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CN106906927B - A kind of curtain wall for building - Google Patents

A kind of curtain wall for building Download PDF

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Publication number
CN106906927B
CN106906927B CN201710218724.7A CN201710218724A CN106906927B CN 106906927 B CN106906927 B CN 106906927B CN 201710218724 A CN201710218724 A CN 201710218724A CN 106906927 B CN106906927 B CN 106906927B
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curtain wall
parts
temperature
heat preservation
copper alloy
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CN106906927A (en
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陈利
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Shenzhen Gasu Adorn Design Engineering Co., Ltd.
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SHENZHEN GASU ADORN DESIGN ENGINEERING Co Ltd
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Priority to CN201811303784.XA priority Critical patent/CN109267678B/en
Priority to CN201710218724.7A priority patent/CN106906927B/en
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    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B2/00Walls, e.g. partitions, for buildings; Wall construction with regard to insulation; Connections specially adapted to walls
    • E04B2/88Curtain walls
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/30Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
    • C04B28/32Magnesium oxychloride cements, e.g. Sorel cement
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C9/00Alloys based on copper
    • C22C9/05Alloys based on copper with manganese as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/08Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of copper or alloys based thereon
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/30Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
    • C04B2201/32Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Structural Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Architecture (AREA)
  • Metallurgy (AREA)
  • Mechanical Engineering (AREA)
  • Electromagnetism (AREA)
  • Civil Engineering (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Finishing Walls (AREA)
  • Laminated Bodies (AREA)
  • Load-Bearing And Curtain Walls (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

A kind of curtain wall for building, including cement base heat preservation inner plating and the curtain wall metal outer plate being pasted on outside cement base heat preservation inner plating, curtain wall metal outer plate is coated with antirust agent, copper alloy plate of the present invention has intensity high as curtain wall outer layer, hardness is high, thermal conductivity is good, service life extends when this allows for it as curtain wall facade, it is less likely to be damaged, reduce maintenance cost and maintenance load, copper alloy surface antirust agent of the present invention, copper alloy surface antirust agent is quickly forming a nanometer protective layer in copper alloy surface, and after metal surface forms nanometer protective layer, make matrix that there is excellent Corrosion Protection, and environmental pollution is small, it will not skin ambustion when use, it is harmless, securely and reliably, it is easily operated.

Description

A kind of curtain wall for building
Technical field
The present invention relates to a kind of curtain wall for building, belongs to curtain wall field.
Background technique
Curtain wall is the exterior wall encirclement of building, and not load-bearing is hung up as curtain, therefore also known as suspension wall, is modern Large-scale and skyscraper commonly has the lightweight wall of decorative effect.It is made of structural framing with plate is inlayed, does not undertake master The architectural exterior-protecting construction of body structural loads and effect.At present both at home and abroad traditional curtain wall be mainly stone curtain wall, glass curtain wall and Metal curtain wall, these three curtain walls can satisfy the basic decoration demand of industry and civil buildings substantially.But these three curtain walls are by certainly The limitation of body material property has very big hidden danger and disadvantage: stone curtain wall weight is big, energy consumption is high, fire prevention is poor;Glass curtain Energy consumption is high for wall, light pollution is serious, fire prevention is poor;Exclusive use metal curtain wall weatherability is poor, and thermal insulation property and intensity are lower.
Summary of the invention
In order to solve the problems, such as that curtain wall exists in the prior art, of the invention provides a kind of curtain for building Wall, to solve above-mentioned technical problem.
