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CN106589679A - Antistatic and flame-retardant laundry detergent barrel - Google Patents

Antistatic and flame-retardant laundry detergent barrel Download PDF

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Publication number
CN106589679A
CN106589679A CN201611083584.9A CN201611083584A CN106589679A CN 106589679 A CN106589679 A CN 106589679A CN 201611083584 A CN201611083584 A CN 201611083584A CN 106589679 A CN106589679 A CN 106589679A
Authority
CN
China
Prior art keywords
liquid detergent
detergent bucket
weight portions
organic solvent
antistatic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201611083584.9A
Other languages
Chinese (zh)
Inventor
徐维
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Set Up In Wuhu Packaging Co Ltd
Original Assignee
Set Up In Wuhu Packaging Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Set Up In Wuhu Packaging Co Ltd filed Critical Set Up In Wuhu Packaging Co Ltd
Priority to CN201611083584.9A priority Critical patent/CN106589679A/en
Publication of CN106589679A publication Critical patent/CN106589679A/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/04Antistatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses an antistatic and flame-retardant laundry detergent barrel which comprises polyvinyl chloride, fluororubber, polypropylene, a coupling agent, an antistatic agent, an organic solvent and active magnesium oxide. The antistatic and flame-retardant laundry detergent barrel is excellent in antistatic property and flame retardancy; moreover, a method for preparing the laundry detergent barrel is simple, and the raw materials are readily available.

