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CN106772788B - A cut-off wavelength shifted single-mode fiber - Google Patents

A cut-off wavelength shifted single-mode fiber Download PDF

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CN106772788B
CN106772788B CN201710100067.6A CN201710100067A CN106772788B CN 106772788 B CN106772788 B CN 106772788B CN 201710100067 A CN201710100067 A CN 201710100067A CN 106772788 B CN106772788 B CN 106772788B
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cladding
optical fiber
wavelength
refractive index
range
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CN106772788A (en
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蒋新力
范艳层
汤明明
周慧
沈一春
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State Grid Corp of China SGCC
State Grid Information and Telecommunication Co Ltd
Global Energy Interconnection Research Institute
State Grid Heilongjiang Electric Power Co Ltd
Jiangsu Zhongtian Technology Co Ltd
Zhongtian Technology Precision Material Co Ltd
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Jiangsu Zhongtian Technology Co Ltd
Zhongtian Technology Precision Material Co Ltd
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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/02Optical fibres with cladding with or without a coating
    • G02B6/036Optical fibres with cladding with or without a coating core or cladding comprising multiple layers
    • G02B6/03616Optical fibres characterised both by the number of different refractive index layers around the central core segment, i.e. around the innermost high index core layer, and their relative refractive index difference
    • G02B6/03661Optical fibres characterised both by the number of different refractive index layers around the central core segment, i.e. around the innermost high index core layer, and their relative refractive index difference having 4 layers only
    • G02B6/03683Optical fibres characterised both by the number of different refractive index layers around the central core segment, i.e. around the innermost high index core layer, and their relative refractive index difference having 4 layers only arranged - - + +

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  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
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Abstract

本发明提供一种截止波长位移单模光纤,包括芯层、依次包覆的内包层、凹陷包层、中包层和外包层。所述芯层的半径R1的范围为5.5~8.5μm,所述芯层相对所述外包层的折射率差△n1的范围为0.1%~0.3%;所述内包层的厚度R2‑R1的范围为5~25μm,所述内包层相对所述外包层的折射率差△n2的范围为‑0.2%~0%;所述凹陷包层的厚度R3‑R2的范围为4.5~12μm,所述凹陷包层相对所述外包层的折射率差△n3的范围为‑0.45%~‑0.25%;所述中包层的厚度R4‑R3的范围大于10μm,所述中包层相对所述外包层的折射率差△n4的范围为△n2~0%;所述外包层的半径R5的范围为60~65μm。本发明提供的光纤不仅具有低衰减、大有效面积及低弯曲损耗等优异性能,且可实现光纤截止波长的可控性。

The invention provides a cut-off wavelength shifted single-mode optical fiber, which comprises a core layer, an inner cladding layer coated sequentially, a depressed cladding layer, a middle cladding layer and an outer cladding layer. The radius R 1 of the core layer ranges from 5.5 to 8.5 μm, and the refractive index difference Δn 1 of the core layer relative to the outer cladding layer ranges from 0.1% to 0.3%; the thickness of the inner cladding layer R 2 - The range of R 1 is 5-25 μm, the range of the refractive index difference Δn 2 of the inner cladding relative to the outer cladding is -0.2%-0%; the range of the thickness R 3 -R 2 of the depressed cladding is 4.5 to 12 μm, the range of the refractive index difference Δn 3 of the depressed cladding relative to the outer cladding is -0.45% to -0.25%; the range of the thickness R 4 -R 3 of the middle cladding is greater than 10 μm, so The refractive index difference Δn 4 of the middle cladding layer relative to the outer cladding layer ranges from Δn 2 to 0%; the radius R 5 of the outer cladding layer ranges from 60 μm to 65 μm. The optical fiber provided by the invention not only has excellent properties such as low attenuation, large effective area and low bending loss, but also can realize the controllability of the cut-off wavelength of the optical fiber.

Description

一种截止波长位移单模光纤A cut-off wavelength shifted single-mode fiber

技术领域technical field

本发明涉及光通信领域,尤其涉及一种截止波长位移单模光纤。The invention relates to the field of optical communication, in particular to a cut-off wavelength shifted single-mode optical fiber.

背景技术Background technique

光纤作为光通信网络的基础传输物理媒介,对其传输系统性能的改善可以直接体现在对光信噪比(OSNR)的改善上。光纤的损耗和非线性效应是限制高速大容量光纤通信系统OSNR的关键因素。通过相关研究证明,增大光纤的有效面积(Aeff),不仅可以增加入纤光功率,还可以有效降低非线性效应。所以增加光纤有效面积,降低光纤损耗是克服光纤损耗和非线性效应这两个制约因素的主要途径。Optical fiber is the basic transmission physical medium of the optical communication network, and the improvement of its transmission system performance can be directly reflected in the improvement of the optical signal-to-noise ratio (OSNR). The loss and nonlinear effects of optical fibers are the key factors that limit the OSNR of high-speed and large-capacity optical fiber communication systems. It has been proved by relevant research that increasing the effective area (A eff ) of the optical fiber can not only increase the optical power entering the fiber, but also effectively reduce the nonlinear effect. Therefore, increasing the effective area of the fiber and reducing the fiber loss are the main ways to overcome the two restrictive factors of fiber loss and nonlinear effects.

目前光通信中最常用的单模光纤G.652在1550nm波长的衰减典型值是0.19dB/km,截止波长的上限是1260nm。受到截止波长的限制,其效面积典型值是83μm2。而截止波长位移单模光纤(G.654)的截止波长上限是1530nm,其有效面积通常大于100μm2At present, the most commonly used single-mode fiber G.652 in optical communication has a typical attenuation value of 0.19dB/km at a wavelength of 1550nm, and the upper limit of the cut-off wavelength is 1260nm. Limited by the cut-off wavelength, the typical effective area is 83μm 2 . The upper limit of the cut-off wavelength of the cut-off wavelength-shifted single-mode fiber (G.654) is 1530 nm, and its effective area is usually larger than 100 μm 2 .