A kind of curtain wall for building, it is characterised in that: including cement base heat preservation inner plating and be pasted on cement base heat preservation internal layer Curtain wall metal outer plate outside plate, curtain wall metal outer plate are coated with antirust agent,
Weigh 100 parts of mass parts cement first, 80-120 parts of glass bead, 100-130 parts of sand, 30-40 parts of magnesia, partially 25-30 parts of kaolin, 15-20 parts of magnesium chloride, 5-9 parts of aerosil, 3-5 parts of xanthan gum, calcium lignosulfonate 2-7 Part, 2-4 parts of cellulose ether, after mixing, molding obtains cement base heat preservation inner plating to 40-60 parts of water,
Curtain wall metal outer plate is copper alloy plate, and manufacturing process: stocking up according to the proportion, and raw material is carried out melting, It 1090-1100 DEG C of smelting temperature, is poured to obtain casting after melting, is 750-770 DEG C by casting heating temperature, keeps the temperature 20- 30 minutes, carry out first stage rolling later, first stage start rolling temperature is 750-770 DEG C, single pass reduction ratio 6~8%, Mill speed is 0.2-0.3m/s, and 710-730 DEG C of first stage finishing temperature, slab thickness reaches 10-15mm, then by plate Base is heated to 870-890 DEG C, keeps the temperature 10-15 minutes, carries out second stage rolling later, and second stage start rolling temperature is 870- 890 DEG C, single pass reduction ratio is in 14-20%, mill speed 0.5-0.7m/s, 820-830 DEG C of second stage finishing temperature, plate Base thickness reaches 4-6mm, then by slab at 810-830 DEG C, keeps the temperature 10-20 minutes, carries out phase III rolling later, the Three stage start rolling temperatures are 810-830 DEG C, and single pass reduction ratio is in 10-12%, mill speed 0.4-0.6m/s, phase III 760-780 DEG C of finishing temperature, cooled to room temperature, slab thickness reaches 1-2mm, and slab is reheated to 560-600 DEG C, 40-50 minutes are kept the temperature, then slab is cut according to required size, obtains curtain wall metal outer plate, outside curtain wall metal Laminate is pasted on the outside of cement base heat preservation inner plating, and copper alloy is made of following element mass percentage: Mn 5-6%, Mg 3-4%, Ni 2-4%, Zr 0.8-1%, Sn 0.6-0.7%, Zn 0.2-0.3%, V 0.07-0.08%, Ti 0.07-0.08%, Copper alloy surface antirust agent is uniformly applied to curtain wall metal outer plate surface, it is small to stand 24 by Ce0.05-0.06%, surplus Cu When, obtain the curtain wall for building.
Preferably, a kind of curtain wall for building, first stage start rolling temperature is 765 DEG C, and single pass reduction ratio is 6 ~8%, mill speed 0.2m/s, 710 DEG C of first stage finishing temperature,
Preferably, a kind of curtain wall for building, second stage start rolling temperature is 880 DEG C, and single pass reduction ratio exists 14-20%, mill speed 0.5-0.7m/s, 820 DEG C of second stage finishing temperature.
Preferably, a kind of curtain wall for building, phase III start rolling temperature is 810 DEG C, and single pass reduction ratio exists 10-12%, mill speed 0.4-0.6m/s, 760 DEG C of phase III finishing temperature.
Preferably, a kind of curtain wall for building, antirust agent preparation method: vinyltrimethoxysilane is heated To 40-45 DEG C, the mixed solution of tetrabutyl titanate and ethyl alcohol is added, is stirred evenly with the mixing speed of 200r/min, then protects It is 20-25 minutes warm, triethanolamine oleate is added and is uniformly mixed, adjusting PH is 8~9, and phthalic acid ester is added and isomery alcohol is poly- Ethylene oxide ether with the mixing speed of 300r/min be uniformly mixed, 50-55 DEG C heat preservation 30-40 minutes, obtain copper alloy surface prevent Rust agent.
Preferably, a kind of curtain wall for building, antirust agent preparation method: vinyltrimethoxysilane is heated To 42 DEG C, the mixed solution of tetrabutyl titanate and ethyl alcohol is added, is stirred evenly with the mixing speed of 200r/min, then keeps the temperature 25 Minute, triethanolamine oleate is added and is uniformly mixed, adjusting PH is 8~9, and phthalic acid ester and isomeric alcohol polyethenoxy ether is added It is uniformly mixed with the mixing speed of 300r/min, keeps the temperature 35 minutes at 55 DEG C, obtain copper alloy surface antirust agent.
