CN1065282A - Protection method for prolonging storage period of antifouling paint layer in air and protective agent thereof - Google Patents
Protection method for prolonging storage period of antifouling paint layer in air and protective agent thereof Download PDFInfo
- Publication number
- CN1065282A CN1065282A CN 92100383 CN92100383A CN1065282A CN 1065282 A CN1065282 A CN 1065282A CN 92100383 CN92100383 CN 92100383 CN 92100383 A CN92100383 A CN 92100383A CN 1065282 A CN1065282 A CN 1065282A
- Authority
- CN
- China
- Prior art keywords
- defoamer
- air
- antifouling paint
- protective
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000003373 anti-fouling effect Effects 0.000 title claims abstract description 20
- 238000000034 method Methods 0.000 title claims abstract description 11
- 239000003973 paint Substances 0.000 title abstract 5
- 239000003223 protective agent Substances 0.000 title 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims abstract description 27
- 230000001681 protective effect Effects 0.000 claims abstract description 20
- 239000000463 material Substances 0.000 claims abstract description 17
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 11
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 11
- 239000013535 sea water Substances 0.000 claims abstract description 9
- 239000002904 solvent Substances 0.000 claims abstract description 8
- 239000013530 defoamer Substances 0.000 claims description 12
- 239000012466 permeate Substances 0.000 claims description 12
- 239000002966 varnish Substances 0.000 claims description 11
- 239000004902 Softening Agent Substances 0.000 claims description 10
- 239000012528 membrane Substances 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000004922 lacquer Substances 0.000 claims description 7
- -1 dioctyl maleate sodium phosphate Chemical compound 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- GSWAOPJLTADLTN-UHFFFAOYSA-N oxidanimine Chemical group [O-][NH3+] GSWAOPJLTADLTN-UHFFFAOYSA-N 0.000 claims 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- TVWTZAGVNBPXHU-FOCLMDBBSA-N dioctyl (e)-but-2-enedioate Chemical group CCCCCCCCOC(=O)\C=C\C(=O)OCCCCCCCC TVWTZAGVNBPXHU-FOCLMDBBSA-N 0.000 claims 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 238000005553 drilling Methods 0.000 abstract description 3
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 230000000149 penetrating effect Effects 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 1
- LBJNMUFDOHXDFG-UHFFFAOYSA-N copper;hydrate Chemical compound O.[Cu].[Cu] LBJNMUFDOHXDFG-UHFFFAOYSA-N 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
A protecting method for prolonging the storage period of antifouling paint layer in air features that a layer of protecting film which can automatically shed off when it meets seawater is coated on the surface of antifouling paint layer. The protective film takes polyvinyl alcohol and formaldehyde as base materials and is matched with a solvent, a defoaming agent, a plasticizer and a penetrating agent. The protective film can greatly prolong the storage time of the antifouling paint on the surface of marine facilities such as ships, drilling platforms, buoys, mines and the like in the air on land, and the protective film can automatically fall off after meeting seawater, so that the antifouling paint can play a normal antifouling role.
Description
The present invention is a kind of Offshore Units and article such as drilling unit, naval vessel, buoy, navigation mark and submarine mine of being used for, and prolongs guard method and the protective material thereof of its surface soiling enamelled coating shelf-time in the air of land.
The surface of present many Offshore Units and article all scribbles antifouling varnish, to prevent halobiontic growth or to adhere to.Antifouling varnish is also varied.Yet all these antifouling varnishs but all face a problem jointly: the antifouling varnish brushing is behind product surface, and the airborne shelf-time is no more than 15 days on land, comes to this as submarine mine.In case the shelf-time is long, proof lacquer coat just takes place dry and cracked, and main is that main poison contained in the antifouling varnish expects that Red copper oxide is oxidized, has reduced the antifouling effect of antifouling varnish in seawater.
The object of the present invention is to provide guard method and the protective material thereof of a kind of staging life that prolongs proof lacquer coat in air.
Method of the present invention is achieved in that the external coating layer protecting film at proof lacquer coat, and isolated antifouling varnish contacts with air, and this protective membrane can come off after meeting seawater voluntarily.
This protective membrane (agent) is a base-material with polyvinyl alcohol and formaldehyde; auxiliary material can add solvent, defoamer, softening agent, permeate agent and make; wherein the weight percent of polyvinyl alcohol and formaldehyde is respectively 3.07-10.42; 1.22-3.06; the weight percent of solvent, defoamer, softening agent, permeate agent is respectively 55.15-122.56; 0.003-3; 0.03-0.48; 0.03-0.48 described solvent, defoamer, softening agent, permeate agent can be water, organosilicon, ammonium chloride, dioctyl maleate sodium phosphate respectively.The optimum weight per-cent of protective membrane is polyvinyl alcohol 6.13, formaldehyde 1.53, water 91.92, defoamer 0.3, softening agent 0.06, permeate agent 0.06.Also can be polyvinyl alcohol 7.2, formaldehyde 1.8, water 90.51, defoamer 0.36, softening agent 0.07, permeate agent 0.06.Perhaps, polyvinyl alcohol 6.45, formaldehyde 1.61, water 91.44, defoamer 0.32, softening agent 0.08, permeate agent 0.1.