对于光纤的有效面积Aeff,其与模场直径MFD之间的关系如式(1)所示,For the effective area A eff of the fiber, the relationship between it and the mode field diameter MFD is shown in formula (1),

式中,k为修正系数。In the formula, k is the correction coefficient.

由式(1)可知,光纤的有效面积Aeff与MFD的平方成正比,因此大有效面积意味着大的模场直径。通常可通过增大光纤的芯层外径或减小芯层与光纤内包层间的折射率差以增大模场直径。It can be seen from formula (1) that the effective area A eff of the fiber is proportional to the square of the MFD, so a large effective area means a large mode field diameter. Generally, the mode field diameter can be increased by increasing the outer diameter of the core layer of the fiber or reducing the refractive index difference between the core layer and the inner cladding layer of the fiber.

通信光纤的主要成分是二氧化硅。在光纤预制棒制造过程中,一般通过掺入二氧化锗来提高芯层的折射率,而掺入氟元素来降低包层折射率,其中,光纤具有渐变型折射率时,其折射率变化可以用折射率沿半径的分布函数n(ρ)来表示,The main component of communication optical fiber is silica. In the manufacturing process of optical fiber preform, the refractive index of the core layer is generally increased by doping germanium dioxide, and the refractive index of the cladding layer is reduced by doping fluorine. Among them, when the optical fiber has a graded refractive index, the refractive index change can be Expressed by the distribution function n(ρ) of the refractive index along the radius,

式中:n1为芯层11轴心的折射率,n2为芯层11外内包层13的折射率,α为折射率系数,R1为芯层11的半径。经过40年的努力,预制棒和光纤的制造工艺已经达到了极致。除了二氧化硅的本征吸收外,掺杂二氧化锗的吸收和散射是通信光纤衰减的最主要来源,故减小芯层二氧化锗的含量是降低光纤衰减的主要方向。现有典型G.654单模光纤设计中,虽然其芯层的折射率和二氧化锗的含量显著低于典型G.652光纤,但是其模场直径、截止波长λcc和弯曲损耗限制了芯层二氧化锗掺杂量的进一步下降。In the formula: n 1 is the refractive index of the axis of the core layer 11, n 2 is the refractive index of the outer and inner cladding 13 of the core layer 11, α is the refractive index coefficient, and R1 is the radius of the core layer 11. After 40 years of hard work, the manufacturing process of preforms and optical fibers has reached the extreme. In addition to the intrinsic absorption of silicon dioxide, the absorption and scattering of doped germanium dioxide are the main sources of attenuation of communication optical fibers, so reducing the content of germanium dioxide in the core layer is the main direction to reduce the attenuation of optical fibers. In the existing typical G.654 single-mode fiber design, although the refractive index and germanium dioxide content of the core layer are significantly lower than the typical G.652 fiber, the mode field diameter, cut-off wavelength λ cc and bending loss limit the core Layer germanium dioxide doping amount further decreased.

发明内容Contents of the invention

有鉴于此,有必要提供一种光纤,其通过合理的光纤结构设计,使光纤的损耗进一步降低,且同时满足G.654对模场直径、截止波长和弯曲损耗等参数的要求。In view of this, it is necessary to provide an optical fiber, which can further reduce the loss of the optical fiber through a reasonable optical fiber structure design, and at the same time meet the requirements of G.654 on parameters such as mode field diameter, cut-off wavelength, and bending loss.

本发明提供一种截止波长位移单模光纤,包括渐变型折射率的芯层、依次包覆的阶跃折射率的内包层、凹陷包层、中包层和外包层,其中:The present invention provides a cut-off wavelength shifted single-mode optical fiber, which includes a core layer with a graded refractive index, an inner cladding layer with a step refractive index, a depressed cladding layer, a middle cladding layer and an outer cladding layer coated sequentially, wherein:

所述芯层的半径为R1,R1的范围为5.5~8.5μm,所述芯层轴心的折射率为n1,所述芯层轴心相对所述外包层的折射率差为△n1,△n1的范围为0.1%~0.3%;The radius of the core layer is R 1 , the range of R 1 is 5.5-8.5 μm, the refractive index of the core layer axis is n 1 , and the refractive index difference between the core layer axis and the outer cladding is Δ n 1 , the range of △n 1 is 0.1%~0.3%;

所述内包层的半径为R2,所述内包层的厚度为R2-R1,R2-R1的范围为5~25μm,所述内包层的折射率为n2,所述内包层相对所述外包层的折射率差为△n2,△n2的范围为-0.2%~0%;The radius of the inner cladding is R 2 , the thickness of the inner cladding is R 2 -R 1 , the range of R 2 -R 1 is 5-25 μm, the refractive index of the inner cladding is n 2 , the inner cladding The refractive index difference relative to the outer cladding is Δn 2 , and the range of Δn 2 is -0.2% to 0%;

所述凹陷包层的半径为R3,所述凹陷包层的厚度为R3-R2,R3-R2的范围为4.5~12μm,所述凹陷包层的折射率为n3,所述凹陷包层相对所述外包层的折射率差为△n3,△n3的范围为-0.45%~-0.25%;The radius of the depressed cladding is R 3 , the thickness of the depressed cladding is R 3 -R 2 , the range of R 3 -R 2 is 4.5-12 μm, and the refractive index of the depressed cladding is n 3 , so The refractive index difference between the depressed cladding layer and the outer cladding layer is Δn 3 , and the range of Δn 3 is -0.45%~-0.25%;

所述中包层的半径为R4,所述中包层的厚度为R4-R3,R4-R3的范围为大于10μm,所述中包层的折射率为n4,所述中包层相对所述外包层的折射率差为△n4,△n4的范围为△n2~0%;The radius of the middle cladding layer is R 4 , the thickness of the middle cladding layer is R 4 -R 3 , the range of R 4 -R 3 is greater than 10 μm, the refractive index of the middle cladding layer is n 4 , and the The refractive index difference between the middle cladding layer and the outer cladding layer is Δn 4 , and the range of Δn 4 is Δn 2 to 0%;

所述外包层的半径为R5,R5的范围为60~65μm,所述外包层的折射率为ncThe radius of the outer cladding is R 5 , the range of R 5 is 60-65 μm, and the refractive index of the outer cladding is n c .