Preferably, a kind of curtain wall for building, vinyltrimethoxysilane: tetrabutyl titanate: ethyl alcohol: oleic acid Triethanolamine: phthalic acid ester: isomeric alcohol polyethenoxy ether mass ratio 2-4:1-2:5-7:0.5-0.8:0.2-0.3:0.05- 0.1。
A kind of manufacturing method of curtain wall for building, curtain wall for building include cement base heat preservation inner plating and are pasted on cement base The curtain wall metal outer plate outside inner plating is kept the temperature, curtain wall metal outer plate is coated with antirust agent,
Weigh 100 parts of cement first, 80-120 parts of glass bead, 100-130 parts of sand, 30-40 parts of magnesia, metakaolin 25-30 parts, 15-20 parts of magnesium chloride, 5-9 parts of aerosil, 3-5 parts of xanthan gum, 2-7 parts of calcium lignosulfonate, fiber Plain ether 2-4 parts, after mixing, molding obtains cement base heat preservation inner plating to 40-60 parts of water,
Curtain wall metal outer plate is copper alloy plate, and manufacturing process: stocking up according to the proportion, and raw material is carried out melting, It 1090-1100 DEG C of smelting temperature, is poured to obtain casting after melting, is 750-770 DEG C by casting heating temperature, keeps the temperature 20- 30 minutes, carry out first stage rolling later, first stage start rolling temperature is 750-770 DEG C, single pass reduction ratio 6~8%, Mill speed is 0.2-0.3m/s, and 710-730 DEG C of first stage finishing temperature, slab thickness reaches 10-15mm, then by plate Base is heated to 870-890 DEG C, keeps the temperature 10-15 minutes, carries out second stage rolling later, and second stage start rolling temperature is 870- 890 DEG C, single pass reduction ratio is in 14-20%, mill speed 0.5-0.7m/s, 820-830 DEG C of second stage finishing temperature, plate Base thickness reaches 4-6mm, then by slab at 810-830 DEG C, keeps the temperature 10-20 minutes, carries out phase III rolling later, the Three stage start rolling temperatures are 810-830 DEG C, and single pass reduction ratio is in 10-12%, mill speed 0.4-0.6m/s, phase III 760-780 DEG C of finishing temperature, cooled to room temperature, slab thickness reaches 1-2mm, and slab is reheated to 560-600 DEG C, 40-50 minutes are kept the temperature, then slab is cut according to required size, obtains curtain wall metal outer plate, outside curtain wall metal Laminate is pasted on the outside of cement base heat preservation inner plating, and copper alloy is made of following element mass percentage: Mn 5-6%, Mg 3-4%, Ni 2-4%, Zr 0.8-1%, Sn 0.6-0.7%, Zn 0.2-0.3%, V 0.07-0.08%, Ti 0.07-0.08%, Copper alloy surface antirust agent is uniformly applied to curtain wall metal outer plate surface, it is small to stand 24 by Ce0.05-0.06%, surplus Cu When, obtain the curtain wall for building.
Preferably, a kind of manufacturing method of curtain wall for building, first stage start rolling temperature is 765 DEG C, single track Secondary reduction ratio is in 6~8%, mill speed 0.2m/s, and 710 DEG C of first stage finishing temperature,
Preferably, a kind of manufacturing method of curtain wall for building, second stage start rolling temperature is 880 DEG C, single track Secondary reduction ratio is in 14-20%, mill speed 0.5-0.7m/s, and 820 DEG C of second stage finishing temperature.
Preferably, a kind of manufacturing method of curtain wall for building, phase III start rolling temperature is 810 DEG C, single track Secondary reduction ratio is in 10-12%, mill speed 0.4-0.6m/s, and 760 DEG C of phase III finishing temperature.
Preferably, a kind of manufacturing method of curtain wall for building, copper alloy surface antirust agent preparation method: by second Alkenyl trimethoxy silane is heated to 40-45 DEG C, the mixed solution of tetrabutyl titanate and ethyl alcohol is added, with the stirring of 200r/min Speed stirs evenly, then heat preservation 20-25 minutes, and triethanolamine oleate is added and is uniformly mixed, and adjusting PH is 8~9, and adjacent benzene is added Dicarboxylic acid esters and isomeric alcohol polyethenoxy ether are uniformly mixed with the mixing speed of 300r/min, at 50-55 DEG C of heat preservation 30-40 points Clock obtains copper alloy surface antirust agent.
