CN106480352A - A kind of refractory metal material - Google Patents
A kind of refractory metal material Download PDFInfo
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- CN106480352A CN106480352A CN201611099012.XA CN201611099012A CN106480352A CN 106480352 A CN106480352 A CN 106480352A CN 201611099012 A CN201611099012 A CN 201611099012A CN 106480352 A CN106480352 A CN 106480352A
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- China
- Prior art keywords
- parts
- metal material
- nickel
- zirconium
- elevated temperatures
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- 239000000463 material Substances 0.000 title claims abstract description 39
- 239000003870 refractory metal Substances 0.000 title claims abstract description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 20
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 20
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 20
- GNMQOUGYKPVJRR-UHFFFAOYSA-N nickel(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Ni+3].[Ni+3] GNMQOUGYKPVJRR-UHFFFAOYSA-N 0.000 claims abstract description 20
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 10
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910007948 ZrB2 Inorganic materials 0.000 claims abstract description 10
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 10
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910000416 bismuth oxide Inorganic materials 0.000 claims abstract description 10
- VWZIXVXBCBBRGP-UHFFFAOYSA-N boron;zirconium Chemical compound B#[Zr]#B VWZIXVXBCBBRGP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000011195 cermet Substances 0.000 claims abstract description 10
- 229910052802 copper Inorganic materials 0.000 claims abstract description 10
- 239000010949 copper Substances 0.000 claims abstract description 10
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052732 germanium Inorganic materials 0.000 claims abstract description 10
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052742 iron Inorganic materials 0.000 claims abstract description 10
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 10
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 10
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 10
- 239000010955 niobium Substances 0.000 claims abstract description 10
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims abstract description 10
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 10
- 239000011701 zinc Substances 0.000 claims abstract description 10
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 10
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims abstract description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 6
- 229910052748 manganese Inorganic materials 0.000 claims description 6
- 239000011572 manganese Substances 0.000 claims description 6
- 239000007769 metal material Substances 0.000 abstract description 18
- 229910052751 metal Inorganic materials 0.000 abstract description 5
- 239000002184 metal Substances 0.000 abstract description 3
- 239000010953 base metal Substances 0.000 abstract description 2
- 239000002131 composite material Substances 0.000 abstract description 2
- 230000007797 corrosion Effects 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- 230000000704 physical effect Effects 0.000 abstract description 2
- 229910052761 rare earth metal Inorganic materials 0.000 abstract description 2
- 238000005728 strengthening Methods 0.000 abstract description 2
- 239000013078 crystal Substances 0.000 abstract 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000013013 elastic material Substances 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C30/00—Alloys containing less than 50% by weight of each constituent
- C22C30/06—Alloys containing less than 50% by weight of each constituent containing zinc
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C30/00—Alloys containing less than 50% by weight of each constituent
- C22C30/02—Alloys containing less than 50% by weight of each constituent containing copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C32/00—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
- C22C32/0005—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with at least one oxide and at least one of carbides, nitrides, borides or silicides as the main non-metallic constituents
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Powder Metallurgy (AREA)
Abstract
The present invention is a kind of refractory metal material, and described resistant to elevated temperatures cermet material includes the material of following weight：12 23 parts of nickel sesquioxide, 47 parts of manganese, 6 11 parts of magnesia, 24 parts of nickel, 8 11 parts of zirconium diboride, 23 parts of antimony, 24 parts of thorium anhydride, 34 parts of niobium, 37 parts of bismuth oxide, 69 parts of zinc, 7 13 parts of copper, 13 parts of zirconium, 24 parts of germanium, 11 18 parts of iron.The composition material of the resistant to elevated temperatures metal material of the present invention is different from conventional metal material, the some other physical property such as its higher hardness is remained at a higher temperature, can be used in some fields higher to heat resistant requirements such as engine, structural member, improving the performance of the product for preparing as heat-resisting metal material.Present invention adds part rare earth element, can slough the harmful element in base metal, play a part of purifying molten metal, control the microstructure form of metal material, crystal grain thinning, strengthening surface tension force, significantly improve metal material resist dry, web rot corrosion.
Description
Technical field
The present invention relates to a kind of chemical materials manufactures field, particularly a kind of pipeline highly elastic material.
Background technology
Metal material refers to the general designation of metallic element or the material with metallic character constituted based on metallic element.Bag
Include simple metal, alloy, metal material intermetallic compound and special metal material etc..It is widely used in life, metal material
High temperature resistant difference, is difficult to apply in a lot of fields, the heat-resistant quality of metal material, determines metal material spy in some cases
Determine purposes, which has higher heat-resistant quality to occur in that some new metal materials on the market, but its resistance to thermal property still has
Wait to improve.It is thus desirable to a kind of new more resistant to elevated temperatures metal material.
