CN102951871A - Multifunctional liquid jade coating and preparation method thereof - Google Patents
Multifunctional liquid jade coating and preparation method thereof Download PDFInfo
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Abstract
The invention discloses a multifunctional liquid jade coating, which comprises: 10-15 parts of a hydroxyethyl cellulose aqueous solution; 24-36 parts of an adhesive; 56-65 parts of natural color jade powder; 3-5 parts of a borosilicate inorganic glass flake; 3-5 parts of an inorganic flame retardant; 3-5 parts of talcum powder; 0.5 part of natural color mica or composite mica titanium; 0.15 part of an antimildew agent; 0.15 part of an antioxidant; and 0.2 part of a functional aid. Being non-toxic, odorless, nonflammable, and convenient for storage and transportation, the multifunctional liquid jade coating provided in the invention is a multifunctional high-quality coating with acid and alkali resistance, high temperature resistance and other properties, and has the characteristics of heat insulation, sound insulation, waterproofness, corrosion resistance, weathering resistance, flexibility and cracking resistance, strong adhesion and shedding resistance, green and environmental protection, and wide using range. The invention also discloses a preparation method of the liquid jade coating, and the method is simple and is easy to implement.
Description
Technical field
The present invention relates to a kind of liquid jade, particularly a kind of for the protection of wall insulating layer and liquid jade coating of decoration and preparation method thereof.
Background technology
Expansion polyphenyl plate thin plastering exterior wall heat-insulation system is that China is most widely used at present, and market is maximum, and cost is moderate, a kind of heat-insulation system that heat preservation and energy conservation effects is good.This system is as the thermal insulation separation thermosphere take polystyrol plastic foam plate (EPS plate) or extruded polystyrene cystose (XPS plate).Adopt bonding mode, be aided with crab-bolt and be fixed in base course wall, and make protective layer with the anticracking grout composite glass-fiber latticed fabric, flexible putty and elastic coating are made the outer heat preservation system of finish coat.The great advantage of this system is: thermal insulation separation thermosphere thermal conductivity is little, high insulating effect; Styrofoam is unicellular structure, does not absorb water, and is corrosion-resistant, and material is light, and cost is low, is well suited for China's national situation.Yet the protective layer of this system and finish coat, by use practice in recent years, the problem of appearance is many: such as the difference variation because of the height inequality, and the protection finish coat problem of Cracking that causes; The lagging material digestion time is inadequate, because of expanding with heat and contract with cold and the protection facing crack problem that causes of moisture expansion and drying shrinkage of self; Differ in more than 20 times the situation irreversible thermal contraction distortion, the protection finish coat problem of Cracking of initiation at thermal insulation layer thermal conductivity coefficient and protective layer thermal conductivity coefficient; The chemical shrinkage of cement-based mortar, dry shrinkage, self-constriction, temperature shrinkage, plastic shrinkage and the protection facing problem of Cracking that causes; The protection finish coat problem of Cracking of creeping, dropping and causing because the styrofoam load is overweight; The protection facing of incomplete insulation protection and non-integral and cause temperature stress, the insulation position of initiation and crack problem without insulation joint, position; Material conversion place of heat-preserving cut-off position because the density of its material is different, has determined that the Young's modulus between material is different with the linear coefficient of expansion, and the distortion under the thermal stress effect is also different, and then the aspect crack problem that causes etc.
Because the frequent appearance of crack problem, the fire problem of the seepage problem that brings immediately, the problem that comes off, organic materials, life problems of heat-insulation system etc. also just come one after another.This has not only brought economic problems, more the people has been caused safely threat.Therefore be necessary to develop a kind of new facing layer material.
The liquid jade, adopted the principle of " decomposition-reduction ", pure natural solid jade through the washing color separation, is then worn into the powder raw material, be atomized into again liquid paste product, can be sprayed on any body surface by spray gun special at last, become again the appearance of natural jade after the normal temperature drying is solidified, its shape is different and different according to the shape of accompanying article, and intensity is high, flexible, temp. variation resistant does not ftracture, and is difficult for efflorescence, not easy to change, decoration texture nature, the surface can be smooth, can be beautiful bright, also can be concavo-convex, be a kind of very excellent finishing material.