Preferably, a kind of manufacturing method of curtain wall for building, copper alloy surface antirust agent antirust agent preparation side Method: vinyltrimethoxysilane is heated to 42 DEG C, the mixed solution of tetrabutyl titanate and ethyl alcohol is added, with 200r/min's Mixing speed stirs evenly, then heat preservation 25 minutes, and triethanolamine oleate is added and is uniformly mixed, and adjusting PH is 8~9, is added adjacent Phthalic acid ester and isomeric alcohol polyethenoxy ether are uniformly mixed with the mixing speed of 300r/min, are kept the temperature 35 minutes at 55 DEG C, are obtained To copper alloy surface antirust agent.
Preferably, a kind of manufacturing method of curtain wall for building, vinyltrimethoxysilane: the positive fourth of metatitanic acid Ester: ethyl alcohol: triethanolamine oleate: phthalic acid ester: isomeric alcohol polyethenoxy ether mass ratio 2-4:1-2:5-7:0.5-0.8: 0.2-0.3:0.05-0.1.
A side surface is coated with copper alloy surface antirust agent to curtain wall metal outer plate outwardly.
Curtain wall metal outer plate, can be to curtain wall metal outer plate court before being pasted on the outside of cement base heat preservation inner plating Outer and inward faces are coated with copper alloy surface antirust agent, carry out curtain wall metal outer plate again later and are pasted on cement base heat preservation Process on the outside of inner plating.
High temperature, room temperature plasticity and the intergranular knot that copper alloy of the present invention is improved by adding Mn, Mg, Ni, Zr of specific quantity With joint efforts, and crystal grain can have been refined, has added Ti, the elements such as V, Ce and copper form intermetallic compound, change microstructure, improve Machining property, to make alloy that there is good mechanical performance.The present invention uses three stage rolling techniques+heat treatment process So that there is copper alloy plate hardness to reach 90~110HB, tensile strength reaches 280~310MPa, and elongation percentage reaches 18~25%, Reach control crystal grain by open rolling finishing temperature and single pass reduction ratio in three stage rolling techniques of control and mill speed to grow up, Degraded in mechanical properties is prevented, copper alloy plate of the present invention has intensity high as curtain wall outer layer, and hardness is high, and thermal conductivity is good, this is just So that service life extends when it is as curtain wall facade, it is not easy to damage, reduce maintenance cost and maintenance load, this hair Bright copper alloy surface antirust agent, copper alloy surface antirust agent is quickly forming a nanometer protective layer in copper alloy surface, and metal watch After face forms nanometer protective layer, make matrix that there is excellent Corrosion Protection, and environmental pollution is small, and when use will not burn Skin, it is harmless, it is securely and reliably, easily operated.Cement base of the present invention keeps the temperature inner plating intensity heat insulating ability with higher, protects Demonstrate,prove the bulk life time and thermal insulation property of curtain wall.
