Substances 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 3
- 230000002708 enhancing effect Effects 0.000 description 3
- 230000008595 infiltration Effects 0.000 description 3
- 238000001764 infiltration Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 238000000265 homogenisation Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 241000270708 Testudinidae Species 0.000 description 1
- 210000001015 abdomen Anatomy 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 210000004907 gland Anatomy 0.000 description 1
- 229940097275 indigo Drugs 0.000 description 1
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 210000001672 ovary Anatomy 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L91/06—Waxes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/12—Reserving parts of the material before dyeing or printing ; Locally decreasing dye affinity by chemical means
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
- Medicinal Preparation (AREA)
Abstract
A kind of batik resist printing wax and preparation method thereof suitable for burlap, belongs to wax-dyeing process field.Resist printing wax includes paraffin, beeswax, palm wax, gum dammar, stearic acid, sheep oil and sodium carboxymethylcellulose.When preparation, weighs 30-40 parts by weight paraffin and 10-20 parts by weight beeswax is heated to 70-80 DEG C and melts and keep the temperature 0.5-1h obtaining the first mixture；Weigh 5-10 parts by weight palm wax, 2-4 parts by weight gum dammar and 5-8 parts by weight stearic acid, 1-1.5 parts by weight sheep oil and 0.5-1 parts by weight sodium carboxymethylcellulose are heated to 140-150 DEG C and melt and keep the temperature 0.5-1h obtaining the second mixture；The second mixture is added in the first mixture at a temperature of 120-130 DEG C, 20-30min is stirred with 400-600r/min revolving speed, it is cooling.Preparation method is simple, and osmotic effect of the resist printing wax obtained on burlap is good, adhesive capacity is strong, waxing is uniform.
Description
Technical field
The present invention relates to wax-dyeing process fields, and in particular to a kind of suitable for the batik resist printing wax of burlap and its preparation side
Method.
Background technique
Batik is the ancient ethnic group's folk tradition textile printing and dyeing handicraft in China, Gu claim wax, with twist figured silk fabrics (tie dyeing),
Press from both sides figured silk fabrics (hollow out stamp) and the referred to as big stamp skill of Ancient Times in China three.Batik is good at by the nationalitys such as Guizhou, Yunnan Miao ethnic group, the Bouyei.
Batik is to be dipped in dewaxing with wax spatula and drawn to disseminate with indigo after Hua Yubu, both contaminates wax, cloth cover takes on blue bottom white flower or white background is blue
Colored multiple patterns, meanwhile, in dip dyeing, as the wax exposure cracking of resist agent, make cloth cover that special " ice line " be presented, it is outstanding to have
Glamour.Since batik pattern is abundant, tone is plain, unique style, for making dress and personal adornment and various life utilities, it appears
Simple generous, pure and fresh pleasing, rich in national characters, the market demand increases year by year.
But the wax material in wax operation is being drawn in existing wax printing technology, generally use single paraffin or single
Beeswax heat carries out picture wax operation after melting.The hardness of paraffin is larger, is used for picture wax and operates easy exposure cracking in dyeing course
Pigment figure is generated, but its adhesiveness is lower, being easy to fall off in dyeing course causes to generate stain.The adhesiveness of beeswax is not easy well
It falls off, but its hardness is lower, and exposure cracking is difficult in dyeing course and generates pigment figure, while its asking there is also higher cost
Topic.For above-mentioned problem, the prior art is by the way that paraffin and beeswax to be simply mixed, while keeping its adhesiveness preferable
Enough exposure crackings, but it still has the problems such as permeability is poor, waxing is uneven.And due to the superficiality of different clothes
Can be different, it needs to be surface-treated for different clothes.
Summary of the invention
The purpose of the present invention is to provide a kind of batik resist printing waxes suitable for burlap, in carrying out picture wax operation,
Osmotic effect on burlap is good, adhesive capacity is strong, waxing is uniform.
