CN106785132A - Charging method and device - Google Patents
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- CN106785132A CN106785132A CN201611080956.2A CN201611080956A CN106785132A CN 106785132 A CN106785132 A CN 106785132A CN 201611080956 A CN201611080956 A CN 201611080956A CN 106785132 A CN106785132 A CN 106785132A
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- 238000007600 charging Methods 0.000 title claims abstract description 270
- 238000000034 method Methods 0.000 title claims abstract description 125
- 230000008569 process Effects 0.000 claims abstract description 85
- 238000004364 calculation method Methods 0.000 claims description 14
- 230000010287 polarization Effects 0.000 abstract description 14
- 238000010280 constant potential charging Methods 0.000 description 10
- 238000010277 constant-current charging Methods 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 238000010586 diagram Methods 0.000 description 8
- 230000014759 maintenance of location Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 239000007774 positive electrode material Substances 0.000 description 2
- 238000004904 shortening Methods 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000007773 negative electrode material Substances 0.000 description 1
- 239000004984 smart glass Substances 0.000 description 1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/44—Methods for charging or discharging
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/44—Methods for charging or discharging
- H01M10/448—End of discharge regulating measures
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- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02J—CIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
- H02J7/00—Circuit arrangements for charging or depolarising batteries or for supplying loads from batteries
- H02J7/0069—Charging or discharging for charge maintenance, battery initiation or rejuvenation
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Power Engineering (AREA)
- Charge And Discharge Circuits For Batteries Or The Like (AREA)
- Secondary Cells (AREA)
Abstract
本发明实施例提供一种充电方法及装置。本发明实施例提供的充电方法,包括:N个充电阶段,每个充电阶段包括M次充电过程,N为大于或者等于2的整数,M为大于或者等于1的整数;每个充电过程包括:对电池以恒定电流进行充电,直到电池达到截止电压时停止;以及,对电池以恒定电压进行充电,直到电池达到截止电流时停止;其中,第i个充电阶段中各充电过程所使用的截止电流小于第i+1个充电阶段中各充电过程所使用的截止电流;i的取值范围是[1,N‑1]。本发明的技术方案中,通过调整截止电流大小的方式,降低电池的极化现象,延长电池的寿命。
The embodiment of the present invention provides a charging method and device. The charging method provided by the embodiment of the present invention includes: N charging stages, each charging stage includes M charging processes, N is an integer greater than or equal to 2, and M is an integer greater than or equal to 1; each charging process includes: charging the battery at a constant current until the battery reaches a cut-off voltage; and charging the battery at a constant voltage until the battery reaches a cut-off current; wherein the cut-off current used in each charging process in the i-th charging stage is less than the cut-off current used in each charging process in the i+1-th charging stage; the value range of i is [1, N-1]. In the technical solution of the present invention, by adjusting the cut-off current, the polarization phenomenon of the battery is reduced and the battery life is extended.
Description
技术领域technical field
本发明涉及电池技术领域,尤其涉及一种充电方法及装置。The invention relates to the technical field of batteries, in particular to a charging method and device.
背景技术Background technique
随着社会的不断发展和进步,利用电能作为动力来源的产品越来越多,例如,电子设备、电动汽车等。技术的进步使得产品具备的功能变的多样化,使得耗电量也随之增加。由于电池的额定容量是固定的,所以为电池充电的频率也会随之增大。随着电芯制作工艺水平的限制,电池可使用的循环次数是有限的,充电的频率增大直接影响电池所在的产品的使用寿命。With the continuous development and progress of society, more and more products use electric energy as a power source, such as electronic equipment, electric vehicles, etc. Advances in technology have diversified the functions of products and increased power consumption. Since the rated capacity of the battery is fixed, the frequency of charging the battery will also increase accordingly. With the limitation of the production process level of the battery cell, the number of cycles that the battery can be used is limited, and the increase in the frequency of charging directly affects the service life of the product where the battery is located.
现有技术中为电池充电的方法通常采用恒流恒压充电的方式,使用恒定电流为电池进行充电直到电池的电压达到截止电压,采用恒定电压继续为电池进行充电,直到电池的电压达到截止电流为止。The method of charging the battery in the prior art usually adopts the method of constant current and constant voltage charging, uses a constant current to charge the battery until the voltage of the battery reaches the cut-off voltage, and uses a constant voltage to continue charging the battery until the voltage of the battery reaches the cut-off current until.
采用现有技术中的方式为电池进行充电,随着充电次数的增多,电池的极化现象逐渐严重,导致使用恒定电流进行充电时,电压上升速度变快,进而恒流充电时长变短,而使用恒定电压进行充电时,电流下降速度变慢,进而恒压充电时长会变长,使得电池在较高电压下电芯材料的结构不稳定性增强,进而导致电池的容量衰减严重,缩短了电池的寿命。Using the method in the prior art to charge the battery, as the number of charging increases, the polarization of the battery gradually becomes serious, resulting in a faster rise in voltage when charging with a constant current, and thus a shorter duration of constant current charging, and When charging with a constant voltage, the current drop rate will slow down, and the constant voltage charging time will become longer, which will increase the structural instability of the battery cell material at a higher voltage, which will lead to serious attenuation of the battery capacity and shorten the battery life. lifespan.
发明内容Contents of the invention
本发明实施例提供一种充电方法及装置,通过调整截止电流大小的方式,降低电池的极化现象,延长电池的寿命。The embodiments of the present invention provide a charging method and device, which can reduce the polarization phenomenon of the battery and prolong the service life of the battery by adjusting the magnitude of the cut-off current.