Description

A kind of anti-static inflaming-retarding liquid detergent bucket
Technical field
The present invention relates to liquid detergent bucket, in particular it relates to a kind of anti-static inflaming-retarding liquid detergent bucket.
Background technology
Liquid detergent bucket is the bogey that industrial production goes out liquid detergent, as people increasingly increase to the demand of liquid detergent bucket Plus, to the performance requirement of liquid detergent bucket also all the more strict.
Although present liquid detergent bucket species is various, long-term makes it easy to generation electrostatic with contact with clothing, can make Into potential safety hazard.So anti-static inflaming-retarding liquid detergent bucket is the direction of those skilled in the art's research.
The content of the invention
It is an object of the invention to provide a kind of anti-static inflaming-retarding liquid detergent bucket, the liquid detergent bucket has good winter explosion-proof Anti- broken performance, good toughness, cold performance is high, is adapted to be used under some low temperature or adverse circumstances.
To achieve these goals, the invention provides a kind of anti-static inflaming-retarding liquid detergent bucket, liquid detergent bucket is included:Polychlorostyrene Ethene, fluorubber, polypropylene, coupling agent, antistatic agent, organic solvent, activated magnesia.
Present invention also offers a kind of preparation method of anti-static inflaming-retarding liquid detergent bucket, the method includes:
1) polyvinyl chloride, fluorubber, polypropylene, coupling agent, antistatic agent, organic solvent, activated magnesia are added high Smelting rear extrusion obtains masterbatch A in fast mixer;
(2) masterbatch A is poured in mould, Jing hydraulic press extrusion moldings, cooling obtains liquid detergent bucket.By above-mentioned technical side Case so that liquid detergent bucket has excellent resistance to low temperature and explosion-proof performance.
Other features and advantages of the present invention will be described in detail in subsequent specific embodiment part.
Specific embodiment
The specific embodiment of the present invention is described in detail below.It should be appreciated that described herein concrete Embodiment is merely to illustrate and explains the present invention, is not limited to the present invention.
The invention provides a kind of anti-static inflaming-retarding liquid detergent bucket, the liquid detergent bucket is included:It is polyvinyl chloride, fluorubber, poly- Propylene, coupling agent, antistatic agent, organic solvent, activated magnesia.
In the present invention, the molecule aggregation degree of polyvinyl chloride can be selected in wide in range scope, but in order that be obtained Liquid detergent bucket there is excellent antistatic performance, it is preferable that the molecule aggregation degree of polyvinyl chloride be 3000.
In the present invention, coupling agent can be antioxidant generally in the art, but in order that obtained liquid detergent bucket tool There is excellent antistatic performance, it is preferable that coupling agent is silane coupler.
In the present invention, antistatic agent can be antistatic agent generally in the art, but in order that obtained liquid detergent Bucket has excellent antistatic performance, it is preferable that antistatic agent is macromolecule permanent antistatic agent.
In the present invention, organic solvent can be organic solvent generally in the art, but in order that obtained liquid detergent Bucket has excellent antistatic performance, it is preferable that organic solvent is styrene.
In the present invention, select in the scope that the quality proportioning of each material of liquid detergent bucket can be wide in range again, but in order that Obtain obtained liquid detergent bucket and there is excellent antistatic performance, it is preferable that relative to the polyvinyl chloride of 100 weight portions, each material Consumption be:The fluorubber of 28-44 weight portions, the polypropylene of 20-22 weight portions, the coupling agent of 10-18 weight portions, 15-18 matter The activated magnesia of the antistatic agent, the organic solvent of 20-22 weight portions and 6-10 weight portions of amount.
Present invention also offers a kind of preparation method of anti-static inflaming-retarding liquid detergent bucket:By polyvinyl chloride, fluorubber, poly- third Alkene, coupling agent, antistatic agent, organic solvent, activated magnesia add smelting rear extrusion in high-speed mixer to obtain masterbatch A; Masterbatch A is poured in mould, Jing hydraulic press extrusion moldings, cooling obtains liquid detergent bucket..
In the present invention, the mixing speed of mixer can be selected in wide in range scope, but in order that obtained wash Clothing liquid bucket has excellent antistatic performance, it is preferable that the mixing speed of high-speed mixer is 160-170r/min.
In the present invention, the heating-up temperature of mixer can be selected in wide in range scope, but in order that obtained wash Clothing liquid bucket has excellent antistatic performance, it is preferable that the heating-up temperature of high-speed mixer is 145-175 DEG C.
In the present invention, the incorporation time of mixer can be selected in wide in range scope, but in order that obtained wash Clothing liquid bucket has excellent antistatic performance, it is preferable that the incorporation time of high-speed mixer is 0.6-1h.
Hereinafter will be described the present invention by embodiment.
Embodiment 1
By polyvinyl chloride, fluorubber, polypropylene, coupling agent, antistatic agent, organic solvent, activated magnesia according to 100: 28:20:10:15:20:6 weight portion is put into tells in mixer, at a temperature of 145 DEG C, with the speed of 160r/min, mixing 0.6h, obtains masterbatch, says that masterbatch is poured in mould and obtains liquid detergent bucket A1 after extrusion molding cooling.
Embodiment 2
By polyvinyl chloride, fluorubber, polypropylene, coupling agent, antistatic agent, organic solvent, activated magnesia according to 100: 44:22:18:18:22:10 weight portion is put into tells in mixer, at a temperature of 170 DEG C, with the speed of 175r/min, mixing 1h, obtains masterbatch, says that masterbatch is poured in mould and obtains liquid detergent bucket A2 after extrusion molding cooling.
Embodiment 3
By polyvinyl chloride, fluorubber, polypropylene, coupling agent, antistatic agent, organic solvent, activated magnesia according to 100: 36:21:14:16:21:8 weight portion is put into tells in mixer, at a temperature of 162 DEG C, with the speed of 165r/min, mixing 0.8h, obtains masterbatch, says that masterbatch is poured in mould and obtains liquid detergent bucket A3 after extrusion molding cooling.
Comparative example 1
Method according to embodiment 1 is obtained liquid detergent bucket B1, except for the difference that, fluorubber is not used.
Comparative example 2
Method according to embodiment 1 is obtained liquid detergent bucket B2, except for the difference that, coupling agent is not used.
Comparative example 3
Method according to embodiment 1 is obtained liquid detergent bucket B3, except for the difference that, antistatic agent is not used.
Detection example 1
The antistatic performance of above-mentioned liquid detergent bucket is detected, as a result for:The antistatic performance of liquid detergent bucket A1-A3 is excellent In the antistatic performance of liquid detergent bucket B1-B3.
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited in above-mentioned embodiment Detail, the present invention range of the technology design in, various simple variants can be carried out to technical scheme, this A little simple variants belong to protection scope of the present invention.
It is further to note that each particular technique feature described in above-mentioned specific embodiment, in not lance In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to it is various can The combination of energy is no longer separately illustrated.
Additionally, can also be combined between a variety of embodiments of the present invention, as long as it is without prejudice to this The thought of invention, it should equally be considered as content disclosed in this invention.

