CN106630583A - High-strength basalt fiber composite bar - Google Patents
High-strength basalt fiber composite bar Download PDFInfo
- Publication number
- CN106630583A CN106630583A CN201611145771.5A CN201611145771A CN106630583A CN 106630583 A CN106630583 A CN 106630583A CN 201611145771 A CN201611145771 A CN 201611145771A CN 106630583 A CN106630583 A CN 106630583A
- Authority
- CN
- China
- Prior art keywords
- basalt
- basalt fibre
- strength
- composite reinforcement
- fibre composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920002748 Basalt fiber Polymers 0.000 title claims abstract description 66
- 239000002131 composite material Substances 0.000 title claims abstract description 41
- 229920005989 resin Polymers 0.000 claims abstract description 28
- 239000011347 resin Substances 0.000 claims abstract description 28
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 23
- 239000011159 matrix material Substances 0.000 claims abstract description 18
- 239000000835 fiber Substances 0.000 claims abstract description 17
- 239000004575 stone Substances 0.000 claims abstract description 11
- 238000002360 preparation method Methods 0.000 claims abstract description 10
- 229920001567 vinyl ester resin Polymers 0.000 claims abstract description 6
- 239000011435 rock Substances 0.000 claims abstract 2
- 230000002787 reinforcement Effects 0.000 claims description 27
- 238000000465 moulding Methods 0.000 claims description 11
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 claims description 10
- 239000007864 aqueous solution Substances 0.000 claims description 9
- 229910021532 Calcite Inorganic materials 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- 239000003292 glue Substances 0.000 claims description 6
- 238000002791 soaking Methods 0.000 claims description 6
- 239000004925 Acrylic resin Substances 0.000 claims description 5
- 229920000178 Acrylic resin Polymers 0.000 claims description 5
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 claims description 5
- 230000003750 conditioning effect Effects 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 4
- 238000010792 warming Methods 0.000 claims description 4
- 241000233855 Orchidaceae Species 0.000 claims description 3
- 229910000629 Rh alloy Inorganic materials 0.000 claims description 3
- 239000002585 base Substances 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 238000002386 leaching Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 238000010422 painting Methods 0.000 claims description 3
- PXXKQOPKNFECSZ-UHFFFAOYSA-N platinum rhodium Chemical compound [Rh].[Pt] PXXKQOPKNFECSZ-UHFFFAOYSA-N 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 241001163600 Bathylaco nigricans Species 0.000 claims 1
- 239000012756 surface treatment agent Substances 0.000 claims 1
- 238000005491 wire drawing Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000003208 petroleum Substances 0.000 abstract description 2
- -1 polypropylene Polymers 0.000 abstract description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 abstract 1
- 239000004743 Polypropylene Substances 0.000 abstract 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 abstract 1
- 238000010276 construction Methods 0.000 abstract 1
- 238000009776 industrial production Methods 0.000 abstract 1
- 229920001155 polypropylene Polymers 0.000 abstract 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 abstract 1
- 239000003365 glass fiber Substances 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 230000003014 reinforcing effect Effects 0.000 description 5
- 238000005452 bending Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000007547 defect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 208000019693 Lung disease Diseases 0.000 description 1
- 241001274660 Modulus Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 210000003205 muscle Anatomy 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B37/00—Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/28—Macromolecular compounds or prepolymers obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C03C25/30—Polyolefins
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Reinforced Plastic Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a high-strength basalt fiber composite bar which is a fiber bar prepared by treating basalt fibers with a surface treating agent, immersing and curing by a matrix resin, wherein the basalt fibers are made of the following components: basalt stone, nano-titanium carbide and ginger-like rock; the matrix resin is prepared from polypropylene resin, vinyl ester resin and rosin. The basalt fiber composite bar according to the invention has strong mechanical properties and can be widely used in industrial and civil construction industries, petroleum industries, aviation industries and the like. The preparation method of the basalt fiber composite bar provided by the invention not only is simple and rapid in step, but also can realize large-scale industrial production, and is low in production cost.
Description
Technical field
The present invention relates to field of compound material, more particularly to a kind of high-strength basalt fibre composite reinforcement.
Background technology
In existing field of compound material, mainly there are glass fibre, carbon fiber, boron fine as the fiber of composite reinforcing reinforcement
Dimension, alumina fibre, silicon carbide fibre, polyethylene fibre etc., but due to the restriction of price factor, most of fiber is all served only for
Military field, only glass fibre are also widely used for civil area, but in actual application, glass fibre is used as compound
Also there is certain defect in muscle reinforcement, such as：（1）The production process energy consumption of glass fibre is larger, is unfavorable for energy-conserving and environment-protective；（2）
To harmful, especially glass fibre hair can produce stimulation, suction to the preparation technology of glass fibre to human body skin
Can not be decomposed after human body or absorb, it is likely that cause pulmonary disease or even produce canceration；（3）Environmental pollution is big, glass fibre
Can not recycle or natural degradation after composite reinforcing is discarded, be unfavorable for protection of environment, etc..
