CN106750136A - A kind of hydrate colour environmental protection super abrasive plastic cement race track material - Google Patents
A kind of hydrate colour environmental protection super abrasive plastic cement race track material Download PDFInfo
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- CN106750136A CN106750136A CN201710003077.8A CN201710003077A CN106750136A CN 106750136 A CN106750136 A CN 106750136A CN 201710003077 A CN201710003077 A CN 201710003077A CN 106750136 A CN106750136 A CN 106750136A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3203—Polyhydroxy compounds
- C08G18/3212—Polyhydroxy compounds containing cycloaliphatic groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
- C08G18/4808—Mixtures of two or more polyetherdiols
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4825—Polyethers containing two hydroxy groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4854—Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
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Abstract
A kind of hydrate colour environmental protection super abrasive plastic cement race track material, in parts by weight, its preparing raw material includes：20 30 parts of diisocyanate, 40 50 parts of PPG, 10 20 parts of plasticizer, 0.01 0.1 parts of antioxidant, 1 10 parts of pigment, 50 80 parts of filler, 0.5 2 parts of chain extender.
Description
Technical field
The present invention relates to polyurethane material field, more particularly to a kind of hydrate colour environmental protection super abrasive plastic cement race track material.
Background technology
Polyurethane full name is polyurethanes, is to contain the macromolecular compound for repeating carbamate groups on main chain
General designation.It is formed with dihydroxy or polyol addition polymerization by organic diisocyanate or polyisocyanates.It is poly- at present
Urethane foamed plastics is widely used, and its excellent characteristic is allowed to play irreplaceable work in the manufacture of physical education facilities facility
With.From footwear clothes to equipment, then built to place, polyurethane material is more and more of interest by people, and its characteristic is carried out
Research.In the athletic competition of track and field, many some projects will be carried out on plastic cement race track.Meanwhile, with motion the whole peopleization,
Community, also has increasing place to need to lay plastic cement race track.Plastic cement race track has that flatness is good, compression strength is high, hard
Degree elasticity is appropriate, the characteristic of stable physical property, is conducive to the performance of sportsman's speed and technology, effectively improves and moves into
Achievement, reduces tumble injury rate.Now, polyurethane has been popularized in the manufacture laying of runway.
Currently used for the paver of polyurethane runway, mainly it is made up of two kinds of components, one of which is also main component
The polyurethane material with isocyanates as Material synthesis, its production technology mainly has two kinds：
1st, performed polymer is made with toluene di-isocyanate(TDI) (TDI) and special polyether completely, free TDI in this performed polymer
Content is high, and environmental pollution is serious, although this technique cost is relatively low, current less direct use.
2nd, prepolymerization reaction is carried out with modified diphenylmethane diisocyanate (MDI) and special polyether, is made performed polymer.
Health hazards of the MDI to people is small, and product is environmentally friendly, because poisonous component content is relatively low and its is active high easily and water in MDI
Reaction, is widely used in a variety of applications it, but required MDI amounts are larger during production and processing, relatively costly.
The content of the invention
The present invention provides a kind of hydrate colour environmental protection super abrasive plastic cement race track material, in parts by weight, its preparing raw material bag
Include：
In some embodiments, the diisocyanate is selected from naphthalene diisocyanate, toluene di-isocyanate(TDI), diphenyl
At least one in methane diisocyanate, hexamethylene diisocyanate.
In some embodiments, the diisocyanate is naphthalene diisocyanate and 1, the mixing of hexamethylene-diisocyanate
Thing, the naphthalene diisocyanate and 1, the weight ratio of hexamethylene-diisocyanate is 3：20.
In some embodiments, the PPG is selected from polyoxypropyleneglycol and/or polytetrahydrofuran diol.
In some embodiments, the PPG is the mixing of polyoxypropyleneglycol and polytetrahydrofuran diol
The weight ratio of thing, the polyoxypropyleneglycol and polytetrahydrofuran diol is 5：1.
In some embodiments, the plasticizer be selected from phthalic ester plasticizer, glutaric acid ester plasticizer,
Adipic acid ester plasticizer, azelaic acid ester plasticizer, sebacic acid ester plasticizer, phosphate plasticizer, stearic acid esters
Plasticizer, laurate ester plasticizer, citric acid ester plasticizer, oleic acid ester plasticizer, trimellitic acid esters plasticizer, ring
Oxygen analog derivative plasticizer, sulfonic acid plasticizer, polyol derivative plasticizer, maleic acid ester plasticizer, fumaric acid
One kind in ester plasticizer, itaconic acid ester plasticizer.
In some embodiments, the antioxidant is selected from phenolic antioxidant, amine antioxidants, phosphorous acid esters antioxygen
Agent, containing the one kind in sulphur ester antioxidant.
In some embodiments, the pigment be selected from titanium white, iron oxide yellow, iron oxide red, iron oxide black, cadmium yellow, cadmium red, cadmium orange, chrome yellow,
At least one in zinc yellow, molybdate orange, chrome vermillion, chrome green, barba hispanica, lithopone, zinc white, stibium trioxide, pucherite, titanate.
In some embodiments, described filler be selected from calcium carbonate, talcum powder, potter's clay, blanc fixe, gypsum, mica powder,
At least one in white carbon, diatomite, calcium silicates.
In some embodiments, the chain extender is selected from polyalcohols chain extender, alicyclic ring alcohols chain extender, aromatic alcohols and expands
One kind in chain agent, alcamines chain extender, Diamines chain extender.
The track material elasticity for providing of the invention is appropriate, flatness is good, frictional force is big, can as needed allocate various face
Color, it is bright in colour, it is elegant in appearance.
Specific embodiment
Unless otherwise defined, all technologies used herein and scientific terminology have and the common skill of art of the present invention
The identical implication that art personnel are generally understood that.When there is contradiction, the definition in this specification is defined.
Quality, concentration, temperature, time or other values or parameter are preferred with scope, preferred scope or a series of upper limits
During the Range Representation that value and lower preferable values are limited, this is appreciated that and specifically discloses by any range limit or preferred value
The all scopes formed with any pairing of any range lower limit or preferred value, regardless of whether whether the scope separately discloses.
For example, the scope of 1-50 be understood to include selected from 1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,
19、20、21、22、23、24、25、26、27、28、29、30、31、32、33、34、35、36、37、38、39、40、41、42、43、
44th, 45,46,47,48,49 or 50 any numeral, number combinatorics on words or subrange and all between above-mentioned integer
Fractional value, for example, 1.1,1.2,1.3,1.4,1.5,1.6,1.7,1.8 and 1.9.It is specific to consider from scope on subrange
Interior any end points starts the nested subrange for extending.For example, the nested subrange of exemplary range 1-50 can include one
1-10,1-20,1-30 and 1-40 on individual direction, or 50-40,50-30,50-20 and 50-10 on other direction.
The present invention provides a kind of hydrate colour environmental protection super abrasive plastic cement race track material, in parts by weight, its preparing raw material bag
Include：
In some embodiments, the diisocyanate is selected from naphthalene diisocyanate, toluene di-isocyanate(TDI), diphenyl
At least one in methane diisocyanate, hexamethylene diisocyanate.
In some embodiments, the diisocyanate is naphthalene diisocyanate and 1, the mixing of hexamethylene-diisocyanate
Thing, the naphthalene diisocyanate and 1, the weight ratio of hexamethylene-diisocyanate is 3：20.
In some embodiments, the PPG is selected from polyoxypropyleneglycol and/or polytetrahydrofuran diol.
In some embodiments, the PPG is the mixing of polyoxypropyleneglycol and polytetrahydrofuran diol
The weight ratio of thing, the polyoxypropyleneglycol and polytetrahydrofuran diol is 5：1.
Inventor has found that the naphthalene diisocyanate and 1, hexamethylene-diisocyanate can play synergy under study for action,
Particularly the weight ratio of naphthalene diisocyanate and hexamethylene diisocyanate is 3：When 20, track material can be allowed to obtain very good
Abrasion resistant effect.The ratio of regulation polyoxypropyleneglycol and polytetrahydrofuran diol can improve the elasticity of track material, hair
A person of good sense is found surprisingly that when the weight ratio of polyoxypropyleneglycol and polytetrahydrofuran diol is 5：When 1, the PPG
Unexpected technique effect can be produced with the diisocyanate, while obtaining preferable wearability and elasticity.
In some embodiments, the plasticizer be selected from phthalic ester plasticizer, glutaric acid ester plasticizer,
Adipic acid ester plasticizer, azelaic acid ester plasticizer, sebacic acid ester plasticizer, phosphate plasticizer, stearic acid esters
Plasticizer, laurate ester plasticizer, citric acid ester plasticizer, oleic acid ester plasticizer, trimellitic acid esters plasticizer, ring
Oxygen analog derivative plasticizer, sulfonic acid plasticizer, polyol derivative plasticizer, maleic acid ester plasticizer, fumaric acid
One kind in ester plasticizer, itaconic acid ester plasticizer.
As the example of phthalic ester plasticizer, including but not limited to：Repefral, O-phthalic
Diethyl phthalate, dipropyl phthalate, n-butyl phthalate, diisobutyl phthalate, phthalic acid fourth
The just own ester of monooctyl ester, diamyl phthalate, phthalic acid two, phthalic acid two (2- ethyls fourth) ester, phthalic acid
Dicyclohexyl maleate, phthalic acid two (methyl cyclohexane) ester, the positive fourth cyclohexyl of phthalic acid, dibutyl phthalate (DHP), adjacent benzene
Dioctyl phthalate two (2- ethyl hexyls) ester, di-n-octyl phthalate, diisooctyl phthalate, phthalic acid di-secondary are pungent
Ester, dinonyl phthalate, diisononyl phthalate, diisooctyl phthalate, didecyl phthalate, neighbour
Phthalic acid fourth last of the ten Heavenly stems ester, n-octyl-n-decyl phthalate, iso-octyl isodecyl phthalate ester, phthalic acid ethylhexyl
Last of the ten Heavenly stems ester, phthalic acid two (11) ester, phthalic acid two (12) ester, phthalic acid two (13) ester, O-phthalic
Misery 13 ester, the ester of the phthalic acid last of the ten Heavenly stems 13, the ester of phthalic acid fourth 14, capryl octyl phthalate,
Diphenyl phthalate, dibenzyl phthalate, BBP(Butyl Benzyl Phthalate, OBP, adjacent benzene
Dioctyl phthalate two (methoxyl group second) ester, phthalic acid two (ethyoxyl second) ester, phthalic acid two (butoxy second) ester, methyl are adjacent
Phenyl-diformyl base ethyl glycolate, ethyl phthalyl acetoacetic ester, butyl phthalyl acid butyl ester, neighbour
Phthalic acid C6~C10 n-alkanols mixed ester, phthalic acid C7~C9 alcohol mixed ester, phthalic acid C7~C10 alcohol mixing
Ester, phthalic acid C8~C10 n-alkanols mixed ester, phthalic acid C9~C11 alcohol mixed ester, phthalic acid C7~C11
Alcohol mixed ester, phthalic acid two (C8~C13) ester, tetrahydrophthalic acid two (2- ethyl hexyls) ester, tetrahydro neighbour's benzene two
Formic acid di-n-octyl, the isodecyl ester of tetrahydrophthalic acid two, tetrahydrophthalic acid C7~C10 Arrcostabs, hexahydro are adjacent
Phthalic acid two (2- ethyl hexyls) ester, phthalic acid dibenzyl must alcohol ester, phthalic acid dihydro rosin alcohol ester,
Santicizer 213,218A, 267,679,885, Loxiol W100, W101, W300S, plasticizer DGPO, plasticizer BD.
As the example of glutaric acid ester plasticizer, including but not limited to：Dioctyl Glutaricate, didecyl glutarate, penta
The isodecyl ester of diacid two, the fourth 2-ethoxyethyl acetate of glutaric acid two, the fourth oxygen ethoxy ethyl ester of glutaric acid two.
As the example of adipic acid ester plasticizer, including but not limited to：Di-n-butyl Adipate, the isobutyl of adipic acid two
Ester, di-n-hexyl adipate, dioctyl adipate, diisooctyl adipate, dinonyl adipate, diisononyl adipate, oneself
The isodecyl ester of diacid two, the positive butyl benzyl of adipic acid, BOA, the fourth 2-ethoxyethyl acetate of the adipic acid two, (butoxy of adipic acid two
Ethyoxyl second) ester, adipic acid two (610 alkyl) ester, adipic acid C7~C9 linear esters, n-octyl n-decyl adipate (NODA), adipic acid be different
Pungent isodecyl ester, adipic acid two (methyl cyclohexane) ester, adipic acid two (diethylene glycol monobutyl ether) ester.
