CN106834811A - A kind of high-strength corrosion-resisting aluminium alloy conductor and preparation method thereof - Google Patents
A kind of high-strength corrosion-resisting aluminium alloy conductor and preparation method thereof Download PDFInfo
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- CN106834811A CN106834811A CN201510876869.7A CN201510876869A CN106834811A CN 106834811 A CN106834811 A CN 106834811A CN 201510876869 A CN201510876869 A CN 201510876869A CN 106834811 A CN106834811 A CN 106834811A
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- aluminium alloy
- strength corrosion
- alloy conductor
- resisting aluminium
- resisting
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- 229910000838 Al alloy Inorganic materials 0.000 title claims abstract description 49
- 239000004020 conductor Substances 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title abstract description 5
- 229910052777 Praseodymium Inorganic materials 0.000 claims abstract description 20
- 229910052796 boron Inorganic materials 0.000 claims abstract description 20
- 229910052742 iron Inorganic materials 0.000 claims abstract description 20
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 19
- 239000000956 alloy Substances 0.000 claims abstract description 19
- 239000012535 impurity Substances 0.000 claims abstract description 19
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 19
- 229910052707 ruthenium Inorganic materials 0.000 claims abstract description 19
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 19
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000005266 casting Methods 0.000 claims description 14
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
- 239000004411 aluminium Substances 0.000 claims description 7
- 238000000137 annealing Methods 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 7
- 238000007872 degassing Methods 0.000 claims description 7
- 238000001192 hot extrusion Methods 0.000 claims description 7
- 230000006698 induction Effects 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 238000007670 refining Methods 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- 230000005540 biological transmission Effects 0.000 abstract description 7
- 238000005275 alloying Methods 0.000 abstract description 3
- 229910052761 rare earth metal Inorganic materials 0.000 abstract description 3
- 238000010276 construction Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 1
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Abstract
The invention discloses a kind of high-strength corrosion-resisting aluminium alloy conductor and preparation method thereof, the high-strength corrosion-resisting aluminium alloy conductor contains following element by mass percentage：0.05%~0.50%Pr, 0.5%~1.5%Fe, 0.005%~0.010%B, 0.03%~0.05%Mo, 0.02%~0.05%Si, 0.1%~0.2%Ru, balance of Al and inevitable impurity.The present invention is by adding rare earth element Pr, coordinate the performance of other alloying elements, make this alloy lead wire on the premise of with conductance higher, the mechanical property and decay resistance that optimize alloy lead wire of high degree disclosure satisfy that the demand of long-span electric transmission line.
Description
Technical field
The invention belongs to alloy lead wire preparing technical field, and in particular to a kind of high-strength corrosion-resisting aluminium alloy conductor and preparation method thereof.
Background technology
With the high speed development of Chinese national economy, the construction of power industry is presented the trend advanced by leaps and bounds, develop in terms of high-pressure trend, high capacity, long distance ionization and extend in the long-span electric transmission line built, the demand of transferring electricity from the west to the east, north and south supply mutually, on national network strategic plan and long-span electric transmission line can not have been met using only traditional wire.
In power industry, the transmission of wire has very big influence to power industry.The material and construction of wire determine the resistance sizes and electrical conductivity of wire.Larger resistance and relatively low electrical conductivity limits application of the wire in power industry, and resistance is excessive, and larger loss is had in power transmission, and the energy is wasted to a certain extent.
In addition, in actual production, the corrosion resistance of aluminium alloy conductor, tensile strength and conductance are conflict bodies, are want on the premise of improving the tensile strength of aluminum conductor and ensureing qualified conductance, preferably decay resistance is obtained, there certainly will be requirement higher to the alloy species and content that add.Therefore the more excellent matching for how obtaining mechanical property, decay resistance and electric conductivity is the main contents of the area research.
The content of the invention
The purpose of the present invention is to solve the shortcomings of the prior art, there is provided a kind of high-strength corrosion-resisting aluminium alloy conductor and preparation method thereof.The high-strength corrosion-resisting aluminium alloy conductor is by adding Rare Earth Elements of Praseodymium, coordinate the performance of other alloying elements, make this alloy lead wire on the premise of with conductance higher, the mechanical property and decay resistance that optimize alloy lead wire of high degree, disclosure satisfy that the demand of long-span electric transmission line.
