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CN106881339A - Pin-connected panel original position drip washing is electronic with EKG to cooperate with the device and method for removing heavy metal-polluted soil - Google Patents

Pin-connected panel original position drip washing is electronic with EKG to cooperate with the device and method for removing heavy metal-polluted soil Download PDF

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CN106881339A
CN106881339A CN201710096949.XA CN201710096949A CN106881339A CN 106881339 A CN106881339 A CN 106881339A CN 201710096949 A CN201710096949 A CN 201710096949A CN 106881339 A CN106881339 A CN 106881339A
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heavy metal
ekg
soil
polluted soil
ekg electrode
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CN106881339B (en
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李青云
汤显强
胡艳平
潘婵娟
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Bureau of Hydrology Changjiang Water Resources Commission
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C1/00Reclamation of contaminated soil
    • B09C1/02Extraction using liquids, e.g. washing, leaching, flotation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C1/00Reclamation of contaminated soil
    • B09C1/08Reclamation of contaminated soil chemically
    • B09C1/085Reclamation of contaminated soil chemically electrochemically, e.g. by electrokinetics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C2101/00In situ

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  • Life Sciences & Earth Sciences (AREA)
  • Soil Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

本发明公开了一种拼装式原位淋洗与EKG电动协同去除土壤重金属的装置,包括淋洗‑电动协同作业平台、安装于淋洗‑电动协同作业平台的用于插入土壤中的EKG电动去除模块、以及电源、淋洗液渗透装置、蠕动泵、土壤重金属溶液储存罐。所述EKG电动去除模块包括EKG电极固定板及固定于EKG电极固定板的EKG电极、土壤重金属溶液收集槽。EKG电极和蠕动泵与电源连接,重金属溶液抽提软管固定于EKG电极固定板,下端伸入土壤重金属溶液收集槽,上端通过蠕动泵后与土壤重金属溶液储存罐联通。本发明为可拼装式装置,无需开挖土壤,不用脱附电极,直接将淋洗液原位渗透到土壤污染层,利用电场作用,原位洗脱和迁移重金属,并将淋洗后的重金属溶液从土层分离储存,实现重金属的水土分离。

The invention discloses an assembled in-situ leaching and EKG electric cooperative removal device for soil heavy metals, comprising a leaching-electric cooperative operation platform, and an EKG electric removal device installed on the leaching-electric cooperative operation platform for inserting into the soil Module, and power supply, eluent penetration device, peristaltic pump, soil heavy metal solution storage tank. The EKG electric removal module includes an EKG electrode fixing plate, an EKG electrode fixed on the EKG electrode fixing plate, and a soil heavy metal solution collection tank. The EKG electrode and peristaltic pump are connected to the power supply, the heavy metal solution extraction hose is fixed on the EKG electrode fixing plate, the lower end extends into the soil heavy metal solution collection tank, and the upper end passes through the peristaltic pump and communicates with the soil heavy metal solution storage tank. The invention is an assembleable device, without excavating the soil, without using desorption electrodes, directly infiltrates the eluent into the soil pollution layer in situ, uses the electric field to elute and migrate heavy metals in situ, and removes the heavy metals after leaching The solution is separated and stored from the soil layer to realize the separation of heavy metals from water and soil.

Description

拼装式原位淋洗与EKG电动协同去除土壤重金属的装置及 方法A device for removing heavy metals from soil in combination with in-situ leaching and EKG electric synergy method

技术领域technical field

本发明涉及土壤环境保护与土壤重金属污染修复领域,具体是一种拼装式原位淋洗与EKG电动协同去除土壤重金属的装置及方法。The invention relates to the field of soil environmental protection and soil heavy metal pollution restoration, in particular to an assembled in-situ leaching and EKG electric synergistic device and method for removing soil heavy metals.

背景技术Background technique

随着工农业发展,土壤重金属污染问题日益凸显,对人民群众的生命健康造成了严重威胁。因而,亟需重金属污染土壤进行修复和治理。化学淋洗法是一种高效的重金属污染土壤修复方法,但对低渗透性土壤中重金属的去除效果不佳,且原位化学淋洗还存在淋洗液排放难的问题。电动修复是指在污染土壤通入低压直流电,利用电场作用将土壤污染物通过电迁移和电渗析逐步迁移分离,是一种绿色、高效和新型的原位修复技术,在低渗透性土壤污染修复方面具有独特优势。因此,若能将淋洗和电动修复进行优势互补,可大幅提高土壤重金属污染的修复效率。国内外目前关于重金属污染土壤淋洗与电动修复方面进行了较多的理论研究和一些工艺参数和方法探讨,但电动修复装置较少,特别是原位淋洗+电动修复的协同去除土壤重金属的装置更少。With the development of industry and agriculture, the problem of soil heavy metal pollution has become increasingly prominent, posing a serious threat to the lives and health of the people. Therefore, there is an urgent need for remediation and treatment of heavy metal-contaminated soils. Chemical leaching is an efficient method for the remediation of heavy metal-contaminated soils, but it is not effective in removing heavy metals in low-permeability soils, and in-situ chemical leaching also has the problem of difficult drainage of eluent. Electric remediation refers to the introduction of low-voltage direct current into polluted soil, and the use of electric field to gradually migrate and separate soil pollutants through electromigration and electrodialysis. It is a green, efficient and new in-situ remediation technology. has unique advantages. Therefore, if the advantages of leaching and electric remediation can be complemented, the remediation efficiency of soil heavy metal pollution can be greatly improved. At present, there have been many theoretical studies and discussions on some process parameters and methods on the leaching and electric restoration of heavy metal contaminated soil at home and abroad, but there are few electric restoration devices, especially the coordinated removal of heavy metals in soil by in-situ leaching + electric restoration. There are fewer devices.

发明专利“一种重金属污染土壤的淋洗电动联合修复装置和方法”(申请号:201510298674.9)公开了一种针对重金属污染土壤的异位修复(ex-situ)方法,该方法将重金属污染土壤挖出后,调节pH,然后把土壤放入淋洗槽中进行淋洗搅拌及固液分离,再将淋洗后的土壤转入电动修复室进行电动处理。The invention patent "A combined leaching electric repair device and method for heavy metal-contaminated soil" (application number: 201510298674.9) discloses an ex-situ repair method for heavy metal-contaminated soil. After leaving, adjust the pH, then put the soil into the leaching tank for leaching, stirring and solid-liquid separation, and then transfer the leached soil to the electric restoration room for electric treatment.

