CN106833310B - A kind of textile fabric of UV resistance - Google Patents
A kind of textile fabric of UV resistance Download PDFInfo
- Publication number
- CN106833310B CN106833310B CN201710053525.5A CN201710053525A CN106833310B CN 106833310 B CN106833310 B CN 106833310B CN 201710053525 A CN201710053525 A CN 201710053525A CN 106833310 B CN106833310 B CN 106833310B
- Authority
- CN
- China
- Prior art keywords
- parts
- powder
- resistance
- textile fabric
- fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 230000006750 UV protection Effects 0.000 title claims abstract description 50
- 239000004744 fabric Substances 0.000 title claims abstract description 41
- 239000004753 textile Substances 0.000 title claims abstract description 22
- 239000000843 powder Substances 0.000 claims abstract description 50
- XUMBMVFBXHLACL-UHFFFAOYSA-N Melanin Chemical class O=C1C(=O)C(C2=CNC3=C(C(C(=O)C4=C32)=O)C)=C2C4=CNC2=C1C XUMBMVFBXHLACL-UHFFFAOYSA-N 0.000 claims abstract description 42
- 229920006305 unsaturated polyester Polymers 0.000 claims abstract description 42
- 239000011248 coating agent Substances 0.000 claims abstract description 38
- 238000000576 coating method Methods 0.000 claims abstract description 38
- 229910052624 sepiolite Inorganic materials 0.000 claims abstract description 33
- 235000019355 sepiolite Nutrition 0.000 claims abstract description 33
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000002904 solvent Substances 0.000 claims abstract description 20
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000839 emulsion Substances 0.000 claims abstract description 12
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 12
- 239000010703 silicon Substances 0.000 claims abstract description 12
- 229920002545 silicone oil Polymers 0.000 claims abstract description 12
- JJTUDXZGHPGLLC-UHFFFAOYSA-N lactide Chemical compound CC1OC(=O)C(C)OC1=O JJTUDXZGHPGLLC-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 11
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims abstract description 4
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims abstract description 4
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims abstract description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 18
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 16
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 15
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- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 6
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- MTJGVAJYTOXFJH-UHFFFAOYSA-N 3-aminonaphthalene-1,5-disulfonic acid Chemical compound C1=CC=C(S(O)(=O)=O)C2=CC(N)=CC(S(O)(=O)=O)=C21 MTJGVAJYTOXFJH-UHFFFAOYSA-N 0.000 claims description 3
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims description 3
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 3
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- 239000011668 ascorbic acid Substances 0.000 claims description 3
- 238000002242 deionisation method Methods 0.000 claims description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims description 3
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- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
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- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
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- 150000002148 esters Chemical class 0.000 description 1
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 description 1
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- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
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- 230000002285 radioactive effect Effects 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
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- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/68—Particle size between 100-1000 nm
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/121—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyesters, polycarbonates, alkyds
- D06N3/123—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyesters, polycarbonates, alkyds with polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/128—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with silicon polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2205/00—Condition, form or state of the materials
- D06N2205/10—Particulate form, e.g. powder, granule
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/06—Properties of the materials having thermal properties
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/10—Properties of the materials having mechanical properties
- D06N2209/103—Resistant to mechanical forces, e.g. shock, impact, puncture, flexion, shear, compression, tear
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/1678—Resistive to light or to UV
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- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
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Abstract
The present invention relates to technical field of textile fabric, and in particular to a kind of textile fabric of UV resistance.UV resistance coating including tissue layer and coating on the fabric, the UV resistance coating includes the component of following parts by weight meter: 30-35 parts of unsaturated polyester (UP), hydroxy-end capped poly- methyl-silicone oil 20-25 parts, 2-5 parts of polyvinylpyrrolidone, 3-8 parts of organic silicon emulsion, 0.1-0.5 parts of modified or unmodified melanin powder, 3-8 parts of modified meerschaum powder, 0.2-0.5 parts of titanium dioxide, 3-7 parts of lactide, 5-20 parts of solvent.The fabric high temperature resistant, anti-aging property is good, and structural strength is high, and excellent tenacity can use under long-term direct sunlight, and has good ultraviolet-resistant effect for a long time.
Description
Technical field
The present invention relates to technical field of textile fabric, and in particular to a kind of textile fabric of UV resistance.
Background technique
Since the major part of solar ultraviolet radiation is absorbed by molecules such as Ozone in Atmosphere, oxygen, nitrogen, in earth table
Face, ultraviolet radioactive weaken significantly.But in recent years, it is largely discharged by the fluoride gas of representative of freon, atmosphere is smelly
Oxygen layer reduces filtering and barrier action of the ozone layer to ultraviolet light by irreversible destruction.Scientific investigations showed that smelly
Oxygen layer destruction is one of the main reason for human skin carcinogenesis rate is constantly soaring.Because the radiation of ultraviolet light can change groups of cells
The structure and function divided, when the ultraviolet radiation that cell is subject to, which reaches, to be suffered, which can lose the communication with other cells
In turn apoptosis occurs for ability.Therefore, it is to prevent the effective measures of cutaneum carcinoma that protection skin, which resists ultraviolet radiation,.To human skin
The ultraviolet radiation damaged is mainly long-wave UV radiation (UVA, 320~400nm of wavelength) and ultraviolet B radiation spoke
Two kinds of (UVB, 290~300nm of wavelength) is penetrated, UVA radiation accounts for 90 or more the percent of solar radiation, and the radiation transmission is extremely
The surface layer of skin and skin corium, to accelerate the actinic aging of skin.In contrast, UVB radiation proportion is lower, but its
It is easier to make skin tanning, causes DNA Damage, and then cause skin cancer.
There are the anti-radiation clothes of anti-ultraviolet radiation in the market in ultraviolet radiation in order to prevent.It is common in existing market
The technological means of production ultraviolet-resistant fabric is predominantly mixed into antiultraviolet material in spinning to achieve the effect that antiultraviolet.
But this mode is helpless to the improvement of subsequent product since polymerization.
Summary of the invention
The purpose of the present invention is to solve the above problems, provide a kind of textile fabric of UV resistance.
In order to achieve the above object of the invention, the invention adopts the following technical scheme:
A kind of textile fabric of UV resistance, the UV resistance coating including tissue layer and coating on the fabric, the UV resistance
Coating includes the component of following parts by weight meter: 30-35 parts of unsaturated polyester (UP), hydroxy-end capped poly- methyl-silicone oil 20-25 parts, and poly- second
2-5 parts of alkene pyrrolidone, 3-8 parts of organic silicon emulsion, 0.1-0.5 parts of modified or unmodified melanin powder, modified meerschaum
3-8 parts of powder, 0.2-0.5 parts of titanium dioxide, 3-7 parts of lactide, 5-20 parts of solvent.
The present invention is changed existing Uvr Protective Fabric fabric and is arranged using antiultraviolet, and melanin powder sheet is utilized
Melanin is applied to textile technology field by the ultraviolet resistance that body has；Melanin of the invention belongs to natural UV resistance
Light absorbers, melanin will not decompose generation noxious material in the use process of fabric and impact to the health of human body；With
This simultaneously as melanin itself there are also blue light is absorbed so that the color of fabric in the sun is more mild soft and graceful；This
The ultraviolet protection coefficient of the Uvr Protective Fabric fabric of invention can reach 48 or more, transmitance < 5% of ultraviolet light；Of the invention is anti-
Ultra-violet layer is located at fabric inner layer, is guaranteeing that ultraviolet resistance is persistent simultaneously, the surface layer for not influencing fabric is beautiful
Property is adapted for use on clothes, on shoes and hats, umbrella and curtain etc., is especially suitable for doing parasol, curtain etc..
Present invention improves over the compound systems of unsaturated polyester resin, for the deficiency of coating toughness and intensity, this hair
It is bright to be especially added with modified meerschaum powder, using the modified high length-diameter ratio in surface, nanometer and submicron-scale, with unsaturated-resin
And other materials preparation can have the coating of excellent toughness and intensity and endurance can by the modification to sepiolite
Significantly improve coating material enhancing and toughening effect.