To achieve these goals, present invention employs following technical scheme：
A kind of high-strength corrosion-resisting aluminium alloy conductor, contains following element by mass percentage：0.05%~0.50%Pr, 0.5%~1.5%Fe, 0.005%~0.010%B, 0.03%~0.05%Mo, 0.02%~0.05%Si, 0.1%~0.2%Ru, balance of Al and inevitable impurity.
Further preferred technical scheme：The high-strength corrosion-resisting aluminium alloy conductor is by mass percentage containing as follows：0.20%~0.50%Pr, 1.0%~1.5%Fe, 0.005%~0.010%B, 0.03%~0.04%Mo, 0.02%~0.04%Si, 0.1%~0.2%Ru, balance of Al and inevitable impurity.
Further preferred technical scheme：The high-strength corrosion-resisting aluminium alloy conductor is by mass percentage containing as follows：0.30%Pr, 1.5%Fe, 0.008%B, 0.04%Mo, 0.03%Si, 0.15%Ru, balance of Al and inevitable impurity.
A kind of method for preparing above-mentioned high-strength corrosion-resisting aluminium alloy conductor, comprises the following steps：
Step one, according to mass percent of each element in alloy lead wire finished product, weighs the simple substance or compound of each element respectively；
Step 2,99.7% technical pure aluminium ingot is put into after being melted in medium-frequency induction furnace, first addition element Pr, Fe, B, insulated and stirred, after stirring, adds elements Mo, Si, Ru, insulated and stirred, the removal of impurity, refining, degasification, slagging-off, stand more than 30 minutes, and temperature control is between 750 DEG C~800 DEG C；Period is analyzed and adjusts to composition in stove；
Step 3, uses conticaster direct casting, and direct casting is into aluminium alloy cast ingot；Aluminium alloy rod is pressed into 420 DEG C~450 DEG C hot extrusions by extruder, carries out making annealing treatment for 60 minutes at 400 DEG C, then on drawing machine, by the drawing of 7~9 passages, be prepared into the high-strength corrosion-resisting aluminium alloy conductor of dimension.
Advantages of the present invention：
1. after measured, its resistivity is 0.0025 Ω mm to alloy lead wire of the invention2/ m~0.0035 Ω mm2/ m, can be widely used in power transmission, effectively reduce the loss of electric power resource.
2. alloy lead wire of the invention passes through the content for adding and controlling the metallic elements such as the excellent Mo of conductance, improves the conductance of alloy lead wire；The content of the simultaneously element such as Fe, B, Ru, Si of control mechanics performance and fine corrosion resistance is added, the physicochemical property of alloy lead wire is improved；Coordinate the performance of each alloying element by adding rare earth element Pr, the metallurgical structure of optimized alloy wire is improved well so that alloy lead wire of the invention is provided simultaneously with excellent electric conductivity, mechanical property and decay resistance.
Specific embodiment
With reference to specific embodiment, the present invention is further described, but protection scope of the present invention is not limited solely to the specific record of following examples.
Embodiment 1：
A kind of high-strength corrosion-resisting aluminium alloy conductor, contains following element by mass percentage：0.05%Pr, 0.5%Fe, 0.005%B, 0.03%Mo, 0.02%Si, 0.1%Ru, balance of Al and inevitable impurity.
The method for preparing the high-strength corrosion-resisting aluminium alloy conductor of the present embodiment, comprises the following steps：
Step one, according to mass percent of each element in alloy lead wire finished product, weighs the simple substance or compound of each element respectively；
Step 2,99.7% technical pure aluminium ingot is put into after being melted in medium-frequency induction furnace, first addition element Pr, Fe, B, insulated and stirred, after stirring, elements Mo, Si, Ru, insulated and stirred, the removal of impurity are added, refining, degasification, slagging-off, stand more than 30 minutes, and temperature control is at 750 DEG C；Period is analyzed and adjusts to composition in stove；
Step 3, uses conticaster direct casting, and direct casting is into aluminium alloy cast ingot；Aluminium alloy rod is pressed into 420 DEG C of hot extrusions by extruder, carries out making annealing treatment for 60 minutes at 400 DEG C, then on drawing machine, by the drawing of 7 passages, be prepared into the high-strength corrosion-resisting aluminium alloy conductor of dimension.