As the example of azelaic acid ester plasticizer, including but not limited to：Diisobutyl azelate, azelaic acid two just oneself
Ester, azelaic acid two (2- ethyls fourth) ester, azelaic acid two (2- ethyl hexyls) ester, diisooctyl azelate, the thio (2- of azelaic acid two of 4-
Ethyl hexyl) ester, the fourth 2-ethoxyethyl acetate of azelaic acid two, dibenzyl azelate, dicyclohexyl azelate.
As the example of sebacic acid ester plasticizer, including but not limited to：Dimethyl sebacate, n-butyl sebacate,
Diisopropyl sebacate, di-n-octyl sebacate, Plexol 201, decanedioic acid di-sec-octyl, di-n-nonyl sebacate, decanedioic acid
Two (butoxy second) esters, decanedioic acid two (Butoxyethoxy second) ester, dibenzyl sebacate, two C7 of decanedioic acid~C9 alcohol esters, the last of the ten Heavenly stems
Diethyl adipate, dihexyl sebacate, butyl benzyl sebacate.
As the example of phosphate plasticizer, including but not limited to：Triethyl phosphate, tributyl phosphate, phosphide three are pungent
Ester, diphenyl 2 ethylhexyl phosphate, triphenyl phosphate, phosphate toluene diphenyl ester, tricresyl phosphate, tricresyl phosphate (dimethylbenzene)
Ester, xylyl diphenyl phosphate, isodecyl diphenyl phosphate, tricresyl phosphate (butoxy second) ester, phosphoric acid tri-isopropyl benzene ester, tricresyl phosphate
(2- chloroethenes) ester, tricresyl phosphate (dichloro the third) ester, mono phosphoric acid ester neighbour biphenyl diphenyl phosphate, di(2-ethylhexyl)phosphate (adjacent biphenyl) monophenyl, Phosflex
200,300, Santicizer 145.
As the example of stearic acid ester plasticizer, including but not limited to：BS, glycerin monostearate,
Stearic acid 2- butoxyethyls, butyl acetoxystearate, monostearate 1,2- propylene glycol esters, (acetoxyl group is hard for glycerine three
Resin acid) ester, distearyl acid diethylene glycol (DEG) ester, methyl pentachlorostearate, stearic acid methoxy ethyl ester.
As the example of laurate ester plasticizer, including but not limited to：Mono laurate 1,2- propylene glycol esters, mono laurate
Glyceride, mono laurate diethylene glycol (DEG) ester, laurate fourth 2-ethoxyethyl acetate, polyethylene glycol (400) dilaurate.
As the example of citric acid ester plasticizer, including but not limited to：Triethyl citrate, tri-n-butyl citrate,
The positive fourth fat of ATEC, acetyl tributyl citrate three, ATHC, acetyl tributyl citrate three (2- ethyl hexyls)
Ester, acetyl tributyl citrate three (the just pungent positive last of the ten Heavenly stems) ester.
As the example of oleic acid ester plasticizer, including but not limited to：Methyl oleate, n propyl oleate, butyl oleate, oil
Sour tetrahydrofuran methyl esters, methoxyethyl oleate, oleic acid 2- fourths 2-ethoxyethyl acetate, glyceryl monooleate, single diglycol oleate.
As the example of trimellitic acid esters plasticizer, including but not limited to：Tri trimellitate (2- ethyl hexyls) ester, inclined benzene
Three sour three n-octyls, triisooctyl trimellitate, triisodecyl trimellitate, the secondary monooctyl ester of tri trimellitate, tri trimellitate are different
Nonyl ester, tri trimellitate (the just pungent positive last of the ten Heavenly stems) ester, diisooctyl manoisodecyl trimellitate, tri n hexyl trimellitate,
Santicizer 79TM、TX-85。
As the example of epoxy analog derivative plasticizer, including but not limited to：Epoxidized soybean oil, epoxy Linseed oil, 4,
5- epoxies diisodecyl tetrahydrophthalate, 4,5- epoxies tetrahydrophthalic acid two (2- ethyl hexyls) ester, epoxystearic acid
Butyl ester, epoxystearic acid 2- Octyl Nitrites, the different monooctyl ester of epoxystearic acid, epoxidized tall oil acid 2- Octyl Nitrites, epoxidized soybean oil
Sour 2- Octyl Nitrites, epoxidized methyl acetorieinoleate, epoxy pupal fat acid butyl ester, epoxyfuoic-oleic, epoxidation glycerine three
Acid esters, epoxy chlorinated paraffin, epoxy chloroparaffin, epoxy cotton seed oil, epoxyoleic acid last of the ten Heavenly stems ester, Monoplex S-70, Flexol GPE.
As the example of sulfonic acid plasticizer, including but not limited to：Benzene sulfonyl butylamine, neighbour, para toluene sulfonamide, N-
Ethyl-neighbour, p-methylphenyl sulphonylamine, N- cyclohexyl-p-methylphenyl sulphonylamine, phenyl alkylsulf.
As the example of polyol derivative plasticizer, including but not limited to：Diethylene glycol dibenzoate, triethylene glycol hexichol
Formic acid esters, triethylene glycol two (2 Ethylbutanoic acid) ester, triethylene glycol two (2 ethyl hexanoic acid) ester, triethylene glycol dieaprylate, triethylene glycol two
(C7-9 carboxylates), tetraethylene glycol two (2 ethyl hexanoic acid) ester, diethylene glycol dipelargonate, triethylene glycol dipelargonate, the triethylene glycol pungent last of the ten Heavenly stems
Acid esters, triethylene glycol diheptylate, tetraethylene glycol diheptanoate, ethylene diacetate, triethylene glycol diacetate, 59 acid glycerides,
C5~C9 fatty acid mixeds glycol ester, polyethylene glycol, polyethylene glycol (200) dibenzoate, polyethylene glycol (600) hexichol first
Acid esters, diglycol benzoate and dipropylene glycol benzoate mixture (1:1), neopentyl glycol dibenzoate, triphen
It is formic acid glyceride, dipropylene glycol dibenzoate, propylene glycol dibenzoate, trimethylolethane trimethacrylate benzoic ether, sweet
Oily monoacetate, glyceryl diacetate, triacetin, glycerin tributyrate, glycerol ether acetate, glycerin tripropionate,
(C5~C9 is mixed for pentaerythritol fatty ester, pentaerythritol tetrabenzoate, the caprylatecaprate of pentaerythrite four, pentaerythrite four
Close fatty acid ester), bipentaerythrite support adipic acid six (C5~C9 mixed aliphatic esters).