Preferably, the UV resistance coating includes the component of following parts by weight meter: 30-32 parts of unsaturated polyester (UP), hydroxyl
Poly- methyl-silicone oil 20-23 parts of base sealing end, 4-5 parts of polyvinylpyrrolidone, 3-5 parts of organic silicon emulsion, modified black element powder
0.1-0.3 parts, 5-8 parts of modified meerschaum powder, 0.2-0.5 parts of titanium dioxide, 3-5 parts of lactide, 5-20 parts of solvent.
The modified meerschaum powder is prepared from the following steps:
(1) sepiolite is calcined at 460-500 DEG C 30-60min, after Temperature fall, crushes and be sieved through ball mill；
(2) by the mixed solution of the polymethyl siloxane of sepiolite powder and mass concentration 10-12%% and ethyl acetate,
It is stirred the dispersion liquid that is uniformly dispersed to obtain, wherein the mass ratio of polymethyl siloxane and ethyl acetate is 1:2；Then to dispersion liquid
Middle addition accounts for the ascorbic acid that dispersion liquid quality is 0.5-1%, and is ultrasonically treated 20 minutes, simultaneously 60 DEG C of deionization washing after filtering
It dries below；
(3) then combination solution is used to mix, combination solution is neopelex and silane coupling agent
Ethanol solution, the mass concentration of neopelex are 5%, and the mass concentration of silane coupling agent is 20%, at 40 DEG C
Then lower mixing 30min is filtered and is dried to obtain modified meerschaum powder at 70-80 DEG C.
Unmodified sepiolite powder is easy to reunite, is unfavorable for following process in this way, and to coating material since particle is thinner
Performance raising have adverse effect.Inventor, can by above-mentioned processing mode by finding after long-term experimental study
It effectively solves the problems, such as the unity of sepiolite powder, lays a good foundation for the effect performance of sepiolite in the coating.Simultaneously as even
Join the effect of agent, sepiolite is combined more uniform after hardening with other components, and bond strength is good, avoids the coating being prepared into
The strength of materials reduces the generation of cracking.
Preferably, the unsaturated polyester (UP) is vinylite or bisphenol A-type unsaturated polyester (UP).
Preferably, solvent is toluene, acetone or butanone.
Preferably, the partial size of the modified meerschaum powder is 100-150nm.
Preferably, the partial size of the melanin powder is 50-100 nanometers.
Preferably, the method for modifying of the melanin powder specifically:
(1) 2-5 parts of melanin powder are dispersed in 100 parts of dimethyl sulfoxides, and are wherein being added 5-15 parts
1,2- propylene oxide and 0.3-0.5 parts of citric acid, then exist, and are stirred to react 2-5h at 30-50 DEG C；
(2) it is added 20-30 parts of n-butanol in systems again, 1-5 parts of dodecyl bromide stirs 30min at 110 DEG C,
Then 20-30 parts of dimethyl silicone polymer and 3-5 parts of disodium ethylene diamine tetraacetate is added, then stirs 30- at 120 DEG C
60min；It is filtered, washed and dried；Drying temperature is 70-80 DEG C；
(3) 1-3 parts of product obtained are added in 10-30 parts of dimethylformamides, 2-5 parts of maleic acid is then added
Acid anhydride and 1-3 parts of fumaric acid, stir 20-30min at 60 DEG C, and citric acid 0.5-1 parts is added wherein.
Same melanin powder is also to be easy reunion, and untreated melanin will receive temperature to ultraviolet assimilation effect
The influence of degree, i.e., with the raising of temperature, processing capacity can be reduced, it is therefore desirable to be modified to melanin powder.Pass through
Modified, melanin powder can disperse more uniform in component, and absorption and barrier to ultraviolet light have better stability.
Compared with prior art, the present invention beneficial effect is: high temperature resistant, anti-aging property is good, and structural strength is high, and toughness is excellent
It is different, it can be used under long-term direct sunlight, and there is good ultraviolet-resistant effect for a long time.