A protectant concrete making method is: the water that adds 10kg in retort; heat 60 ℃-80 ℃ the time; the polyvinyl alcohol of 0.8kg is added in the entry, and continuously stirring is when treating that temperature rises to 90 ℃-100 ℃; control 100 minutes; polyvinyl alcohol is all dissolved, add the formaldehyde of 0.2kg then, and continuously stirring; continue 5-10 minute; after stirring evenly, add the defoamer of 0.04kg, the softening agent of 0.008kg; 0.007kg permeate agent; continuously stirring 30 minutes waits to reduce to room temperature below 35 ℃, crosses 160 purpose sieves; tested viscosity requires to be advisable second at 40-55, is preferably 45 seconds.
Be not less than 10 ℃ in temperature, humidity is not more than 85%, and under the condition that dry humidity is low 20 ℃, with external coating 2-4 time at proof lacquer coat of above-mentioned protective material goods, the preceding interval of every layer of brushing is no less than 4 hours and gets final product.
The present invention has prevented the dry and cracked and oxidation of antifouling varnish, can make the various Offshore Units and the article that scribble antifouling varnish, as naval vessel, drilling unit, navigation mark, submarine mine etc., in the air of land, be difficult for wearing out, chap, come off, shelf-time prolongs greatly, the outdoor shady and cool following shelf-time of condition extended to more than half a year, more than indoor storage time lengthening to a year.After the product that scribbles protective membrane enters seawater; in marine life growth or before beginning to adhere to (being generally about 20 days), protective membrane is just soft voluntarily through the immersion of seawater, come off, and seawater is contacted with antifouling varnish; antifouling varnish continuously discharges Cu under seawater eroding
+, normally brought into play its antifouling effect.
Claims (9)
1, the guard method of a kind of staging life that prolongs proof lacquer coat in air, what it is characterized in that isolated antifouling varnish and air contacts the protective membrane that can come off voluntarily behind external coating one deck chance seawater of proof lacquer coat.
2, guard method as claimed in claim 1 is characterized in that it is base-material that protective membrane is selected polyvinyl alcohol and formaldehyde for use.
3, guard method as claimed in claim 2 is characterized in that the protective membrane auxiliary material selects solvent, defoamer, softening agent, permeate agent for use.
4, guard method as claimed in claim 3 is characterized in that described solvent is a water, and defoamer is an organosilicon, and softening agent is an ammonium oxide, and permeate agent is a dioctyl maleate acid sodium.
5, a kind of protective material is characterized in that protectant base-material is polyvinyl alcohol and the formaldehyde that weight percent is respectively 3.07-10.42 and 1.22-3.06.
6, protective material as claimed in claim 5, the weight percent that it is characterized in that solvent in protectant auxiliary material is 55.15-122.56.
7, protective material as claimed in claim 6 is characterized in that the weight percent of defoamer, softening agent, permeate agent in protectant auxiliary material is respectively 0.003-3,0.03-0.48,0.03-0.48.
8, protective material as claimed in claim 7 is characterized in that described solvent, defoamer, permeate agent are respectively water, organosilicon, ammonium oxide, dioctyl maleate sodium phosphate.
9, protective material as claimed in claim 8 is characterized in that the weight percent of polyvinyl alcohol, formaldehyde, water, defoamer, permeate agent is respectively 6.13,1.53,91.92,0.3,0.06,0.06.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 92100383 CN1065282A (en) | 1992-01-18 | 1992-01-18 | Protection method for prolonging storage period of antifouling paint layer in air and protective agent thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 92100383 CN1065282A (en) | 1992-01-18 | 1992-01-18 | Protection method for prolonging storage period of antifouling paint layer in air and protective agent thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1065282A true CN1065282A (en) | 1992-10-14 |
Family
ID=4938548
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 92100383 Pending CN1065282A (en) | 1992-01-18 | 1992-01-18 | Protection method for prolonging storage period of antifouling paint layer in air and protective agent thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1065282A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1044612C (en) * | 1995-04-07 | 1999-08-11 | 清华大学 | Paint capable of stripping and removing radioactive contamination |
| CN1044613C (en) * | 1995-04-07 | 1999-08-11 | 清华大学 | Exfoliative, antipolluting and protective coating material |
-
1992
- 1992-01-18 CN CN 92100383 patent/CN1065282A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1044612C (en) * | 1995-04-07 | 1999-08-11 | 清华大学 | Paint capable of stripping and removing radioactive contamination |
| CN1044613C (en) * | 1995-04-07 | 1999-08-11 | 清华大学 | Exfoliative, antipolluting and protective coating material |
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| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication |