CN103030905A - High-strength and high-stability modified PVC and preparation method thereof - Google Patents
High-strength and high-stability modified PVC and preparation method thereof Download PDFInfo
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- CN103030905A CN103030905A CN2012105852742A CN201210585274A CN103030905A CN 103030905 A CN103030905 A CN 103030905A CN 2012105852742 A CN2012105852742 A CN 2012105852742A CN 201210585274 A CN201210585274 A CN 201210585274A CN 103030905 A CN103030905 A CN 103030905A
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- Prior art keywords
- modified pvc
- pvc
- strength height
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- polyvinyl chloride
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- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 40
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 35
- 239000011347 resin Substances 0.000 claims abstract description 15
- 229920005989 resin Polymers 0.000 claims abstract description 15
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000004801 Chlorinated PVC Substances 0.000 claims abstract description 7
- 229920000457 chlorinated polyvinyl chloride Polymers 0.000 claims abstract description 7
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical group [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 11
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 9
- 230000004048 modification Effects 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 7
- 238000012986 modification Methods 0.000 claims description 7
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004902 Softening Agent Substances 0.000 claims description 4
- 239000003963 antioxidant agent Substances 0.000 claims description 4
- 230000003078 antioxidant effect Effects 0.000 claims description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 4
- 239000000945 filler Substances 0.000 claims description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 230000036760 body temperature Effects 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000007822 coupling agent Substances 0.000 claims description 3
- 238000005453 pelletization Methods 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical group CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 claims description 2
- 244000248349 Citrus limon Species 0.000 claims description 2
- 235000005979 Citrus limon Nutrition 0.000 claims description 2
- 239000006229 carbon black Substances 0.000 claims description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 2
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 230000008901 benefit Effects 0.000 abstract description 3
- 230000007797 corrosion Effects 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 2
- 230000008569 process Effects 0.000 abstract description 2
- 239000003381 stabilizer Substances 0.000 abstract description 2
- 239000003086 colorant Substances 0.000 abstract 1
- 239000002530 phenolic antioxidant Substances 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 230000032683 aging Effects 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000002715 modification method Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses high-strength and high-stability modified PVC (polyvinyl chloride) which comprises the following components in parts by weight: 100 parts of PVC resin, 20-55 parts of CPVC (chlorinated polyvinyl chloride) resin, 15-20 parts of phenolic antioxidant, 1-12 parts of titanium dioxide, 15-35 parts of plasticizer, 2-8 parts of stabilizer, 0-3 parts of colorant, and 2-10 parts of filling. The high-strength and high-stability modified PVC has the benefits that: the modified PVC has good mechanical property, high strength, good balance of stiffness and toughness, heat resistance, light resistance, corrosion resistance, and high stability; the service life of a product is ensured; in addition, the preparation method is good in repeatability; the process is controllable; the manufacturing cost is low; and the industrial large-scale application is facilitated.
Description
Technical field
The present invention relates to a kind of PVC of modification, have high strength and high stability, be particularly useful for the rubbing strip in the automobile manufacturing field, belong to polymeric material field.
Background technology
The PVC(polyvinyl chloride) material has better mechanical property, the advantage that fire-retardant, electric insulating quality is good, and the lower and easy processing of manufacturing cost, is widely used in producing the various fields such as plastics soft goods, pipeline, the packing of product.Development along with automotive industry, research finds that polyvinyl chloride is expected to be widely used in use as rubbing strip in the automobile making, but general PVC performance is difficult to satisfy the high strength of rubbing strip, the requirement of high stability, so, in the urgent need to PVC is carried out modification, make it have better mechanical property, have intensity high, the characteristics such as rigid-tough balance is good, and is heat-resisting, fast light, corrosion-resistant.
Summary of the invention
For solving the deficiencies in the prior art, the object of the invention is to overcome the defective of prior art, PVC of a kind of modification and preparation method thereof is provided, have high strength and high stability.
In order to realize above-mentioned target, the present invention adopts following technical scheme:
The steady modified PVC of a kind of high-strength height is comprised of by following weight part following composition:
100 parts of polyvinyl chloride (PVC) RESINS
Chlorinated polyvinyl chloride resin 20-55 part
Phenol antioxidant 15-20 part
Titanium dioxide 1-12 part
Softening agent 15-35 part
Stablizer 2-8 part
Tinting material 0-3 part
Filler 2-10 part
The mean polymerisation degree of aforementioned polyvinyl chloride (PVC) RESINS is 800-1500.
Chlorinity is 65%-70% in the aforementioned chlorinated polyvinyl chloride resin.
Aforementioned titanium dioxide is nano level, and its median size is 20-80nm.
Aforementioned phenol antioxidant is dihydroxyphenyl propane.
Aforementioned softening agent is a kind of in o-phthalic acid dibutyl ester, dibutyl phthalate, the triphenylphosphate.
Aforementioned tinting material is a kind of in carbon black, red iron oxide, the lemon yellow.
Aforementioned filler is calcium carbonate.
Aforementioned calcium carbonate is for having adopted titanate coupling agent to carry out surface-treated calcium carbonate.
Prepare the steady modified PVC of aforesaid a kind of high-strength height, comprise the steps:
S1, take by weighing each component according to weight ratio, in premixing machine, mix and be heated to 70-90 ℃, be incubated 15 minutes;
S2, the mixture of step S1 gained is added twin screw extruder, body temperature is 160 ℃, and district's temperature is 180 ℃, and two district's temperature are 200 ℃, and three district's temperature are 205 ℃, and engine speed is 20-35rpm;
S3, extrude the polyvinyl chloride resin of modification, cooling, through the tablets press pelletizing, minute grade packaged.
Usefulness of the present invention is: modified PVC of the present invention, have good mechanical property, and intensity is high, and rigid-tough balance is good, and is heat-resisting, fast light, corrosion-resistant, and stability is strong, has guaranteed the work-ing life of product.And preparation method's good reproducibility, process is controlled, and production cost is low, is convenient to large-scale industrialization and uses.
Embodiment
Carry out each composition of proportioning by the weight shown in the table 1.
Each composition weight of table 1 embodiment 1-4
Wherein, among the embodiment 1-4, the mean polymerisation degree of polyvinyl chloride (PVC) RESINS is 800-1500; Chlorinity is 65%-70% in the chlorinated polyvinyl chloride resin; The median size of nano titanium oxide is respectively 20nm, 40nm, 60nm, 80nm; Stablizer is organotin stabilizer.
Calcium carbonate surface-treated concrete grammar is: calcium carbonate is dropped in the mixing machine, be heated to 60 ℃ and be incubated appropriate time, then add titanate coupling agent in the mixing machine and mix, discharging is stand-by after 10-25 minute, note keeping calcium carbonate dry, prevent moisture absorption.
Preparation process is as follows: S1, take by weighing each component according to the weight of table 1, mix and be heated to 70-90 ℃ in premixing machine, be incubated 15 minutes;
S2, the mixture of step S1 gained is added twin screw extruder, body temperature is 160 ℃, and district's temperature is 180 ℃, and two district's temperature are 200 ℃, and three district's temperature are 205 ℃, and engine speed is 20-35rpm;
S3, extrude the polyvinyl chloride resin of modification, cooling, through the tablets press pelletizing, minute grade packaged.
The performance of the modified PVC that embodiment 1-4 prepares sees Table 2.
| ? | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Comparative Examples |
| Tensile strength/MPa | 85 | 88 | 93 | 80 | 65 |
| Shore hardness | A95 +5 | A95 +5 | A95 +5 | A95 +5 | A95 +5 |
| Elongation at break | 360% | 380% | 355% | 400% | 260% |
| Colour fastness (the xenon irradiation is after 1000 hours) | 〉=4.5 grades | 〉=4.5 grades | 〉=4.5 grades | 〉=4.5 grades | ＜4.5 grades |
| Ageing-resistant performance (in the ageing oven 60 ℃, behind the 240h) | Without aging | Without aging | Without aging | Without aging | Have aging |
The performance of each embodiment of table 2 and right, wherein, Comparative Examples is unmodified PVC.
This shows, through modifying character for PVC material, intensity is higher, and in the essentially identical situation of shore hardness, the PVC elongation at break of modification is longer, illustrates that its rigid-tough balance is better; And the colour fastness of the PVC of modification and ageing-resistant performance all obviously be better than unmodified PVC, and its weathering resistance and longer service life are described, the rubbing strip that can satisfy in the automotive field uses.