Content of the invention
The technical problem to be solved in the present invention is for the deficiencies in the prior art, proposes a kind of refractory metal material.
The technical problem to be solved in the present invention is achieved through the following technical solutions.The present invention is a kind of refractory metal
Material, described resistant to elevated temperatures cermet material include the material of following weight：
Nickel sesquioxide 12-23 part,
Manganese 4-7 part,
Magnesia 6-11 part,
Nickel 2-4 part,
Zirconium diboride 8-11 part,
Antimony 2-3 part
Thorium anhydride 2-4 part,
Niobium 3-4 part
Bismuth oxide 3-7 part,
Zinc 6-9 part,
Copper 7-13 part,
Zirconium 1-3 part,
Germanium 2-4 part,
Iron 11-18 part.
In a kind of refractory metal material of the present invention, further preferred technical scheme is characterized in that：
1st, described resistant to elevated temperatures cermet material includes the material of following weight：
Nickel sesquioxide 15-23 part,
Manganese 5-7 part,
Magnesia 7-11 part,
Nickel 3-4 part,
Zirconium diboride 8-10 part,
Antimony 2-3 part
Thorium anhydride 3-4 part,
Niobium 3-4 part
Bismuth oxide 4-7 part,
Zinc 7-9 part,
Copper 7-12 part,
Zirconium 1-3 part,
Germanium 2-4 part,
Iron 13-18 part.
2nd, described resistant to elevated temperatures cermet material includes the material of following weight：
20 parts of nickel sesquioxide,
6 parts of manganese,
8 parts of magnesia,
4 parts of nickel,
9 parts of zirconium diboride,
3 parts of antimony
3 parts of thorium anhydride,
4 parts of niobium
6 parts of bismuth oxide,
8 parts of zinc,
10 parts of copper,
2 parts of zirconium,
3 parts of germanium,
15 parts of iron.
The composition material of the resistant to elevated temperatures metal material of the present invention is different from conventional metal material, at a higher temperature
Some other physical property such as its higher hardness is remained, engine, structural member etc. can be used for as heat-resisting metal material
In some fields higher to heat resistant requirements, the performance of the product for preparing is improved.Present invention adds part rare earth element, can
The harmful element in base metal is sloughed, plays a part of purifying molten metal, control the microstructure form of metal material, refinement is brilliant
Grain, strengthening surface tension force, significantly improve anti-dry, the web rot corrosion of metal material.
Specific embodiment
The concrete technical scheme of the present invention is further described, and this is further understood that in order to those skilled in the art
Bright, and do not constitute the restriction of its power.
Embodiment 1, a kind of refractory metal material, described resistant to elevated temperatures cermet material include the material of following weight
Material：
Nickel sesquioxide 12-23 part,
Manganese 4-7 part,
Magnesia 6-11 part,
Nickel 2-4 part,
Zirconium diboride 8-11 part,
Antimony 2-3 part
Thorium anhydride 2-4 part,
Niobium 3-4 part
Bismuth oxide 3-7 part,
Zinc 6-9 part,
Copper 7-13 part,
Zirconium 1-3 part,
Germanium 2-4 part,
Iron 11-18 part.
Embodiment 2, in a kind of refractory metal material described in embodiment 1：By described resistant to elevated temperatures cermet material
Material includes the material of following weight：
Nickel sesquioxide 15-23 part,
Manganese 5-7 part,
Magnesia 7-11 part,
Nickel 3-4 part,
Zirconium diboride 8-10 part,
Antimony 2-3 part
Thorium anhydride 3-4 part,
Niobium 3-4 part
Bismuth oxide 4-7 part,
Zinc 7-9 part,
Copper 7-12 part,
Zirconium 1-3 part,
Germanium 2-4 part,
Iron 13-18 part.
Embodiment 3, in a kind of refractory metal material described in embodiment 1 or 2：Described resistant to elevated temperatures cermet material
Material includes the material of following weight：
20 parts of nickel sesquioxide,
6 parts of manganese,
8 parts of magnesia,
4 parts of nickel,
9 parts of zirconium diboride,
3 parts of antimony
3 parts of thorium anhydride,
4 parts of niobium
6 parts of bismuth oxide,
8 parts of zinc,
10 parts of copper,
2 parts of zirconium,
3 parts of germanium,
15 parts of iron.