Specific embodiment
Embodiment 1
A kind of curtain wall for building, including cement base heat preservation inner plating and the curtain wall gold being pasted on outside cement base heat preservation inner plating Belonging to lamina rara externa, curtain wall metal outer plate is coated with antirust agent,
Weigh 100 parts of cement first, 90 parts of glass bead, 120 parts of sand, 32 parts of magnesia, 30 parts of metakaolin, magnesium chloride 15 parts, 6 parts of aerosil, 3 parts of xanthan gum, 5 parts of calcium lignosulfonate, 4 parts of cellulose ether, 45 parts of water are uniformly mixed Afterwards, molding obtains cement base heat preservation inner plating,
Curtain wall metal outer plate is copper alloy plate, and manufacturing process: stocking up according to the proportion, and raw material is carried out melting, It 1100 DEG C of smelting temperature, is poured to obtain casting after melting, is 750 DEG C by casting heating temperature, keeps the temperature 20-30 minutes, it First stage rolling is carried out afterwards, and first stage start rolling temperature is 750 DEG C, and single pass reduction ratio is in 6~8%, mill speed 0.2-0.3m/s, 710 DEG C of first stage finishing temperature, slab thickness reaches 10-15mm, then by heating of plate blank to 890 DEG C, Heat preservation 10-15 minutes carries out second stage rolling later, and second stage start rolling temperature is 890 DEG C, and single pass reduction ratio is in 14- 20%, mill speed 0.5-0.7m/s, 830 DEG C of second stage finishing temperature, slab thickness reaches 4-6mm, then by slab At 820 DEG C, 10-20 minutes are kept the temperature, carries out phase III rolling later, phase III start rolling temperature is 820 DEG C, single pass pressure Rate is in 10-12%, mill speed 0.4-0.6m/s, and 760 DEG C of phase III finishing temperature, cooled to room temperature, slab is thick Degree reaches 1-2mm, and slab is reheated to 580 DEG C, 40-50 minutes is kept the temperature, is then cut according to required size to slab It cuts, obtains curtain wall metal outer plate, curtain wall metal outer plate is pasted on the outside of cement base heat preservation inner plating, and copper alloy is by following member Plain mass percentage composition: Mn 5%, Mg 3.5%, Ni 2%, Zr 0.85%, Sn 0.7%, Zn 0.2%, V 0.075%, Ti Copper alloy surface antirust agent is uniformly applied to curtain wall metal outer plate surface, stands 24 by 0.07%, Ce0.05%, surplus Cu Hour, the curtain wall for building is obtained,
Antirust agent preparation method: vinyltrimethoxysilane is heated to 40-45 DEG C, tetrabutyl titanate and ethyl alcohol is added Mixed solution, stirred evenly with the mixing speed of 200r/min, then heat preservation 20-25 minute, be added triethanolamine oleate mix It closes uniformly, adjusting PH is 8~9, and it is mixed with the mixing speed of 300r/min that phthalic acid ester and isomeric alcohol polyethenoxy ether is added Close uniformly, 50-55 DEG C heat preservation 30-40 minutes, obtain copper alloy surface antirust agent, vinyltrimethoxysilane: metatitanic acid is just Butyl ester: ethyl alcohol: triethanolamine oleate: phthalic acid ester: isomeric alcohol polyethenoxy ether mass ratio 4:1:5:0.6:0.25: 0.08。
Embodiment 2
A kind of curtain wall for building, including cement base heat preservation inner plating and the curtain wall gold being pasted on outside cement base heat preservation inner plating Belonging to lamina rara externa, curtain wall metal outer plate is coated with antirust agent,
Weigh 100 parts of cement first, 80 parts of glass bead, 110 parts of sand, 35 parts of magnesia, 30 parts of metakaolin, magnesium chloride 20 parts, 6 parts of aerosil, 3 parts of xanthan gum, 3 parts of calcium lignosulfonate, 4 parts of cellulose ether, 50 parts of water are uniformly mixed Afterwards, molding obtains cement base heat preservation inner plating,
Curtain wall metal outer plate is copper alloy plate, and manufacturing process: stocking up according to the proportion, and raw material is carried out melting, It 1095 DEG C of smelting temperature, is poured to obtain casting after melting, is 770 DEG C by casting heating temperature, keeps the temperature 20-30 minutes, it First stage rolling is carried out afterwards, and first stage start rolling temperature is 770 DEG C, and single pass reduction ratio is in 6~8%, mill speed 0.2-0.3m/s, 720 DEG C of first stage finishing temperature, slab thickness reaches 10-15mm, then by heating of plate blank to 885 DEG C, Heat preservation 10-15 minutes carries out second stage rolling later, and second stage start rolling temperature is 885 DEG C, and single pass reduction ratio is in 14- 20%, mill speed 0.5-0.7m/s, 830 DEG C of second stage finishing temperature, slab thickness reaches 4-6mm, then by slab At 830 DEG C, 10-20 minutes are kept the temperature, carries