As the example of maleic acid ester plasticizer, including but not limited to：N-butyl maleate, (the 2- second of maleic acid two
Base oneself) ester, dimethyl maleate, diethyl maleate.
As the example of fumaric acid esters plasticizer, including but not limited to：Di n butyl fumarate, (the 2- second of fumaric acid two
Base oneself) ester, diisooctyl fumarate.
As the example of itaconic acid ester plasticizer, including but not limited to：Itaconic acid list formic acid, monobutyl itaconate, clothing
Health dimethyl phthalate, diethyl itaconate, dibutyl itaconate, itaconic acid two (2- ethyl hexyls) ester.
In some embodiments, the antioxidant is selected from phenolic antioxidant, amine antioxidants, phosphorous acid esters antioxygen
Agent, containing the one kind in sulphur ester antioxidant.
As the example of phenolic antioxidant, including but not limited to：1- hydroxy-3-methyl -4- cumenes, the tertiary fourths of 2,6- bis-
Base phenol, 2,6- di-t-butyl -4- ethyl -phenols, 2,6 di tert butyl 4 methyl phenol, 2,6- di-t-butyl -4- normal-butyls
Phenol, 4 hydroxymethyl 2,6 di t butyl phenol, butylhydroxy anisole, 2- (1- methylcyclohexyls) -4,6- dimethyl benzenes
Phenol, 2,4 dimethyl 6 tert butyl phenol, 2 methyl 4,6 dinonyl phenol, 2,6- di-t-butyls-alpha, alpha-dimethyl amino-to first
Double (the octylsulfo) -1,3,5- three of phenol, 2,4,6- tri-butyl-phenols, 6- (4- hydroxyl -3,5- di-tert-butyls amido) -2,4-
Double (4- hydroxyl -3,5- di-t-butyls the phenoxy group) -2- n-octylthio -1,3,5- triazines of piperazine, 4,6-, β-(3,5- di-t-butyls -
4- hydroxy phenyls) methyl propionate, the β-positive octadecanol ester of (4-hydroxyl-3,5-di-tert-butyl-phenyl) propionic acid, styrol benzene
Phenol, 4,4 '-dihydroxybiphenyl, butylated octylated phenol, butylated stytrene cresols, 2,2 '-methylene bis (4- methyl -6-
Tert-butyl phenol), 2,2 '-methylene bis (4- ethyl -6- tert-butyl phenols), 2,2 '-methylene bis (4- methyl -6- cyclohexyl benzenes
Phenol), 4,4 '-methylene bis(2,6-di-butyl phenol), 2,2 '-methylene bis (6- α-methylbenzyls paracresol), 4,4 '-isopropylidene
Bis-phenol, 4,4 '-fourth fork double (3 methy 6 tert butyl phenols), 1,1- double (4- hydroxy benzenes) hexamethylene, 2,2 '-methylene bis (4- first
Base -6- (Alpha-Methyl cyclohexyl) phenol), 1,3,5- trimethyls -2,4,6- three (3,5- di-tert-butyl-4-hydroxyl benzyls) benzene, 1,
1,3- tri- (2- methyl -4- hydroxyl -5- tert-butyl-phenyls) butane, four (3- (3 ' 5 '-di-t-butyl -4 '-hydroxy phenyl) propionic acid)
Pentaerythritol ester, 4,4 '-thiobis (the 6- tert-butyl group -3- methylphenols), 4,4 '-thiobis (2- methyl-6-tert-butylphenols),
2,2 '-thiobis (4- methyl-6-tert-butylphenols), hexylene glycol double (β-(3,5- di-tert-butyl-hydroxy phenyls) propionic ester),
2,2 '-thiobis (3 ,-(3,5- di-tert-butyl-hydroxy phenyls) ethyl propionate), N, N '-hexamethylene pair (3,5- di-t-butyls-
4- hydroxyls hydrocinnamamide), 1,3,5- tri- (the 4- tert-butyl group-3- hydroxyl-2,6- dimethyl benzyls) 1,3,5-triazine-2,4,6-
(1H, 3H, 5H)-triketone, 1,3,5- tri- (3,5- di-tert-butyl-4-hydroxyl benzyls) guanamine, 4,6- (1H, 3H, 5H) triketone,
Isocyanuric acid three [β-(3,5- di-tert-butyl-hydroxy phenyls) propionyloxy ethyl ester], double [double (3 '-tert-butyl groups -4 '-hydroxyl of 3,3-
Base phenyl) butyric acid] glycol ester, 1,1 '-thiobis (beta naphthal), double (3,5- di-tert-butyl-4-hydroxyl benzyls) thioethers, 2,5-
Di-tert-butyl hydroquinone, 2,5 di tert amyl hydroquinone, 3,5- di-tert-butyl-4-hydroxyl benzyls di(2-ethylhexyl)phosphate (18) ester,
Double -3- (3- tertiary butyl-4-hydroxy -5- the first of 3,5- di-tert-butyl-4-hydroxyl benzyls diethyl phosphate, octylatcd phenol, triethylene glycol
Base phenyl) propionic ester, hydroquinone dibenzyl ether, " Ethyl " Antioxidant 728, " Ethyl " Antioxidant 733,
“Ethyl”Antioxidant 735、Cyanox 96、Cyanox 53、Cyanox LF、Cyanox 1735、Antioxidant
Q-328、Santonox、Antioxidant MBP-5P、MBP-5T、TBM-6P、TBM-6T、Irganox 1890、MD-1024、
Seenox M-100、M-200、M-220、Vanox GT、SKT、Escoflex A122、A123、Sumilizer MPO、
Sumilizer-NW、Sumilizer CS-4、Sumilizer CS-42、Santowhite MK、Nonox-HO、Nonox-EX、
Nonox-EXN, Nonox-EXP, Nonox-WMP, Nonox-WSO, Antioxidant KSM, KSM-EM-33%, TSP, DS,
DS/F、NKF、Naugawhite、Naugawhite 434、Naugawhite 431、Naugawhite Powder。
As the example of amine antioxidants, including but not limited to：Alcohol between N- PAs, N- PBNAs, fourth
Aldehyde-alpha-naphthylamine, DPPD N,N' diphenyl p phenylene diamine, N- isopropyls-N '-diphenyl-para-phenylene diamine, N, N '-two-betanaphthyl is to benzene two
Amine, N, N '-bis- (1,4- dimethyl amyl groups) p-phenylenediamine, N, N '-bis- (1- ethyl -3- methyl amyls) p-phenylenediamine, N- hexamethylenes
Base-N '-diphenyl-para-phenylene diamine, N, N '-bis- (1- methylheptyls) p-phenylenediamine, N- (1,3- dimethylbutyls)-N '-phenyl are to benzene
Diamines, N- phenyl-N '-octyl group p-phenylenediamine, 6- ethyoxyl -2,2,4- trimethyl -1,2- dihyaroquinolines, 2,2,4- front threes
Base -1,2- dihyaroquinolines condensate, 6- dodecyl -2,2,4- trimethyl -1,2- dihyaroquinolines, N- (methacryls
Base oxo -2- hydroxypropyls)-N '-diphenyl-para-phenylene diamine, N- cyclohexyl-P-nethoxyaniline, right, right '-dimethoxy hexichol
Amine, p- (p- tolylsulfonyl- amido) diphenylamines, double-(propyloxy phenyl fork) -4,4 '-diphenylamines, N, N '-diphenyl second two
Amine, N, N '-di-o-tolyl-ethylene-diamine, N,N' diphenyl propylenediamine, p- isopropoxydiphenylamine, N, N '-di-sec-butyl pair