进一步地,所述外包层的半径R5的典型值为62.5μm。Further, a typical value of the radius R 5 of the outer cladding is 62.5 μm.

进一步地,所述光纤在波长1550nm下的有效面积为100~170μm2;在波长1550nm下的色散大于18ps/nm/km;在波长1550nm下的衰减系数低于0.18dB/km;所述光纤的光缆截止波长小于1530nm。Further, the effective area of the optical fiber at a wavelength of 1550nm is 100-170μm 2 ; the dispersion at a wavelength of 1550nm is greater than 18ps/nm/km; the attenuation coefficient at a wavelength of 1550nm is lower than 0.18dB/km; The cut-off wavelength of the optical cable is less than 1530nm.

进一步地,所述光纤的有效面积为100~145μm2时,在波长1550nm下,30mm半径-100圈的宏弯损耗小于0.05dB,在波长1625nm下,30mm半径-100圈的宏弯损耗小于0.1dB。Further, when the effective area of the optical fiber is 100-145 μm2, at a wavelength of 1550 nm, the macrobending loss of 30 mm radius-100 turns is less than 0.05 dB, and at a wavelength of 1625 nm, the macrobending loss of 30 mm radius-100 turns is less than 0.1 dB.

进一步地,所述光纤的有效面积为145~170μm2时,在波长1550nm下,30mm半径-100圈的宏弯损耗小于0.15dB,在波长1625nm下,30mm半径-100圈的宏弯损耗小于0.3dB。Further, when the effective area of the optical fiber is 145-170 μm2, at a wavelength of 1550 nm, the macrobending loss of 30 mm radius-100 turns is less than 0.15 dB, and at a wavelength of 1625 nm, the macrobending loss of 30 mm radius-100 turns is less than 0.3 dB.

进一步地,所述光纤的应用波长范围为1535~1625nm。Further, the applicable wavelength range of the optical fiber is 1535-1625 nm.

进一步地,所述光纤为截止波长位移的低损耗单模光纤。Further, the optical fiber is a low-loss single-mode optical fiber with shifted cut-off wavelength.

由本发明提供的光纤结构设计而成的光纤不仅能够满足G.654光纤的模场直径、光缆截止波长λcc和弯曲损耗等参数要求,而且具有低衰减、大有效面积及低弯曲损耗的特点;同时可通过对光纤结构(中包层)折射率的调节,实现光纤截止波长的可控性。The optical fiber designed by the optical fiber structure provided by the present invention can not only meet the parameters requirements such as the mode field diameter of the G.654 optical fiber, the cut-off wavelength λ cc of the optical cable and the bending loss, but also has the characteristics of low attenuation, large effective area and low bending loss; At the same time, the controllability of the cut-off wavelength of the fiber can be realized by adjusting the refractive index of the fiber structure (middle cladding layer).

附图说明Description of drawings

下面将结合说明书附图及实施例对本发明作进一步说明。The present invention will be further described below in conjunction with the accompanying drawings and embodiments.

图1示出了本发明实施例的光纤的横截面示意图;Fig. 1 shows a schematic cross-sectional view of an optical fiber according to an embodiment of the present invention;

图2示出了图1所示光纤的结构设计示意图;Figure 2 shows a schematic diagram of the structural design of the optical fiber shown in Figure 1;

图3示出了例1光纤的折射率剖面图;Fig. 3 shows the refractive index profile of example 1 optical fiber;

图4示出了例2光纤的折射率剖面图;Fig. 4 shows the refractive index profile of example 2 optical fiber;

图5示出了例3光纤的折射率剖面图;Fig. 5 shows the refractive index profile of example 3 optical fiber;

图6示出了例4光纤的折射率剖面图;Fig. 6 shows the refractive index profile of example 4 optical fiber;

图7示出了例5光纤的折射率剖面图;Fig. 7 shows the refractive index profile of example 5 optical fiber;

图8示出了例6光纤的折射率剖面图;Fig. 8 shows the refractive index profile of example 6 optical fiber;

图9示出了例7光纤的折射率剖面图;Fig. 9 shows the refractive index profile of example 7 optical fiber;

图10示出了例8光纤的折射率剖面图。Fig. 10 shows the refractive index profile of the fiber of Example 8.

主要元件符号说明Explanation of main component symbols

光纤optical fiber 1010 芯层core layer 1111 内包层Inner cladding 1313 凹陷包层Depressed cladding 1515 中包层Middle cladding 1717 外包层Outer cladding 1919

如下具体实施方式将结合上述附图进一步说明本发明。The following specific embodiments will further illustrate the present invention in conjunction with the above-mentioned drawings.

具体实施方式Detailed ways

下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。可以理解,附图仅提供参考与说明用,并非用来对本发明加以限制。附图中显示的连接仅仅是为便于清晰描述,而并不限定连接方式。The following will clearly and completely describe the technical solutions in the embodiments of the present invention with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only some, not all, embodiments of the present invention. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without making creative efforts belong to the protection scope of the present invention. It can be understood that the drawings are provided for reference and illustration only, and are not intended to limit the present invention. The connection shown in the drawings is only for the convenience of clear description, and does not limit the connection method.

需要说明的是,当一个件被认为是“连接”另一个件,它可以是直接连接到另一个件或者可能同时存在居中件。除非另有定义,本文所使用的所有的技术和科学术语与属于本发明的技术领域的技术人员通常理解的含义相同。本文中在本发明的说明书中所使用的术语只是为了描述具体的实施例的目的,不是旨在于限制本发明。It should be noted that when an element is considered to be "connected" to another element, it may be directly connected to the other element or intervening elements may also exist. Unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the technical field of the invention. The terms used herein in the description of the present invention are for the purpose of describing specific embodiments only, and are not intended to limit the present invention.