Embodiment 2：
A kind of high-strength corrosion-resisting aluminium alloy conductor, contains following element by mass percentage：0.50%Pr, 1.5%Fe, 0.010%B, 0.05%Mo, 0.05%Si, 0.2%Ru, balance of Al and inevitable impurity.
The method for preparing the high-strength corrosion-resisting aluminium alloy conductor of the present embodiment, comprises the following steps：
Step one, according to mass percent of each element in alloy lead wire finished product, weighs the simple substance or compound of each element respectively；
Step 2,99.7% technical pure aluminium ingot is put into after being melted in medium-frequency induction furnace, first addition element Pr, Fe, B, insulated and stirred, after stirring, elements Mo, Si, Ru, insulated and stirred, the removal of impurity are added, refining, degasification, slagging-off, stand more than 30 minutes, and temperature control is between 800 DEG C；Period is analyzed and adjusts to composition in stove；
Step 3, uses conticaster direct casting, and direct casting is into aluminium alloy cast ingot；Aluminium alloy rod is pressed into 450 DEG C of hot extrusions by extruder, carries out making annealing treatment for 60 minutes at 400 DEG C, then on drawing machine, by the drawing of 9 passages, be prepared into the high-strength corrosion-resisting aluminium alloy conductor of dimension.
Embodiment 3：
A kind of high-strength corrosion-resisting aluminium alloy conductor, contains following element by mass percentage：0.30%Pr, 1.5%Fe, 0.008%B, 0.04%Mo, 0.03%Si, 0.15%Ru, balance of Al and inevitable impurity.
The method for preparing the high-strength corrosion-resisting aluminium alloy conductor of the present embodiment, comprises the following steps：
Step one, according to mass percent of each element in alloy lead wire finished product, weighs the simple substance or compound of each element respectively；
Step 2,99.7% technical pure aluminium ingot is put into after being melted in medium-frequency induction furnace, first addition element Pr, Fe, B, insulated and stirred, after stirring, elements Mo, Si, Ru, insulated and stirred, the removal of impurity are added, refining, degasification, slagging-off, stand more than 30 minutes, and temperature control is between 770 DEG C；Period is analyzed and adjusts to composition in stove；
Step 3, uses conticaster direct casting, and direct casting is into aluminium alloy cast ingot；Aluminium alloy rod is pressed into 440 DEG C of hot extrusions by extruder, carries out making annealing treatment for 60 minutes at 400 DEG C, then on drawing machine, by the drawing of 8 passages, be prepared into the high-strength corrosion-resisting aluminium alloy conductor of dimension.
Embodiment 4：
A kind of high-strength corrosion-resisting aluminium alloy conductor, contains following element by mass percentage：0.20%Pr, 1.0%Fe, 0.005%B, 0.03%Mo, 0.02%Si, 0.1%Ru, balance of Al and inevitable impurity.
The method for preparing the high-strength corrosion-resisting aluminium alloy conductor of the present embodiment, comprises the following steps：
Step one, according to mass percent of each element in alloy lead wire finished product, weighs the simple substance or compound of each element respectively；
Step 2,99.7% technical pure aluminium ingot is put into after being melted in medium-frequency induction furnace, first addition element Pr, Fe, B, insulated and stirred, after stirring, elements Mo, Si, Ru, insulated and stirred, the removal of impurity are added, refining, degasification, slagging-off, stand more than 30 minutes, and temperature control is between 750 DEG C；Period is analyzed and adjusts to composition in stove；
Step 3, uses conticaster direct casting, and direct casting is into aluminium alloy cast ingot；Aluminium alloy rod is pressed into 420 DEG C of hot extrusions by extruder, carries out making annealing treatment for 60 minutes at 400 DEG C, then on drawing machine, by the drawing of 7 passages, be prepared into the high-strength corrosion-resisting aluminium alloy conductor of dimension.
Embodiment 5：
A kind of high-strength corrosion-resisting aluminium alloy conductor, contains following element by mass percentage：0.50%Pr, 1.5%Fe, 0.010%B, 0.04%Mo, 0.04%Si, 0.2%Ru, balance of Al and inevitable impurity.