本发明实施例提供一种充电方法,包括:N个充电阶段,每个充电阶段包括M次充电过程,N为大于或者等于2的整数,M为大于或者等于1的整数;An embodiment of the present invention provides a charging method, including: N charging stages, each charging stage includes M charging processes, N is an integer greater than or equal to 2, and M is an integer greater than or equal to 1;
每个充电过程包括:Each charging process includes:
对电池以恒定电流进行充电,直到电池达到截止电压时停止;以及,Charging the battery at a constant current until the battery reaches a cutoff voltage; and,
对电池以恒定电压进行充电,直到电池达到截止电流时停止;Charge the battery with a constant voltage until the battery reaches the cut-off current;
其中,第i个充电阶段中各充电过程所使用的截止电流小于第i+1个充电阶段中各充电过程所使用的截止电流;i的取值范围是[1,N-1]。Wherein, the cutoff current used in each charging process in the i-th charging stage is smaller than the cut-off current used in each charging process in the i+1th charging stage; the value range of i is [1, N-1].
如上所述的方面和任一可能的实现方式,进一步提供一种实现方式,According to the above aspects and any possible implementation, an implementation is further provided,
各充电阶段对应的M的取值相等;或者,The values of M corresponding to each charging stage are equal; or,
各充电阶段对应的M的取值各不相等;或者,The values of M corresponding to each charging stage are different; or,
各充电阶段对应的M的取值部分相等。The value of M corresponding to each charging stage is partially equal.
如上所述的方面和任一可能的实现方式,进一步提供一种实现方式,According to the above aspects and any possible implementation, an implementation is further provided,
还包括:Also includes:
计算预设的电流调整值与第i个充电阶段中各充电过程所使用的截止电流之和,以作为第i+1个充电阶段中各充电过程所使用的截止电流。The sum of the preset current adjustment value and the cut-off current used in each charging process in the i-th charging stage is calculated as the cut-off current used in each charging process in the i+1th charging stage.
如上所述的方面和任一可能的实现方式,进一步提供一种实现方式,According to the above aspects and any possible implementation, an implementation is further provided,
每次计算截止电流时所使用的电流调整值相同;或者,The same current adjustment value is used each time the cutoff current is calculated; or,
每次计算截止电流时所使用的电流调整值相同各不相同;或者The same and different current adjustment values are used each time the cut-off current is calculated; or
每次计算截止电流时所使用的电流调整值部分相同。The current adjustment value used is partly the same each time the cutoff current is calculated.
如上所述的方面和任一可能的实现方式,进一步提供一种实现方式,According to the above aspects and any possible implementation, an implementation is further provided,
所述电流调整值等于0.025C。The current adjustment value is equal to 0.025C.
本发明实施例还提供一种充电装置,应用于N个充电阶段,每个充电阶段包括M次充电过程,N为大于或者等于2的整数,M为大于或者等于1的整数;The embodiment of the present invention also provides a charging device, which is applied to N charging stages, and each charging stage includes M charging processes, N is an integer greater than or equal to 2, and M is an integer greater than or equal to 1;
所述装置包括:The devices include:
第一充电模块,用于在每个充电过程中,对电池以恒定电流进行充电,直到电池达到截止电压时停止;以及,The first charging module is used to charge the battery with a constant current until the battery reaches the cut-off voltage during each charging process; and,
第二充电模块,用于在每个充电过程中,对电池以恒定电压进行充电,直到电池达到截止电流时停止;The second charging module is used to charge the battery with a constant voltage during each charging process until the battery reaches the cut-off current and stops;
其中,第i个充电阶段中各充电过程所使用的截止电流小于第i+1个充电阶段中各充电过程所使用的截止电流;i的取值范围是[1,N-1]。Wherein, the cutoff current used in each charging process in the i-th charging stage is smaller than the cut-off current used in each charging process in the i+1th charging stage; the value range of i is [1, N-1].
如上所述的方面和任一可能的实现方式,进一步提供一种实现方式,According to the above aspects and any possible implementation, an implementation is further provided,
各充电阶段对应的M的取值相等;或者,The values of M corresponding to each charging stage are equal; or,
各充电阶段对应的M的取值各不相等;或者,The values of M corresponding to each charging stage are different; or,
各充电阶段对应的M的取值部分相等。The value of M corresponding to each charging stage is partially equal.
如上所述的方面和任一可能的实现方式,进一步提供一种实现方式,According to the above aspects and any possible implementation, an implementation is further provided,
还包括:Also includes:
计算模块,用于计算预设的电流调整值与第i个充电阶段中各充电过程所使用的截止电流之和,以作为第i+1个充电阶段中各充电过程所使用的截止电流。The calculation module is used to calculate the sum of the preset current adjustment value and the cut-off current used in each charging process in the i-th charging stage as the cut-off current used in each charging process in the i+1th charging stage.
如上所述的方面和任一可能的实现方式,进一步提供一种实现方式,According to the above aspects and any possible implementation, an implementation is further provided,
每次计算截止电流时所使用的电流调整值相同;或者,The same current adjustment value is used each time the cutoff current is calculated; or,
每次计算截止电流时所使用的电流调整值相同各不相同;或者The same and different current adjustment values are used each time the cut-off current is calculated; or
每次计算截止电流时所使用的电流调整值部分相同。The current adjustment value used is partly the same each time the cutoff current is calculated.
如上所述的方面和任一可能的实现方式,进一步提供一种实现方式,According to the above aspects and any possible implementation, an implementation is further provided,
所述电流调整值等于0.025C。The current adjustment value is equal to 0.025C.