Above demonstration and described ultimate principle of the present invention, principal character and advantage.The technician of the industry should understand, and above-described embodiment does not limit the present invention in any form, and all employings are equal to replaces or technical scheme that the mode of equivalent transformation obtains, all drops in protection scope of the present invention.
Claims (10)
1. the modified PVC that high-strength height is steady is characterized in that, is comprised of by following weight part following composition:
100 parts of polyvinyl chloride (PVC) RESINS
Chlorinated polyvinyl chloride resin 20-55 part
Phenol antioxidant 15-20 part
Titanium dioxide 1-12 part
Softening agent 15-35 part
Stablizer 2-8 part
Tinting material 0-3 part
Filler 2-10 part.
2. the steady modified PVC of a kind of high-strength height according to claim 1 is characterized in that, the mean polymerisation degree of above-mentioned polyvinyl chloride (PVC) RESINS is 800-1500.
3. the steady modified PVC of a kind of high-strength height according to claim 1 is characterized in that, chlorinity is 65%-70% in the above-mentioned chlorinated polyvinyl chloride resin.
4. the steady modified PVC of a kind of high-strength height according to claim 1 is characterized in that, above-mentioned titanium dioxide is nano level, and its median size is 20-80nm.
5. the steady modified PVC of a kind of high-strength height according to claim 1 is characterized in that, above-mentioned phenol antioxidant is dihydroxyphenyl propane.
6. the steady modified PVC of a kind of high-strength height according to claim 1 is characterized in that, above-mentioned softening agent is a kind of in o-phthalic acid dibutyl ester, dibutyl phthalate, the triphenylphosphate.
7. the steady modified PVC of a kind of high-strength height according to claim 1 is characterized in that, above-mentioned tinting material is a kind of in carbon black, red iron oxide, the lemon yellow.
8. the steady modified PVC of a kind of high-strength height according to claim 1 is characterized in that, above-mentioned filler is calcium carbonate.
9. the steady modified PVC of a kind of high-strength height according to claim 8 is characterized in that, above-mentioned calcium carbonate is for having adopted titanate coupling agent to carry out surface-treated calcium carbonate.
10. the steady modified PVC of preparation claim each described a kind of high-strength height of 1-9 is characterized in that, comprises the steps:
S1, take by weighing each component according to weight ratio, in premixing machine, mix and be heated to 70-90 ℃, be incubated 15 minutes;
S2, the mixture of step S1 gained is added twin screw extruder, body temperature is 160 ℃, and district's temperature is 180 ℃, and two district's temperature are 200 ℃, and three district's temperature are 205 ℃, and engine speed is 20-35rpm;
S3, extrude the polyvinyl chloride resin of modification, cooling, through the tablets press pelletizing, minute grade packaged.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012105852742A CN103030905A (en) | 2012-12-30 | 2012-12-30 | High-strength and high-stability modified PVC and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012105852742A CN103030905A (en) | 2012-12-30 | 2012-12-30 | High-strength and high-stability modified PVC and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN103030905A true CN103030905A (en) | 2013-04-10 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012105852742A Pending CN103030905A (en) | 2012-12-30 | 2012-12-30 | High-strength and high-stability modified PVC and preparation method thereof |
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| Country | Link |
|---|---|
| CN (1) | CN103030905A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103396629A (en) * | 2013-07-15 | 2013-11-20 | 安徽省振云塑胶有限公司 | Smoke-suppressing flame-retardant sound-insulating PVC (polyvinyl chloride) and preparation method thereof |