请参照图1和图2,本实施例提供一种光纤10,其能够实现低损耗和大有效面积。在本实施方式中,光纤10为G.654单模光纤,其模场直径、光缆截止波长λcc和弯曲损耗等参数符合G.654光纤的参数标准。光纤10包括位于中心位置的芯层11、包覆在芯层11外表面上的内包层13、包覆在内包层13外表面上的凹陷包层15、包覆在凹陷包层15外表面上的中包层17及包覆在中包层17外表面上的外包层19。如图1所示,芯层11、内包层13、凹陷包层15、中包层17和外包层19的横截面示意图为五个同心圆。本实施例中,凹陷包层15的增加有利于单模光纤10弯曲损耗的优化;外包层19一般由纯二氧化硅制成。在本发明的其他实施方式中,外包层19也可为轻微掺杂其他附加材料的二氧化硅,如轻微掺氟的二氧化硅。Referring to FIG. 1 and FIG. 2 , this embodiment provides an optical fiber 10 capable of achieving low loss and large effective area. In this embodiment, the optical fiber 10 is a G.654 single-mode optical fiber, and its parameters such as mode field diameter, optical cable cut-off wavelength λ cc and bending loss conform to the parameter standards of the G.654 optical fiber. The optical fiber 10 includes a core 11 at the center, an inner cladding 13 coated on the outer surface of the core 11, a depressed cladding 15 coated on the outer surface of the inner cladding 13, and a depressed cladding 15 coated on the outer surface of the depressed cladding 15. The middle cladding layer 17 and the outer cladding layer 19 coated on the outer surface of the middle cladding layer 17. As shown in FIG. 1 , the schematic cross-sections of the core layer 11 , the inner cladding layer 13 , the depressed cladding layer 15 , the middle cladding layer 17 and the outer cladding layer 19 are five concentric circles. In this embodiment, the addition of the depressed cladding 15 is beneficial to the optimization of the bending loss of the single-mode optical fiber 10; the outer cladding 19 is generally made of pure silica. In other embodiments of the present invention, the outer cladding layer 19 may also be silicon dioxide lightly doped with other additional materials, such as silicon dioxide lightly doped with fluorine.

芯层11的半径为R1,具有渐变型折射率。另外,芯层11轴心与外包层19之间的折射率差为△n1,其中,R1的范围为5.5~8.5μm,△n1的范围为0.1%~0.3%。芯层11与外包层19之间折射率差的改变可通过在芯层11掺杂二氧化锗来实现。The core layer 11 has a radius R 1 and has a graded refractive index. In addition, the refractive index difference between the axis of the core layer 11 and the outer cladding layer 19 is Δn 1 , wherein R 1 ranges from 5.5 to 8.5 μm, and Δn 1 ranges from 0.1% to 0.3%. The change of the refractive index difference between the core layer 11 and the outer cladding layer 19 can be realized by doping the core layer 11 with germanium dioxide.

内包层13的半径为R2,内包层13的折射率为n2,内包层13与外包层19之间的折射率差为△n2,其中,内包层13的厚度R2-R1的范围为5~25μm,△n2的范围为-0.2%~0%。The radius of the inner cladding 13 is R 2 , the refractive index of the inner cladding 13 is n 2 , and the refractive index difference between the inner cladding 13 and the outer cladding 19 is Δn 2 , wherein the thickness of the inner cladding 13 is R 2 −R 1 The range is 5 to 25 μm, and the range of Δn 2 is -0.2% to 0%.

凹陷包层15的半径为R3,凹陷包层15的折射率为n3,凹陷包层15与外包层19之间的折射率差为△n3,其中,凹陷包层15的厚度R3-R2的范围为4.5~12μm,△n3的范围为-0.45%~-0.25%。The radius of the depressed cladding 15 is R 3 , the refractive index of the depressed cladding 15 is n 3 , and the refractive index difference between the depressed cladding 15 and the outer cladding 19 is Δn 3 , wherein the thickness of the depressed cladding 15 is R 3 -R 2 ranges from 4.5 to 12 μm, and Δn 3 ranges from -0.45% to -0.25%.

中包层17的半径为R4,中包层17的折射率为n4,中包层17与外包层19之间的折射率差为△n4,其中,中包层17的厚度R4-R3的范围为大于10μm,△n4的范围为△n2~0%。The radius of the middle cladding layer 17 is R 4 , the refractive index of the middle cladding layer 17 is n 4 , and the refractive index difference between the middle cladding layer 17 and the outer cladding layer 19 is Δn 4 , wherein the thickness of the middle cladding layer 17 is R 4 The range of -R 3 is greater than 10 μm, and the range of Δn 4 is Δn 2 to 0%.

外包层19的半径为R5,外包层19的折射率为n5,外包层19的厚度为R5-R4,其中,R5的范围为60~65μm,其典型值为62.5μm,即光纤10的半径范围为60~65μm,其典型值为62.5μm。The radius of the outer cladding 19 is R 5 , the refractive index of the outer cladding 19 is n 5 , and the thickness of the outer cladding 19 is R 5 -R 4 , wherein the range of R 5 is 60-65 μm, and its typical value is 62.5 μm, namely The radius range of the optical fiber 10 is 60-65 μm, and its typical value is 62.5 μm.

以下表I示出了根据本发明光纤10的结构设计的实例,以及本发明范围外其他设计的比较例。其中例3、例5、例7和例8是根据本发明结构设计的例子,例1、例2、例4和例6在本发明的保护范围之外且是为了进行比较所给出的例子。Table I below shows examples of structural designs for optical fibers 10 according to the present invention, as well as comparative examples of other designs outside the scope of the present invention. Wherein example 3, example 5, example 7 and example 8 are examples according to structural design of the present invention, and example 1, example 2, example 4 and example 6 are outside the scope of protection of the present invention and are the examples given for comparison .