External wall of high-rise building carries out top grade with Ma Fuke, sintering face brick, dry-hang stone etc. to be decorated, and these finishing material not only pose a big pressure to body of wall, and also easily coming off causes the accident, and inconvenient maintenance.Dalian, District of Shanghai were stipulated already the high building restriction more than 6 layers and were banned use of these materials the nineties.In recent years, this behave progressively is extended to a lot of cities from Beijing, and this will advance the liquid jade Application of coatings that can build easily the Fu Ke that goes into action, sintering face brick, cladding emmarble effect greatly.And the sparkling and crystal-clear texture of liquid jade, abundant color, natural quality, durable time, thicker and light weight, convenient construction without difficulty etc., be better than far away and paste porcelain and hang stone.Along with people to environment and healthy pay attention to day by day, the volatile organic compounds emission standard is required more and more higher, and grouan, marble radionuclide are unavoidable, the solvent reducible coatings metal content is higher, have certain toxicity, and flammable probability is higher, cost is also high; Film coating contains artificial color mostly, and compole is short during weather-proof anti-efflorescence, and easily peeling comes off.Because Highrise buildings is difficult to carry out routine maintenance and secondary, repeatedly application, generally be maintenance in 10 years once, the needs that have 15 years.This just requires exterior coating to have high-weatherability, anti-staining property and high tint retention, thereby the research and development of this high-performance, multifunctional coating are just become active at present field, and this also is the direction of exterior coating development.
Summary of the invention
Technical problem to be solved by this invention is, a kind of full-service fluid jade coating is provided, this liquid jade coating light of filming, do not chap, nondiscoloration is used for any stationary body surface, waterproof, anticorrosion, fire prevention and beautifying and decorating, the present invention also provides the preparation method of this liquid jade coating, and the method is simple.
Technical scheme of the present invention: in order to solve the problems of the technologies described above, this liquid jade coating comprises following composition:
Hydroxyethyl cellulose aqueous solution 10-15 part;
Tackiness agent 24-36 part;
Natural colorful jade powder 56-65 part;
Borosilicate unorganic glass scale 3-5 part;
Inorganic combustion inhibitor 3-5 part;
Talcum powder 3-5 part;
0.5 part of natural colorful mica or combined mica titanium;
0.15 part of mould inhibitor;
0.15 part in oxidation inhibitor;
0.2 part of functional agent.
Described hydroxyethyl cellulose aqueous solution mass concentration is 1.5%-2%.
Described tackiness agent is the heterocomplex modified emulsion of particle diameter 5-10 nanometer, comprises the acrylic ester emulsion of 16-20 part, the modified inorganic resin of the high elastic aqueous polyurethane of 4-6 part and 4-10 part; The colloid diameter that this tackiness agent is less and narrower size-grade distribution had both solved cohesive strength and adsorptive power, had improved again the Young's modulus of hybrid film forming layer and weathering resistance, water resisting property, fast light thermotolerance.
The solid content of described acrylic ester emulsion 〉=46%.
The specification of described natural colorful jade powder is selected particle diameter 80-160 order.
The specification of described borosilicate unorganic glass scale is selected sheet footpath 120-160 order, and thickness is 2-5 μ m.
Described inorganic combustion inhibitor is the modified aluminium hydroxide that has added any one material in silane-titanate, sodium stearate or the aluminate coupling agent.
For aforesaid full-service fluid jade coating, adopt successively the following steps preparation,
A, hydroxyethyl cellulose aqueous solution is put in the kneader;
B, unlatching kneader stir, and add high elastic aqueous polyurethane;
C, mix after, slowly add while stirring acrylic ester emulsion and film coalescence aid;
D, rear adding modified inorganic resin stirs;
E, order progressively adds natural colorful jade powder, borosilicate unorganic glass scale, modified aluminium hydroxide, talcum powder, natural colorful mica or combined mica titanium, mould inhibitor, oxidation inhibitor in proportion;
F, when solid-liquid in the kneader mediate fully evenly and viscosity qualified after, regulate pH value to 8-9 with functional agent, continue to stir and mediated 15 minutes, sieve, discharging is finished product.
The borosilicate unorganic glass scale that uses in the described step e is through following pre-treatment: first scale was cleaned 30 minutes in 70 ℃, 5% NaOH solution, to PH=7-8, then oven dry, stand-by under 90 ℃ after in 10%-20% titanate coupling agent gasoline solution, soaked 30 minutes under the room temperature, filtering.