实用新型专利“一种电修复式土壤污染治理车”(专利号:201520782269.X)通过把污染土壤装入工程车,然后进行电动修复和电热修复,具有可移动性的优点,但也属于异位修复。The utility model patent "An Electric Restoration Type Soil Pollution Treatment Vehicle" (Patent No.: 201520782269.X) has the advantage of mobility by loading the polluted soil into the engineering vehicle and then performing electric restoration and electrothermal restoration. bit fixes.

实用新型专利“采用电动方法强化处理重金属污染土壤的淋洗装置”(专利号:201320357655.5)提供了一种电动修复与淋洗联用的异位修复(ex-situ)装置,将淋洗和电动修复放在同一圆形结构装置,装置外圈为阳极,圆中心处为阴极,重金属从阳极向阴极迁移,淋洗液通过管道从装置上方注入。The utility model patent "Leaching device for enhanced treatment of heavy metal-contaminated soil by electric method" (Patent No.: 201320357655.5) provides an ex-situ repair (ex-situ) device combining electric repair and leaching. The repair is placed in the same circular structure device. The outer ring of the device is the anode, and the center of the circle is the cathode. Heavy metals migrate from the anode to the cathode, and the eluent is injected from the top of the device through the pipeline.

实用新型专利“一种移动式场地污染土壤的原位电动修复工程装置”(专利号:201520899695.1),该装置的电极为中空的圆形电极组,电极材料为铁、钛、不锈钢或者石墨电极,电极中空腔体中的重金属溶液经抽提,进入过滤柱、氧化柱和吸附柱等,装置为可拆除的组装式设计,具有良好移动性。Utility model patent "In-situ Electric Remediation Engineering Device for Mobile Site Contaminated Soil" (Patent No.: 201520899695.1), the electrode of the device is a hollow circular electrode group, and the electrode material is iron, titanium, stainless steel or graphite electrodes. The heavy metal solution in the electrode hollow cavity is extracted and enters the filter column, oxidation column and adsorption column, etc. The device is a detachable assembly design with good mobility.

本发明人在实现本发明的过程中发现,现有的淋洗+电动修复装置不多,且主要存在如下不足:(1)现有电动修复装置较少考虑污染土壤的现场条件,缺乏可拼装性,适用性较差;(2)原位处理装置,大多数电动修复装置为异位处理装置,土壤挖掘成本高;(3)并不多见的原位土壤电动修复(in-situ)装置采用的电极多是圆形中空电极,电极材料主要是铁、钛、不锈钢或者石墨电极,现场覆盖面小,修复效率低,电极耐酸碱腐蚀性差、不易安装;(4)原位土壤电动修复过程中,侧重将土壤重金属离子在电极上吸附与富集,然后再对电极进行洗脱分离,操作步骤多,分离效率低。The inventor found in the process of realizing the present invention that there are not many existing rinsing+electric restoration devices, and there are mainly the following deficiencies: (1) The existing electric restoration devices seldom consider the field conditions of polluted soil, and lack the ability to assemble (2) In-situ treatment devices, most electric repair devices are ex-situ treatment devices, and the cost of soil excavation is high; (3) Rare in-situ soil electric repair (in-situ) devices Most of the electrodes used are circular hollow electrodes, and the electrode materials are mainly iron, titanium, stainless steel or graphite electrodes. The site coverage is small, the repair efficiency is low, the electrodes have poor acid and alkali corrosion resistance, and are not easy to install; (4) In-situ soil electric repair process In this method, the heavy metal ions in the soil are adsorbed and enriched on the electrode, and then the electrode is eluted and separated. There are many operating steps and the separation efficiency is low.

发明内容Contents of the invention

针对上述问题,本发明采用兼具导水和导电性能的电动土工合成材料(EKG)为电极,利用EKG电极的电渗脱水和电迁移作用,提出了一种拼装式原位淋洗与EKG电动协同去除土壤重金属的装置及方法,该装置为模块化可拼装式装置,无需开挖土壤,不用脱附电极,直接将淋洗液原位渗透到土壤污染层,利用电场作用,原位洗脱和迁移重金属,并将淋洗后的重金属溶液从土层分离储存,实现重金属的水土分离,该装置安装方便,重金属去除效率高,可批量和规模化应用,尤其适用于重金属污染底泥或农田土壤修复。In view of the above problems, the present invention uses electrokinetic geosynthetics (EKG) with both water-conducting and conductive properties as electrodes, and utilizes the electroosmotic dehydration and electromigration of EKG electrodes to propose an assembled in-situ leaching and EKG electrokinetic A device and method for synergistically removing heavy metals from soil. The device is a modular and assembleable device. It does not need to excavate the soil, and does not need a desorption electrode. It directly infiltrates the eluent into the soil pollution layer in situ, and uses the electric field to elute in situ and transfer heavy metals, and separate and store the heavy metal solution after leaching from the soil layer to realize the separation of heavy metals from water and soil. The device is easy to install, has high removal efficiency of heavy metals, and can be applied in batches and large scale, especially suitable for heavy metal contaminated sediment or farmland soil remediation.

一种拼装式原位淋洗与EKG电动协同去除土壤重金属的装置,包括淋洗-电动协同作业平台、安装于淋洗-电动协同作业平台的用于插入土壤中的EKG电动去除模块、以及电源、淋洗液渗透装置、蠕动泵、土壤重金属溶液储存罐,所述EKG电动去除模块包括EKG电极固定板及固定于EKG电极固定板的EKG电极、土壤重金属溶液收集槽,EKG电极和蠕动泵与电源连接,重金属溶液抽提软管固定于EKG电极固定板,下端伸入土壤重金属溶液收集槽,上端通过蠕动泵后与土壤重金属溶液储存罐联通,淋洗液渗透装置用于将淋洗液分散进入土壤,EKG电极上形成有导水槽,用于将EKG电极通电后淋洗出的土壤重金属离子导入土壤重金属溶液收集槽,蠕动泵用于将土壤重金属溶液从土壤重金属溶液收集槽抽入淋洗-电动协同作业平台上的土壤重金属溶液储存罐。An assembled in-situ leaching and EKG electric cooperative removal device for soil heavy metals, including a leaching-electric cooperative operation platform, an EKG electric removal module installed on the leaching-electric cooperative operation platform for inserting into the soil, and a power supply , eluent penetration device, peristaltic pump, soil heavy metal solution storage tank, the EKG electric removal module includes EKG electrode fixed plate and EKG electrode fixed on the EKG electrode fixed plate, soil heavy metal solution collection tank, EKG electrode and peristaltic pump and Power connection, the heavy metal solution extraction hose is fixed on the EKG electrode fixing plate, the lower end extends into the soil heavy metal solution collection tank, the upper end passes through the peristaltic pump and communicates with the soil heavy metal solution storage tank, and the eluent penetration device is used to disperse the eluent Into the soil, a water guide groove is formed on the EKG electrode, which is used to guide the soil heavy metal ions leached out after the EKG electrode is energized into the soil heavy metal solution collection tank, and the peristaltic pump is used to pump the soil heavy metal solution from the soil heavy metal solution collection tank into the leaching - Soil heavy metal solution storage tank on the electric cooperative operation platform.