Specific embodiment
Below by specific embodiment the technical scheme of the present invention will be further described explanation.
If raw material employed in the embodiment of the present invention is raw material commonly used in the art without specified otherwise, implement
Method employed in example, is the conventional method of this field.
Wherein melanin had both included the natural black pigment by extracting in animal and plant body, also included the artificial black that synthesis obtains
Element.Its main component is that tyrosine or the third ammonia of 3,4- dihydroxyphenyl pass through a succession of chemical reaction and is formed by polymer.Or it is
Crystal pigment (OLP, Ocular Lense Pigment), chemical component are as follows: 3-Hydroxykynurenine (3-OHKyn),
The oxidative polymerization product of 3-hydroxykynurenine.
A kind of textile fabric of UV resistance, the UV resistance coating including tissue layer and coating on the fabric, the UV resistance
Coating includes the component of following parts by weight meter: 30-35 parts of unsaturated polyester (UP), hydroxy-end capped poly- methyl-silicone oil 20-25 parts, and poly- second
2-5 parts of alkene pyrrolidone, 3-8 parts of organic silicon emulsion, 0.1-0.5 parts of modified black element powder, 3-8 parts of modified meerschaum powder, two
0.2-0.5 parts of titanium oxide, 3-7 parts of lactide, 5-20 parts of solvent.
Wherein: the unsaturated polyester (UP) is vinylite or bisphenol A-type unsaturated polyester (UP)；Solvent be toluene, acetone or
Butanone；The partial size of the modified meerschaum powder is 100-150nm；The partial size of the melanin powder is 50-100 nanometers.
Wherein: the modified meerschaum powder is prepared from the following steps: (1) being calcined sepiolite at 460-500 DEG C
30-60min after Temperature fall, is crushed and is sieved through ball mill；(2) by the poly- first of sepiolite powder and mass concentration 10-12%%
In the mixed solution of radical siloxane and ethyl acetate, it is stirred the dispersion liquid that is uniformly dispersed to obtain, wherein polymethyl siloxane and second
The mass ratio of acetoacetic ester is 1:2；Then the ascorbic acid for accounting for that dispersion liquid quality is 0.5-1% is added into dispersion liquid, and at ultrasound
Reason 20 minutes, deionization washing and 60 DEG C or less dryings after filtering；(3) then combination solution is used to mix, combination solution
For the ethanol solution of neopelex and silane coupling agent, the mass concentration of neopelex is 5%,
The mass concentration of silane coupling agent is 20%, and 30min is mixed at 40 DEG C, then filters and is dried to obtain modification at 70-80 DEG C
Sepiolite powder.
Wherein: the method for modifying of the melanin powder specifically:
(1) 2-5g melanin powder is dispersed in 100g dimethyl sulfoxide, and is wherein being added the 1,2- of 5-15g
The citric acid of propylene oxide and 0.3-0.5g, then exists, and is stirred to react 2-5h at 30-50 DEG C；
(2) n-butanol of 20-30g is added in systems again, the dodecyl bromide of 1-5g stirs 30min at 110 DEG C, so
The dimethyl silicone polymer of 20-30g and the disodium ethylene diamine tetraacetate of 3-5g are added afterwards, then stirs 30- at 120 DEG C
60min；It is filtered, washed and dried；Drying temperature is 70-80 DEG C；
(3) obtained product 1-3g is added in 10-30g dimethylformamide, the maleic anhydride of 2-5g is then added
With the fumaric acid of 1-3g, 20-30min is stirred at 60 DEG C, and citric acid 0.5-1g is added wherein.
Embodiment 1:
A kind of textile fabric of UV resistance, the UV resistance coating including tissue layer and coating on the fabric, the UV resistance
Coating includes following components: unsaturated polyester (UP) vinylite 300g, hydroxy-end capped poly- methyl-silicone oil 230g, polyvinylpyrrolidine
Ketone 50g, organic silicon emulsion 30g, unmodified melanin powder 3g, modified meerschaum powder 80g, titanium dioxide 2g, lactide 60g,
Solvent 200g, solvent are toluene.