本发明实施例提供的充电方法及装置,通过在不同的充电阶段,调整对电池进行恒定电压充电时,电池的截止电流的大小,随着充电次数的增多,将电池的截止电流调整为越来越大,使得在恒定电压充电时,电流降低到截止电流需要的时间变短,因此缩短了对电池进行充电的时间,同时还能够降低电池的极化现象,进而延长了电池的寿命,解决了现有技术中采用固定不变的充电方法对电池进行多次充电后导致的电池的极化现象逐渐严重,使得恒定电流充电的时间变短,恒定电压充电的时间会变长,电池在较高电压下电芯材料的结构不稳定性增强,进而导致电池的容量衰减严重,缩短电池的寿命的问题。In the charging method and device provided by the embodiments of the present invention, by adjusting the cut-off current of the battery when the battery is charged with a constant voltage at different charging stages, the cut-off current of the battery is adjusted to be higher and lower as the number of charging times increases. The larger the value, the shorter the time required for the current to drop to the cut-off current when charging at a constant voltage, thus shortening the time for charging the battery, and at the same time reducing the polarization of the battery, thereby prolonging the life of the battery and solving the problem In the prior art, the polarization phenomenon of the battery caused by repeated charging of the battery by a fixed charging method is gradually serious, so that the time for constant current charging becomes shorter, and the time for constant voltage charging becomes longer. The structural instability of the cell material increases under voltage, which in turn leads to serious attenuation of the capacity of the battery and shortens the life of the battery.
附图说明Description of drawings
为了更清楚地说明本发明实施例或现有技术中的技术方案,下面将对实施例或现有技术描述中所需要使用的附图作一简单地介绍,显而易见地,下面描述中的附图是本发明的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动性的前提下,还可以根据这些附图获得其他的附图。In order to more clearly illustrate the technical solutions in the embodiments of the present invention or the prior art, the following will briefly introduce the drawings that need to be used in the description of the embodiments or the prior art. Obviously, the accompanying drawings in the following description These are some embodiments of the present invention. For those skilled in the art, other drawings can also be obtained according to these drawings without any creative effort.
图1为本发明实施例提供的充电方法实施例一的流程图;FIG. 1 is a flow chart of Embodiment 1 of the charging method provided by the embodiment of the present invention;
图2为现有技术中充电时间与充电电流关系图;Fig. 2 is a relation diagram between charging time and charging current in the prior art;
图3为本发明实施例提供的充电方法实施例的充电时间与充电电流关系图;FIG. 3 is a graph showing the relationship between charging time and charging current in an embodiment of a charging method provided by an embodiment of the present invention;
图4为本发明实施例提供的充电方法实施例二的流程图;FIG. 4 is a flow chart of Embodiment 2 of the charging method provided by the embodiment of the present invention;
图5为实施方案一中关于循环次数和容量保持率的对比图;Fig. 5 is a comparison chart about the number of cycles and capacity retention in Embodiment 1;
图6为实施方案二中关于循环次数和容量保持率的对比图;Figure 6 is a comparison chart of the number of cycles and capacity retention in Embodiment 2;
图7为本发明实施例提供的充电装置实施例一的结构示意图;Fig. 7 is a schematic structural diagram of Embodiment 1 of the charging device provided by the embodiment of the present invention;
图8为本发明实施例提供的充电装置实施例二的结构示意图。FIG. 8 is a schematic structural diagram of Embodiment 2 of the charging device provided by the embodiment of the present invention.
具体实施方式detailed description
为使本发明实施例的目的、技术方案和优点更加清楚,下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其它实施例,都属于本发明保护的范围。In order to make the purpose, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below in conjunction with the drawings in the embodiments of the present invention. Obviously, the described embodiments It is a part of embodiments of the present invention, but not all embodiments. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without creative efforts fall within the protection scope of the present invention.
应当理解,本文中使用的术语“和/或”仅仅是一种描述关联对象的关联关系,表示可以存在三种关系,例如,A和/或B,可以表示:单独存在A,同时存在A和B,单独存在B这三种情况。另外,本文中字符“/”,一般表示前后关联对象是一种“或”的关系。It should be understood that the term "and/or" used herein is only an association relationship describing associated objects, which means that there may be three relationships, for example, A and/or B, which may mean that A exists alone, and A and B exist simultaneously. B, there are three situations of B alone. In addition, the character "/" in this article generally indicates that the contextual objects are an "or" relationship.
实施例一Embodiment one
图1为本发明实施例提供的充电方法实施例一的流程图,如图1所示,本实施例的充电方法,具体可以包括如下步骤:Fig. 1 is a flow chart of the first embodiment of the charging method provided by the embodiment of the present invention. As shown in Fig. 1, the charging method of this embodiment may specifically include the following steps:
101、对电池以恒定电流进行充电,直到电池达到截止电压时停止。101. Charge the battery with a constant current until the battery reaches the cut-off voltage and stop.
本发明实施例中,使用不同正极材料、负极材料制成电池的电芯,由于其电芯材料自身性质的不同,所以共同决定了电池的性能。随着对电池多次进行充电、放电,电池内的电芯所发生的化学变化会逐渐积累。因此,在电池的性能难以改变的情况下,为了降低电池内电芯的极化现象对电芯材料结构稳定性破坏的概率,通过调整截止电流的方式来提高电池的循环次数。In the embodiment of the present invention, different positive electrode materials and negative electrode materials are used to make battery cells. Due to the different properties of the battery cell materials themselves, the performance of the battery is jointly determined. As the battery is charged and discharged many times, the chemical changes in the cells inside the battery will gradually accumulate. Therefore, in the case that the performance of the battery is difficult to change, in order to reduce the probability that the polarization phenomenon of the battery in the battery will damage the stability of the battery material structure, the number of cycles of the battery is increased by adjusting the cut-off current.
需要说明的是,在本发明实施例中,循环次数指代的是电池满充一次与满放一次。在本发明实施例中,充电过程采用恒流恒压充电的方式对电池进行充电或者采用分步(step-charge)充电方式对电池进行充电。It should be noted that, in the embodiment of the present invention, the number of cycles refers to one full charge and one full discharge of the battery. In the embodiment of the present invention, the charging process adopts a constant current and constant voltage charging method to charge the battery or adopts a step-charge charging method to charge the battery.