Compared with prior art, it is high that the present invention not only has liquid jade intensity, flexible, temp. variation resistant does not ftracture, and is difficult for efflorescence, not easy to change, decoration texture nature, the surface can be smooth, can be beautiful bright, also can be concavo-convex, and finishing effect is compared with natural jade, and the characteristic that can mix the spurious with the genuine is also because reasonable material and rational proportion, have the following advantages: (1) its aggregate can adopt the shallow table material of tankage and jade ore deposit after the processing of pure natural solid jade handicraft, be the very abundant material of nature, low with respect to the organic materials power consumption, economic benefit is high, be not subjected to the impact of any economic wind and cloud both at home and abroad, price is basicly stable.(2) used adhesive material is the heterocomplex modified emulsion of acrylate, urethane, inorganic resin formation, its particle diameter is the 5-10 nanometer, less colloid diameter and narrower size-grade distribution, both solve cohesive strength and adsorptive power, improved again the Young's modulus of hybrid film forming layer and weathering resistance, water resisting property, fast light thermotolerance.(3) product does not contain any organic nutrient substance, and is tasteless, nuisanceless without any toxic ingredient so mushroom and microorganism do not grow condition, belongs to the pure natural environment protection product.(4) product manufacture is simple, disobeys thermotonus, and without heat energy consumption, cost is low.(5) product is by heterocomplex glue film forming, the heterocomplex glue can be excellent, inferior position is complementary, broken through the in the past set pattern of one matter film forming, both brought into play the high-weatherability of inorganic materials, brought into play again the high ductibility of organic materials, process preferably cohesive strength and shock strength, guaranteed high pliable and tough anti crack performance and water repelling property.
In sum, this product be a kind of nontoxic, tasteless, nonflammable, be convenient to the high-quality coating of high function that anti-soda acid, the characteristic such as high temperature resistant were transported, had in keeping.Have heat insulation, sound insulation, waterproof, anti-corrosion, weather-proof, pliable and tough cracking resistance, by force sticking anticreep, environmental protection, characteristics that use range is wide.The approximate rubber mass material of its snappiness and bituminous material, limit flexing degree can reach φ 20mm rod and not ftracture summer.Winter, limit flexing degree can reach φ 40mm rod flawless.Weathering resistance, pure jade green product can fade the efflorescence phase near former jade.Technique is simple, and cost is moderate, take water as thinner.The light of filming does not chap, and nondiscoloration is coupled hardness with softness, and is used for any stationary body surface, waterproof, anticorrosion, fire prevention and beautifying and decorating.
Embodiment
Embodiments of the invention 1: the essentially consist of full-service fluid jade coating of the present invention following (its umber all calculates with mass parts):
Mass concentration is hydroxyethyl cellulose aqueous solution 10-15 part of 1.5%-2%;
Acrylic ester emulsion 16-20 part of solid content 〉=46%, high elastic aqueous polyurethane 4-6 part, modified inorganic resin 4-10 part, the particle diameter of the heterocomplex modified emulsion that this three samples material forms is the 5-10 nanometer;
Particle diameter 80-160 purpose natural colorful jade powder 56-65 part;
Sheet footpath 120-160 order, thickness is borosilicate unorganic glass scale 3-5 part of 2-5 μ m;
Added modified aluminium hydroxide 3-5 part (this modified aluminium hydroxide is as inorganic combustion inhibitor) of any one material in silane-titanate, sodium stearate or the aluminate coupling agent;
Talcum powder 3-5 part;
0.5 part of natural colorful mica or mica titanium;
0.15 part of mould inhibitor;
0.15 part in oxidation inhibitor (phosphorous acid ester);
0.2 part of AMP-95 functional agent (functional agent also can be other functional agent, and the functional agent here is mainly used in regulating the pH value of mixture, increases simultaneously some other ilities).
In addition, can also add as required the additives such as a certain amount of glitter, photostabilizer.
This full-service fluid jade coating adopts the following steps preparation successively,
A, hydroxyethyl cellulose aqueous solution is put in the kneader;
B, unlatching kneader stir, and add high elastic aqueous polyurethane;
C, mix after, slowly add while stirring acrylic ester emulsion and film coalescence aid;
D, rear adding modified inorganic resin stirs;
E, order progressively adds natural colorful jade powder, borosilicate unorganic glass scale, modified aluminium hydroxide, talcum powder, natural colorful mica or combined mica titanium, mould inhibitor, oxidation inhibitor in proportion; Wherein, employed borosilicate unorganic glass scale is through following pre-treatment: first scale was cleaned 30 minutes in 70 ℃, 5% NaOH solution, to PH=7-8, then oven dry, stand-by under 90 ℃ after in 10%-20% titanate coupling agent gasoline solution, soaked 30 minutes under the room temperature, filtering; Employed modified aluminium hydroxide can adopt commercially available active aluminium hydroxide product, commercially available active aluminium hydroxide namely forms through surface actives such as titanic acid ester or silane coupling agents, has good flame retardant resistance, also can obtain by oneself according to certain proportioning: place kneader device to stir in aluminium hydroxide, to join in the aluminium hydroxide powder with the spray form as one of silane-titanate, sodium stearate or aluminate coupling agent of properties-correcting agent, after fully mixing, dried for standby.