Embodiment 2:
A kind of textile fabric of UV resistance, the UV resistance coating including tissue layer and coating on the fabric, the UV resistance
Coating includes following components: unsaturated polyester (UP) bisphenol A-type unsaturated polyester (UP) 70g, hydroxy-end capped poly- methyl-silicone oil 40g, polyethylene
Pyrrolidones 8g, organic silicon emulsion 16g, modified black element powder 0.2g, modified meerschaum powder 10g, titanium dioxide 1g, lactide
6g, solvent 20g, solvent are acetone.
Embodiment 3:
A kind of textile fabric of UV resistance, the UV resistance coating including tissue layer and coating on the fabric, the UV resistance
Coating includes following components: unsaturated polyester (UP) vinylite 160g, hydroxy-end capped poly- methyl-silicone oil 125g, polyvinylpyrrolidine
Ketone 10g, organic silicon emulsion 30g, modified black element powder 2.5g, modified meerschaum powder 15g, titanium dioxide 1.5g, lactide
35g, solvent 25g, solvent are toluene.
Embodiment 4:
A kind of textile fabric of UV resistance, the UV resistance coating including tissue layer and coating on the fabric, the UV resistance
Coating includes following components: unsaturated polyester (UP) bisphenol A-type unsaturated polyester (UP) 96g, hydroxy-end capped poly- methyl-silicone oil 60g, polyethylene
Pyrrolidones 15g, organic silicon emulsion 9g, modified black element powder 0.9g, modified meerschaum powder 15g, titanium dioxide 1.5g, third hands over
Ester 9g, solvent 60g.
Comparative example 1:
A kind of textile fabric of UV resistance, the UV resistance coating including tissue layer and coating on the fabric, the UV resistance
Coating includes following components: unsaturated polyester (UP) vinylite 300g, hydroxy-end capped poly- methyl-silicone oil 230g, polyvinylpyrrolidine
Ketone 50g, organic silicon emulsion 30g, modified meerschaum powder 80g, titanium dioxide 2g, lactide 60g, solvent 200g, solvent is toluene.
Comparative example 2:
A kind of textile fabric of UV resistance, the UV resistance coating including tissue layer and coating on the fabric, the UV resistance
Coating includes following components: unsaturated polyester (UP) bisphenol A-type unsaturated polyester (UP) 70g, hydroxy-end capped poly- methyl-silicone oil 40g, polyethylene
Pyrrolidones 8g, organic silicon emulsion 16g, modified meerschaum powder 10g, titanium dioxide 1g, lactide 6g, solvent 20g, solvent third
Ketone.
Embodiment 1-4 and the performance data for comparing 1-2 see the table below:
| Ultraviolet permeability % | UV protection factor | 30-40 DEG C of simulation direct sunlight 300h | |
| Embodiment 1 | <2.5% | 50+ | Uv resistance reduces > 10% |
| Embodiment 2 | <3% | 50+ | Uv resistance reduces < 5% |
| Embodiment 3 | <3% | 50+ | Uv resistance reduces < 5% |
| Embodiment 4 | <2% | 50+ | Uv resistance reduces < 5% |
| Comparative example 1 | >68% | ||
| Comparative example 2 | >70% |
Claims (6)
1. a kind of textile fabric of UV resistance, which is characterized in that including the UV resistance coating of tissue layer and coating on the fabric, institute
State the component that UV resistance coating includes following parts by weight meter: 30-35 parts of unsaturated polyester (UP), hydroxy-end capped poly- methyl-silicone oil 20-
25 parts, 2-5 parts of polyvinylpyrrolidone, 3-8 parts of organic silicon emulsion, 0.1-0.5 parts of modified melanin powder, modified meerschaum
3-8 parts of powder, 0.2-0.5 parts of titanium dioxide, 3-7 parts of lactide, 5-20 parts of solvent；
The modified meerschaum powder is prepared from the following steps:
(1) sepiolite is calcined at 460-500 DEG C 30-60min, after Temperature fall, crushes and be sieved through ball mill；
(2) sepiolite powder is placed in the polymethyl siloxane of mass concentration 10-12% and the mixed solution of ethyl acetate, is stirred