Phenylenediamine, N, it is N '-dimethyl-N, N '-two (1- methyl-propyls) p-phenylenediamine, right, right '-dioctyl diphenylamine, 4,4 '-bis- (α-
Methyl-benzyl)-diphenylamines, Antioxidant 445, Goodrite 3120, Goodrite 3140, Irganox LD-62,
Wingstay 29。
As the example of phosphite ester kind antioxidant, including but not limited to：The triphenyl phosphite, (nonyl benzene of phosphorous acid three
Ester), the different monooctyl ester of phosphorous acid three, triisodecyl phosphite ester, the isodecyl ester of phosphorous acid benzene two, trilauryl trithiophosphite, phosphorous
Sour three lauryls, phosphorous acid three (octadecyl ester), the isodecyl ester of diphosphorous acid pentaerythrite two, diphosphorous acid pentaerythrite distearyl alcohol
Ester, 4,4 '-fourth fork double (phosphorous acid (3- methyl-6-tert butyl phenyl) two (tridecyl) esters), isooctyl diphenyl phosphite, Asias
Phosphoric acid benzene di-isooctyl, octyl diphenyl phosphite, phosphorous acid hexichol isodecyl ester, dioctyl phosphite, phosphorous acid dilauryl, Asia
Double 13 esters of dimethyl phosphate, dioleyl phosphite, didecyl phosphite, dibutyl phosphite, phosphorous acid, phosphorous acid double ten
Double (the nonyls of four esters, triethyl phosphite, tributyl phosphite, triisopropyl phosphite, the monooctyl ester of phosphorous acid three, phosphorous acid-benzene
Benzene) ester, phosphorous acid hexichol nonyl phenyl ester, phosphorous acid three (2- chloroethenes) ester, phosphorous acid three (2,4- di-tert-butyl-phenyls) ester, phosphorous
Sour bisphenol-A ester, phosphorous acid three (single nonyl benzene and dinonyl benzene mixed ester), Mark 329, Mark 1500, Mark C, Wytox
345、Wytox 438、Wytox X-540。
As the example containing sulphur ester antioxidant, including but not limited to：Dilauryl thiodipropionate, thio-2 acid two
Stearic alcohol ester, β, β '-thio two butyric acid two (18) ester, thio-2 acid bay octadecyl ester, thio-2 acid two (13) ester,
Thio-2 acid two (14) ester.
In some embodiments, the pigment be selected from titanium white, iron oxide yellow, iron oxide red, iron oxide black, cadmium yellow, cadmium red, cadmium orange, chrome yellow,
At least one in zinc yellow, molybdate orange, chrome vermillion, chrome green, barba hispanica, lithopone, zinc white, stibium trioxide, pucherite, titanate.
In some embodiments, described filler be selected from calcium carbonate, talcum powder, potter's clay, blanc fixe, gypsum, mica powder,
At least one in white carbon, diatomite, calcium silicates.
Calcium carbonate includes：Powdered whiting, precipitated calcium carbonate, activated Calcium carbonate, winnofil, dry powder, water Ying Shi
Powder, gel calcium carbonate, English white.
The preparation method of calcium carbonate has two kinds of mechanical crushing method and chemical precipitation method.
Mechanical crushing method is that natural limestone is obtained through mechanical crushing, screening, and product is commonly referred to as powdered whiting.Crush
Method has two kinds of dry and wet, and dry method product answers stone flour also known as dry powder, wet method product alias water.
Chemical precipitation method be by limestone calcination decomposition, aquation, carbonization, drying, screening and obtain, product is commonly referred to as lightweight carbon
Sour calcium or winnofil.
The calcium carbonate that surface treated is crossed claims activated Calcium carbonate or gel calcium carbonate.Conventional surface conditioning agent also has silane
Class and titante coupling agent, lignin and fatty acid ester (alone or be used in combination).
English white is the powder obtained after shell is crushed through weathering.
The main component of talcum powder is hydrated magnesium silicate, is to be crushed selected by natural talcum and obtained.High-quality sterling is white
Flake-like crystal, and contain fibrous material, containing impurity person in colors such as yellowish, pale green, pale blue.Talcum powder crystal belongs to monoclinic crystal
System, in hexagon or rhombus.Chemical property torpescence, powder dead-soft, there is soapy feeling.
Potter's clay primary chemical composition is aluminium hydrosilicate.Mainly by the igneous rock in rock, hydrogenic rock, become the mothers such as diagenesis
Rock is decomposed through natural slacking and formed.Production process include dig up mine and processing two stages, process divide again wet method with
Two kinds of dry method.Typically, the product as obtained in wet method is pure compared with dry method product, and size distribution is good.For potter's clay of the invention be
450~600 DEG C through calcining dewatered product sample, also known as calcinated argil.The particle of pure potter's clay is in thin hexagonal plate crystal, many water
Potter's clay particle is preferably hexagonal plate body in the crystallization such as hollow tubular, needle-like for potter's clay of the invention.The color of potter's clay is with product
Ground and impurity (particularly iron) content and it is different, be light grey, faint yellow or even brown, the deeper person of color be not suitable for be used as filling
Agent.The color and luster of calcinated argil is preferably, pure white and bright., through strong reductant such as zine hydrosulfite, color and luster is big after bleaching for wet method potter's clay
To improve.