It is obtained anti-another object of the present invention is to provide a kind of preparation method of batik resist printing wax suitable for burlap
Osmotic effect of the dye wax on burlap is good, adhesive capacity is strong, waxing is uniform.
The present invention solves its technical problem and adopts the following technical solutions to realize.
The present invention proposes a kind of batik resist printing wax suitable for burlap, by weight includes: 30-40 parts of paraffin, beeswax
10-20 parts, 5-10 parts of palm wax, 2-4 parts of gum dammar, 5-8 parts of stearic acid, 1-1.5 parts of sheep oil and sodium carboxymethylcellulose
0.5-1 parts.
The present invention also proposes a kind of preparation method of batik resist printing wax suitable for burlap, weighs the stone of 30-40 parts by weight
Wax and the beeswax of 10-20 parts by weight are heated to 70-80 DEG C and melt and keep the temperature 0.5-1h obtaining the first mixture；Weigh 5-10 parts by weight
Palm wax, 2-4 parts by weight gum dammar and the stearic acid of 5-8 parts by weight, the sheep oil of 1-1.5 parts by weight and 0.5-1 weight
The sodium carboxymethylcellulose of amount part is heated to 140-150 DEG C and melts and keep the temperature 0.5-1h obtaining the second mixture；In 120-130 DEG C of temperature
The second mixture is added in the first mixture under degree, 20-30min is stirred with 400-600r/min revolving speed, it is cooling.
The beneficial effect of the embodiment of the present invention is:
Batik resist printing wax provided by the invention suitable for burlap, paraffin hardness is larger, is easy exposure cracking in dyeing
Form pigment figure；Beeswax hardness is smaller, and adhesiveness is strong, can enhance adhesion stability of the resist printing wax on cloth.With paraffin and bee
Wax is wax-matrix, and the adherency of resist printing wax stablizes, easily forms pigment figure.Palm wax has good Oil keeping, and character is thin and viscid
Spend small, resin content is low, good flowing properties, can be improved the osmosis of resist printing wax to improve resist printing effect.Da Ma tree
Rouge is widely used in enhancing ink used for plastic, compound oil ink, the adhesive force of table printing ink, mobility such as PP and PE, can be into one
The osmosis and adhesion property of step enhancing resist printing wax.Since the quality of burlap is thick and stiff, the efficiency that wax is seeped during waxing is lower,
Wax layer is coarse uneven and is easy to fall off.It is whole that the mixture of stearic acid, sheep oil and sodium carboxymethylcellulose carries out surface to burlap
Reason, the compatibility that can soften burlap surface, improve burlap fiber and wax oil are waxing uniformly and further increase wax oil in fiber crops
The osmotic efficiency of cloth.
The preparation method of the batik resist printing wax provided by the invention for being used in burlap, due to the fusing point of paraffin and beeswax compared with
It is low, paraffin and beeswax are first melted at a lower temperature, prevent the rotten or oxidation for causing paraffin and beeswax when high-temperature operation.
Heat preservation operation after raw material is melted makes to be sufficiently mixed between raw material, improves the consistency and structural homogenity of product, from
And improve resist printing effect.
Specific embodiment
It in order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below will be in the embodiment of the present invention
Technical solution be clearly and completely described.The person that is not specified actual conditions in embodiment, according to normal conditions or manufacturer builds
The condition of view carries out.Reagents or instruments used without specified manufacturer is the conventional production that can be obtained by commercially available purchase
Product.
The batik resist printing wax and preparation method thereof suitable for burlap of the embodiment of the present invention is specifically described below.
A kind of batik resist printing wax suitable for burlap includes: 30-40 parts of paraffin, 10-20 parts of beeswax, palm fibre by weight
5-10 parts of palmitic acid wax, 2-4 parts of gum dammar, 5-8 parts of stearic acid, 1-1.5 parts of sheep oil and 0.5-1 parts of sodium carboxymethylcellulose.