随着电池循环次数的增加,电芯内部的材料,如正极材料钴酸锂等,会脱出较多的锂离子,进而使得电芯材料的结构会变得不稳定。因此,本发明实施例中的充电方法,将对电池进行充电的过程分为N个充电阶段,每个充电阶段包括M次充电过程,N为大于或者等于2的整数,M为大于或者等于1的整数。As the number of battery cycles increases, the materials inside the cell, such as the positive electrode material lithium cobaltate, etc., will release more lithium ions, which will make the structure of the cell material unstable. Therefore, in the charging method in the embodiment of the present invention, the process of charging the battery is divided into N charging stages, each charging stage includes M charging processes, N is an integer greater than or equal to 2, and M is greater than or equal to 1 an integer of .
例如,将对电池进行充电的过程分为5个充电阶段,每个充电阶段包括50次充电过程,则第一个充电阶段为1~50次充电过程,第二个充电阶段为51~100次充电过程,以此类推。For example, the process of charging the battery is divided into 5 charging stages, each charging stage includes 50 charging processes, then the first charging stage is 1 to 50 charging processes, and the second charging stage is 51 to 100 times charging process, and so on.
由于不同型号电池的电芯材料组成成分不同,额定容量也会不同,相应的电池的性能会有不同,即电池在充电过程中发生的化学变化也会不相同。或者,型号相同的电池,其在充电过程中发生的化学变化也会出现不相同的情况。因此,在一个具体的实现过程中,各充电阶段对应的M的取值相等;或者,各充电阶段对应的M的取值各不相等;或者,各充电阶段对应的M的取值部分相等。Due to the different components of the cell materials of different types of batteries, the rated capacity will also be different, and the performance of the corresponding batteries will be different, that is, the chemical changes that occur during the charging process of the battery will also be different. Or, batteries of the same model may have different chemical changes during charging. Therefore, in a specific implementation process, the values of M corresponding to each charging stage are equal; or, the values of M corresponding to each charging stage are not equal; or, the values of M corresponding to each charging stage are partially equal.
例如,将对电池进行充电的过程分为4个充电阶段,每个充电阶段充电过程次数取值相等,均包括100次充电过程,则第一个充电阶段为1~100次充电过程,第二个充电阶段为101~200次充电过程,以此类推。For example, the charging process of the battery is divided into 4 charging stages, and the number of charging processes in each charging stage is equal, including 100 charging processes, then the first charging stage is 1 to 100 charging processes, and the second A charging stage is 101 to 200 charging processes, and so on.
又例如,将对电池进行充电的过程分为4个充电阶段,每个充电阶段充电过程取值均不相等,则第一个充电阶段为1~100次充电过程,第二个充电阶段为101~250次充电过程,第三个充电阶段为251~400次充电过程,第四个充电阶段为401~600次充电过程。For another example, the process of charging the battery is divided into 4 charging stages, and the value of the charging process in each charging stage is not equal, then the first charging stage is 1 to 100 charging processes, and the second charging stage is 101 ~250 times of charging process, the third charging stage is 251~400 times of charging process, and the fourth charging stage is 401~600 times of charging process.
又例如,将对电池进行充电的过程分为4个充电阶段,每个充电阶段充电过程取值部分相等,则第一个充电阶段为1~100次充电过程,第二个充电阶段为101~200次充电过程,第三个充电阶段为201~400次充电过程,第四个充电阶段为401~600次充电过程。For another example, the process of charging the battery is divided into 4 charging stages, and the value of the charging process in each charging stage is partially equal, then the first charging stage is 1 to 100 times of charging, and the second charging stage is 101 to 100 times. 200 times of charging, the third charging stage is 201~400 times of charging, and the fourth charging stage is 401~600 times of charging.
因此,使用恒定电流对电池进行充电,使得电池的电压随着充电时间的增长而逐渐增加,直到电池达到截止电压时停止对电池进行充电。Therefore, use a constant current to charge the battery, so that the voltage of the battery increases gradually with the charging time, and stops charging the battery when the battery reaches the cut-off voltage.
102、对电池以恒定电压进行充电,直到电池达到截止电流时停止。102. Charge the battery with a constant voltage until the battery reaches the cut-off current and stop.
图2为现有技术中充电时间与充电电流关系图,图3为本发明实施例提供的充电方法实施例的充电时间与充电电流关系图,如图2和图3所示,随着电池的循环次数的增加,电池的极化现象逐渐变强,使得恒流充电时,电压升高的速度变快,因此电压升高到截止电压的时间变短,相应的电池内存储的电量会变少。当使用恒定电压继续为电池进行充电时,为了减弱极化现象,使得电池的电量能够达到额定容量,电池在达到截止电流时充电时间就会逐渐变长,电池在长时间的较高电压状态下,电池更容易发生容量的损失。因此,在本发明实施例中,采用调整每个充电阶段的截止电流的方式,来缩短充电时间。Fig. 2 is a diagram showing the relationship between charging time and charging current in the prior art, and Fig. 3 is a diagram showing the relationship between charging time and charging current in the embodiment of the charging method provided by the embodiment of the present invention, as shown in Fig. 2 and Fig. 3 , as the battery As the number of cycles increases, the polarization of the battery gradually becomes stronger, making the voltage rise faster during constant current charging, so the time for the voltage to rise to the cut-off voltage becomes shorter, and the corresponding power stored in the battery will decrease. . When using a constant voltage to continue charging the battery, in order to weaken the polarization phenomenon, so that the battery can reach the rated capacity, the charging time of the battery will gradually become longer when the battery reaches the cut-off current, and the battery will be in a high voltage state for a long time. , the battery is more prone to capacity loss. Therefore, in the embodiment of the present invention, the charging time is shortened by adjusting the cut-off current of each charging stage.