Blanc fixe has two kinds of preparation methods, one be by natural crystal (barite) it is size-reduced, water is eliminated, dry after be obtained, it is this
Product is referred to as blanc fixe, and particle is thicker, and impurity is also more.Another preparation method is that blanc fixe is solvable with charcoal heating reduction generation
Property barium sulphide, then with sulfuric acid or sodium sulphate effect generation blanc fixe.
Calcium sulfate has natural product gypsum (CaSO4·2H2O), anhydrite (CaSO4) and chemical precipitation calcium sulfate (CaSO4·
2H2O or CaSO4) point.Calcium sulfate containing two crystallizations water is the compound of stabilizer pole, insoluble in bronsted lowry acids and bases bronsted lowry, but 120~
130 DEG C of dehydrations form the calcium sulfate (CaSO of hypocrystalline water4·1/2H2O), anhydrous slufuric acid is turned into when calcining at higher temperatures
Calcium.Hypocrystalline H 2 O calcium sulphate solidifies quickly with water reaction, and dead plaster does not react with water.
The composition of mica is extremely complex, is the silicate compound of the metals such as aluminium, potassium, sodium, magnesium, iron.Mica powder is by natural
Mica is crushed and obtained.Conventional mica powder has two kinds of muscovite and phlogopite, and especially with muscovite application at most, muscovite is in white
Color, phlogopite is in yellow or brown.
The preparation method of white carbon has two kinds of dry and wet.Dry method, also known as vapor phase method, thermal decomposition method or combustion method, is with halogenation
Silicon (such as silicon tetrachloride) is raw material in hydrolysis under high temperature (1000~1200 DEG C), the superfine white carbon of generation particle.Wet method also known as
The precipitation method or liquid phase method, are to be decomposed with sour (such as hydrochloric acid, sulfuric acid) by soluble silicate (such as sodium metasilicate) and obtained.
Diatomite is obtained after being ground by natural diatomaceous earth through 1200 DEG C of high-temperature calcinations, removal organic impurities.
In some embodiments, the chain extender is selected from polyalcohols chain extender, alicyclic ring alcohols chain extender, aromatic alcohols and expands
One kind in chain agent, alcamines chain extender, Diamines chain extender.
The instantiation of polyalcohols chain extender includes but is not limited to ethylene glycol, propane diols, BDO, a contracting diethyl
Glycol, glycerine, trimethylolpropane；The instantiation of alicyclic ring alcohols chain extender includes but is not limited to Isosorbide-5-Nitrae-cyclohexanediol, hydrogen
Change bisphenol-A；The instantiation of aromatic alcohols chain extender includes but is not limited to dimethylenebenzene glycol, hydroquinones bis-beta-hydroxyethyl second
Base ether, resorcinol hydroxy ether；The instantiation of alcamines chain extender includes but is not limited to diethanol amine, triethanolamine, methyl
Diethanol amine；The instantiation of Diamines chain extender includes but is not limited to diethyl toluene diamine, 3,5- dimethyl sulphur-baseds toluene two
Amine.
In the synthesis of polyurethane foam, using it is most be BDO.Polyurethane is substantially (A-B) x types
Linear structure block copolymer, its soft chain segment is made up of polyalcohols macromolecular, and hard segment is by diisocyanate and low molecule
Glycol reaction is constituted, and BDO has moderate carbon-to-carbon chain length, and soft, hard segment can be made to produce microcell to separation, makes
The crystallinity of urethane hard segment more preferably, that is, causes that MDI-1, the hard chain of 4 butanediols can be oriented preferably；Crystallization and orientation row
Row are more readily formed hydrogen chain between making polymer molecule, it is meant that can produce preferable ordered crystalline, and the resistance rotation of crystallization is acted on and poly-
Polymer segments are migrated, and finally showing polymer has excellent toughness and hardness.
Chain extender based on aliphatic alcohols, in foam class product, be mainly used in the soft bubble of resilience high, partly hard bubble, RIM it is hard
In the production of product such as bubble and micro-pore elastomer, they are not only involved in reaction, with chain extension and crosslinked action, adjust foams
Structure and percent opening, improve resilience, rigidity and the mechanical property of product, while it can also reduce raw material components viscosity, improve
The intermiscibility of feed components.
Aliphatic alcohols chain extender is application especially in MDI bases PUR products in the products such as polyurethane elastomer, coating
Extremely wide chain extender.In alcohols chain extender newly developed, it is worth proposing two kinds with aromatic ring two that are referred to as HQEE and HER
Alcohol chain extender.
In aliphatic alcohols chain extender, in addition to two function based compounds, also commonly using trifunctional or tetrafunctional base
Compound.It is conventional to have trimethylolpropane and pentaerythrite etc..They make with isocyanates reaction generation carbamate groups
While strand increases, the reflecting point of side chain can be also drawn in the strand of generation, polymer molecule is produced certain journey
Degree crosslinking, forms network structure.
Low-molecular-weight diamine compounds are very fierce with di-isocyanate reaction, and plastic speed is rapid, produce not easily-controllable
System, but its urea groups high with isocyanates reaction generation cohesive energy, can assign polyether polyols good physical and mechanical properties；
Hindered amine compound is generally used, wherein foremost is chloro- 4, the 4- diaminodiphenyl-methanes of 3,3'- bis-；At MOCA points
In son, due to the electron attraction and steric hindrance function that there is chlorine atom at the ortho position of amino, so that the reactivity of amino is fitted
Work as reduction, polyurethane gle technique can be well adapted for.
At present using more alcamines chain extender mainly have monoethanolamine, diethanol amine, triethanolamine, triisopropanolamine and
Double (2- hydroxypropyls) aniline of N, N- etc..They act not only as the initiator in common polyether synthesis, while can also make poly- ammonia
The chain extender of ester material and be used for the soft bubble of resilience high, partly hard bubble and hard bubble formula in, they have reduce material viscosity, improve thing
Material emulsifying capacity, is conducive to material to be full of complicated mold cavity.When the use of the aromatic amines such as aniline, toluenediamine being initiator, make epoxy
Ethane or expoxy propane carry out polymerisation, control extent of polymerization, prepare the fragrant amidogen ether oligomer of molecular weight 200-600,
In the productions of product such as they can be widely used in partly hard bubbling as chain extender, RIM hard bubbles, elastomer.
The present invention is expanded on further with reference to specific embodiment.