Principal character of the present invention and advantage is had been shown and described above, it should be understood by those skilled in the art that, the present invention
It is not restricted to the described embodiments, the specific embodiment that the present invention is simply described described in above-described embodiment and specification,
Without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, and these changes and improvements are all
Fall in scope of the claimed invention.The claimed scope of the invention is by appending claims and its equivalent circle.
Fixed.
Claims (3)
1. a kind of refractory metal material, it is characterised in that described resistant to elevated temperatures cermet material includes following weight
Material：
Nickel sesquioxide 12-23 part,
Manganese 4-7 part,
Magnesia 6-11 part,
Nickel 2-4 part,
Zirconium diboride 8-11 part,
Antimony 2-3 part
Thorium anhydride 2-4 part,
Niobium 3-4 part
Bismuth oxide 3-7 part,
Zinc 6-9 part,
Copper 7-13 part,
Zirconium 1-3 part,
Germanium 2-4 part,
Iron 11-18 part.
2. refractory metal material according to claim 1, it is characterised in that described resistant to elevated temperatures cermet material
Material includes the material of following weight：
Nickel sesquioxide 15-23 part,
Manganese 5-7 part,
Magnesia 7-11 part,
Nickel 3-4 part,
Zirconium diboride 8-10 part,
Antimony 2-3 part
Thorium anhydride 3-4 part,
Niobium 3-4 part
Bismuth oxide 4-7 part,
Zinc 7-9 part,
Copper 7-12 part,
Zirconium 1-3 part,
Germanium 2-4 part,
Iron 13-18 part.
3. refractory metal material according to claim 1, it is characterised in that described resistant to elevated temperatures cermet material
Material includes the material of following weight：
20 parts of nickel sesquioxide,
6 parts of manganese,
8 parts of magnesia,
4 parts of nickel,
9 parts of zirconium diboride,
3 parts of antimony
3 parts of thorium anhydride,
4 parts of niobium
6 parts of bismuth oxide,
8 parts of zinc,
10 parts of copper,
2 parts of zirconium,
3 parts of germanium,
15 parts of iron.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611099012.XA CN106480352A (en) | 2016-12-04 | 2016-12-04 | A kind of refractory metal material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611099012.XA CN106480352A (en) | 2016-12-04 | 2016-12-04 | A kind of refractory metal material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106480352A true CN106480352A (en) | 2017-03-08 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611099012.XA Pending CN106480352A (en) | 2016-12-04 | 2016-12-04 | A kind of refractory metal material |
Country Status (1)
| Country | Link |
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| CN (1) | CN106480352A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101244937A (en) * | 2007-02-16 | 2008-08-20 | 宝山钢铁股份有限公司 | Nanocomposite cermet powder for corrosion resistance of molten metal and manufacturing method thereof |
| CN102776492A (en) * | 2011-05-13 | 2012-11-14 | 比亚迪股份有限公司 | Selective metallization method of surface of ceramic, and ceramic and its application |
| CN103418790A (en) * | 2012-05-17 | 2013-12-04 | 枣阳秦鸿新材料有限公司 | Anti-abrasion metal-ceramic composite product and preparation method thereof |
| CN103981385A (en) * | 2014-05-29 | 2014-08-13 | 西北有色金属研究院 | Method for preparing molybdenum-chromium-zirconium boride composite material |
| CN104159681A (en) * | 2012-03-06 | 2014-11-19 | 杰富意钢铁株式会社 | Warm hot press molding method and automobile frame parts |
-
2016
- 2016-12-04 CN CN201611099012.XA patent/CN106480352A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101244937A (en) * | 2007-02-16 | 2008-08-20 | 宝山钢铁股份有限公司 | Nanocomposite cermet powder for corrosion resistance of molten metal and manufacturing method thereof |
| CN102776492A (en) * | 2011-05-13 | 2012-11-14 | 比亚迪股份有限公司 | Selective metallization method of surface of ceramic, and ceramic and its application |
| CN104159681A (en) * | 2012-03-06 | 2014-11-19 | 杰富意钢铁株式会社 | Warm hot press molding method and automobile frame parts |
| CN103418790A (en) * | 2012-05-17 | 2013-12-04 | 枣阳秦鸿新材料有限公司 | Anti-abrasion metal-ceramic composite product and preparation method thereof |
| CN103981385A (en) * | 2014-05-29 | 2014-08-13 | 西北有色金属研究院 | Method for preparing molybdenum-chromium-zirconium boride composite material |
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| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170308 |
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