The dispersion liquid that is uniformly dispersed to obtain is mixed, wherein the mass ratio of polymethyl siloxane and ethyl acetate is 1:2；Then add into dispersion liquid
Enter to account for the ascorbic acid that dispersion liquid quality is 0.5-1%, and is ultrasonically treated 20 minutes, simultaneously 60 DEG C or less of deionization washing after filtering
It is dry；
(3) then combination solution is used to mix, combination solution is the anhydrous of neopelex and silane coupling agent
Ethanol solution, the mass concentration of neopelex are 5%, and the mass concentration of silane coupling agent is 20%, are mixed at 40 DEG C
30min is closed, then filter and is dried to obtain modified meerschaum powder at 70-80 DEG C；
The method of modifying of the melanin powder specifically:
(1) 2-5 parts of melanin powder are dispersed in 100 parts of dimethyl sulfoxides, and the 1,2- of wherein 5-15 parts of addition
Then propylene oxide and 0.3-0.5 parts of citric acid are stirred to react 2-5h at 30-50 DEG C；
(2) it is added 20-30 parts of n-butanol in systems again, 1-5 parts of dodecyl bromide stirs 30min at 110 DEG C, then
20-30 parts of dimethyl silicone polymer and 3-5 parts of disodium ethylene diamine tetraacetate is added, then stirs 30- at 120 DEG C
60min；It is filtered, washed and dried；Drying temperature is 70-80 DEG C；
(3) 1-3 parts of product obtained are added in 10-30 parts of dimethylformamides, then be added 2-5 part maleic anhydride with
1-3 parts of fumaric acid stirs 20-30min at 60 DEG C, and citric acid 0.5-1 parts is added wherein.
2. a kind of textile fabric of UV resistance according to claim 1, which is characterized in that the UV resistance coating include with
The component of lower parts by weight meter: 30-32 parts of unsaturated polyester (UP), hydroxy-end capped poly- methyl-silicone oil 20-23 parts, polyvinylpyrrolidone
4-5 parts, 3-5 parts of organic silicon emulsion, 0.1-0.3 parts of modified black element powder, 5-8 parts of modified meerschaum powder, titanium dioxide 0.2-
0.5 part, 3-5 parts of lactide, 5-20 parts of solvent.
3. a kind of textile fabric of UV resistance according to claim 1 or 2, which is characterized in that the unsaturated polyester (UP) is
Vinylite or bisphenol A-type unsaturated polyester (UP).
4. a kind of textile fabric of UV resistance according to claim 1 or 2, which is characterized in that solvent be toluene, acetone or
Butanone.
5. a kind of textile fabric of UV resistance according to claim 1 or 2, which is characterized in that the modified meerschaum powder
Partial size be 100-150nm.
6. a kind of textile fabric of UV resistance according to claim 1 or 2, which is characterized in that the melanin powder
Partial size is 50-100 nanometers.
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| CN103465418A (en) * | 2013-09-10 | 2013-12-25 | 上海康耐特光学股份有限公司 | Manufacturing method of blue light prevention resin lens and blue light prevention resin lens |
| CN103835140A (en) * | 2014-03-13 | 2014-06-04 | 武汉纺织大学 | Ultraviolet-protection fabric lining |
| CN105820770A (en) * | 2016-05-27 | 2016-08-03 | 东莞市睿泰涂布科技有限公司 | A kind of melanin anti-blue light protective film and preparation method thereof |
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| CN103465418A (en) * | 2013-09-10 | 2013-12-25 | 上海康耐特光学股份有限公司 | Manufacturing method of blue light prevention resin lens and blue light prevention resin lens |
| CN103835140A (en) * | 2014-03-13 | 2014-06-04 | 武汉纺织大学 | Ultraviolet-protection fabric lining |
| CN105820770A (en) * | 2016-05-27 | 2016-08-03 | 东莞市睿泰涂布科技有限公司 | A kind of melanin anti-blue light protective film and preparation method thereof |
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