To overcome the use defect of above-mentioned composite reinforcing reinforcement, there has been proposed being increased as composite reinforcing using basalt fibre
The use of strong body.
The content of the invention
It is an object of the invention to provide a kind of high-strength basalt fibre composite reinforcement, is achieved through the following technical solutions：
A kind of high-strength basalt fibre composite reinforcement, described high-strength basalt fibre composite reinforcement is by basalt fibre Jing tables
After face inorganic agent is processed, then the fiber bar material for being impregnated by matrix resin and being solidified；
The basalt fibre is made up by weight of following component：Basalt building stones 120-130, nano titanium carbide 0.2-
0.3rd, calcite 0.5-0.6；
Described matrix resin is made up by weight of acrylic resin 8-10, vinyl ester resin 42-45, Colophonium 1-2.
Further：Described basalt fibre preparation method is：Basalt building stones, nano titanium carbide, calcite exist
After melting at 1480 DEG C, by the continuous fiber of platinum-rhodium alloy bushing high speed pulling.
Further：Described basalt fibre is a diameter of 6-13 μm.
Further：Described surface conditioning agent is that fertile orchid inorganic agent and KH560 inorganic agents press 4:1 mass ratio mix and
Into.
Further, the preparation method of described high-strength basalt fibre composite reinforcement, comprises the steps：
（1）Basalt fibre is surface-treated：By surface conditioning agent it is deployed after, with deionized water press 1:85 mass ratios mixing system
Into mixed aqueous solution, by basalt be put into made by soak in mixed aqueous solution, soaking temperature is 55 DEG C, and soak time is
40min, then takes out, drying, places after 10min naturally, places in mixed aqueous solution and soaks, and soaking temperature is 45 DEG C, leaching
The bubble time is 30min, is then taken out, and is dried, you can；
（2）Infusing matrix resin：Accelerator and firming agent are sequentially added in matrix resin, glue, base are obtained after stirring
Body resin：Accelerator：The weight proportion of firming agent is 350:0.4:0.8, the glue is applied using painting tool is covered with Jing tables
On basalt fibre after the process of face；
（3）Curing molding：By step（2）Obtained basalt fibre is put into curing molding according to 0 ° or 90 ° of direction orthogonal arrangement
Pressurize 1.2MPa in device, is warming up to 125 DEG C, after 30min, and moulding pressure is adjusted to 0.8MPa, temperature adjustment to 100 DEG C, 1h
Afterwards, you can high-strength basalt fibre composite reinforcement is obtained.
Beneficial effect of the present invention：Basalt fiber composite rib according to the present invention has stronger mechanical property, can be extensive
It is applied to the building trade such as industrial, civilian, petroleum industry and aircraft industry etc..It is prepared by Basalt fiber composite rib of the present invention
Not only making step is simple, quick for method, is also capable of achieving industrialized large-scale production, and cost of manufacture is cheap, by the present invention
Preparation method can improve the tensile strength of Basalt fiber composite rib 3-4% and the bending strength of 1-2%.Tests prove that, lead to
Cross and add a certain amount of titanium carbide and calcite when basalt building stones prepare basalt fibre, basalt can greatly be improved
Fibre single thread tensile strength, thus made by Basalt fiber composite rib performance it is more excellent, basalt prepared by the present invention is fine
The features such as dimension composite reinforcing has corrosion-resistant and good air stability, toughness and high intensity.
Specific embodiment
Embodiment 1
A kind of high-strength basalt fibre composite reinforcement, described high-strength basalt fibre composite reinforcement is by basalt fibre Jing tables
After face inorganic agent is processed, then the fiber bar material for being impregnated by matrix resin and being solidified；
The basalt fibre is made up by weight of following component：Basalt building stones 120, nano titanium carbide 0.2, calcite
0.5；
Described matrix resin is made up by weight of acrylic resin 8, vinyl ester resin 42, Colophonium 1.
Embodiment 2
A kind of high-strength basalt fibre composite reinforcement, described high-strength basalt fibre composite reinforcement is by basalt fibre Jing tables
After face inorganic agent is processed, then the fiber bar material for being impregnated by matrix resin and being solidified；
The basalt fibre is made up by weight of following component：Basalt building stones 130, nano titanium carbide 0.3, calcite
0.6；
Described matrix resin is made up by weight of acrylic resin 10, vinyl ester resin 45, Colophonium 2.