Embodiment 1
A kind of hydrate colour environmental protection super abrasive plastic cement race track material, in parts by weight, its preparing raw material includes：Two isocyanic acids
23 parts of ester, 45 parts of PPG, 12 parts of epoxyoleic acid last of the ten Heavenly stems ester, 0.08 part of dilauryl thiodipropionate, 8 parts of zinc yellow, activity
62 parts of calcium carbonate, 1.2 parts of Isosorbide-5-Nitrae-cyclohexanediol.Wherein, diisocyanate is naphthalene diisocyanate and 1, hexamethylene-diisocyanate
Mixture, the naphthalene diisocyanate and 1, the weight ratio of hexamethylene-diisocyanate is 3：20.The PPG is poly-
The weight of the mixture of propylene oxide glycol and polytetrahydrofuran diol, the polyoxypropyleneglycol and polytetrahydrofuran diol
Than being 5：1.
Embodiment 2
A kind of hydrate colour environmental protection super abrasive plastic cement race track material, in parts by weight, its preparing raw material includes：Two isocyanic acids
23 parts of ester, 45 parts of PPG, 12 parts of epoxyoleic acid last of the ten Heavenly stems ester, 0.08 part of dilauryl thiodipropionate, 8 parts of zinc yellow, activity
62 parts of calcium carbonate, 1.2 parts of Isosorbide-5-Nitrae-cyclohexanediol.Wherein, diisocyanate is naphthalene diisocyanate and 1, hexamethylene-diisocyanate
Mixture, the naphthalene diisocyanate and 1, the weight ratio of hexamethylene-diisocyanate is 20：3.The PPG is poly-
The weight of the mixture of propylene oxide glycol and polytetrahydrofuran diol, the polyoxypropyleneglycol and polytetrahydrofuran diol
Than being 5：1.
Embodiment 3
A kind of hydrate colour environmental protection super abrasive plastic cement race track material, in parts by weight, its preparing raw material includes：Two isocyanic acids
23 parts of ester, 45 parts of PPG, 12 parts of epoxyoleic acid last of the ten Heavenly stems ester, 0.08 part of dilauryl thiodipropionate, 8 parts of zinc yellow, activity
62 parts of calcium carbonate, 1.2 parts of Isosorbide-5-Nitrae-cyclohexanediol.Wherein, diisocyanate is naphthalene diisocyanate and 1, hexamethylene-diisocyanate
Mixture, the naphthalene diisocyanate and 1, the weight ratio of hexamethylene-diisocyanate is 3：20.The PPG is poly-
The weight of the mixture of propylene oxide glycol and polytetrahydrofuran diol, the polyoxypropyleneglycol and polytetrahydrofuran diol
Than being 1：5.
Embodiment 4
A kind of hydrate colour environmental protection super abrasive plastic cement race track material, in parts by weight, its preparing raw material includes：Two isocyanic acids
23 parts of ester, 45 parts of PPG, 12 parts of epoxyoleic acid last of the ten Heavenly stems ester, 0.08 part of dilauryl thiodipropionate, 8 parts of zinc yellow, activity
62 parts of calcium carbonate, 1.2 parts of Isosorbide-5-Nitrae-cyclohexanediol.Wherein, diisocyanate is naphthalene diisocyanate.The PPG is poly-
The weight of the mixture of propylene oxide glycol and polytetrahydrofuran diol, the polyoxypropyleneglycol and polytetrahydrofuran diol
Than being 5：1.
Embodiment 5
A kind of hydrate colour environmental protection super abrasive plastic cement race track material, in parts by weight, its preparing raw material includes：Two isocyanic acids
23 parts of ester, 45 parts of PPG, 12 parts of epoxyoleic acid last of the ten Heavenly stems ester, 0.08 part of dilauryl thiodipropionate, 8 parts of zinc yellow, activity
62 parts of calcium carbonate, 1.2 parts of Isosorbide-5-Nitrae-cyclohexanediol.Wherein, diisocyanate is 1, hexamethylene-diisocyanate.The PPG
For polyoxypropyleneglycol and the mixture of polytetrahydrofuran diol, the polyoxypropyleneglycol and polytetrahydrofuran diol
Weight ratio is 5：1.
Embodiment 6
A kind of hydrate colour environmental protection super abrasive plastic cement race track material, in parts by weight, its preparing raw material includes：Two isocyanic acids
23 parts of ester, 45 parts of PPG, 12 parts of epoxyoleic acid last of the ten Heavenly stems ester, 0.08 part of dilauryl thiodipropionate, 8 parts of zinc yellow, activity
62 parts of calcium carbonate, 1.2 parts of Isosorbide-5-Nitrae-cyclohexanediol.Wherein, diisocyanate is naphthalene diisocyanate and 1, hexamethylene-diisocyanate
Mixture, the naphthalene diisocyanate and 1, the weight ratio of hexamethylene-diisocyanate is 3：20.The PPG is poly-
Propylene oxide glycol.
Embodiment 7
A kind of hydrate colour environmental protection super abrasive plastic cement race track material, in parts by weight, its preparing raw material includes：Two isocyanic acids
23 parts of ester, 45 parts of PPG, 12 parts of epoxyoleic acid last of the ten Heavenly stems ester, 0.08 part of dilauryl thiodipropionate, 8 parts of zinc yellow, activity
62 parts of calcium carbonate, 1.2 parts of Isosorbide-5-Nitrae-cyclohexanediol.Wherein, diisocyanate is naphthalene diisocyanate and 1, hexamethylene-diisocyanate
Mixture, the naphthalene diisocyanate and 1, the weight ratio of hexamethylene-diisocyanate is 3：20.The PPG is poly-
Erythritan.
The preparation method of embodiment 1-7 is：
(1) diisocyanate, PPG are added in a reservoir, is stirred, be warmed up to 50 DEG C, stir 1.5h, then
Isosorbide-5-Nitrae-cyclohexanediol is added, 1h is stirred, 90 DEG C are warmed up to, continues to stir 10h；
(2) after reaction terminates, vacuum distillation, then with tetrahydrofuran/recrystallizing methanol, vacuum drying is obtained final product.
According to the hardness and tensile strength of GB/T 14833-93 testing example 1-7.
| Embodiment | Hardness (Shao A), degree | Tensile strength, MPa |
| Embodiment 1 | 75 | 1.4 |
| Embodiment 2 | 68 | 1.1 |
| Embodiment 3 | 72 | 0.6 |
| Embodiment 4 | 65 | 1.2 |
| Embodiment 5 | 60 | 1.1 |
| Embodiment 6 | 70 | 0.6 |
| Embodiment 7 | 71 | 0.4 |
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto, and appoints
What those familiar with the art the invention discloses in the range of, technology according to the present invention scheme and inventive concept
It is subject to equivalent or change, belongs to protection scope of the present invention.