进一步的,所述EKG电动去除模块还包括EKG电极保护板,EKG电极保护板与EKG电极之间间隔一定间距,EKG电极保护板后拔出可最大限度避免土壤颗粒堵塞EKG电极导水槽。进一步的,Further, the EKG electric removal module also includes an EKG electrode protection plate, and there is a certain distance between the EKG electrode protection plate and the EKG electrodes. Pulling out the EKG electrode protection plate can prevent soil particles from clogging the EKG electrode water guide groove to the greatest extent. further,

进一步的,所述EKG电动去除模块还包括安装于EKG电极固定板上的液位计,液位计的下端伸入土壤重金属溶液收集槽中,用于实时监测土壤重金属溶液收集槽的液面高度,当液面高度增长缓慢或不变后,启动蠕动泵将土壤重金属溶液从土壤重金属溶液收集槽抽入淋洗-电动协同作业平台上的土壤重金属溶液储存罐。Further, the EKG electric removal module also includes a liquid level gauge installed on the EKG electrode fixing plate, and the lower end of the liquid level gauge extends into the soil heavy metal solution collection tank for real-time monitoring of the liquid level of the soil heavy metal solution collection tank , when the liquid level increases slowly or remains unchanged, start the peristaltic pump to pump the soil heavy metal solution from the soil heavy metal solution collection tank into the soil heavy metal solution storage tank on the leaching-electric cooperative operation platform.

进一步的,所述淋洗液渗透装置包括淋洗液储存槽和与淋洗液储存槽联通且竖直设于淋洗液储存槽下方的带孔渗透柱,带孔渗透柱的长度与土壤污染层厚度相同,淋洗液加入到淋洗液储液槽后,经带孔渗透柱分散进入土壤污染层。Further, the eluent permeation device includes a eluent storage tank and a perforated permeable column connected with the eluent storage tank and vertically arranged below the eluent storage tank, the length of the perforated permeable column is related to the soil pollution The thickness of the layer is the same. After the eluent is added to the eluent storage tank, it is dispersed into the soil pollution layer through the perforated permeable column.

进一步的,EKG电极固定板和EKG电极保护板插接固定在土壤重金属溶液收集槽上部。Further, the EKG electrode fixing plate and the EKG electrode protection plate are plugged and fixed on the upper part of the soil heavy metal solution collection tank.

进一步的,土壤重金属溶液收集槽上部设有EKG电极固定板卡槽和EKG电极保护板卡槽,EKG电极固定板和EKG电极保护板分别插接在EKG电极固定板卡槽和EKG电极保护板卡槽中。Further, the upper part of the soil heavy metal solution collection tank is provided with an EKG electrode fixing plate slot and an EKG electrode protection plate slot, and the EKG electrode fixing plate and the EKG electrode protection plate are plugged into the EKG electrode fixing plate slot and the EKG electrode protection plate respectively. in the slot.

进一步的,土壤重金属溶液收集槽内设有可容纳重金属溶液的中空腔体。Further, the soil heavy metal solution collection tank is provided with a hollow cavity that can accommodate the heavy metal solution.

进一步的,EKG电极固定板和土壤重金属溶液收集槽上端分别设有EKG电极固定板预留孔和重金属溶液收集槽预留孔,用于放置液位计和重金属溶液抽提软管,重金属溶液抽提软管和液位计下端从金属溶液收集槽预留孔伸入中空腔体中。Further, the upper ends of the EKG electrode fixing plate and the soil heavy metal solution collection tank are respectively provided with reserved holes for the EKG electrode fixing plate and the heavy metal solution collection tank, which are used to place the liquid level gauge and the heavy metal solution extraction hose, and the heavy metal solution extraction hose. The lifting hose and the lower end of the liquid level gauge extend into the hollow cavity from the reserved hole of the metal solution collection tank.

进一步的,所述EKG电极包括导电铜线、EKG电极导电材料、包裹EKG导电材料的土工布、EKG电极导水槽,EKG电极导电材料表面形成由上至下的EKG电极导水槽。Further, the EKG electrode includes a conductive copper wire, an EKG electrode conductive material, a geotextile wrapped with the EKG conductive material, and an EKG electrode water guide groove, and an EKG electrode water guide groove is formed on the surface of the EKG electrode conductive material from top to bottom.

一种原位淋洗与EKG电动协同去除土壤重金属的方法,其特征在于使用上述装置进行,所述方法包括如下步骤:A method for in-situ leaching and EKG electric synergistic removal of heavy metals in soil is characterized in that the above-mentioned device is used to carry out, and the method comprises the following steps:

原位淋洗与EKG电动协同去除启动:在淋洗液渗透装置中添加淋洗液,淋洗液通过淋洗液渗透装置的淋洗液渗透柱分散进入土壤,渗透柱长度与土壤耕作层厚度相同,EKG电极接通直流稳压电源,在EKG电场作用下,淋洗液对重金属污染土壤进行原位淋洗,洗脱出的重金属离子与土壤孔隙水,在电迁移和电渗析的作用下向EKG电动去除模块的EKG电极迁移;Start-up of in-situ leaching and EKG electric cooperative removal: Add eluent to the eluent penetration device, and the eluent will disperse into the soil through the eluent penetration column of the eluent penetration device. The length of the penetration column is related to the thickness of the soil cultivation layer Similarly, the EKG electrode is connected to a DC regulated power supply, and under the action of the EKG electric field, the eluent performs in-situ leaching on the heavy metal-contaminated soil, and the eluted heavy metal ions and soil pore water, under the action of electromigration and electrodialysis Migration to the EKG electrode of the EKG electrokinetic removal module;