Embodiment 3
A kind of high-strength basalt fibre composite reinforcement, described high-strength basalt fibre composite reinforcement is by basalt fibre Jing tables
After face inorganic agent is processed, then the fiber bar material for being impregnated by matrix resin and being solidified；
The basalt fibre is made up by weight of following component：Basalt building stones 125, nano titanium carbide 0.25, material Rhizoma Zingiberis Recens
Stone 0.55；
Described matrix resin is made up by weight of acrylic resin 9, vinyl ester resin 43, Colophonium 1.5.
In above-described embodiment：
Further：Described basalt fibre preparation method is：Basalt building stones, nano titanium carbide, calcite are at 1480 DEG C
After lower melting, by the continuous fiber of platinum-rhodium alloy bushing high speed pulling.
Further：Described basalt fibre is a diameter of 6-13 μm.
Further：Described surface conditioning agent is that fertile orchid inorganic agent and KH560 inorganic agents press 4:1 mass ratio mix and
Into.
Further, the preparation method of described high-strength basalt fibre composite reinforcement, comprises the steps：
（1）Basalt fibre is surface-treated：By surface conditioning agent it is deployed after, with deionized water press 1:85 mass ratios mixing system
Into mixed aqueous solution, by basalt be put into made by soak in mixed aqueous solution, soaking temperature is 55 DEG C, and soak time is
40min, then takes out, drying, places after 10min naturally, places in mixed aqueous solution and soaks, and soaking temperature is 45 DEG C, leaching
The bubble time is 30min, is then taken out, and is dried, you can；
（2）Infusing matrix resin：Accelerator and firming agent are sequentially added in matrix resin, glue, base are obtained after stirring
Body resin：Accelerator：The weight proportion of firming agent is 350:0.4:0.8, the glue is applied using painting tool is covered with Jing tables
On basalt fibre after the process of face；
（3）Curing molding：By step（2）Obtained basalt fibre is put into curing molding according to 0 ° or 90 ° of direction orthogonal arrangement
Pressurize 1.2MPa in device, is warming up to 125 DEG C, after 30min, and moulding pressure is adjusted to 0.8MPa, temperature adjustment to 100 DEG C, 1h
Afterwards, you can high-strength basalt fibre composite reinforcement is obtained.
Comparative example 1：It is only that Basalt fiber composite rib is prepared using parabasalt fiber with the difference of embodiment 1.
Comparative example 2：It is only without nano titanium carbide when basalt fibre is prepared with the difference of embodiment 1.
Comparative example 3：When differing only in the curing molding in Basalt fiber composite rib preparation process with embodiment 1,
By step（2）Obtained basalt fibre is put in solidifying and molding device and pressurizes according to 0 ° or 90 ° of direction orthogonal arrangement
1.2MPa, is warming up to 125 DEG C, after 30min, you can high-strength basalt fibre composite reinforcement is obtained.
Basalt fiber composite rib performance（Basalt fibre is a diameter of 7 microns, and basalt fibre volume content is 37%）：
Table 1
| Tensile strength MPa | Elastic modelling quantity MPa | Bending strength MPa | Bending moduluses MPa | |
| Embodiment 1 | 286.8 | 16.9 | 504.3 | 17.7 |
| Embodiment 2 | 286.4 | 16.8 | 504.1 | 17.6 |
| Embodiment 3 | 286.5 | 16.6 | 504.2 | 17.4 |
| Comparative example 1 | 257.4 | 14.2 | 478.7 | 15.6 |
| Comparative example 2 | 262.5 | 14.9 | 489.4 | 16.2 |
| Comparative example 3 | 277.4 | 16.3 | 498.9 | 17.1 |
The Basalt fiber composite rib superior performance that as can be seen from Table 1 prepared by the present invention.
Claims (5)
1. a kind of high-strength basalt fibre composite reinforcement, it is characterised in that：Described high-strength basalt fibre composite reinforcement be by
After the agent of basalt fibre surface treated is processed, then the fiber bar material for being impregnated by matrix resin and being solidified；
The basalt fibre is made up by weight of following component：Basalt building stones 120-130, nano titanium carbide 0.2-
0.3rd, calcite 0.5-0.6；
Described matrix resin is made up by weight of acrylic resin 8-10, vinyl ester resin 42-45, Colophonium 1-2.
2. a kind of high-strength basalt fibre composite reinforcement according to claim 1, it is characterised in that：Described basalt is fine
Tieing up preparation method is：After basalt building stones, nano titanium carbide, calcite are melted at 1480 DEG C, leaked by platinum-rhodium alloy wire drawing
The continuous fiber of plate high speed pulling.