其中,第i个充电阶段中各充电过程所使用的截止电流小于第i+1个充电阶段中各充电过程所使用的截止电流;i的取值范围是[1,N-1]。Wherein, the cutoff current used in each charging process in the i-th charging stage is smaller than the cut-off current used in each charging process in the i+1th charging stage; the value range of i is [1, N-1].
可以理解的是,随着充电过程次数的逐渐增加,电池的截止电流逐渐增大。It can be understood that as the number of charging processes gradually increases, the cut-off current of the battery gradually increases.
例如,将对电池进行充电的过程分为4个充电阶段,每个充电阶段充电过程的次数取值相等,均为100次充电过程。则第一个充电阶段的截止电流为0.001C,第二个充电阶段的截止电流为0.003C,第三个充电阶段的截止电流为0.01C,第四个充电阶段的截止电流为0.01C。For example, the process of charging the battery is divided into 4 charging stages, and the number of charging processes in each charging stage is equal to 100 charging processes. Then the cut-off current of the first charging stage is 0.001C, the cut-off current of the second charging stage is 0.003C, the cut-off current of the third charging stage is 0.01C, and the cut-off current of the fourth charging stage is 0.01C.
在一个具体的实现过程中,每个充电阶段中各充电过程所使用的截止电流既可以是预先设定的,也可以是实时计算的。In a specific implementation process, the cut-off current used in each charging process in each charging stage can be preset or calculated in real time.
在一个具体的实现过程中,使用本发明实施例中的充电方法所充电的电池,可以应用于终端、可穿戴设备、电动工具、移动电源、无人机、电动车、电动汽车中。In a specific implementation process, the battery charged by using the charging method in the embodiment of the present invention can be applied to terminals, wearable devices, electric tools, mobile power supplies, drones, electric vehicles, and electric vehicles.
需要说明的是,本发明实施例中所涉及的终端可以包括但不限于个人计算机(Personal Computer,PC)、个人数字助理(Personal Digital Assistant,PDA)、无线手持设备、平板电脑(Tablet Computer)、手机、MP3播放器、MP4播放器等。It should be noted that the terminals involved in the embodiments of the present invention may include but not limited to personal computers (Personal Computer, PC), personal digital assistants (Personal Digital Assistant, PDA), wireless handheld devices, tablet computers (Tablet Computer), Mobile phones, MP3 players, MP4 players, etc.
需要说明的是,本发明实施例中所涉及的可穿戴设备可以包括但不限于智能手环、智能手表、智能眼镜、蓝牙耳机等。It should be noted that the wearable devices involved in the embodiments of the present invention may include, but are not limited to, smart bracelets, smart watches, smart glasses, bluetooth earphones, and the like.
需要说明的是,本发明实施例中所涉及的电动车可以包括但不限于电动自行车、电动三轮车、电动平衡车等。It should be noted that the electric vehicles involved in the embodiments of the present invention may include but not limited to electric bicycles, electric tricycles, electric balance vehicles and the like.
本发明实施例提供的充电方法,通过在不同的充电阶段,调整对电池进行恒定电压充电时,电池的截止电流的大小,随着充电次数的增多,将电池的截止电流调整为越来越大,使得在恒定电压充电时,电流降低到截止电流需要的时间变短,因此缩短了对电池进行充电的时间,同时还能够降低电池的极化现象,进而延长了电池的寿命,解决了现有技术中采用固定不变的充电方法对电池进行多次充电后导致的电池的极化现象逐渐严重,使得恒定电流充电的时间变短,恒定电压充电的时间会变长,电池在较高电压下电芯材料的结构不稳定性增强,进而导致电池的容量衰减严重,缩短电池的寿命。In the charging method provided by the embodiment of the present invention, by adjusting the cut-off current of the battery when the battery is charged with a constant voltage at different charging stages, the cut-off current of the battery is adjusted to be larger and larger as the charging times increase. , so that when the constant voltage is charged, the time required for the current to decrease to the cut-off current is shortened, so the time for charging the battery is shortened, and at the same time, the polarization of the battery can be reduced, thereby prolonging the life of the battery and solving the existing problem In the technology, the polarization phenomenon of the battery caused by repeated charging of the battery with a fixed charging method is gradually serious, which makes the time of constant current charging shorter and the time of constant voltage charging longer, and the battery is charged at a higher voltage. The structural instability of the battery material increases, which in turn leads to serious attenuation of the battery capacity and shortens the life of the battery.
实施例二Embodiment two
图4为本发明实施例提供的充电方法实施例二的流程图,如图4所示,本实施例的充电方法,具体可以包括如下步骤:Fig. 4 is a flow chart of the second embodiment of the charging method provided by the embodiment of the present invention. As shown in Fig. 4, the charging method of this embodiment may specifically include the following steps:
201、对电池以恒定电流进行充电,直到电池达到截止电压时停止。201. Charge the battery with a constant current until the battery reaches the cut-off voltage and stop.
步骤201的具体过程,详见上述实施例一中步骤101中的描述,本发明实施例中其原理和实现过程相同,此处不再赘述。For the specific process of step 201, refer to the description of step 101 in the first embodiment above. The principle and implementation process are the same in the embodiment of the present invention, and will not be repeated here.
202、计算预设的电流调整值与第i个充电阶段中各充电过程所使用的截止电流之和,以作为第i+1个充电阶段中各充电过程所使用的截止电流。202. Calculate the sum of the preset current adjustment value and the cut-off current used in each charging process in the i-th charging stage as the cut-off current used in each charging process in the i+1th charging stage.
可以理解的是,电流调整值为用于调整截止电流大小的数值,在本发明实施例中,第一个充电阶段中的截止电流不需要进行调整,根据第一个充电阶段中的截止电流调整第二个充电阶段中的截止电流,根据第二个充电阶段中的截止电流调整第三个充电阶段中的截止电流,以此类推。It can be understood that the current adjustment value is a value used to adjust the cut-off current. In the embodiment of the present invention, the cut-off current in the first charging stage does not need to be adjusted. The cut-off current in the second charging stage adjusts the cut-off current in the third charging stage according to the cut-off current in the second charging stage, and so on.
具体的调整的方式为,第二个充电阶段中的截止电流=第一个充电阶段中的截止电流+电流调整值,第三个充电阶段中的截止电流=第二个充电阶段中的截止电流+电流调整值,以此类推。The specific adjustment method is, cut-off current in the second charging stage=cut-off current in the first charging stage+current adjustment value, cut-off current in the third charging stage=cut-off current in the second charging stage + current adjustment value, and so on.
在一个具体的实现过程中,每次计算截止电流时所使用的电流调整值相同;或者,每次计算截止电流时所使用的电流调整值相同各不相同;或者每次计算截止电流时所使用的电流调整值部分相同。In a specific implementation process, the current adjustment value used for each calculation of the cut-off current is the same; or, the current adjustment value used for each calculation of the cut-off current is the same and different; or the current adjustment value used for each calculation of the cut-off current is different; The current adjustment value of the part is the same.
例如,将对电池进行充电的过程分为4个充电阶段,每次计算截止电流时所使用的电流调整值相同,均为0.01C,第一个充电阶段的截止电流为0.001C,则第二个充电阶段的截止电流为0.011C,第三个充电阶段的截止电流为0.021C,第四个充电阶段的截止电流为0.031C。For example, the process of charging the battery is divided into 4 charging stages, and the current adjustment value used in each calculation of the cut-off current is the same, which is 0.01C. The cut-off current of the first charging stage is 0.001C, and the second The cut-off current of the first charging stage is 0.011C, the cut-off current of the third charging stage is 0.021C, and the cut-off current of the fourth charging stage is 0.031C.
又例如,将对电池进行充电的过程分为5个充电阶段,每次计算截止电流时所使用的电流调整值均不相同,分别为0.01C,0.02C,0.03C,0.04C,第一个充电阶段的截止电流为0.001C,则第二个充电阶段的截止电流为0.011C,第三个充电阶段的截止电流为0.031C,第四个充电阶段的截止电流为0.061C,第五个充电阶段的截止电流为0.101C。For another example, the process of charging the battery is divided into 5 charging stages, and the current adjustment values used in each calculation of the cut-off current are different, which are 0.01C, 0.02C, 0.03C, 0.04C, and the first The cut-off current of the charging stage is 0.001C, then the cut-off current of the second charging stage is 0.011C, the cut-off current of the third charging stage is 0.031C, the cut-off current of the fourth charging stage is 0.061C, and the cut-off current of the fifth charging stage is 0.011C. The cut-off current of the stage is 0.101C.
又例如,将对电池进行充电的过程分为5个充电阶段,每次计算截止电流时所使用的电流调整值均部分相同,分别为0.01C,0.02C,0.01C,0.02C,第一个充电阶段的截止电流为0.001C,则第二个充电阶段的截止电流为0.011C,第三个充电阶段的截止电流为0.031C,第四个充电阶段的截止电流为0.041C,第五个充电阶段的截止电流为0.061C。For another example, the process of charging the battery is divided into 5 charging stages, and the current adjustment values used in each calculation of the cut-off current are partly the same, which are 0.01C, 0.02C, 0.01C, 0.02C, and the first The cut-off current of the charging stage is 0.001C, then the cut-off current of the second charging stage is 0.011C, the cut-off current of the third charging stage is 0.031C, the cut-off current of the fourth charging stage is 0.041C, and the cut-off current of the fifth charging stage is 0.011C. The cut-off current of the stage is 0.061C.
在一个具体的实现过程中,为了实现较好的调整效果,电流调整值可以等于0.025C。In a specific implementation process, in order to achieve a better adjustment effect, the current adjustment value may be equal to 0.025C.
203、对电池以恒定电压进行充电,直到电池达到截止电流时停止。203. Charge the battery with a constant voltage until the battery reaches the cut-off current and stop.
步骤203的具体过程,详见上述实施例一中步骤102中的描述,本发明实施例中其原理和实现过程相同,此处不再赘述。For the specific process of step 203, refer to the description of step 102 in the first embodiment above. The principle and implementation process are the same in the embodiment of the present invention, and will not be repeated here.
本发明实施例提供的充电方法,通过在不同的充电阶段,调整对电池进行恒定电压充电时,计算每个充电阶段电池的截止电流的大小,然后根据相应的截止电流的大小进行恒定电压充电,随着充电次数的增多,将电池的截止电流调整为越来越大,使得在恒定电压充电时,电流降低到截止电流需要的时间变短,因此缩短了对电池进行充电的时间,同时还能够降低电池的极化现象,进而延长了电池的寿命,解决了现有技术中采用固定不变的充电方法对电池进行多次充电后导致的电池的极化现象逐渐严重,使得恒定电流充电的时间变短,恒定电压充电的时间会变长,电池在较高电压下电芯材料的结构不稳定性增强,进而导致电池的容量衰减严重,缩短电池的寿命。The charging method provided by the embodiment of the present invention calculates the magnitude of the cut-off current of the battery in each charging stage by adjusting the constant voltage charging of the battery in different charging stages, and then performs constant voltage charging according to the corresponding magnitude of the cut-off current, As the number of charging times increases, the cut-off current of the battery is adjusted to be larger and larger, so that the time required for the current to drop to the cut-off current becomes shorter when charging at a constant voltage, thus shortening the time for charging the battery and at the same time being able to Reduce the polarization phenomenon of the battery, thereby prolonging the life of the battery, and solve the problem that the polarization phenomenon of the battery caused by charging the battery multiple times with a fixed charging method in the prior art is gradually serious, making the time for constant current charging Shorter, the time for constant voltage charging will be longer, and the structural instability of the battery cell material will increase at a higher voltage, which will lead to serious attenuation of the battery capacity and shorten the battery life.