土壤重金属分离与去除:迁移到EKG电极表面的重金属溶液在重力作用下沿着EKG电极导水槽经土壤重金属溶液导流槽流到EKG电动去除模块的土壤重金属溶液收集槽,液位计实时监测土壤重金属溶液收集槽的液面高度,及时启动蠕动泵将重金属溶液从土壤重金属溶液收集槽抽入淋洗-电动协同作业平台上的土壤重金属溶液收集罐,达到重金属水-土分离与原位去除的目的;Separation and removal of heavy metals in soil: The heavy metal solution migrated to the surface of the EKG electrode flows along the EKG electrode water guide channel through the soil heavy metal solution guide channel to the soil heavy metal solution collection tank of the EKG electric removal module under the action of gravity, and the liquid level gauge monitors the soil in real time The liquid level height of the heavy metal solution collection tank, start the peristaltic pump in time to pump the heavy metal solution from the soil heavy metal solution collection tank into the soil heavy metal solution collection tank on the leaching-electric cooperative operation platform, to achieve the separation and in-situ removal of heavy metals Purpose;

及时采集土壤重金属溶液收集槽抽提出来溶液的目标重金属浓度,并测定受处理土壤目标重金属含量,当土壤重金属含量达标或土壤重金属溶液收集槽抽提溶液目标重金属浓度较低时,即可结束处理。Timely collect the target heavy metal concentration of the solution extracted from the soil heavy metal solution collection tank, and measure the target heavy metal content of the treated soil. When the soil heavy metal content reaches the standard or the target heavy metal concentration of the soil heavy metal solution collection tank is low, the treatment can be ended .

本发明的有益效果和显著技术进步如下:Beneficial effect of the present invention and significant technical progress are as follows:

1、模块化设计电动修复装置,可组装式布置淋洗与电动修复,一体化考虑重金属污染土壤淋洗,土壤内淋洗出重金属溶液收集,土壤淋洗出重金属溶液分离等过程,实现了土壤重金属的原位淋洗和水-土分离,最大限度将淋洗出的重金属移除土壤,修复周期短,见效快。1. Modular design of electric repair device, which can be assembled and arranged for leaching and electric repair, integrated consideration of heavy metal contaminated soil leaching, collection of heavy metal solution from leaching in soil, separation of heavy metal solution from soil leaching, etc., realizing soil The in-situ leaching and water-soil separation of heavy metals can remove the leached heavy metals from the soil to the greatest extent, and the repair period is short and the effect is quick.

2、采用具有导水和导电作用的EKG作为电极,并设计了三层结构的可插拔卡槽式EKG电动去除模块,便利EKG电极的现场安装及工程应用。利用EKG电极固定板镶嵌安装EKG电极,确保EKG电极平整及与污染层土壤的全面接触,通过EKG电极保护板防止土壤颗粒堵塞EKG导水槽,最大限度发挥EKG电渗脱水和电迁移去除重金属性能。2. EKG with water conduction and conduction functions is used as the electrode, and a pluggable slot-type EKG electric removal module with a three-layer structure is designed to facilitate the on-site installation and engineering application of the EKG electrode. Use the EKG electrode fixing plate to inlay and install the EKG electrode to ensure that the EKG electrode is flat and in full contact with the soil in the polluted layer. The EKG electrode protection plate is used to prevent soil particles from clogging the EKG water guide groove, and to maximize the performance of EKG electroosmotic dehydration and electromigration to remove heavy metals.

3、淋洗-电动协同作业平台上搭载了淋洗液渗透装置,设计了淋洗液补加和高效分散等功能,淋洗液渗透装置在宽度上与EKG电极相同,淋洗液渗透装置的渗透柱在长度上与污染层土壤深度上相同,这样能够使淋洗液在EKG电场驱动作用下,全方位充分接触土壤污染层,提高重金属污染土壤的淋洗效率。3. The eluent penetration device is equipped on the leaching-electric cooperative operation platform, and functions such as eluent replenishment and high-efficiency dispersion are designed. The width of the eluent penetration device is the same as that of the EKG electrode. The length of the permeation column is the same as the soil depth of the polluted layer, so that the eluent can fully contact the soil polluted layer in all directions under the drive of the EKG electric field, and the leaching efficiency of the heavy metal polluted soil can be improved.

4、EKG电动去除模块设计了土壤重金属溶液收集槽,并在EKG电极固定板内留置了液位计与重金属溶液抽提软管,能够快速收集、监测和排出EKG电动去除模块的重金属溶液,将液位计与重金属溶液抽提软管和EKG电动去除模块耦合,装置结构紧凑、功能齐全、空间利用效率高。4. The EKG electric removal module is designed with a soil heavy metal solution collection tank, and a liquid level gauge and a heavy metal solution extraction hose are left in the EKG electrode fixing plate, which can quickly collect, monitor and discharge the heavy metal solution of the EKG electric removal module. The liquid level gauge is coupled with the heavy metal solution extraction hose and the EKG electric removal module. The device has compact structure, complete functions and high space utilization efficiency.

5、EKG电动去除模块与淋洗-电动协同作业平台为拼装式设计,安装简便快速,可批量生产,且可根据现场需求进行多个EKG电动去除模块的拼接,具备规模化应用基础。5. The EKG electric removal module and the rinsing-electric cooperative operation platform are assembled design, which is easy and fast to install, and can be mass-produced. Multiple EKG electric removal modules can be spliced according to site requirements, which has the basis for large-scale application.

附图说明Description of drawings

图1为本发明拼装式原位淋洗与EKG电动协同去除土壤重金属的装置的结构示意图;Fig. 1 is a structural schematic diagram of the device for removing heavy metals in soil in combination with assembled in-situ leaching and EKG electric operation in accordance with the present invention;

图2为图1中A-A断面剖视图;Fig. 2 is A-A sectional view in Fig. 1;

图3为图1中B-B断面剖视图;Fig. 3 is B-B sectional view in Fig. 1;

图4为本发明中EKG电极的结构示意图;Fig. 4 is the structural representation of EKG electrode among the present invention;

图5为本发明中淋洗液渗透装置的剖视图。Fig. 5 is a cross-sectional view of the eluent permeation device in the present invention.