3. a kind of high-strength basalt fibre composite reinforcement according to claim 1 and 2, it is characterised in that：The described Black Warrior
Rock fibre diameter is 6-13 μm.
4. a kind of high-strength basalt fibre composite reinforcement according to claim 1, it is characterised in that：Described surface treatment
Agent is that fertile orchid inorganic agent and KH560 inorganic agents press 4:1 mass ratio is mixed.
5. a kind of high-strength basalt fibre composite reinforcement according to claim 1, it is characterised in that described high intensity is profound
The preparation method of military rock fibre composite reinforcement, comprises the steps：
（1）Basalt fibre is surface-treated：By surface conditioning agent it is deployed after, with deionized water press 1:85 mass ratios mixing system
Into mixed aqueous solution, by basalt be put into made by soak in mixed aqueous solution, soaking temperature is 55 DEG C, and soak time is
40min, then takes out, drying, places after 10min naturally, places in mixed aqueous solution and soaks, and soaking temperature is 45 DEG C, leaching
The bubble time is 30min, is then taken out, and is dried, you can；
（2）Infusing matrix resin：Accelerator and firming agent are sequentially added in matrix resin, glue, base are obtained after stirring
Body resin：Accelerator：The weight proportion of firming agent is 350:0.4:0.8, the glue is applied using painting tool is covered with Jing tables
On basalt fibre after the process of face；
（3）Curing molding：By step（2）Obtained basalt fibre is put into curing molding according to 0 ° or 90 ° of direction orthogonal arrangement
Pressurize 1.2MPa in device, is warming up to 125 DEG C, after 30min, and moulding pressure is adjusted to 0.8MPa, temperature adjustment to 100 DEG C, 1h
Afterwards, you can high-strength basalt fibre composite reinforcement is obtained.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611145771.5A CN106630583A (en) | 2016-12-13 | 2016-12-13 | High-strength basalt fiber composite bar |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611145771.5A CN106630583A (en) | 2016-12-13 | 2016-12-13 | High-strength basalt fiber composite bar |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106630583A true CN106630583A (en) | 2017-05-10 |
Family
ID=58825686
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611145771.5A Pending CN106630583A (en) | 2016-12-13 | 2016-12-13 | High-strength basalt fiber composite bar |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106630583A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108101446A (en) * | 2017-12-07 | 2018-06-01 | 成都天府轨谷科技有限公司 | Basalt fiber composite rib concrete and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007089286A2 (en) * | 2006-01-26 | 2007-08-09 | Rock Fiber Technology, Inc. | Process for producing chopped rock fibers |
| CN102470546A (en) * | 2009-08-03 | 2012-05-23 | 应用纳米结构方案公司 | Incorporation of nanoparticles in composite fibers |
| CN102674873A (en) * | 2012-05-24 | 2012-09-19 | 中南大学 | Prestressing tendon reinforced composite material and manufacturing method thereof |
| CN103435324A (en) * | 2013-07-27 | 2013-12-11 | 国家电网公司 | Foundation bolt make of basalt fiber and preparation method thereof |
| CN104059238A (en) * | 2014-06-25 | 2014-09-24 | 四川航天五源复合材料有限公司 | Preparation method of basalt fiber reinforced polymer rebar |
-
2016
- 2016-12-13 CN CN201611145771.5A patent/CN106630583A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007089286A2 (en) * | 2006-01-26 | 2007-08-09 | Rock Fiber Technology, Inc. | Process for producing chopped rock fibers |
| CN102470546A (en) * | 2009-08-03 | 2012-05-23 | 应用纳米结构方案公司 | Incorporation of nanoparticles in composite fibers |
| CN102674873A (en) * | 2012-05-24 | 2012-09-19 | 中南大学 | Prestressing tendon reinforced composite material and manufacturing method thereof |
| CN103435324A (en) * | 2013-07-27 | 2013-12-11 | 国家电网公司 | Foundation bolt make of basalt fiber and preparation method thereof |
| CN104059238A (en) * | 2014-06-25 | 2014-09-24 | 四川航天五源复合材料有限公司 | Preparation method of basalt fiber reinforced polymer rebar |
Non-Patent Citations (1)
| Title |
|---|
| 赵志凤等: "《材料化学》", 31 August 2012, 哈尔滨工业大学出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108101446A (en) * | 2017-12-07 | 2018-06-01 | 成都天府轨谷科技有限公司 | Basalt fiber composite rib concrete and preparation method thereof |
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Application publication date: 20170510 |
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