表ITable I

以下表II示出了表I所示实例和比较例的主要性能的测试值。本发明在测试前,例1至例8描述的光纤均在零张力下复绕在一420mm直径的圆盘上,再采用光时域反射仪(PK8000-OTDR)测试光纤在各个波长下的衰减,以消除宏弯曲对衰减测试结果的影响。Table II below shows the test values of the main properties of the examples and comparative examples shown in Table I. Before the test of the present invention, the optical fibers described in Examples 1 to 8 were all rewound on a disc with a diameter of 420mm under zero tension, and then the optical time domain reflectometer (PK8000-OTDR) was used to test the attenuation of the optical fiber at each wavelength , to eliminate the influence of macrobending on the attenuation test results.

表IITable II

请参照图3至图10,同时结合表I和表II分析各实例与对比例的不同及优越性。例1至例5(图3至图7)是采用轴向气相沉积法(VAD)、或VAD与改进的化学气相沉积(MCVD)掺氟石英套管混合法制作光纤的例子。例1与普通的G.652光纤((Δn1+|Δn2|)约0.35%)具有类似的折射率分布,是最简单的光纤设计也是目前最常用的G.654光纤的设计,其一方面通过增大芯层11的半径来增大有效面积;另一方面通过降低芯层11与内包层13的折射率差(Δn1+|Δn2|约0.29%)来增大有效面积。相对于G.652光纤的性能,例1光纤具有较低的衰减系数和大的模场直径,但由于受光缆截止波长和弯曲损耗的限制,芯层11与内包层13之间的折射率差优化范围及有效面积的增加量都非常有限(模场直径的标称值通常小于12.5μm)。如果需要进一步提高模场直径,除了调整芯层11与内包层13的折射率差和芯层直径,还采用凹陷结构控制光纤的弯曲损耗。Please refer to FIG. 3 to FIG. 10 , and analyze the differences and advantages of each example and comparative example in combination with Table I and Table II. Examples 1 to 5 (FIG. 3 to FIG. 7) are examples of optical fibers produced by axial vapor deposition (VAD), or a hybrid method of VAD and modified chemical vapor deposition (MCVD) fluorine-doped silica sleeve. Example 1 has a similar refractive index distribution to the common G.652 fiber ((Δn 1 + |Δn 2 |) about 0.35%), which is the simplest fiber design and the most commonly used G.654 fiber design. On the one hand, the effective area is increased by increasing the radius of the core layer 11; on the other hand, the effective area is increased by reducing the refractive index difference between the core layer 11 and the inner cladding layer 13 (Δn 1 +|Δn 2 |about 0.29%). Compared with the performance of the G.652 optical fiber, the optical fiber in Example 1 has a lower attenuation coefficient and a large mode field diameter, but due to the limitation of the cut-off wavelength and bending loss of the optical cable, the refractive index difference between the core layer 11 and the inner cladding layer 13 The optimization range and the increase in the effective area are very limited (the nominal value of the mode field diameter is usually less than 12.5μm). If the mode field diameter needs to be further increased, in addition to adjusting the refractive index difference between the core layer 11 and the inner cladding layer 13 and the core layer diameter, a concave structure is also used to control the bending loss of the optical fiber.

例2和例1具有相同的(Δn1+|Δn2|)(约0.29%)。为进一步降低光纤损耗,例2通过减小芯层11二氧化锗的掺杂量降低n1,为了保持模场直径不变,同时降低n2。测试结果显示例2光纤在1550nm处的衰减系数稍微有所下降,但光缆截止波长较低(1298nm)。虽然内包层13的厚度很大(约22μm),但弯曲损耗严重变差(在1550nm和1625nm处,30mm半径-100圈的宏弯损耗分别高达0.27dB和0.93dB)。Example 2 and Example 1 have the same (Δn 1 +|Δn 2 |) (about 0.29%). In order to further reduce the fiber loss, in Example 2, n 1 is reduced by reducing the doping amount of germanium dioxide in the core layer 11, and n 2 is reduced at the same time in order to keep the mode field diameter unchanged. The test results show that the attenuation coefficient of the optical fiber in Example 2 is slightly lowered at 1550nm, but the cutoff wavelength of the optical cable is lower (1298nm). Although the thickness of the inner cladding layer 13 is large (about 22 μm), the bending loss is severely deteriorated (at 1550 nm and 1625 nm, the macrobending loss of 30 mm radius-100 turns is as high as 0.27 dB and 0.93 dB, respectively).

例3在例2的基础上添加了凹陷包层15和中包层17,从表II可以看出例3光纤的弯曲损耗得到显著降低(在1550nm和1625nm处,30mm半径-100圈的宏弯损耗分别达0.01dB和0.02dB),且1550nm处的衰减系数较低,光缆截止波长也显著提高(1444nm)。Example 3 adds depressed cladding 15 and middle cladding 17 on the basis of example 2, as can be seen from Table II, the bending loss of example 3 optical fiber is significantly reduced (at 1550nm and 1625nm, the macrobend of 30mm radius-100 turns The loss reaches 0.01dB and 0.02dB respectively), and the attenuation coefficient at 1550nm is low, and the cut-off wavelength of the optical cable is also significantly increased (1444nm).

例4与例2和例3有相同的n2。为了增加模场直径同时进一步降低光纤衰减,例4有非常低的Δn1(0.12%),其(Δn1+|Δn2|)约为0.2%。该实例采用了传统的凹陷结构(即凹陷包层15)来降低弯曲损耗,但是表II的数据显示凹陷结构对于大圈的弯曲损耗改进有限(在1550nm和1625nm处,30mm半径-100圈的宏弯损耗分别达0.20dB和0.39dB);同时由于Δn1的减小,例4光纤的光缆截止波长过低(1021nm),且所述光缆截止波长不易调整和控制。Example 4 has the same n 2 as Example 2 and Example 3. In order to increase the mode field diameter while further reducing the fiber attenuation, Example 4 has a very low Δn 1 (0.12%), and its (Δn 1 + |Δn 2 |) is about 0.2%. This example adopts the traditional concave structure (i.e. concave cladding 15) to reduce the bending loss, but the data in Table II shows that the concave structure has limited improvement in bending loss for large circles (at 1550nm and 1625nm, the macro of 30mm radius-100 circles The bending losses are up to 0.20dB and 0.39dB respectively); at the same time, due to the reduction of Δn 1 , the cut-off wavelength of the optical fiber in example 4 is too low (1021nm), and the cut-off wavelength of the optical cable is not easy to adjust and control.