The hardness of paraffin is higher, is easy exposure cracking.During batik dyeing, what dyestuff can be generated by cracking
Gap colours on cloth, to generate the natural pigment figure of lines.But since the adhesion property of paraffin is poor, it is used alone
For paraffin as wax-matrix, stain can be formed on cloth by falling off in dyeing course paraffin, influence the effect of batik pattern.
The adhesion property of beeswax is preferable, it is not easy to fall off.But since the hardness of beeswax is lower, it is not easy to tortoise occur
Split generation pigment figure.
During drawing wax, wax oil is flowed out from wax spatula to permeate and freezes solidly on cloth, has the function that local resist printing.Due to wax
Oil is fast from sharp temperature drop, the setting rate of wax oil after wax spatula outflow, it is desirable that wax oil seepage velocity with higher makes wax oil
It can be impregnated with cloth, to guarantee the resist printing effect of picture wax.
Palm wax has good Oil keeping, and character is thin and viscosity is small, and resin content is low, good flowing properties,
It can be improved the osmosis of batik resist printing wax, to improve resist printing effect.
Gum dammar is widely used in enhancing the ink used for plastic such as PP and PE, compound oil ink, the adhesive force of table printing ink, flowing
Property, the osmosis and adhesion property of resist printing wax can be further enhanced, resist printing is made good use of, and effectively prevent generating stain,
Further increase the quality of batiks.
Further, peregal and sapn are added in batik resist printing wax of the invention, with preferable peptizaiton, energy
Promote peptizaiton of the wax oil in cloth, the osmosis of wax oil is improved, to further increase the resist printing of batik resist printing wax
Effect.
Wax-dyeing process is especially prevailing in Guizhou province, but different regions like using cloth be not quite similar.The southeast of Guizhou Province
Be often used burlap with one band of the south of Guizhou Province, the west of Guizhou Province, one band of Northwestern Guizhou Province Miao ethnic group then like with burlap and felt.
The quality of burlap is thick and stiff, and the efficiency that wax is seeped during waxing is lower, and wax layer is coarse uneven and is easy to fall off and causes
Resist printing effect is low, resist printing unevenly and in dyeing course is also easy to produce stain, to influence the effect of batik.
Through inventor the study found that carrying out the table of burlap using the mixture of stearic acid, sheep oil and sodium carboxymethylcellulose
Surface treatment, can significantly improve the compatibility of burlap and wax oil, to improve the osmotic efficiency of wax oil.The mixture can simultaneously
Softening burlap surface, especially stearic acid have apparent bating effect to the surface of burlap, make to wax uniform and not easily to fall off.It will
The mixture is added in batik resist printing wax, and the uniformity for the wax layer that the osmotic effect of wax oil and waxing obtain is significantly improved.
This is suitable for the preparation method of the batik resist printing wax of burlap, comprising: weighs the paraffin and 10-20 of 30-40 parts by weight
The beeswax of parts by weight is heated to 70-80 DEG C and melts and keep the temperature 0.5-1h obtaining the first mixture；Weigh 5-10 parts by weight palm wax,
The gum dammar of 2-4 parts by weight and stearic acid, the sheep oil of 1-1.5 parts by weight and the carboxylic first of 0.5-1 parts by weight of 5-8 parts by weight
Base sodium cellulosate is heated to 140-150 DEG C and melts and keep the temperature 0.5-1h obtaining the second mixture；By first at a temperature of 120-130 DEG C
The second mixture is added in mixture, stirs 20-30min with 400-600r/min revolving speed, cooling.
Peregal and sapn is added after first mixture and the mixing of the second mixture, the process with stirring makes the first mixing
Object and the second mixture are uniformly dispersed, and improve the homogenization of resist printing wax material interior tissue.
Since the fusing point of paraffin and beeswax is lower and easy to oxidize rotten, it is melted at low temperature, prevent and its
His raw material melts under the high temperature conditions leads to oxidation deterioration etc..Raw material carries out isothermal holding after thawing, can make between raw material
It is sufficiently mixed, disperses, homogenize production die further, pore size after material condensation can be effectively reduced, improve batik
The consistency of resist printing wax further increases the resist printing performance of material.
Further, cooling down operation carries out under the pressure of 0.2-0.3MPa, can promote fine and close combination between raw material, into
One step increases the consistency of material, improves the mobility and permeability of wax oil.
Beeswax is a kind of fatty matter being secreted by 4 pairs of wax glands of worker bee abdomen of the right age in bee colony.In bee colony,
Worker bee builds honeycomb, ovary capping and the capping of feed room using the wax that oneself is secreted.Honeycomb is to hoard food, cultivate for honeybee
Bee and the place for inhabiting conglomeration, beeswax is both the product of bee colony and it is survived and the necessary material of breeding, therefore beeswax
In usually contain more insoluble impurities, influence the quality of batik resist printing wax.
Therefore it is further, in the present invention, before paraffin and beeswax heating and melting are mixed, purification behaviour is carried out to beeswax
Make.
Specifically, since the density of beeswax is small compared with water, and insoluble impurities water content and nutrition content in beeswax
Higher, density is greater than water.In purification operations, cooling, beeswax are stood after beeswax and water are mixed and heated to 65-75 DEG C of thawing
In insoluble impurities be sunken to the bottom of water, beeswax floats on the surface of water and gradually condenses, and beeswax is taken out after the completion of condensation and is
Complete purification operations.
In order to be sufficiently separated insoluble impurities with beeswax, the mass ratio of preferable beeswax and water is generally 1:2.Into one
Step, 2-3 identical purification operations can be repeated, convenient for impurity to be sufficiently separated.
Feature and performance of the invention are described in further detail with reference to embodiments.
Embodiment 1
A kind of preparation method of the batik resist printing wax suitable for burlap, comprising:
The paraffin of 30 parts by weight and the beeswax of 10 parts by weight are weighed, beeswax and 20g water are mixed and heated to 65-75 DEG C of thawing
Standing cooling afterwards, the beeswax after taking out purification, the beeswax by paraffin and after purifying are heated to 70-80 DEG C and melt and keep the temperature 0.5-1h
Obtain the first mixture；Weigh the palm wax of 5 parts by weight, the gum dammar of 2 parts by weight, the stearic acid of 5 parts by weight, 1 parts by weight
The sodium carboxymethylcellulose of sheep oil and 0.5 parts by weight is heated to 140-150 DEG C and melts and keep the temperature 0.5-1h obtaining the second mixture；
The second mixture is added in the first mixture at a temperature of 120-130 DEG C, adds the peregal and 0.3 weight of 0.5 parts by weight
The sapn of part stirs 20-30min with 400-600r/min revolving speed.It is cooling under 0.2-0.3MPa pressure.
Embodiment 2
The paraffin of 33 parts by weight and the beeswax of 12 parts by weight are weighed, beeswax and 24g water are mixed and heated to 65-75 DEG C of thawing
Standing cooling afterwards, the beeswax after taking out purification, the beeswax by paraffin and after purifying are heated to 70-80 DEG C and melt and keep the temperature 0.5-1h
Obtain the first mixture；Weigh the palm wax of 7 parts by weight, the gum dammar of 2.5 parts by weight, the stearic acid of 6 parts by weight, 1.1 weight
Part sheep oil and the sodium carboxymethylcelluloses of 0.6 parts by weight be heated to 140-150 DEG C and melt and keep the temperature 0.5-1h to obtain second mixed
Close object；At a temperature of 120-130 DEG C by the first mixture be added the second mixture, add 0.6 parts by weight peregal and
The sapn of 0.35 parts by weight stirs 20-30min with 400-600r/min revolving speed.It is cooling under 0.2-0.3MPa pressure.
Embodiment 3
The paraffin of 35 parts by weight and the beeswax of 14 parts by weight are weighed, beeswax and 28g water are mixed and heated to 65-75 DEG C of thawing
Standing cooling afterwards, the beeswax after taking out purification, the beeswax by paraffin and after purifying are heated to 70-80 DEG C and melt and keep the temperature 0.5-1h
Obtain the first mixture；Weigh the palm wax of 8 parts by weight, the gum dammar of 3 parts by weight, the stearic acid of 6.5 parts by weight, 1.2 weight
Part sheep oil and the sodium carboxymethylcelluloses of 0.65 parts by weight be heated to 140-150 DEG C and melt and keep the temperature 0.5-1h to obtain second mixed
Close object；The second mixture is added in the first mixture at a temperature of 120-130 DEG C, adds the peregal and 0.4 of 0.8 parts by weight
The sapn of parts by weight stirs 20-30min with 400-600r/min revolving speed.It is cooling under 0.2-0.3MPa pressure.
Embodiment 4
The paraffin of 37 parts by weight and the beeswax of 17 parts by weight are weighed, beeswax and 34g water are mixed and heated to 65-75 DEG C of thawing
Standing cooling afterwards, the beeswax after taking out purification, the beeswax by paraffin and after purifying are heated to 70-80 DEG C and melt and keep the temperature 0.5-1h
Obtain the first mixture；Weigh the palm wax of 9 parts by weight, the gum dammar of 3.5 parts by weight, the stearic acid of 7 parts by weight, 1.13 weight
Part sheep oil and the sodium carboxymethylcelluloses of 0.7 parts by weight be heated to 140-150 DEG C and melt and keep the temperature 0.5-1h to obtain second mixed
Close object；The second mixture is added in the first mixture at a temperature of 120-130 DEG C, adds the peregal and 0.5 of 0.9 parts by weight
The sapn of parts by weight stirs 20-30min with 400-600r/min revolving speed.It is cooling under 0.2-0.3MPa pressure.
Embodiment 5
The paraffin of 40 parts by weight and the beeswax of 20 parts by weight are weighed, beeswax and 40g water are mixed and heated to 65-75 DEG C of thawing
Standing cooling afterwards, the beeswax after taking out purification, the beeswax by paraffin and after purifying are heated to 70-80 DEG C and melt and keep the temperature 0.5-1h
Obtain the first mixture；Weigh the palm wax of 10 parts by weight, the gum dammar of 4 parts by weight, the stearic acid of 8 parts by weight, 1.5 parts by weight
Sheep oil and the sodium carboxymethylcelluloses of 1 parts by weight be heated to 140-150 DEG C and melt and keep the temperature 0.5-1h obtaining the second mixture；
The second mixture is added in the first mixture at a temperature of 120-130 DEG C, adds the peregal and 0.6 parts by weight of 1 parts by weight
Sapn, with 400-600r/min revolving speed stir 20-30min.It is cooling under 0.2-0.3MPa pressure.
Embodiment 6
The paraffin of 35 parts by weight and the beeswax of 14 parts by weight are weighed, beeswax and 28g water are mixed and heated to 65-75 DEG C of thawing
Standing cooling afterwards, the beeswax after taking out purification, the beeswax by paraffin and after purifying are heated to 70-80 DEG C and melt and keep the temperature 0.5-1h
Obtain the first mixture；Weigh the palm wax of 8 parts by weight, the gum dammar of 3 parts by weight, the stearic acid of 6.5 parts by weight, 1.2 weight
Part sheep oil and the sodium carboxymethylcelluloses of 0.65 parts by weight be heated to 140-150 DEG C and melt and keep the temperature 0.5-1h to obtain second mixed
Close object；The second mixture is added in the first mixture at a temperature of 120-130 DEG C, 20- is stirred with 400-600r/min revolving speed
30min.It is cooling under 0.2-0.3MPa pressure.
Comparative example 1
The paraffin of 35 parts by weight and the beeswax of 14 parts by weight are weighed, beeswax and 28g water are mixed and heated to 65-75 DEG C of thawing
Standing cooling afterwards, the beeswax after taking out purification, the beeswax by paraffin and after purifying are heated to 70-80 DEG C and melt and keep the temperature 0.5-1h
Obtain the first mixture；The gum dammar of the palm wax and 3 parts by weight that weigh 8 parts by weight is heated to 140-150 DEG C and melts and keep the temperature
0.5-1h obtains the second mixture；The second mixture is added in the first mixture at a temperature of 120-130 DEG C, adds 0.8 weight
The peregal of part and the sapn of 0.4 parts by weight stir 20-30min with 400-600r/min revolving speed.Under 0.2-0.3MPa pressure
It is cooling.
Comparative example 2
The paraffin of 35 parts by weight and the beeswax of 14 parts by weight are weighed, beeswax and 28g water are mixed and heated to 65-75 DEG C of thawing
Standing cooling afterwards, the beeswax after taking out purification, the beeswax by paraffin and after purifying are heated to 70-80 DEG C and melt and keep the temperature 0.5-1h
Obtain the first mixture；Weigh the carboxymethyl cellulose of the stearic acid of 6.5 parts by weight, the sheep oil of 1.2 parts by weight and 0.65 parts by weight
Plain sodium is heated to 140-150 DEG C and melts and keep the temperature 0.5-1h obtaining the second mixture；By the first mixture at a temperature of 120-130 DEG C
The second mixture is added, adds the peregal of 0.8 parts by weight and the sapn of 0.4 parts by weight, is stirred with 400-600r/min revolving speed
Mix 20-30min.It is cooling under 0.2-0.3MPa pressure.
Comparative example 3
The paraffin of 35 parts by weight and the beeswax of 14 parts by weight are weighed, beeswax and 28g water are mixed and heated to 65-75 DEG C of thawing
Standing cooling afterwards, the beeswax after taking out purification, the beeswax by paraffin and after purifying are heated to 70-80 DEG C and melt and keep the temperature 0.5-
The peregal of 0.8 parts by weight and the sapn of 0.4 parts by weight is added, at a temperature of 120-130 DEG C with 400-600r/min revolving speed in 1h
Stir 20-30min.It is cooling under 0.2-0.3MPa pressure.
Comparative example 4
Weigh the palm wax of the paraffin of 35 parts by weight and 8 parts by weight of beeswax of 14 parts by weight, the gum dammar of 3 parts by weight,
The sodium carboxymethylcellulose of the stearic acid of 6.5 parts by weight, the sheep oil of 1.2 parts by weight and 0.65 parts by weight.By beeswax and 28g water
Cooling is stood after being mixed and heated to 65-75 DEG C of thawing, the beeswax after taking out purification mixes the beeswax after purification with other raw materials
140-150 DEG C is heated to melt and keep the temperature 0.5-1h；The peregal and 0.4 weight of 0.8 parts by weight are added at a temperature of 120-130 DEG C
The sapn of part is measured, 20-30min is stirred with 400-600r/min revolving speed.It is cooling under 0.2-0.3MPa pressure.
Comparative example 5
The paraffin of 35 parts by weight and the beeswax of 14 parts by weight are weighed, beeswax and 28g water are mixed and heated to 65-75 DEG C of thawing
Cooling is stood afterwards, and the beeswax after paraffin and purification is heated to 70-80 DEG C and melts to obtain the first mixing by the beeswax after taking out purification
Object；Weigh the palm wax of 8 parts by weight, the gum dammar of 3 parts by weight, the stearic acid of 6.5 parts by weight, 1.2 parts by weight sheep oil with
And 0.65 the sodium carboxymethylcelluloses of parts by weight be heated to 140-150 DEG C and melt to obtain the second mixture；At a temperature of 120-130 DEG C
The second mixture is added in first mixture, the peregal of 0.8 parts by weight and the sapn of 0.4 parts by weight are added, with 400-
600r/min revolving speed stirs 20-30min.It is cooling under 0.2-0.3MPa pressure.
Comparative example 6
The paraffin of 35 parts by weight and the beeswax of 14 parts by weight are weighed, beeswax and 28g water are mixed and heated to 65-75 DEG C of thawing
Standing cooling afterwards, the beeswax after taking out purification, the beeswax by paraffin and after purifying are heated to 70-80 DEG C and melt and keep the temperature 0.5-1h
Obtain the first mixture；Weigh the palm wax of 8 parts by weight, the gum dammar of 3 parts by weight, the stearic acid of 6.5 parts by weight, 1.2 weight
Part sheep oil and the sodium carboxymethylcelluloses of 0.65 parts by weight be heated to 140-150 DEG C and melt and keep the temperature 0.5-1h to obtain second mixed
Close object；The second mixture is added in the first mixture at a temperature of 120-130 DEG C, adds the peregal and 0.4 of 0.8 parts by weight
The sapn of parts by weight stirs 20-30min with 400-600r/min revolving speed.It is cooling.
It chooses 60 specifications and is divided into 12 groups for C 32X32 68X68, the identical dimity of size shape, every group 5 is opened the fiber crops
Cloth cloth.Using batik resist printing wax made from embodiment 1-6 and comparative example 1-6 respectively as the resist agent of every group of cloth, production
The identical batik works of pattern.
200 people are randomly selected respectively in the west of Guizhou Province and Northwestern Guizhou Province successively pigment figure to be imitated to 60 batik works obtained above
Fruit, infiltration resist printing effect and the marking of anti-dewaxing effect, respectively 1,2,3,4,5,6 point of six class, point higher expression batik effect
Fruit is better, and result average mark is as shown in table 1.
1. batik works grade form of table
As shown in Table 1, embodiment 1-6 is obtained is suitable for its pigment figure effect of the batik resist printing wax of burlap, infiltration resist printing effect
Fruit and anti-dewaxing excellent effect.Burlap is not surface-treated using stearic acid etc. in comparative example 1 and comparative example 3, wax oil exists
The osmotic efficiency of burlap is low, and the adhesion property between wax layer and hard burlap is lower, waxing is uneven, and pigment figure effect, infiltration are anti-
Dye effect and anti-dewaxing effect significantly reduce.Palm wax and gum dammar, anti-dewaxing are not used in comparative example 2 and comparative example 3
Adhesion property reduce, anti-dewaxing effect is substantially reduced, and being easy to generate stain at resist printing position influences batik effect.Comparative example 4
It is middle that raw material is not subjected to heat preservation homogenization, densification operations to raw material in 140-150 DEG C of high-temperature heating, comparative example 5 together,
Cooling procedure in comparative example 6 operates without pressurization, and batik effect is significantly reduced.
In conclusion the preparation method of the batik resist printing wax suitable for burlap of the embodiment of the present invention is easy to operate, system
The batik resist printing wax suitable for burlap obtained is good to the osmotic effect on burlap, adhesive capacity is strong, waxing is uniform.
Embodiments described above is a part of the embodiment of the present invention, instead of all the embodiments.Reality of the invention
The detailed description for applying example is not intended to limit the range of claimed invention, but is merely representative of selected implementation of the invention
Example.Based on the embodiments of the present invention, obtained by those of ordinary skill in the art without making creative efforts
Every other embodiment, shall fall within the protection scope of the present invention.
Claims (9)
1. a kind of batik resist printing wax suitable for burlap, which is characterized in that by weight include: 30-40 parts of paraffin, beeswax
10-20 parts, 5-10 parts of palm wax, 2-4 parts of gum dammar, 5-8 parts of stearic acid, 1-1.5 parts of sheep oil and sodium carboxymethylcellulose
0.5-1 parts；
The batik resist printing wax suitable for burlap obtains by the following method: the paraffin and the beeswax are heated to 70-
80 DEG C melt and keep the temperature 0.5-1h and obtain the first mixture, by the palm wax, the gum dammar, the stearic acid, the sheep
The oily and described sodium carboxymethylcellulose is heated to 140-150 DEG C and melts and keep the temperature 0.5-1h obtaining the second mixture, in 120-130
Second mixture is added in first mixture at a temperature of DEG C, 20-30min is stirred with 400-600r/min revolving speed,
It is cooling under 0.2-0.3MPa pressure.
2. the batik resist printing wax according to claim 1 suitable for burlap, which is characterized in that by weight, comprising: institute
State 33-37 parts of paraffin, beeswax 12-17 parts described, palm wax 7-9 parts described, the gum dammar 2.5-3.5 parts described, tristearin
1-1.3 parts of 6-7 parts sour, the described sheep oil and sodium carboxymethylcellulose 0.5-0.8 parts described.
3. the batik resist printing wax according to claim 2 suitable for burlap, which is characterized in that by weight, comprising: institute
State 35 parts of paraffin, 14 parts of the beeswax, 8 parts of the palm wax, 3 parts of the gum dammar, 6.5 parts of the stearic acid, the sheep
1.2 parts and 0.65 part of the sodium carboxymethylcellulose of oil.
4. the batik resist printing wax according to claim 1 suitable for burlap, which is characterized in that by weight, further includes:
0.5-1 parts of peregal, 0.3-0.6 parts of sapn；
The batik resist printing wax suitable for burlap obtains by the following method: first mixture addition described second is mixed
After closing object, the peregal and the sapn is added before stirring.
5. the batik resist printing wax according to claim 4 suitable for burlap, which is characterized in that the peregal and the department
The weight ratio of disk is 2:1.
6. a kind of preparation method of the batik resist printing wax suitable for burlap characterized by comprising weigh 30-40 parts by weight
Paraffin and the beeswax of 10-20 parts by weight are heated to 70-80 DEG C and melt and keep the temperature 0.5-1h obtaining the first mixture；Weigh 5-10 weight
The palm wax, the gum dammar of 2-4 parts by weight, the stearic acid of 5-8 parts by weight, the sheep oil of 1-1.5 parts by weight and 0.5-1 weight of part
The sodium carboxymethylcellulose of amount part is heated to 140-150 DEG C and melts and keep the temperature 0.5-1h obtaining the second mixture；In 120-130 DEG C of temperature
Degree is lower to be added second mixture for first mixture, 20-30min is stirred with 400-600r/min revolving speed, in 0.2-
It is cooling under 0.3MPa pressure.
7. preparation method according to claim 6, which is characterized in that before the paraffin and the beeswax heating and melting,
The beeswax is purified.
8. preparation method according to claim 7, which is characterized in that the purification operations of the beeswax are as follows: by the beeswax
Cooling is stood after being mixed and heated to 65-75 DEG C of thawing with water, separates the precipitating in water phase and water phase.
9. preparation method according to claim 6, which is characterized in that second mixing is added in first mixture
After object, the peregal of 0.5-1 parts by weight and the sapn of 0.3-0.6 parts by weight is added before stirring.
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| CN109266023A (en) * | 2018-11-25 | 2019-01-25 | 福泉市筑梦服装有限公司 | A kind of batik mixing cerate and preparation method thereof |
| CN109518490A (en) * | 2018-11-25 | 2019-03-26 | 福泉市筑梦服装有限公司 | A kind of nationality's batik cerate and preparation method thereof |
| CN109370238A (en) * | 2018-11-26 | 2019-02-22 | 福泉市筑梦服装有限公司 | A kind of cerate and preparation method thereof for batik |
| CN109486216A (en) * | 2018-11-26 | 2019-03-19 | 福泉市筑梦服装有限公司 | A kind of batik cerate and preparation method thereof |
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| ES2573052T3 (en) * | 2008-09-30 | 2016-06-03 | L'oreal | Cosmetic composition composed of an organic silicon compound, -with at least one basic function-, a hydrophobic film-forming polymer, a pigment and a volatile solvent |
| CN106270512A (en) * | 2016-09-01 | 2017-01-04 | 中国地质大学（武汉） | 3D prints support slurry, metal paste and the Method of printing of metal labyrinth |
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