out phase III rolling later, phase III start rolling temperature is 830 DEG C, single pass pressure Rate is in 10-12%, mill speed 0.4-0.6m/s, and 770 DEG C of phase III finishing temperature, cooled to room temperature, slab is thick Degree reaches 1-2mm, and slab is reheated to 590 DEG C, 40-50 minutes is kept the temperature, is then cut according to required size to slab It cuts, obtains curtain wall metal outer plate, curtain wall metal outer plate is pasted on the outside of cement base heat preservation inner plating, and copper alloy is by following member Plain mass percentage composition: Mn 5.5%, Mg 3%, Ni 4%, Zr 0.8%, Sn 0.6%, Zn 0.3%, V 0.07%, Ti Copper alloy surface antirust agent is uniformly applied to curtain wall metal outer plate surface, stands 24 by 0.08%, Ce0.055%, surplus Cu Hour, the curtain wall for building is obtained,
Copper alloy surface antirust agent preparation method: vinyltrimethoxysilane is heated to 40-45 DEG C, metatitanic acid is being added just The mixed solution of butyl ester and ethyl alcohol is stirred evenly with the mixing speed of 200r/min, then heat preservation 20-25 minutes, and oleic acid is added Triethanolamine is uniformly mixed, and adjusting PH is 8~9, and phthalic acid ester and isomeric alcohol polyethenoxy ether is added with 300r/min's Mixing speed be uniformly mixed, 50-55 DEG C heat preservation 30-40 minutes, obtain copper alloy surface antirust agent, vinyl trimethoxy silicon Alkane: tetrabutyl titanate: ethyl alcohol: triethanolamine oleate: phthalic acid ester: isomeric alcohol polyethenoxy ether mass ratio 3:1.5:5: 0.8:0.3:0.06.
Embodiment 3
A kind of curtain wall for building, including cement base heat preservation inner plating and the curtain wall gold being pasted on outside cement base heat preservation inner plating Belonging to lamina rara externa, curtain wall metal outer plate is coated with antirust agent,
Weigh 100 parts of cement first, 110 parts of glass bead, 110 parts of sand, 36 parts of magnesia, 28 parts of metakaolin, chlorination 20 parts of magnesium, 9 parts of aerosil, 3 parts of xanthan gum, 5 parts of calcium lignosulfonate, 2 parts of cellulose ether, 60 parts of water are uniformly mixed Afterwards, molding obtains cement base heat preservation inner plating,
Curtain wall metal outer plate is copper alloy plate, and manufacturing process: stocking up according to the proportion, and raw material is carried out melting, It 1100 DEG C of smelting temperature, is poured to obtain casting after melting, is 770 DEG C by casting heating temperature, keeps the temperature 20-30 minutes, it First stage rolling is carried out afterwards, and first stage start rolling temperature is 770 DEG C, and single pass reduction ratio is in 6~8%, mill speed 0.2-0.3m/s, 715 DEG C of first stage finishing temperature, slab thickness reaches 10-15mm, then by heating of plate blank to 880 DEG C, Heat preservation 10-15 minutes carries out second stage rolling later, and second stage start rolling temperature is 880 DEG C, and single pass reduction ratio is in 14- 20%, mill speed 0.5-0.7m/s, 825 DEG C of second stage finishing temperature, slab thickness reaches 4-6mm, then by slab At 830 DEG C, 10-20 minutes are kept the temperature, carries out phase III rolling later, phase III start rolling temperature is 830 DEG C, single pass pressure Rate is in 10-12%, mill speed 0.4-0.6m/s, and 770 DEG C of phase III finishing temperature, cooled to room temperature, slab is thick Degree reaches 1-2mm, and slab is reheated to 560 DEG C, 40-50 minutes is kept the temperature, is then cut according to required size to slab It cuts, obtains curtain wall metal outer plate, curtain wall metal outer plate is pasted on the outside of cement base heat preservation inner plating, and copper alloy is by following member Plain mass percentage composition: Mn 6%, Mg 3%, Ni 2%, Zr 0.8%, Sn 0.65%, Zn 0.2%, V 0.08%, Ti Copper alloy surface antirust agent is uniformly applied to curtain wall metal outer plate surface, stands 24 by 0.07%, Ce0.05%, surplus Cu Hour, the curtain wall for building is obtained,
Copper alloy surface antirust agent preparation method: vinyltrimethoxysilane is heated to 40-45 DEG C, metatitanic acid is being added just The mixed solution of butyl ester and ethyl alcohol is stirred evenly with the mixing speed of 200r/min, then heat preservation 20-25 minutes, and oleic acid is added Triethanolamine is uniformly mixed, and adjusting PH is 8~9, and phthalic acid ester and isomeric alcohol polyethenoxy ether is added with 300r/min's Mixing speed be uniformly mixed, 50-55 DEG C heat preservation 30-40 minutes, obtain copper alloy surface antirust agent, vinyl trimethoxy silicon Alkane: tetrabutyl titanate: ethyl alcohol: triethanolamine oleate: phthalic acid ester: isomeric alcohol polyethenoxy ether mass ratio 4:1:7: 0.6:0.2:0.1.