F, when solid-liquid in the kneader mediate fully evenly and viscosity qualified after, regulate pH value to 8-9 with the AMP-95 functional agent, continue to stir and mediated 15 minutes, sieve, discharging is finished product.
Existing " expansion polyphenyl plate thinly plastered external insulation system of outer wall ", distinct issues are originally experience irreversible changes behind the stress of the adaptability of protection crack-resistant layer and facing layer material and object condition and system, not bery mate.Therefore, crack problem, seepage problem, the problem that comes off, fire safety problem and work-ing life problem, just come one after another.The function of how to help to address these problems for the liquid jade has just become liquid jade product development crucial.
Being conceived to change the original fragility of material, reducing material to the susceptibility of power, is to improve the flexible Basic Ways of liquid jade material.
It is a kind of method that generally adopts both at home and abroad that fiber increases gentle.The fiber that the liquid jade uses is the higher hydroxyl organic fibre of toughness (can also adopt the protofibril binding structure fiber of natural cellulose), by the fibrous bundle internal friction, provides an effective crackle to stop the stress intensity of chance and reduction crack tip.Gentle can also the increasing by the toughness reinforcing method of micelle accumulation of energy or molecular bridge that increase of material softens to realize.
Acrylic ester emulsion+high elastic aqueous polyurethane+inorganic resin, and be aided with Natvosol (U.S. connection carbon ER30000) aqueous solution and the mould inhibitor of 1.5%-2%, oxidation inhibitor (phosphorous acid ester), glitter, the heterocomplex emulsion that photostabilizer etc. consist of, filmogen for the liquid jade, such heterocomplex glue can be excellent, inferior position is complementary, broken through the in the past set pattern of one matter film forming, both brought into play the high-weatherability of inorganic materials, brought into play again the high ductibility of organic materials, process preferably cohesive strength and shock strength, guaranteed high pliable and tough anti crack performance and water repelling property.
The borosilicate unorganic glass scale that the present invention is used: thickness is 2-5 μ m, and sheet directly is that 80,120,160,200 orders are multiple.This unorganic glass scale has inertia, and is nontoxic, heat-resisting, do not fire, can be overlapping in coating, tile, align, form unique shielding construction.Have extremely good anti-medium osmosis, good wear resistance, shrinking percentage is little during curing, and thermal expansivity is little, and the cataclysm of heatproof degree is good.If a certain amount of and certain thickness is arranged in filming, the disposable application of liquid jade can be weather-proof more than 25 years and do not need scheduled maintenance.Yet any material is not out of this world, and is because glass flake is a kind of surface mass of high polarity, easily contaminated.In order to improve macromolecule resin to the wetting property of unorganic glass scale, reply unorganic glass scale is processed before using.
The combined mica titanium that the present invention is used: the auxiliary material of making liquid jade chromatogram.This product has high specific refractory power and opacifying power, nontoxic, heat-resisting, weather-proof and characteristics that chemical stability is good, can greatly improve visual appearance and work-ing life that the liquid jade is filmed.
The modified aluminium hydroxide (alumina trihydrate) that the present invention is used: the inorganic combustion inhibitor of making the liquid jade.Polymer glue powder in EPS plate in the heat-insulation system, XPS plate, plastic anchor, plastic-coated grid cloth, binding agent and the anti-fissuring agent, solvent based coating etc. all belong to combustiblematerials.Therefore need to improve the fire-proof function of liquid jade coating in heat-insulation system is used.The aluminium hydroxide product is nontoxic, non-volatile, do not separate out, low price, has good flame retardant resistance and smoke elimination function.But aluminium hydroxide is far from it on physical aspect and chemical structure as mineral filler and organic polymer, and both affinities are poor.In order to promote the intermiscibility of itself and organic polymer base-material, need to adopt the strong aluminum oxide of modification, or will carry out modification before using.