为解决例4中存在的不足,例5在例4的基础上添加了中包层17,从表II可以看出例5能够在较低衰减的基础上进一步降低光纤的弯曲损耗(在1550nm和1625nm处,30mm半径-100圈的宏弯损耗分别达0.07dB和0.16dB),且光缆截止波长满足G.654标准。In order to solve the deficiencies in Example 4, Example 5 added middle cladding 17 on the basis of Example 4, as can be seen from Table II, Example 5 can further reduce the bending loss of optical fiber on the basis of lower attenuation (at 1550nm and At 1625nm, the macrobending loss of 30mm radius-100 turns reaches 0.07dB and 0.16dB respectively), and the cut-off wavelength of the optical cable meets the G.654 standard.

例6至例8(图8至图10)是采用MCVD工艺和掺氟石英套管或纯石英套管制作光纤的例子。对比例6光纤至例8光纤的主要性能测试值及结构设计参数,在进一步降低芯层11折射率n1、减小光纤衰减的前提下,仅仅使用凹陷包层15对弯曲损耗的改善是非常有限的,只有增加采用了中包层17的设计,光纤的弯曲损耗才能降低到要求范围之内。例7光纤在1550nm处的光纤衰减系数为0.176dB/km,30mm半径-100圈的宏弯损耗为0.02dB;在1625nm处,光纤衰减系数为0.192dB/km,30mm半径-100圈的宏弯损耗为0.04dB。对比例6与例7和例8,光缆截止波长λcc由1303nm变为1512nm和1405nm,即通过调节中包层折射率n4,可对光纤截止波长进行改变和控制。Examples 6 to 8 (FIG. 8 to FIG. 10) are examples of making optical fibers by MCVD process and fluorine-doped silica sleeve or pure silica sleeve. Comparing the main performance test values and structural design parameters of the fiber of Example 6 to Example 8, under the premise of further reducing the refractive index n 1 of the core layer 11 and reducing the attenuation of the fiber, the improvement of the bending loss by only using the depressed cladding 15 is very Limited, the bending loss of the optical fiber can be reduced to the required range only if the design of the middle cladding 17 is added. Example 7 The optical fiber attenuation coefficient at 1550nm is 0.176dB/km, the macrobending loss of 30mm radius-100 turns is 0.02dB; at 1625nm, the fiber attenuation coefficient is 0.192dB/km, the macrobending loss of 30mm radius-100 turns The loss is 0.04dB. Comparing Example 6 with Example 7 and Example 8, the cutoff wavelength λ cc of the optical cable is changed from 1303nm to 1512nm and 1405nm, that is, the cutoff wavelength of the optical fiber can be changed and controlled by adjusting the refractive index n 4 of the middle cladding.

本发明提供的光纤10中芯层11、内包层13、凹陷包层15、中包层17和外包层19的结构设计具有低衰减、大有效面积及低弯曲损耗的特点。同时芯层11、内包层13、凹陷包层15、中包层17和外包层19的参数可实现如下特征:光纤10的应用波长范围是1535nm至1625nm;在波长1550nm下有效面积为100~170μm2;在波长1550nm下色散大于18ps/nm/km;在波长1550nm下的衰减系数低于0.18dB/km。光纤10的光缆截止波长小于1530nm。The structure design of the core layer 11, the inner cladding layer 13, the depressed cladding layer 15, the middle cladding layer 17 and the outer cladding layer 19 of the optical fiber 10 provided by the present invention has the characteristics of low attenuation, large effective area and low bending loss. At the same time, the parameters of the core layer 11, the inner cladding layer 13, the depressed cladding layer 15, the middle cladding layer 17 and the outer cladding layer 19 can realize the following characteristics: the application wavelength range of the optical fiber 10 is 1535nm to 1625nm; the effective area is 100-170μm at a wavelength of 1550nm 2 ; Dispersion greater than 18ps/nm/km at a wavelength of 1550nm; attenuation coefficient lower than 0.18dB/km at a wavelength of 1550nm. The cable cut-off wavelength of the optical fiber 10 is less than 1530nm.

当光纤10的有效面积范围为100~145μm2,在波长1550nm下,30mm半径-100圈的宏弯损耗小于0.05dB,在波长1625nm下,30mm半径-100圈的宏弯损耗小于0.1dB。当光纤10的有效面积范围为145~170μm2,在波长1550nm下,30mm半径-100圈的宏弯损耗小于0.15dB,在波长1625nm下,30mm半径-100圈的宏弯损耗小于0.3dB。本发明提供的光纤10完全符合G.654标准中关于模场直径、光缆截止波长λcc和弯曲损耗的要求,进一步降低衰减并实现低弯曲损耗及大有效面积,同时,本发明提供的单模光纤10可通过调节中包层17的折射率n4的大小,以实现对光纤截止波长的改变及控制。When the effective area of the optical fiber 10 ranges from 100 to 145 μm 2 , at a wavelength of 1550nm, the macrobending loss of 30mm radius-100 turns is less than 0.05dB, and at a wavelength of 1625nm, the macrobending loss of 30mm radius-100 turns is less than 0.1dB. When the effective area of the optical fiber 10 ranges from 145 to 170 μm 2 , at a wavelength of 1550nm, the macrobending loss of 30mm radius-100 turns is less than 0.15dB, and at a wavelength of 1625nm, the macrobending loss of 30mm radius-100 turns is less than 0.3dB. The optical fiber 10 provided by the present invention fully complies with the requirements of the G.654 standard on mode field diameter, cable cut-off wavelength λ cc and bending loss, further reduces attenuation and realizes low bending loss and large effective area, and at the same time, the single-mode fiber provided by the present invention The optical fiber 10 can change and control the cut-off wavelength of the optical fiber by adjusting the refractive index n 4 of the middle cladding 17 .