Embodiment 4
A kind of curtain wall for building, including cement base heat preservation inner plating and the curtain wall gold being pasted on outside cement base heat preservation inner plating Belonging to lamina rara externa, curtain wall metal outer plate is coated with antirust agent,
Weigh 100 parts of cement first, 80 parts of glass bead, 100 parts of sand, 30 parts of magnesia, 25 parts of metakaolin, magnesium chloride 20 parts, 5 parts of aerosil, 4 parts of xanthan gum, 6 parts of calcium lignosulfonate, 2 parts of cellulose ether, 55 parts of water are uniformly mixed Afterwards, molding obtains cement base heat preservation inner plating,
Curtain wall metal outer plate is copper alloy plate, and manufacturing process: stocking up according to the proportion, and raw material is carried out melting, It 1095 DEG C of smelting temperature, is poured to obtain casting after melting, is 760 DEG C by casting heating temperature, keeps the temperature 20-30 minutes, it First stage rolling is carried out afterwards, and first stage start rolling temperature is 760 DEG C, and single pass reduction ratio is in 6~8%, mill speed 0.2-0.3m/s, 710 DEG C of first stage finishing temperature, slab thickness reaches 10-15mm, then by heating of plate blank to 870 DEG C, Heat preservation 10-15 minutes carries out second stage rolling later, and second stage start rolling temperature is 870 DEG C, and single pass reduction ratio is in 14- 20%, mill speed 0.5-0.7m/s, 820 DEG C of second stage finishing temperature, slab thickness reaches 4-6mm, then by slab At 810 DEG C, 10-20 minutes are kept the temperature, carries out phase III rolling later, phase III start rolling temperature is 810 DEG C, single pass pressure Rate is in 10-12%, mill speed 0.4-0.6m/s, and 760 DEG C of phase III finishing temperature, cooled to room temperature, slab is thick Degree reaches 1-2mm, and slab is reheated to 570 DEG C, 40-50 minutes is kept the temperature, is then cut according to required size to slab It cuts, obtains curtain wall metal outer plate, curtain wall metal outer plate is pasted on the outside of cement base heat preservation inner plating, and copper alloy is by following member Plain mass percentage composition: Mn 5.5%, Mg 3.5%, Ni 2%, Zr 0.8%, Sn 0.7%, Zn 0.25%, V 0.08%, Copper alloy surface antirust agent is uniformly applied to curtain wall metal outer plate surface by Ti 0.07%, Ce0.05%, surplus Cu, is stood 24 hours, the curtain wall for building is obtained,
Copper alloy surface antirust agent preparation method: vinyltrimethoxysilane is heated to 40-45 DEG C, metatitanic acid is being added just The mixed solution of butyl ester and ethyl alcohol is stirred evenly with the mixing speed of 200r/min, then heat preservation 20-25 minutes, and oleic acid is added Triethanolamine is uniformly mixed, and adjusting PH is 8~9, and phthalic acid ester and isomeric alcohol polyethenoxy ether is added with 300r/min's Mixing speed be uniformly mixed, 50-55 DEG C heat preservation 30-40 minutes, obtain copper alloy surface antirust agent, vinyl trimethoxy silicon Alkane: tetrabutyl titanate: ethyl alcohol: triethanolamine oleate: phthalic acid ester: isomeric alcohol polyethenoxy ether mass ratio 3:1.5:6: 0.6:0.2:0.08.