图中:1-EKG电动去除模块,2-电线,3-淋洗-电动协同作业平台,4-直流稳压电源,5-土壤重金属溶液收集罐,6-土壤重金属溶液转移软管,7-蠕动泵,8-淋洗液渗透装置,9-EKG电极固定板,10-EKG电极(10-1-导电铜线,10-2-包裹EKG导电材料的土工布,10-3-EKG电极导水槽,10-4-EKG电极导电材料),11-EKG-电极保护板,12-中空腔体,13-EKG电极固定板卡槽,14-EKG电极保护板卡槽,15-土壤重金属溶液导流槽,16-土壤重金属溶液抽提软管,17-EKG电极固定板预留孔,18-重金属溶液收集槽预留孔,19-土壤重金属溶液收集槽,20-液位计,21-淋洗液渗透柱,22-垫圈,23-固定螺钉,24-淋洗液储存槽,25-淋洗液添加口。In the figure: 1-EKG electric removal module, 2-wire, 3-washing-electric cooperative operation platform, 4-DC stabilized power supply, 5-soil heavy metal solution collection tank, 6-soil heavy metal solution transfer hose, 7- Peristaltic pump, 8-eluent penetration device, 9-EKG electrode fixing plate, 10-EKG electrode (10-1-conductive copper wire, 10-2-geotextile wrapped EKG conductive material, 10-3-EKG electrode conductor Sink, 10-4-EKG electrode conductive material), 11-EKG-electrode protection plate, 12-hollow cavity, 13-EKG electrode fixing plate slot, 14-EKG electrode protection plate slot, 15-soil heavy metal solution guide Launder, 16-soil heavy metal solution extraction hose, 17-EKG electrode fixed plate reserved hole, 18-reserved hole for heavy metal solution collection tank, 19-soil heavy metal solution collection tank, 20-liquid level gauge, 21-shower Eluent permeation column, 22-washer, 23-fixing screw, 24-eluent storage tank, 25-eluent adding port.

具体实施方式detailed description

下面将结合本发明中的附图,对本发明中的技术方案进行清楚、完整地描述。The technical solutions in the present invention will be clearly and completely described below in conjunction with the accompanying drawings in the present invention.

图1所示为本发明拼装式原位淋洗与EKG电动协同去除土壤重金属的装置的结构示意图,所述拼装式原位淋洗与EKG电动协同去除土壤重金属的装置包括两个相对设置的EKG电动去除模块1及一个淋洗-电动协同作业平台3。淋洗-电动协同作业平台3上搭载有直流稳压电源4、淋洗液渗透装置8、蠕动泵7、重金属溶液抽提软管6和土壤重金属溶液储存罐5。Figure 1 is a schematic structural view of the device for the combined in-situ leaching and EKG electric cooperative removal of heavy metals in soil according to the present invention. Electric removal module 1 and a rinsing-electric cooperative operation platform 3. The leaching-electric collaborative operation platform 3 is equipped with a DC stabilized power supply 4 , a leaching solution penetration device 8 , a peristaltic pump 7 , a heavy metal solution extraction hose 6 and a soil heavy metal solution storage tank 5 .

请结合参考图2和图3,所述EKG电动去除模块1包括EKG电极固定板9、EKG电极10、EKG电极保护板11、液位计20和土壤重金属溶液收集槽19。Please refer to FIG. 2 and FIG. 3 , the EKG electrodynamic removal module 1 includes an EKG electrode fixing plate 9 , an EKG electrode 10 , an EKG electrode protection plate 11 , a liquid level gauge 20 and a soil heavy metal solution collection tank 19 .

淋洗液渗透装置8,与EKG近似等宽地安装在淋洗-电动协同作业平台3上,淋洗液渗透装置8和淋洗-电动协同作业平台3之间用垫圈22密封并用螺钉23拧紧,防止淋洗液溢流到淋洗-电动协同作业平台。The eluent permeation device 8 is installed on the eluent-electric cooperative operation platform 3 approximately as wide as the EKG, and the space between the eluent permeation device 8 and the eluent-electric cooperative operation platform 3 is sealed with a gasket 22 and tightened with screws 23 , to prevent the eluent from overflowing to the eluent-electric cooperative operation platform.

如图5所示,淋洗液渗透装置8包括淋洗液储存槽24和与淋洗液储存槽24联通且竖直设于淋洗液储存槽24下方的带孔渗透柱21,带孔渗透柱21的长度与土壤污染层厚度相同,淋洗液加入到淋洗液储液槽24后,经带孔渗透柱21分散进入土壤污染层。As shown in FIG. 5 , the eluent permeation device 8 includes a eluent storage tank 24 and a perforated permeation column 21 that communicates with the eluent storage tank 24 and is vertically arranged below the eluent storage tank 24 . The length of the column 21 is the same as the thickness of the soil contamination layer. After the eluent is added to the eluent liquid storage tank 24, it is dispersed into the soil contamination layer through the perforated permeation column 21.

土壤重金属溶液收集槽19内设有中空腔体12,EKG电极固定板9和EKG电极保护板11插接在土壤重金属溶液收集槽19上部,如图3所示,土壤重金属溶液收集槽19上部设有EKG电极固定板卡槽13和EKG电极保护板卡槽14,EKG电极固定板9和EKG电极保护板11分别插接在EKG电极固定板卡槽13和EKG电极保护板卡槽14中。EKG电极固定板9的卡槽13还可防止抽提重金属溶液时土壤颗粒进入重金属溶液收集槽的中空腔体12。The soil heavy metal solution collection tank 19 is provided with a hollow cavity 12, and the EKG electrode fixing plate 9 and the EKG electrode protection plate 11 are plugged in the soil heavy metal solution collection tank 19 top, as shown in Figure 3, the soil heavy metal solution collection tank 19 tops are provided with There are EKG electrode fixing plate slot 13 and EKG electrode protection plate slot 14, EKG electrode fixing plate 9 and EKG electrode protection plate 11 are plugged into EKG electrode fixing plate slot 13 and EKG electrode protection plate slot 14 respectively. The slot 13 of the EKG electrode fixing plate 9 can also prevent soil particles from entering the hollow cavity 12 of the heavy metal solution collection tank when the heavy metal solution is extracted.