本发明提供的光纤10的光纤芯棒适用于轴向气相沉积法(VAD)、外部化学气相沉积法(OVD)、等离子化学气相沉积法(PCVD)和改进的化学气相沉积法(MCVD)等各种制造工艺或混合工艺。在本实施例中,所述光纤芯棒的制作工艺可采用管内沉积法,即以四氯化硅作为二氧化硅的原料,四氯化锗作为二氧化锗的原料,四氟化硅、六氟化硫或六氟乙烷作为掺氟的原料,在掺氟的石英基管内表面依次沉积凹陷包层15、内包层13和芯层11,再在高温下将所述沉积基管熔缩成所述芯棒,此时所述掺氟的石英基管或部分所述掺氟的石英基管形成中包层17。若中包层17的厚度小于设计值,可采用在所述光纤芯棒外加掺氟套管的方式实现,此时所述光纤芯棒和所述掺氟套管通过套管熔缩法合成一体。所述管内沉积法适用于PCVD、MCVD或熔炉化学气相沉积法(FCVD)制造工艺。The optical fiber core rod of the optical fiber 10 provided by the present invention is suitable for various methods such as axial vapor deposition (VAD), external chemical vapor deposition (OVD), plasma chemical vapor deposition (PCVD) and modified chemical vapor deposition (MCVD). A manufacturing process or a hybrid process. In this embodiment, the manufacturing process of the optical fiber core rod can adopt the in-tube deposition method, that is, silicon tetrachloride is used as the raw material of silicon dioxide, germanium tetrachloride is used as the raw material of germanium dioxide, silicon tetrafluoride, six Sulfur fluoride or hexafluoroethane is used as the fluorine-doped raw material, and the depressed cladding 15, the inner cladding 13 and the core layer 11 are sequentially deposited on the inner surface of the fluorine-doped quartz substrate tube, and then the deposited substrate tube is melted and shrunk at high temperature into The core rod, at this time, the fluorine-doped quartz substrate tube or part of the fluorine-doped quartz substrate tube forms the middle cladding layer 17 . If the thickness of the middle cladding layer 17 is less than the design value, it can be realized by adding a fluorine-doped sleeve to the optical fiber core rod. At this time, the optical fiber core rod and the fluorine-doped sleeve are integrated into one by the sleeve shrinkage method . The in-pipe deposition method is suitable for PCVD, MCVD or Furnace Chemical Vapor Deposition (FCVD) manufacturing processes.

在本发明的其他实施方式中,也可采用其他制作工艺制作所述光纤芯棒,如混合法,即先利用VAD或OVD法制作所述光纤芯棒的内芯棒,所述内芯棒包括芯层11和内包层13;再结合PCVD、MCVD或FCVD法,以四氯化硅作为二氧化硅的原料,四氟化硅、六氟化硫或六氟乙烷作为掺氟的原料,在掺氟石英管内表面沉积凹陷包层15;将所述内芯棒与所述掺氟石英管通过套管熔缩法合成一体,此时所述掺氟石英管或部分所述掺氟石英管形成中包层17,若中包层17的厚度小于设计值,可采用在所述光纤芯棒外另加掺氟套管的方式实现。或其他可生产掺氟高纯石英的方法制备凹陷包层15和中包层17,如掺氟套管或利用OVD粉末沉积结合掺氟烧结法在所述内芯棒外沉积凹陷包层15和中包层17等。In other embodiments of the present invention, other manufacturing processes can also be used to manufacture the optical fiber core rod, such as the hybrid method, that is, the inner core rod of the optical fiber core rod is manufactured by VAD or OVD method first, and the inner core rod includes The core layer 11 and the inner cladding layer 13; combined with PCVD, MCVD or FCVD method, silicon tetrachloride is used as the raw material of silicon dioxide, and silicon tetrafluoride, sulfur hexafluoride or hexafluoroethane are used as raw materials doped with fluorine. A depressed cladding 15 is deposited on the inner surface of the fluorine-doped quartz tube; the inner mandrel and the fluorine-doped quartz tube are synthesized into one body through sleeve melting and shrinkage, and at this time, the fluorine-doped quartz tube or part of the fluorine-doped quartz tube is formed The middle cladding layer 17, if the thickness of the middle cladding layer 17 is less than the design value, can be realized by adding a fluorine-doped sleeve outside the optical fiber core rod. Or other methods that can produce fluorine-doped high-purity quartz to prepare the depressed cladding 15 and the middle cladding 17, such as a fluorine-doped sleeve or utilize OVD powder deposition combined with fluorine-doped sintering to deposit the depressed cladding 15 and the middle cladding 17 outside the inner core rod Middle cladding 17 etc.

由上述方法制备完成的单模光纤10的光纤芯棒经测量计算后,得到所需的芯棒直径和外包层19的厚度,通过热处理延伸、校直得到目标规格的芯棒,再通过石英玻璃管融缩或者外部沉积、融缩的方法形成外包层19,最后通过脱气等工序形成单模光纤10的光纤预制棒。可以理解的,在制作所述光纤芯棒的过程中需精准地实现设计的△n1、△n2、△n3、△n4及α的值,以确保单模光纤10的模场直径、光缆截止波长λcc和弯曲损耗满足G.654标准。The optical fiber core rod of the single-mode optical fiber 10 prepared by the above method is measured and calculated to obtain the required diameter of the core rod and the thickness of the outer cladding 19, and the core rod of the target specification is obtained by extending and straightening through heat treatment, and then passed through the quartz glass The outer cladding layer 19 is formed by tube melting or external deposition and melting, and finally the optical fiber preform rod of the single-mode optical fiber 10 is formed through degassing and other processes. It can be understood that the designed values of Δn 1 , Δn 2 , Δn 3 , Δn 4 and α need to be accurately realized in the process of manufacturing the optical fiber core rod, so as to ensure that the mode field diameter of the single-mode optical fiber 10 , Cable cut-off wavelength λ cc and bending loss meet the G.654 standard.