Table 1: copper alloy plate coats antirust agent characterization
Copper alloy plate coats antirust agent test item As a result
Density g/cm3 1.030-1.060
Damp heat test: humidity 90%, 35 DEG C of temperature, 30 days Without rust spot
Salt spray test: 40 DEG C of 5% salt fog continuously sprays 48 hours Without rust spot
Table 2: copper alloy plate characterization
Copper alloy plate test Elongation percentage δ (%) Hardness (HV) Plastic strain ratio r Yield strength σ s (MPa) Tensile strength sigma b (MPa)
Embodiment 1 37.1 120 1.31 348 445
Embodiment 2 38,5 128 1.34 353 458
Embodiment 3 37.6 135 1.30 355 440
Embodiment 4 36.2 133 1.37 342 451
Table 3: cement base keeps the temperature inner plating characterization
Cement base keeps the temperature inner plating test item As a result
Compression strength/MPa 0.43-0.48
Tensile strength/MPa 0.15-1.9
Thermal coefficient W/mK 0.045-0.058
Dry apparent density/km/m3 135-148
Present invention is not limited to the embodiments described above, all to realize the present invention using structure similar with the present invention and its method All modes of purpose, it is within the scope of the present invention.

Claims (1)

1. a kind of curtain wall for building, it is characterised in that: including cement base heat preservation inner plating and be pasted on cement base heat preservation inner plating Outer curtain wall metal outer plate, curtain wall metal outer plate are coated with antirust agent,
Weigh 100 parts of cement first, 80-120 parts of glass bead, 100-130 parts of sand, 30-40 parts of magnesia, metakaolin 25- 30 parts, 15-20 parts of magnesium chloride, 5-9 parts of aerosil, 3-5 parts of xanthan gum, 2-7 parts of calcium lignosulfonate, cellulose ether 2-4 parts, after mixing, molding obtains cement base heat preservation inner plating to 40-60 parts of water,
Curtain wall metal outer plate is copper alloy plate, and manufacturing process: stocking up according to the proportion, and raw material is carried out melting, melting It 1090-1100 DEG C of temperature, is poured to obtain casting after melting, is 750-770 DEG C by casting heating temperature, 20-30 points of heat preservation Clock carries out first stage rolling later, and first stage start rolling temperature is 750-770 DEG C, and single pass reduction ratio is rolled 6~8% Speed is 0.2-0.3m/s, 710-730 DEG C of first stage finishing temperature, and slab thickness reaches 10-15mm, then adds slab Heat keeps the temperature 10-15 minutes to 870-890 DEG C, carries out second stage rolling later, and second stage start rolling temperature is 870-890 DEG C, Single pass reduction ratio is in 14-20%, mill speed 0.5-0.7m/s, 820-830 DEG C of second stage finishing temperature, slab thickness Reach 4-6mm, then by slab at 810-830 DEG C, keeps the temperature 10-20 minutes, carry out phase III rolling, phase III later Start rolling temperature is 810-830 DEG C, and single pass reduction ratio is in 10-12%, mill speed 0.4-0.6m/s, phase III finish to gauge temperature 760-780 DEG C of degree, cooled to room temperature, slab thickness reaches 1-2mm, slab is reheated to 560-600 DEG C, heat preservation 40-50 minutes, then slab is cut according to required size, obtains curtain wall metal outer plate, curtain wall metal outer plate patch It spreading on the outside of cement base heat preservation inner plating, copper alloy is made of following element mass percentage: Mn 5-6%, Mg 3-4%, Ni 2-4%, Zr 0.8-1%, Sn 0.6-0.7%, Zn 0.2-0.3%, V 0.07-0.08%, Ti 0.07-0.08%, Ce0.05- Copper alloy surface antirust agent is uniformly applied to curtain wall metal outer plate surface, stands 24 hours, obtain by 0.06%, surplus Cu The curtain wall for building.
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