EKG电极固定板9与EKG电极10固定,例如EKG电极10可用膨胀铆钉并排固定在EKG固定板9上,EKG电极10用电线串联后分别与直流稳压电源4的正负极连接。The EKG electrode fixing plate 9 is fixed with the EKG electrode 10. For example, the EKG electrode 10 can be fixed side by side on the EKG fixing plate 9 with expansion rivets.

为保证EKG电极10平整及与土壤剖面全方位接触,EKG电极保护板11与EKG电极10之间有一定间距,用于拔出EKG电极保护板11后,最大限度避免土壤颗粒堵塞EKG电极导水槽10-3。In order to ensure that the EKG electrode 10 is flat and in all-round contact with the soil profile, there is a certain distance between the EKG electrode protection plate 11 and the EKG electrode 10, which is used to prevent soil particles from clogging the EKG electrode water guide groove to the greatest extent after the EKG electrode protection plate 11 is pulled out 10-3.

EKG电极固定板9和土壤重金属溶液收集槽19上端分别设有EKG电极固定板预留孔17和重金属溶液收集槽预留孔18,用于放置液位计20和重金属溶液抽提软管16。重金属溶液抽提软管16和液位计20可贯穿设于EKG电极固定板9中,下端从金属溶液收集槽预留孔18伸入中空腔体12中。The upper ends of the EKG electrode fixing plate 9 and the soil heavy metal solution collection tank 19 are respectively provided with a reserved hole 17 for the EKG electrode fixing plate and a reserved hole 18 for the heavy metal solution collection tank for placing the liquid level gauge 20 and the heavy metal solution extraction hose 16. The heavy metal solution extraction hose 16 and the liquid level gauge 20 can pass through the EKG electrode fixing plate 9, and the lower end extends into the hollow cavity 12 from the reserved hole 18 of the metal solution collection tank.

如图4所示,所述EKG电极10包括导电铜线10-1、EKG电极导电材料10-4、包裹EKG导电材料10-4的土工布10-2、EKG电极导水槽10-3,EKG电极导电材料10-4表面形成由上至下的EKG电极导水槽10-3。As shown in Figure 4, the EKG electrode 10 includes a conductive copper wire 10-1, an EKG electrode conductive material 10-4, a geotextile 10-2 wrapping the EKG conductive material 10-4, an EKG electrode water guide groove 10-3, and an EKG electrode conductive material 10-4. The surface of the electrode conductive material 10-4 forms an EKG electrode water guide groove 10-3 from top to bottom.

2个EKG电动去除模块1与淋洗-电动协同作业平台3通过卡槽拼装,接通直流稳压电源4,土壤孔隙水与淋洗出的土壤重金属离子即可在电场作用下,逐步迁移到EKG电极10的导水槽10-3,并在重力作用下进入土壤重金属溶液收集槽19。Two EKG electric removal modules 1 and the leaching-electric cooperative operation platform 3 are assembled through the card slot, and the DC stabilized power supply 4 is connected, and the soil pore water and the soil heavy metal ions leached out can be gradually migrated to the The water guide tank 10-3 of the EKG electrode 10 enters the soil heavy metal solution collection tank 19 under the action of gravity.

液位计20安装在EKG固定板内,实时监测土壤重金属溶液收集槽的液面高度,当液面高度增长缓慢或不变后,启动蠕动泵7将土壤重金属溶液从土壤重金属溶液收集槽19抽入淋洗-电动协同作业平台3上的土壤重金属溶液储存罐5。The liquid level gauge 20 is installed in the EKG fixed plate to monitor the liquid level height of the soil heavy metal solution collection tank in real time. When the liquid level height increases slowly or remains unchanged, the peristaltic pump 7 is started to pump the soil heavy metal solution from the soil heavy metal solution collection tank 19. Enter the soil heavy metal solution storage tank 5 on the leaching-electric cooperative operation platform 3.

本实施例以重金属污染农田为对象,利用图1所示装置进行原位淋洗与EKG电动协同去除重金属的步骤如下:In this example, the farmland polluted by heavy metals is taken as the object, and the steps of in-situ leaching and EKG electric synergistic removal of heavy metals using the device shown in Figure 1 are as follows:

(1)重金属污染土壤现场调查。根据《土壤检测第1部分:土壤样品的采集、处理和贮存(NY/T 1121.1-2006)》采集重金属污染土壤样品,测定土壤pH值、有机质含量、含水率、土壤粒径组成等理化特性;土样经过预处理后,采用ICP-MS或AAS测定重金属含量,并确定要处理的目标重金属。(1) On-site investigation of heavy metal contaminated soil. Collect heavy metal contaminated soil samples according to "Soil Testing Part 1: Collection, Processing and Storage of Soil Samples (NY/T 1121.1-2006), and measure the physical and chemical properties of soil pH, organic matter content, moisture content, soil particle size composition, etc.; After the soil sample is pretreated, the heavy metal content is determined by ICP-MS or AAS, and the target heavy metal to be processed is determined.

(2)EKG电极10固定。用膨胀铆钉将EKG电极10固定在EKG电极固定板9上,根据需要将单块EKG电极10利用电线串联,拼接更大的EKG电极;(2) The EKG electrode 10 is fixed. Fix the EKG electrode 10 on the EKG electrode fixing plate 9 with expansion rivets, connect the single EKG electrodes 10 in series with wires as required, and splice larger EKG electrodes;

(3)组装EKG电动去除模块1。将EKG电极固定板9和EKG电极保护板11与土壤重金属溶液收集槽19利用卡槽(13、14)进行拼装,从EKG电极固定板9和土壤重金属溶液收集槽上端19的预留孔(17、18)插入重金属溶液抽提软管16和液位计20至土壤重金属溶液收集槽19的中空腔体12,然后将组装好的EKG电动去除模块1插入到重金属污染土壤中,拔出EKG电极保护板11;(3) Assemble the EKG electric removal module 1 . The EKG electrode fixing plate 9 and the EKG electrode protection plate 11 and the soil heavy metal solution collection tank 19 are assembled using the draw-in slots (13, 14), and the reserved holes (17 18) Insert the heavy metal solution extraction hose 16 and liquid level gauge 20 into the hollow cavity 12 of the soil heavy metal solution collection tank 19, then insert the assembled EKG electric removal module 1 into the heavy metal contaminated soil, and pull out the EKG electrode Protection plate 11;

(4)原位淋洗与EKG电动协同体系构建。利用卡槽将两个EKG电动去除模块1安装于淋洗-电动协同作业平台3。两个EKG电动去除模块1的间距与直流稳压电源4的可供给电压和EKG电动修复的电压梯度有关。一般来说,电压梯度为2-4V/cm,EKG电动去除模块1间距不高于50cm。在淋洗-电动协同作业平台3上安装直流稳定电源4、淋洗液渗透装置8、蠕动泵7、土壤重金属溶液抽提软管6和土壤重金属溶液储液罐5;(4) Construction of in-situ elution and EKG electrokinetic coordination system. Two EKG electric removal modules 1 are installed on the rinsing-electric cooperative operation platform 3 by using the card slot. The distance between the two EKG electrodynamic removal modules 1 is related to the available voltage of the DC stabilized power supply 4 and the voltage gradient of the EKG electrodynamic restoration. Generally speaking, the voltage gradient is 2-4V/cm, and the distance between EKG electric removal modules 1 is not higher than 50cm. Install a DC stable power supply 4, a eluent penetration device 8, a peristaltic pump 7, a soil heavy metal solution extraction hose 6 and a soil heavy metal solution storage tank 5 on the leaching-electric cooperative operation platform 3;

(5)原位淋洗与EKG电动协同去除启动。在淋洗液渗透装置8中添加淋洗液(如FeCl3和氯化钙),淋洗液通过淋洗液渗透装置8的淋洗液渗透柱21分散进入土壤,渗透柱长度与土壤耕作层厚度相同(约25cm),EKG电极10接通直流稳压电源4,在EKG电场作用下,淋洗液对重金属污染土壤进行原位淋洗,洗脱出的重金属离子与土壤孔隙水,在电迁移和电渗析的作用下向2个EKG电动去除模块1的EKG电极10迁移;(5) In situ leaching and EKG electrokinetic coordinated removal start. Add eluent (such as FeCl 3 and calcium chloride) in eluent permeation device 8, eluent is dispersed into soil by eluent permeation column 21 of eluent permeation device 8, and permeation column length and soil plowing layer The thickness is the same (about 25cm), the EKG electrode 10 is connected to the DC stabilized voltage power supply 4, and under the action of the EKG electric field, the eluent carries out in-situ elution to the heavy metal contaminated soil, and the heavy metal ions and soil pore water eluted are separated in the electric field. Migrate to the EKG electrodes 10 of the two EKG electrodynamic removal modules 1 under the action of migration and electrodialysis;

(6)土壤重金属分离与去除。迁移到EKG电极10表面的重金属溶液在重力作用下沿着EKG电极导水槽10-3经土壤重金属溶液导流槽15流到EKG电动去除模块1的土壤重金属溶液收集槽19,液位计20实时监测土壤重金属溶液收集槽19的液面高度,及时启动蠕动泵7将重金属溶液从土壤重金属溶液收集槽19抽入淋洗-电动协同作业平台3上的土壤重金属溶液收集罐5,达到重金属水-土分离与原位去除的目的。(6) Separation and removal of heavy metals in soil. The heavy metal solution migrated to the surface of the EKG electrode 10 flows to the soil heavy metal solution collection tank 19 of the EKG electric removal module 1 along the EKG electrode water guide channel 10-3 through the soil heavy metal solution guide channel 15 under the action of gravity, and the liquid level gauge 20 real-time Monitor the liquid level height of the soil heavy metal solution collection tank 19, and start the peristaltic pump 7 in time to draw the heavy metal solution from the soil heavy metal solution collection tank 19 into the soil heavy metal solution collection tank 5 on the soil heavy metal solution collection tank 3 for leaching-electric cooperative operation platform, to reach the heavy metal water- Soil separation and in situ removal purposes.

(7)及时采集土壤重金属溶液收集槽19抽提出来溶液的目标重金属浓度,并测定受处理土壤目标重金属含量,当土壤重金属含量达标或土壤重金属溶液收集槽19抽提溶液目标重金属浓度较低时,即可结束处理。(7) Collect the target heavy metal concentration of the solution extracted from the soil heavy metal solution collection tank 19 in time, and measure the target heavy metal content of the treated soil. When the soil heavy metal content reaches the standard or the soil heavy metal solution collection tank 19 extracts the solution target heavy metal concentration. , to end processing.

(8)现场应用时,可根据处理处理程度和时限要求,在同一区域原地多次处理或拼装后大面积快速处理。淋洗-电动协同作业平台3可利用交流电为直流稳压电源供电,当野外供电不便时,也可采用蓄电池替代直流稳压电源。(8) For on-site application, according to the processing degree and time limit requirements, it can be processed multiple times in the same area or quickly processed in a large area after assembly. The rinsing-electric cooperative operation platform 3 can use alternating current to supply power for the DC stabilized power supply, and when it is inconvenient to supply power in the field, batteries can also be used to replace the DC stabilized voltage power supply.

以上所述,仅为本发明的具体实施方式,但本发明的保护范围并不局限于此,任何属于本技术领域的技术人员在本发明揭露的技术范围内,可轻易想到的变化或替换,都应涵盖在本发明的保护范围之内。因此,本发明的保护范围应该以权利要求的保护范围为准。The above is only a specific embodiment of the present invention, but the scope of protection of the present invention is not limited thereto, any changes or substitutions that can be easily imagined by those skilled in the art within the technical scope disclosed in the present invention, All should be covered within the protection scope of the present invention. Therefore, the protection scope of the present invention should be determined by the protection scope of the claims.