为了使本发明的发明目的、技术方案和技术效果更加清晰,以下结合附图和实施方案,对本发明进一步详细说明。应当理解的是,本说明书中给出的实施方案只是为了解释本发明,并非为了限定本发明,本发明并不局限于说明书中给出的实施方案。In order to make the purpose, technical solution and technical effect of the present invention clearer, the present invention will be further described in detail below in conjunction with the accompanying drawings and embodiments. It should be understood that the embodiments given in the specification are only for explaining the present invention, not for limiting the present invention, and the present invention is not limited to the embodiments given in the specification.
实施方案一Implementation plan one
选择4个相同型号的电池,编号分别为1号、2号、3号与4号。1~4号电池在恒流充电阶段使用相同数据进行充电。在恒压充电阶段中,1号电池和2号电池的截止电流设置为0.025C,3号电池和4号电池的截止电流设置为0.05C。分别对4个电池进行800次循环,记录每次循环中每个电池的剩余容量情况。Choose 4 batteries of the same type, numbered No. 1, No. 2, No. 3 and No. 4. Batteries 1 to 4 are charged with the same data during the constant current charging phase. In the constant voltage charging phase, the cut-off currents of batteries No. 1 and No. 2 are set to 0.025C, and the cut-off currents of batteries No. 3 and No. 4 are set to 0.05C. Perform 800 cycles on the 4 batteries respectively, and record the remaining capacity of each battery in each cycle.
表1为实施方案一中关于截止电流和剩余容量的对比表,图5为实施方案一中关于循环次数和容量保持率的对比图,如图5和表1所示,随着循环的进行,尤其是循环次数越来越大的情况下,采用较大的截止电流时的电池的剩余容量大于较小的截止电流的电池的剩余容量。从表1中的数据可以看出,采用本发明实施例中的充电方法对电池进行充电,能够降低极化现象,保持电池的剩余容量,进而提高电池的使用寿命。Table 1 is a comparison table about the cut-off current and remaining capacity in Embodiment 1, and Figure 5 is a comparison chart about the number of cycles and capacity retention in Embodiment 1, as shown in Figure 5 and Table 1, as the cycle progresses, Especially when the number of cycles is getting larger and larger, the remaining capacity of the battery with a larger cut-off current is greater than that of a battery with a smaller cut-off current. It can be seen from the data in Table 1 that the charging method in the embodiment of the present invention is used to charge the battery, which can reduce the polarization phenomenon, maintain the remaining capacity of the battery, and further improve the service life of the battery.
容量保持率(%)=(循环n次的剩余容量/初始容量)×100%。Capacity retention (%)=(remaining capacity of n cycles/initial capacity)×100%.
表1Table 1
实施方案二Implementation plan two
选择4个相同型号的电池,编号分别为1号、2号、3号与4号。1~4号电池在恒流充电阶段使用相同数据进行充电。在恒压充电阶段中,1号电池和2号电池的截止电流设置为0.025C,分别对2个电池进行800次循环。在1~100次循环中,3号电池和4号电池的截止电流设置为0.025C,在101~200次循环中,3号电池和4号电池的截止电流设置为0.05C,在201~300次循环中,3号电池和4号电池的截止电流设置为0.075C,在301~400次循环中,3号电池和4号电池的截止电流设置为0.1C,以此类推。记录每次循环中每个电池的剩余容量情况。Choose 4 batteries of the same type, numbered No. 1, No. 2, No. 3 and No. 4. Batteries 1 to 4 are charged with the same data during the constant current charging phase. In the constant voltage charging stage, the cut-off current of the No. 1 battery and the No. 2 battery is set to 0.025C, and 800 cycles are performed on the two batteries respectively. In the 1-100 cycle, the cut-off current of the No. 3 battery and the No. 4 battery is set to 0.025C, and in the 101-200 cycle, the cut-off current of the No. In the second cycle, the cut-off current of the No. 3 battery and the No. 4 battery is set to 0.075C, and in the 301~400 cycles, the cut-off current of the No. 3 battery and the No. 4 battery is set to 0.1C, and so on. Record the remaining capacity of each battery for each cycle.
表2为实施方案二中关于截止电流和剩余容量的对比表,图6为实施方案二中关于循环次数和容量保持率的对比图,如图6和表2所示,随着循环的进行,尤其是循环次数越来越大的情况下,采用较大的截止电流时的电池的剩余容量大于较小的截止电流的电池的剩余容量。从表2中的数据可以看出,采用本发明实施例中的充电方法对电池进行充电,能够降低极化现象,保持电池的剩余容量,进而提高电池的使用寿命。Table 2 is a comparison table about the cut-off current and remaining capacity in Embodiment 2, and Figure 6 is a comparison diagram about the number of cycles and capacity retention in Embodiment 2, as shown in Figure 6 and Table 2, as the cycle progresses, Especially when the number of cycles is getting larger and larger, the remaining capacity of the battery with a larger cut-off current is greater than that of a battery with a smaller cut-off current. From the data in Table 2, it can be seen that using the charging method in the embodiment of the present invention to charge the battery can reduce the polarization phenomenon, maintain the remaining capacity of the battery, and further improve the service life of the battery.
表2Table 2
实施例三Embodiment Three
图7为本发明实施例提供的充电装置实施例一的结构示意图,如图5所示,本发明实施例的充电装置,应用于N个充电阶段,每个充电阶段包括M次充电过程,N为大于或者等于2的整数,M为大于或者等于1的整数,包括第一充电模块11和第二充电模块12。Fig. 7 is a schematic structural diagram of the first embodiment of the charging device provided by the embodiment of the present invention. As shown in Fig. 5, the charging device according to the embodiment of the present invention is applied to N charging stages, each charging stage includes M charging processes, and N is an integer greater than or equal to 2, and M is an integer greater than or equal to 1, including the first charging module 11 and the second charging module 12 .