The method for preparing the high-strength corrosion-resisting aluminium alloy conductor of the present embodiment, comprises the following steps：
Step one, according to mass percent of each element in alloy lead wire finished product, weighs the simple substance or compound of each element respectively；
Step 2,99.7% technical pure aluminium ingot is put into after being melted in medium-frequency induction furnace, first addition element Pr, Fe, B, insulated and stirred, after stirring, elements Mo, Si, Ru, insulated and stirred, the removal of impurity are added, refining, degasification, slagging-off, stand more than 30 minutes, and temperature control is between 760 DEG C；Period is analyzed and adjusts to composition in stove；
Step 3, uses conticaster direct casting, and direct casting is into aluminium alloy cast ingot；Aluminium alloy rod is pressed into 430 DEG C of hot extrusions by extruder, carries out making annealing treatment for 60 minutes at 400 DEG C, then on drawing machine, by the drawing of 8 passages, be prepared into the high-strength corrosion-resisting aluminium alloy conductor of dimension.
Claims (4)
1. a kind of high-strength corrosion-resisting aluminium alloy conductor, it is characterised in that：Contain following element by mass percentage：0.05%~0.50%Pr, 0.5%~1.5%Fe, 0.005%~0.010%B, 0.03%~0.05%Mo, 0.02%~0.05%Si, 0.1%~0.2%Ru, balance of Al and inevitable impurity.
2. high-strength corrosion-resisting aluminium alloy conductor according to claim 1, it is characterised in that：The high-strength corrosion-resisting aluminium alloy conductor is by mass percentage containing as follows：0.20%~0.50%Pr, 1.0%~1.5%Fe, 0.005%~0.010%B, 0.03%~0.04%Mo, 0.02%~0.04%Si, 0.1%~0.2%Ru, balance of Al and inevitable impurity.
3. high-strength corrosion-resisting aluminium alloy conductor according to claim 1, it is characterised in that：The high-strength corrosion-resisting aluminium alloy conductor is by mass percentage containing as follows：0.30%Pr, 1.5%Fe, 0.008%B, 0.04%Mo, 0.03%Si, 0.15%Ru, balance of Al and inevitable impurity.
4. a kind of method for preparing the high-strength corrosion-resisting aluminium alloy conductor as described in claim 1-3 is any, it is characterised in that comprise the following steps：
Step one, according to mass percent of each element in alloy lead wire finished product, weighs the simple substance or compound of each element respectively；
Step 2,99.7% technical pure aluminium ingot is put into after being melted in medium-frequency induction furnace, first addition element Pr, Fe, B, insulated and stirred, after stirring, adds elements Mo, Si, Ru, insulated and stirred, the removal of impurity, refining, degasification, slagging-off, stand more than 30 minutes, and temperature control is between 750 DEG C~800 DEG C；Period is analyzed and adjusts to composition in stove；
Step 3, uses conticaster direct casting, and direct casting is into aluminium alloy cast ingot；Aluminium alloy rod is pressed into 420 DEG C~450 DEG C hot extrusions by extruder, carries out making annealing treatment for 60 minutes at 400 DEG C, then on drawing machine, by the drawing of 7~9 passages, be prepared into the high-strength corrosion-resisting aluminium alloy conductor of dimension.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101418401A (en) * | 2008-12-05 | 2009-04-29 | 北京工业大学 | Al-Er alloy conductor material and preparation method thereof |
| JP2013149616A (en) * | 2012-01-17 | 2013-08-01 | Robert Bosch Gmbh | Conductive material |
| CN104946937A (en) * | 2015-07-03 | 2015-09-30 | 苏州科茂电子材料科技有限公司 | Aluminum alloy engineering cable material and preparation method thereof |
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- 2015-12-03 CN CN201510876869.7A patent/CN106834811A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101418401A (en) * | 2008-12-05 | 2009-04-29 | 北京工业大学 | Al-Er alloy conductor material and preparation method thereof |
| JP2013149616A (en) * | 2012-01-17 | 2013-08-01 | Robert Bosch Gmbh | Conductive material |
| CN104946937A (en) * | 2015-07-03 | 2015-09-30 | 苏州科茂电子材料科技有限公司 | Aluminum alloy engineering cable material and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| 《中国电力百科全书》编辑委员会: "《中国电力百科全书》", 31 December 2001 * |
| 中国电机工程学会: "《供用电实用手册》", 31 December 1998 * |
| 朱宪忠等: "《电子材料》", 31 August 2011 * |
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Application publication date: 20170613 |