Claims (10)

1. a kind of pin-connected panel original position drip washing is electronic with EKG cooperates with the device for removing heavy metal-polluted soil, it is characterised in that:Including drenching Wash-electronic work compound platform (3), be installed on drip washing-electronic work compound platform (3) for insert the EKG in soil electricity Dynamic removal module (1) and power supply, leacheate permeability apparatus (8), peristaltic pump (7), heavy metal-polluted soil solution storage tanks (5), institute The electronic removal modules (1) of EKG are stated including ekg electrode fixed plate (9) and the ekg electrode of ekg electrode fixed plate (9) is fixed on (10), heavy metal-polluted soil solution collecting tank (19), ekg electrode (10) and peristaltic pump (7) are connected with power supply, heavy metal solution extracting Flexible pipe (6) is fixed on ekg electrode fixed plate (9), and heavy metal-polluted soil solution collecting tank (19) is stretched into lower end, and upper end passes through peristaltic pump (7) afterwards with heavy metal-polluted soil solution storage tanks (5) UNICOM, leacheate permeability apparatus (8) for leacheate to be dispersed into soil, Guiding gutter (10-3) is formed with ekg electrode (10), for the soil heavy metal ion for going out drip washing after ekg electrode (10) energization Heavy metal-polluted soil solution collecting tank (19) is imported, peristaltic pump (7) is for heavy metal-polluted soil solution to be received from heavy metal-polluted soil solution Collection groove (19) is pumped into the heavy metal-polluted soil solution storage tanks (5) on drip washing-electronic work compound platform (3).
2. pin-connected panel original position drip washing as claimed in claim 1 is electronic with EKG cooperates with the device for removing heavy metal-polluted soil, its feature It is:The electronic removal modules (1) of EKG also include ekg electrode protection board (11), ekg electrode protection board (11) and ekg electrode (10) it is spaced in intervals between, ekg electrode protection board (11) is extracted afterwards can to greatest extent avoid soil particle from blocking ekg electrode Guiding gutter (10-3).
3. pin-connected panel original position drip washing as claimed in claim 1 is electronic with EKG cooperates with the device for removing heavy metal-polluted soil, its feature It is:The electronic removal modules (1) of EKG also include the liquid level gauge (20) being installed in ekg electrode fixed plate (9), liquid level gauge (20) lower end is stretched into heavy metal-polluted soil solution collecting tank (19), for the liquid of real-time monitoring heavy metal-polluted soil solution collecting tank Face highly, after liquid level increasess slowly or be constant, starts peristaltic pump (7) heavy metal-polluted soil solution is molten from heavy metal-polluted soil Liquid collecting tank (19) is pumped into the heavy metal-polluted soil solution storage tanks (5) on drip washing-electronic work compound platform (3).
4. pin-connected panel original position drip washing as claimed in claim 1 is electronic with EKG cooperates with the device for removing heavy metal-polluted soil, its feature It is:The leacheate permeability apparatus (8) including leacheate accumulator tank (24) and with leacheate accumulator tank (24) UNICOM and vertically Infiltration post (21) with holes below leacheate accumulator tank (24), the length and soil pollution thickness degree of infiltration post (21) with holes It is identical, after leacheate is added to leacheate reservoir (24), soil pollution layer is dispersed into through infiltration post (21) with holes.
5. pin-connected panel original position drip washing as claimed in claim 2 is electronic with EKG cooperates with the device for removing heavy metal-polluted soil, its feature It is:Ekg electrode fixed plate (9) and ekg electrode protection board (11) grafting are fixed on heavy metal-polluted soil solution collecting tank (19) Portion.
6. pin-connected panel original position drip washing as claimed in claim 5 is electronic with EKG cooperates with the device for removing heavy metal-polluted soil, its feature It is:Heavy metal-polluted soil solution collecting tank (19) top is provided with ekg electrode fixed plate draw-in groove (13) and ekg electrode protection board draw-in groove (14), ekg electrode fixed plate (9) and ekg electrode protection board (11) are plugged on ekg electrode fixed plate draw-in groove (13) and EKG respectively In electrode protection board groove (14).
7. pin-connected panel original position drip washing as claimed in claim 3 is electronic with EKG cooperates with the device for removing heavy metal-polluted soil, its feature It is:The hollow cavity (12) that can accommodate heavy metal solution is provided with heavy metal-polluted soil solution collecting tank (19).
8. pin-connected panel original position drip washing as claimed in claim 7 is electronic with EKG cooperates with the device for removing heavy metal-polluted soil, its feature It is:Ekg electrode fixed plate (9) and heavy metal-polluted soil solution collecting tank (19) upper end are respectively equipped with ekg electrode fixed plate and reserve Hole (17) and heavy metal solution collecting tank preformed hole (18), for placing liquid level gauge (20) and heavy metal solution extracting flexible pipe (16), heavy metal solution extracting flexible pipe (16) and liquid level gauge (20) lower end are stretched into hollow from metallic solution collecting tank preformed hole (18) In cavity (12).
9. pin-connected panel original position drip washing as claimed in claim 1 is electronic with EKG cooperates with the device for removing heavy metal-polluted soil, its feature It is:The ekg electrode (10) includes conductive copper wire (10-1), ekg electrode conductive material (10-4), parcel EKG conductive materials The geotextiles (10-2) of (10-4), ekg electrode guiding gutter (10-3), ekg electrode conductive material (10-4) surface are formed by up to Under ekg electrode guiding gutter (10-3).
10. a kind of drip washing in situ is electronic with EKG cooperates with the method for removing heavy metal-polluted soil, it is characterised in that usage right requirement 1- Device any one of 9 is carried out, and methods described comprises the following steps:
Drip washing in situ is electronic with EKG to cooperate with removal to start:The addition leacheate in leacheate permeability apparatus (8), leacheate passes through The leacheate of leacheate permeability apparatus (8) permeates post (21) and is dispersed into soil, permeates column length and plough horizon thickness phase Together, ekg electrode (10) connects D.C. regulated power supply (4), and under EKG electric field actions, leacheate heavy metal contaminated soil is carried out Drip washing in situ, the heavy metal ion for eluting and soil pore water, to the electronic removals of EKG in the presence of electromigration and electrodialysis Ekg electrode (10) migration of module (1);
Heavy metal-polluted soil is separated and removal:The heavy metal solution on ekg electrode (10) surface is moved under gravity along EKG Electrode guiding gutter (10-3) flows to the heavy metal-polluted soil of the electronic removal modules (1) of EKG through heavy metal-polluted soil solution guiding gutter (15) Solution collecting tank (19), the liquid level of liquid level gauge (20) real-time monitoring heavy metal-polluted soil solution collecting tank (19) starts in time From heavy metal-polluted soil solution collecting tank (19) be pumped on drip washing-electronic work compound platform (3) heavy metal solution by peristaltic pump (7) Heavy metal-polluted soil solution collecting tank (5), reach heavy metal water-soil and separate purpose with removal in situ;
Collection heavy metal-polluted soil solution collecting tank (19) in time extracts the target heavy metal concentration of solution, and measure is subject to processing Soil target content of beary metal, when heavy metal content in soil is up to standard or heavy metal-polluted soil solution collecting tank (19) extracted solution target When heavy metal concentration is relatively low, you can end is processed.
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