第一充电模块11,用于在每个充电过程中,对电池以恒定电流进行充电,直到电池达到截止电压时停止。The first charging module 11 is configured to charge the battery with a constant current during each charging process until the battery reaches a cut-off voltage and stops.
第二充电模块12,用于在每个充电过程中,对电池以恒定电压进行充电,直到电池达到截止电流时停止;The second charging module 12 is used to charge the battery with a constant voltage during each charging process until the battery reaches the cut-off current and stops;
其中,第i个充电阶段中各充电过程所使用的截止电流小于第i+1个充电阶段中各充电过程所使用的截止电流;i的取值范围是[1,N-1]。Wherein, the cutoff current used in each charging process in the i-th charging stage is smaller than the cut-off current used in each charging process in the i+1th charging stage; the value range of i is [1, N-1].
在一个具体的实现过程中,各充电阶段对应的M的取值相等;或者,In a specific implementation process, the values of M corresponding to each charging stage are equal; or,
各充电阶段对应的M的取值各不相等;或者,The values of M corresponding to each charging stage are different; or,
各充电阶段对应的M的取值部分相等。The value of M corresponding to each charging stage is partially equal.
本实施例的装置,可以用于执行图1所示方法实施例的技术方案,其实现原理和技术效果类似,此处不再赘述。The device of this embodiment can be used to implement the technical solution of the method embodiment shown in FIG. 1 , and its implementation principle and technical effect are similar, and will not be repeated here.
实施例四Embodiment four
图8为本发明实施例提供的充电装置实施例二的结构示意图,如图6所示,本发明实施例的充电装置,在实施例三的基础上,还可以包括:计算模块13。FIG. 8 is a schematic structural diagram of Embodiment 2 of the charging device provided by the embodiment of the present invention. As shown in FIG.
计算模块13用于计算预设的电流调整值与第i个充电阶段中各充电过程所使用的截止电流之和,以作为第i+1个充电阶段中各充电过程所使用的截止电流。The calculation module 13 is used to calculate the sum of the preset current adjustment value and the cut-off current used in each charging process in the i-th charging stage as the cut-off current used in each charging process in the i+1th charging stage.
在一个具体的实现过程中,每次计算截止电流时所使用的电流调整值相同;或者,每次计算截止电流时所使用的电流调整值相同各不相同;或者,每次计算截止电流时所使用的电流调整值部分相同。In a specific implementation process, the current adjustment value used for each calculation of the cut-off current is the same; or, the current adjustment value used for each calculation of the cut-off current is the same and different; or, the current adjustment value used for each calculation of the cut-off current is different; The current trim values used are partly the same.
在一个具体的实现过程中,电流调整值等于0.025C。In a specific implementation, the current adjustment value is equal to 0.025C.
本实施例的装置,可以用于执行图2所示方法实施例的技术方案,其实现原理和技术效果类似,此处不再赘述。The device of this embodiment can be used to implement the technical solution of the method embodiment shown in FIG. 2 , and its implementation principle and technical effect are similar, and will not be repeated here.
所属领域的技术人员可以清楚地了解到,为描述的方便和简洁,上述描述的系统,装置和单元的具体工作过程,可以参考前述方法实施例中的对应过程,在此不再赘述。Those skilled in the art can clearly understand that for the convenience and brevity of the description, the specific working process of the above-described system, device and unit can refer to the corresponding process in the foregoing method embodiment, which will not be repeated here.
所述作为分离部件说明的单元可以是或者也可以不是物理上分开的,作为单元显示的部件可以是或者也可以不是物理单元,即可以位于一个地方,或者也可以分布到多个网络单元上。可以根据实际的需要选择其中的部分或者全部单元来实现本实施例方案的目的。The units described as separate components may or may not be physically separated, and the components displayed as units may or may not be physical units, that is, they may be located in one place, or may be distributed to multiple network units. Part or all of the units can be selected according to actual needs to achieve the purpose of the solution of this embodiment.
以上所描述的装置实施例仅仅是示意性的,其中作为分离部件说明的单元可以是或者也可以不是物理上分开的,作为单元显示的部件可以是或者也可以不是物理单元,即可以位于一个地方,或者也可以分布到至少两个网络单元上。可以根据实际的需要选择其中的部分或者全部模块来实现本实施例方案的目的。本领域普通技术人员在不付出创造性的劳动的情况下,即可以理解并实施。The device embodiments described above are only illustrative, and the units described as separate components may or may not be physically separated, and the components shown as units may or may not be physical units, that is, they may be located in one place , or can also be distributed to at least two network elements. Part or all of the modules can be selected according to actual needs to achieve the purpose of the solution of this embodiment. It can be understood and implemented by those skilled in the art without any creative efforts.
最后应说明的是:以上各实施例仅用以说明本发明的技术方案,而非对其限制;尽管参照前述各实施例对本发明进行了详细的说明,本领域的普通技术人员应当理解:其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分或者全部技术特征进行等同替换;而这些修改或者替换,并不使相应技术方案的本质脱离本发明各实施例技术方案的范围。Finally, it should be noted that: the above embodiments are only used to illustrate the technical solutions of the present invention, rather than limiting them; although the present invention has been described in detail with reference to the foregoing embodiments, those of ordinary skill in the art should understand that: It is still possible to modify the technical solutions described in the foregoing embodiments, or perform equivalent replacements for some or all of the technical features; and these modifications or replacements do not make the essence of the corresponding technical solutions deviate from the technical solutions of the various embodiments of the present invention. scope.
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