Claims (10)

1. a kind of anti-static inflaming-retarding liquid detergent bucket, it is characterised in that the liquid detergent bucket is included:Polyvinyl chloride, fluorubber, poly- third Alkene, coupling agent, antistatic agent, organic solvent, activated magnesia.
2. liquid detergent bucket according to claim 1, it is characterised in that the degree of polymerization of described polyvinyl chloride is 3000.
3. liquid detergent bucket according to claim 1, it is characterised in that described coupling agent is silane coupler.
4. liquid detergent bucket according to claim 1, it is characterised in that described antistatic agent resists quiet for macromolecule permanent type Electric agent.
5. liquid detergent bucket according to claim 1, it is characterised in that described organic solvent is styrene.
6. the liquid detergent bucket according to claim 1-5, it is characterised in that relative to the polyvinyl chloride of 100 weight portions, each thing The consumption of material is:The fluorubber of 28-44 weight portions, the polypropylene of 20-22 weight portions, the coupling agent of 10-18 weight portions, 15-18 The activated magnesia of the antistatic agent, the organic solvent of 20-22 weight portions and 6-10 weight portions of weight portion.
7. the preparation method of the liquid detergent bucket according to claim 1-6, it is characterised in that the preparation method includes:
(1) polyvinyl chloride, fluorubber, polypropylene, coupling agent, antistatic agent, organic solvent, activated magnesia are added mixed at a high speed Smelting rear extrusion obtains masterbatch A in conjunction machine;
(2) masterbatch A is poured in mould, Jing hydraulic press extrusion moldings, cooling obtains liquid detergent bucket.
8. preparation method according to claim 7, it is characterised in that the mixing speed of the high-speed mixer is 160- 170r/min。
9. preparation method according to claim 7, it is characterised in that the heating-up temperature of the high-speed mixer is 145- 175℃。
10. preparation method according to claim 7, it is characterised in that the incorporation time of the high-speed mixer is 0.6-1h。
CN201611083584.9A 2016-11-30 2016-11-30 Antistatic and flame-retardant laundry detergent barrel Withdrawn CN106589679A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611083584.9A CN106589679A (en) 2016-11-30 2016-11-30 Antistatic and flame-retardant laundry detergent barrel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611083584.9A CN106589679A (en) 2016-11-30 2016-11-30 Antistatic and flame-retardant laundry detergent barrel

Publications (1)

Publication Number Publication Date
CN106589679A true CN106589679A (en) 2017-04-26

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611083584.9A Withdrawn CN106589679A (en) 2016-11-30 2016-11-30 Antistatic and flame-retardant laundry detergent barrel

Country Status (1)

Country Link
CN (1) CN106589679A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1709963A (en) * 2005-07-01 2005-12-21 盖州市宝元电工有限责任公司 Polyvinyl chloride hot-dipping plastic compounded product, and its production and use
CN103242589A (en) * 2013-05-23 2013-08-14 福建晟扬管道科技有限公司 Polyvinyl chloride-polypropylene flame-resistant composite material
CN105175943A (en) * 2015-09-25 2015-12-23 苏州莱特复合材料有限公司 Composite for manufacturing trash can and preparation method of composite
CN105602073A (en) * 2016-03-23 2016-05-25 天津一诺塑料制品有限公司 Fireproof plastic bucket

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1709963A (en) * 2005-07-01 2005-12-21 盖州市宝元电工有限责任公司 Polyvinyl chloride hot-dipping plastic compounded product, and its production and use
CN103242589A (en) * 2013-05-23 2013-08-14 福建晟扬管道科技有限公司 Polyvinyl chloride-polypropylene flame-resistant composite material
CN105175943A (en) * 2015-09-25 2015-12-23 苏州莱特复合材料有限公司 Composite for manufacturing trash can and preparation method of composite
CN105602073A (en) * 2016-03-23 2016-05-25 天津一诺塑料制品有限公司 Fireproof plastic bucket

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Application publication date: 20170426