| CN103483875A (en) * | 2013-09-29 | 2014-01-01 | 昆山市华浦塑业有限公司 | Method for modifying nano calcium carbonate by titanate and preparation method of PVC (polyvinyl chloride) plastic |
| CN104672718A (en) * | 2015-03-09 | 2015-06-03 | 苏州市景荣科技有限公司 | Heat-resistant PVC shoe material and preparation method thereof |
| CN105061949A (en) * | 2015-09-07 | 2015-11-18 | 太仓金昊达新材料有限公司 | Insulating PVC (polyvinyl chloride) plastic particle |
| CN107057226A (en) * | 2017-05-06 | 2017-08-18 | 安徽玉发塑业有限公司 | A kind of protective gloves pvc material and preparation method thereof |
| CN108641227A (en) * | 2018-04-29 | 2018-10-12 | 姜丽丽 | One kind is resistance to decompose weather-proof coloring polyvinyl chloride and preparation method thereof |
| CN114656733A (en) * | 2022-04-27 | 2022-06-24 | 广东联塑科技实业有限公司 | Modified polyvinyl chloride, polyvinyl chloride noise reduction composite pipe and preparation method thereof |
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| CN1094421A (en) * | 1993-04-28 | 1994-11-02 | 化学工业部北京化工研究院 | The modified polyvinyl chloride material of high-strength weather-proof |
| EP1048689A1 (en) * | 1999-04-28 | 2000-11-02 | Kyowa Chemical Industry Co., Ltd. | Chlorine-Containing resin composition |
| WO2001021678A1 (en) * | 1999-09-21 | 2001-03-29 | Northwestern University | Self-assembling compounds and use of the same to induce order in organic media |
| CN1500832A (en) * | 2002-11-18 | 2004-06-02 | 华昌工贸有限公司 | Polyvinyl chloride (PVC) plastic-wood panel |
| CN101497727A (en) * | 2009-03-04 | 2009-08-05 | 南亚塑胶工业股份有限公司 | PVC resin composition and product thereof |
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2012
- 2012-12-30 CN CN2012105852742A patent/CN103030905A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1094421A (en) * | 1993-04-28 | 1994-11-02 | 化学工业部北京化工研究院 | The modified polyvinyl chloride material of high-strength weather-proof |
| EP1048689A1 (en) * | 1999-04-28 | 2000-11-02 | Kyowa Chemical Industry Co., Ltd. | Chlorine-Containing resin composition |
| WO2001021678A1 (en) * | 1999-09-21 | 2001-03-29 | Northwestern University | Self-assembling compounds and use of the same to induce order in organic media |
| CN1500832A (en) * | 2002-11-18 | 2004-06-02 | 华昌工贸有限公司 | Polyvinyl chloride (PVC) plastic-wood panel |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103396629A (en) * | 2013-07-15 | 2013-11-20 | 安徽省振云塑胶有限公司 | Smoke-suppressing flame-retardant sound-insulating PVC (polyvinyl chloride) and preparation method thereof |
| CN103396629B (en) * | 2013-07-15 | 2015-07-08 | 胡本巨 | Smoke-suppressing flame-retardant sound-insulating PVC (polyvinyl chloride) and preparation method thereof |
| CN103483875A (en) * | 2013-09-29 | 2014-01-01 | 昆山市华浦塑业有限公司 | Method for modifying nano calcium carbonate by titanate and preparation method of PVC (polyvinyl chloride) plastic |
| CN104672718A (en) * | 2015-03-09 | 2015-06-03 | 苏州市景荣科技有限公司 | Heat-resistant PVC shoe material and preparation method thereof |
| CN105061949A (en) * | 2015-09-07 | 2015-11-18 | 太仓金昊达新材料有限公司 | Insulating PVC (polyvinyl chloride) plastic particle |
| CN107057226A (en) * | 2017-05-06 | 2017-08-18 | 安徽玉发塑业有限公司 | A kind of protective gloves pvc material and preparation method thereof |
| CN108641227A (en) * | 2018-04-29 | 2018-10-12 | 姜丽丽 | One kind is resistance to decompose weather-proof coloring polyvinyl chloride and preparation method thereof |
| CN108641227B (en) * | 2018-04-29 | 2020-09-29 | 乐清市钜派企业管理咨询有限公司 | Decomposition-resistant weather-resistant colored polyvinyl chloride and preparation method thereof |
| CN114656733A (en) * | 2022-04-27 | 2022-06-24 | 广东联塑科技实业有限公司 | Modified polyvinyl chloride, polyvinyl chloride noise reduction composite pipe and preparation method thereof |
| CN114656733B (en) * | 2022-04-27 | 2023-05-09 | 广东联塑科技实业有限公司 | Modified polyvinyl chloride, polyvinyl chloride silencing composite pipe and preparation method thereof |
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Application publication date: 20130410 |