The natural colorful jade powder that the present invention is used, take sheet stone and fibrous stone as main, vitreous luster, the aobvious pearliness of cleavage surface is dumbfounded, is rich in soapy feeling, and good lubricity is arranged, and cleavage thin slice tool is flexible.Electrical isolation and resistance toheat are high, and refractoriness reaches 1400-1500 ℃; Acid-fast alkali-proof, shrinking percentage is low, and rate of expansion is little, and these all are choice criteria.
The talcum that the present invention is used: not only heat-resisting but also not heat conduction of talcum, refractoriness is up to 1490-1510 ℃, and is generally all inoperative with strong acid (sulfuric acid, nitric acid, hydrochloric acid) and highly basic (potassium hydroxide, sodium hydroxide).In 1% hexachloroethane that boils, only dissolve 2%-6%.Under 400 ℃ high temperature, mix with other materials, do not chemically react.The Ultrafine Grinding talcum powder, because its good dispersity, surface-area is large, is coated in body surface and can forms the uniform waterproof of one deck, weathering resistance film.The liquid jade mainly is because of its quality softness, good suspension, good rheological and non-thermal conductivity, fire line, but the multi-functional taste of Effective Raise liquid jade with talcum.
The natural colorful mica also has the luminance brightness of jade because of it in addition, and has the pure natural look, also as the auxiliary colorant of liquid jade, and excellent performance.
Liquid jade coating, be not only the safety guard person of insulating layer of external wall of building, but also expanded indoor and outdoor decorations, sculpture for city, artificial mountain stone, book word just scope and the intention space of selecting in industry and field such as draw a picture, can follow one's bent with the liquid jade at cement or gypsum, glass or mould the stationary body such as plate and make jade sculpture, takes landscape, concavo-convex jade word and the extremely strong animal and plant picture scroll of texture.
The further modification of liquid jade coating:
He expects or this material of minimizing 1-2 part to do masterbatch increase 1-2 part with liquid jade coating, just can be changed into another kind of high weather-proof new function coating: (1) increases silicate powder fiber or the organic paper reinforcement fiber 10%-15% below a kind of long 1.5mm in original formulation, and make thickening material with wilkinite, can spraying place decorative pattern obviously, the effect of high-quality " complex layer coating " that spot is larger and mellow and full, and sagging does not ftracture.Before dried coating film, curing, decorative pattern is without considerable change.(2) be coated with the mica titanium nacreous material of middle increase 4-15% at liquid jade face, be coated with the device bullet and be coated with finishing with rolling pad finishing or bullet, can be coated with out the effect of " cloud paint ", and can present pattern changeable: exterior wall is done marble, the grouan decoration; Interior wall can blue sky and white cloud, and flowers and plants grow thickly.(3) in liquid jade coating original formulation, increase that a kind of (this is a kind of material with very strong refractive power effect through twisting and terylene angel's hair behind 90 ℃ of heat-shapings, twisting can produce soft point reflection after processing, improve decorative effect) 5-10%, can form more high-quality different decors.Such as the quicksand type, the jade original shapes such as floating clouds type, flower rainfall pattern are filmed, and the texture of recovering one's original simplicity is stronger.This liquid jade coating can also carry out other various modifications as required.
Liquid jade coating of the present invention, coating test technical indicator are as shown in the table:
Test conditions is as follows: 1, test basis: JG/T24-2000; 2, test method: GB/T1865-2009; 3, assessment method: GB/T1766-2008
Claims (9)
1. full-service fluid jade coating, it is characterized in that: this liquid jade coating comprises following composition:
Hydroxyethyl cellulose aqueous solution 10-15 part;
Tackiness agent 24-36 part;
Natural colorful jade powder 56-65 part;
Borosilicate unorganic glass scale 3-5 part;
Inorganic combustion inhibitor 3-5 part;
Talcum powder 3-5 part;
0.5 part of natural colorful mica or combined mica titanium;
0.15 part of mould inhibitor;
0.15 part in oxidation inhibitor;
0.2 part of functional agent.
2. full-service fluid jade coating according to claim 1, it is characterized in that: described hydroxyethyl cellulose aqueous solution mass concentration is 1.5%-2%.
3. full-service fluid jade coating according to claim 1, it is characterized in that: described tackiness agent is the heterocomplex modified emulsion of particle diameter 5-10 nanometer, the acrylic ester emulsion that comprises 16-20 part, the modified inorganic resin of the high elastic aqueous polyurethane of 4-6 part and 4-10 part.