本发明提供的单模光纤10不仅能够满足G.654光纤的模场直径、光缆截止波长λcc和弯曲损耗等参数要求,而且具有低衰减、大有效面积及低弯曲损耗的特点;同时可通过对光纤结构折射率的调节,实现光纤截止波长的可控性。本发明提供的截止波长位移的低损耗单模光纤10可应用于若干高速长距离光传输系统,包括海底光纤通信,如陆地与岛屿、岛屿与岛屿、沿海城市之间的通信系统;线路需要穿过沙漠、湖泊、沼泽、森林等地理条件恶劣的地方,及在地理环境复杂或气候较恶劣的地方等;以及高压电力系统沿线专用通信。The single-mode optical fiber 10 provided by the present invention can not only meet the parameter requirements such as the mode field diameter of the G.654 optical fiber, the optical cable cut-off wavelength λ cc and the bending loss, but also has the characteristics of low attenuation, large effective area and low bending loss; The adjustment of the refractive index of the fiber structure realizes the controllability of the cut-off wavelength of the fiber. The low-loss single-mode optical fiber 10 with cut-off wavelength displacement provided by the present invention can be applied to several high-speed long-distance optical transmission systems, including submarine optical fiber communications, such as communication systems between land and islands, islands and islands, and coastal cities; lines need to wear Pass through places with harsh geographical conditions such as deserts, lakes, swamps, forests, etc., and places with complex geographical environments or harsh climates; and dedicated communications along the high-voltage power system.

本申请的说明书和权利要求中,词语“包括/包含”和词语“具有/包括”及其变形,用于指定所陈述的特征、数值步骤或部件的存在,但不排除存在或添加一个或多个其它特征、数值、步骤、组件或它们的组合。In the description and claims of this application, the word "comprises/comprises" and the words "has/comprises" and their variants are used to specify the presence of stated features, numerical steps or components, but do not exclude the presence or addition of one or more other features, values, steps, components or combinations thereof.

为清楚起见,本发明在单独实施例中所描述的某些特征,可以组合在单个实施例中使用。而且,在单个实施例中描述的本发明的各种特征,也可以在单独地或以任何合适形式在子组合中使用。For clarity, certain features of inventions, which are described in separate embodiments, may be used in combination in a single embodiment. Furthermore, various features of the invention which are described in a single embodiment can also be used separately or in any suitable subcombination.

以上所述仅为本发明的较佳实施例而已,并不用以限制本发明,凡在本发明的精神和原则之内所作的任何修改、等同替换和改进等,均应包含在本发明的保护范围之内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention. Any modifications, equivalent replacements and improvements made within the spirit and principles of the present invention should be included in the protection of the present invention. within range.

Claims (6)

1. The utility model provides a cut-off wavelength displacement single mode fiber, its characterized in that, includes the core layer of graded index, the inner cladding of the step index of cladding in proper order, sunken cladding, well cladding and outer cladding, wherein:
The radius of the core layer is R1,R1In the range of 5.5 to 8.5 μm, the refractive index of the core layer axis is n1The refractive index coefficient alpha is 4.4 or 30, and the refractive index difference of the core layer axis relative to the outer cladding layer is delta n1,△n1The range of (A) is 0.1% -0.3%;
The radius of the inner cladding is R2The thickness of the inner cladding is R2-R1,R2-R1In the range of 5 to 25 μm, the refractive index of the inner cladding is n2The refractive index difference of the inner cladding relative to the outer cladding is Deltan2,△n2The range of (A) is-0.2% -0%;
The radius of the concave cladding is R3The thickness of the depressed cladding layer is R3-R2,R3-R2in the range of 4.5 to 12 μm, the refractive index of the depressed cladding being n3The difference of the refractive index of the depressed cladding layer relative to the outer cladding layer is Deltan3,△n3The range of (a) is-0.45 to-0.25 percent;
The radius of the middle cladding is R4The thickness of the middle cladding layer is R4-R3,R4-R3In the range of more than 10 μm, the refractive index of the intermediate cladding being n4The refractive index difference of the middle cladding layer relative to the outer cladding layer is delta n4,△n4In the range of Δ n2~0%;
the outer cladding has a radius R5,R5In the range of 60 to 65 μm, the refractive index of the outer cladding being nc
2. The cutoff wavelength shifted single mode optical fiber of claim 1 wherein one half of the outer cladding layerdiameter R5A typical value of (2) is 62.5 μm.
3. The cut-off wavelength shifted single mode optical fiber according to claim 1, wherein the optical fiber has an effective area of 100 to 170 μm at a wavelength of 1550nm2(ii) a The dispersion at a wavelength of 1550nm is greater than 18 ps/nm/km; the attenuation coefficient under the wavelength of 1550nm is lower than 0.18 dB/km; the optical fiber has a cable cutoff wavelength less than 1530 nm.
4. The cut-off wavelength shifted single mode optical fiber according to claim 3, wherein the effective area of the optical fiber is 100 to 145 μm2And meanwhile, under the wavelength of 1550nm, the macrobend loss of 30mm radius-100 circles is less than 0.05dB, and under the wavelength of 1625nm, the macrobend loss of 30mm radius-100 circles is less than 0.1 dB.
5. The cut-off wavelength shifted single mode optical fiber according to claim 3, wherein the effective area of the optical fiber is 145 to 170 μm2and meanwhile, under the wavelength of 1550nm, the macrobend loss of 30mm radius-100 circles is less than 0.15dB, and under the wavelength of 1625nm, the macrobend loss of 30mm radius-100 circles is less than 0.3 dB.
6. The cut-off wavelength shifted single mode optical fiber according to claim 1, wherein the optical fiber has an application wavelength range of 1535 to 1625 nm.
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