Claims (10)
1. a kind of hydrate colour environmental protection super abrasive plastic cement race track material, it is characterised in that in parts by weight, its preparing raw material bag
Include：
2. hydrate colour as claimed in claim 1 environmental protection super abrasive plastic cement race track material, it is characterised in that two isocyanic acid
Ester be selected from naphthalene diisocyanate, toluene di-isocyanate(TDI), methyl diphenylene diisocyanate, hexamethylene diisocyanate in extremely
Few one kind.
3. hydrate colour as claimed in claim 2 environmental protection super abrasive plastic cement race track material, it is characterised in that two isocyanic acid
Ester is naphthalene diisocyanate and 1, the mixture of hexamethylene-diisocyanate, the naphthalene diisocyanate and 1, hexamethylene-diisocyanate
Weight ratio be 3：20.
4. hydrate colour as claimed in claim 1 environmental protection super abrasive plastic cement race track material, it is characterised in that the polyether polyols
Alcohol is selected from polyoxypropyleneglycol and/or polytetrahydrofuran diol.
5. hydrate colour as claimed in claim 4 environmental protection super abrasive plastic cement race track material, it is characterised in that the polyether polyols
Alcohol is the mixture of polyoxypropyleneglycol and polytetrahydrofuran diol, the polyoxypropyleneglycol and polytetrahydrofuran diol
Weight ratio be 5：1.
6. hydrate colour as claimed in claim 1 environmental protection super abrasive plastic cement race track material, it is characterised in that the plasticizer choosing
From phthalic ester plasticizer, glutaric acid ester plasticizer, adipic acid ester plasticizer, azelaic acid ester plasticizer, the last of the ten Heavenly stems
Two acid ester type plasticizers, phosphate plasticizer, stearic acid ester plasticizer, laurate ester plasticizer, citric acid ester type increase
It is modeling agent, oleic acid ester plasticizer, trimellitic acid esters plasticizer, epoxy analog derivative plasticizer, sulfonic acid plasticizer, many
One kind in first 01 derivatives plasticizer, maleic acid ester plasticizer, fumaric acid esters plasticizer, itaconic acid ester plasticizer.
7. hydrate colour as claimed in claim 1 environmental protection super abrasive plastic cement race track material, it is characterised in that the antioxidant choosing
From phenolic antioxidant, amine antioxidants, phosphite ester kind antioxidant, containing the one kind in sulphur ester antioxidant.
8. hydrate colour as claimed in claim 1 environmental protection super abrasive plastic cement race track material, it is characterised in that the pigment is selected from
Titanium white, iron oxide yellow, iron oxide red, iron oxide black, cadmium yellow, cadmium red, cadmium orange, chrome yellow, zinc yellow, molybdate orange, chrome vermillion, chrome green, barba hispanica, lithopone, zinc white,
At least one in stibium trioxide, pucherite, titanate.
9. hydrate colour as claimed in claim 1 environmental protection super abrasive plastic cement race track material, it is characterised in that described filler is selected from
At least one in calcium carbonate, talcum powder, potter's clay, blanc fixe, gypsum, mica powder, white carbon, diatomite, calcium silicates.
10. hydrate colour as claimed in claim 1 environmental protection super abrasive plastic cement race track material, it is characterised in that the chain extender
Selected from polyalcohols chain extender, alicyclic ring alcohols chain extender, aromatic alcohols chain extender, alcamines chain extender, Diamines chain extender
It is a kind of.
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| CN107236284A (en) * | 2017-07-26 | 2017-10-10 | 保定市日新塑胶制造有限公司 | A kind of thermoplastic polyurethane particle |
| CN107955125A (en) * | 2017-11-30 | 2018-04-24 | 太仓冠联高分子材料有限公司 | A kind of Environment-friendlywear-resistant wear-resistant plastic cement race track material |
| CN108929422A (en) * | 2018-08-23 | 2018-12-04 | 江苏好友地坪科技有限公司 | A kind of modified plastic rubber and preparation method thereof using nano silica foaming reinforcing material |
| CN111087649A (en) * | 2019-12-11 | 2020-05-01 | 中国平煤神马能源化工集团有限责任公司 | Coal-rock mass reinforcing composite plasticizer and application |
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| CN103387652A (en) * | 2013-08-08 | 2013-11-13 | 常熟市中腾塑胶有限公司 | Method for preparing environmentally-friendly polyurethane plastic for track |
| CN104086977A (en) * | 2014-06-09 | 2014-10-08 | 江苏欣润塑胶有限公司 | Preparation method of environment-friendly polyurethane plastic |
| CN105399926A (en) * | 2015-12-23 | 2016-03-16 | 刘家容 | One-component moisture curing-type polyurethane plastic racetrack material and preparation method thereof |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103387652A (en) * | 2013-08-08 | 2013-11-13 | 常熟市中腾塑胶有限公司 | Method for preparing environmentally-friendly polyurethane plastic for track |
| CN104086977A (en) * | 2014-06-09 | 2014-10-08 | 江苏欣润塑胶有限公司 | Preparation method of environment-friendly polyurethane plastic |
| CN105399926A (en) * | 2015-12-23 | 2016-03-16 | 刘家容 | One-component moisture curing-type polyurethane plastic racetrack material and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107236284A (en) * | 2017-07-26 | 2017-10-10 | 保定市日新塑胶制造有限公司 | A kind of thermoplastic polyurethane particle |
| CN107955125A (en) * | 2017-11-30 | 2018-04-24 | 太仓冠联高分子材料有限公司 | A kind of Environment-friendlywear-resistant wear-resistant plastic cement race track material |
| CN108929422A (en) * | 2018-08-23 | 2018-12-04 | 江苏好友地坪科技有限公司 | A kind of modified plastic rubber and preparation method thereof using nano silica foaming reinforcing material |
| CN111087649A (en) * | 2019-12-11 | 2020-05-01 | 中国平煤神马能源化工集团有限责任公司 | Coal-rock mass reinforcing composite plasticizer and application |
| CN111087649B (en) * | 2019-12-11 | 2021-11-09 | 中国平煤神马能源化工集团有限责任公司 | Coal-rock mass reinforcing composite plasticizer and application |
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