4. full-service fluid jade coating according to claim 3 is characterized in that: the solid content of described acrylic ester emulsion 〉=46%.
5. full-service fluid jade coating according to claim 1, it is characterized in that: the specification of described natural colorful jade powder is selected particle diameter 80-160 order.
6. full-service fluid jade coating according to claim 1 is characterized in that: the specification of borosilicate unorganic glass scale is selected sheet footpath 120-160 order, and thickness is 2-5 μ m.
7. full-service fluid jade coating according to claim 1, it is characterized in that: described inorganic combustion inhibitor is the modification oxygen aluminum oxide that has added any one material in silane-titanate, sodium stearate or the aluminate coupling agent.
8. according to claim 1 to the preparation method of the described full-service fluid jade of 7 any one claims coating, it is characterized in that: adopt successively the following steps preparation,
A, hydroxyethyl cellulose aqueous solution is put in the kneader;
B, unlatching kneader stir, and add high elastic aqueous polyurethane;
C, mix after, slowly add while stirring acrylic ester emulsion and film coalescence aid;
D, rear adding modified inorganic resin stirs;
E, order progressively adds natural colorful jade powder, borosilicate unorganic glass scale, modified aluminium hydroxide, talcum powder, natural colorful mica or combined mica titanium, mould inhibitor, oxidation inhibitor in proportion;
F, when solid-liquid in the kneader mediate fully evenly and viscosity qualified after, regulate pH value to 8-9 with functional agent, continue to stir and mediated 15 minutes, sieve, discharging is finished product.
9. the preparation method of full-service fluid jade coating according to claim 8, it is characterized in that: the borosilicate unorganic glass scale that uses in the described step e is through following pre-treatment: first scale was cleaned 30 minutes in 70 ℃, 5% NaOH solution, to PH=7-8, then oven dry, stand-by under 90 ℃ after in 10%-20% titanate coupling agent gasoline solution, soaked 30 minutes under the room temperature, filtering.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104058704A (en) * | 2014-05-29 | 2014-09-24 | 安徽华塑股份有限公司 | Antimicrobial impermeable concrete and preparation method thereof |
| CN105219198A (en) * | 2015-10-30 | 2016-01-06 | 广东筑龙涂料有限公司 | A kind of heat-insulating, fire-preventing stone-like coating |
| CN105860654A (en) * | 2016-05-06 | 2016-08-17 | 安徽雅美油墨有限公司 | Glass-flake-containing modified waterborne polyurethane printing ink and preparation method thereof |
| CN106752241A (en) * | 2016-12-06 | 2017-05-31 | 啄木鸟漆业集团有限公司 | A kind of anion jade putty |
| CN112251053A (en) * | 2020-10-27 | 2021-01-22 | 浙江优艺雅涂料有限公司 | Environment-friendly anti-carbonization coating |
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2011
- 2011-08-17 CN CN 201110235209 patent/CN102951871A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104058704A (en) * | 2014-05-29 | 2014-09-24 | 安徽华塑股份有限公司 | Antimicrobial impermeable concrete and preparation method thereof |
| CN104058704B (en) * | 2014-05-29 | 2016-03-23 | 安徽华塑股份有限公司 | A kind of antibacterial water-tight concrete and preparation method thereof |
| CN105219198A (en) * | 2015-10-30 | 2016-01-06 | 广东筑龙涂料有限公司 | A kind of heat-insulating, fire-preventing stone-like coating |
| CN105219198B (en) * | 2015-10-30 | 2017-12-12 | 广东筑龙涂料有限公司 | A kind of heat-insulating, fire-preventing stone-like coating |
| CN105860654A (en) * | 2016-05-06 | 2016-08-17 | 安徽雅美油墨有限公司 | Glass-flake-containing modified waterborne polyurethane printing ink and preparation method thereof |
| CN106752241A (en) * | 2016-12-06 | 2017-05-31 | 啄木鸟漆业集团有限公司 | A kind of anion jade putty |
| CN112251053A (en) * | 2020-10-27 | 2021-01-22 | 浙江优艺雅涂料有限公司 | Environment-friendly anti-carbonization coating |
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| PB01 | Publication | ||
| DD01 | Delivery of document by public notice |
Addressee: Shaanxi Hengyu Building Material Technology Co., Ltd. Document name: Notification of before Expiration of Request of Examination as to Substance |
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| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20130306 |