CN106422732A - Thermal power plant W type boiler SNCR denitration system and control method thereof - Google Patents
Thermal power plant W type boiler SNCR denitration system and control method thereof Download PDFInfo
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- 238000000034 method Methods 0.000 title claims abstract description 20
- 239000007921 spray Substances 0.000 claims abstract description 142
- 238000009826 distribution Methods 0.000 claims abstract description 60
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 56
- 239000004202 carbamide Substances 0.000 claims abstract description 56
- 238000001514 detection method Methods 0.000 claims abstract description 25
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000003546 flue gas Substances 0.000 claims abstract description 20
- 238000003860 storage Methods 0.000 claims description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
- 239000013307 optical fiber Substances 0.000 claims description 14
- 238000001816 cooling Methods 0.000 claims description 13
- 238000000041 tunable diode laser absorption spectroscopy Methods 0.000 claims description 10
- 230000007423 decrease Effects 0.000 claims description 7
- 238000000691 measurement method Methods 0.000 claims description 6
- 230000001276 controlling effect Effects 0.000 claims 5
- 230000001105 regulatory effect Effects 0.000 claims 1
- 239000000243 solution Substances 0.000 description 38
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 7
- 239000003638 chemical reducing agent Substances 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- 229910021529 ammonia Inorganic materials 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000003245 coal Substances 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 2
- 238000010531 catalytic reduction reaction Methods 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- 238000005235 decoking Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 description 1
- 239000003830 anthracite Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001131 transforming effect Effects 0.000 description 1
- 238000004056 waste incineration Methods 0.000 description 1
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
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- G05D7/00—Control of flow
- G05D7/06—Control of flow characterised by the use of electric means
- G05D7/0617—Control of flow characterised by the use of electric means specially adapted for fluid materials
- G05D7/0623—Control of flow characterised by the use of electric means specially adapted for fluid materials characterised by the set value given to the control element
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
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Abstract
Description
技术领域technical field
本发明涉及火电厂SNCR脱硝技术,具体为一种火电厂W型锅炉SNCR脱硝系统及其控制方法。The invention relates to SNCR denitrification technology of a thermal power plant, in particular to an SNCR denitrification system of a W-type boiler in a thermal power plant and a control method thereof.
背景技术Background technique
W火焰锅炉在燃用低挥发分煤种时,具有低负荷稳燃能力强、燃烧稳定性好、带负荷性能强、运行可靠等特点,因此W火焰锅炉在我国已成为燃用无烟煤或劣质贫煤等低挥发分煤种的主力炉型,但其在实际运行中存在着NOx排放量高的问题。面对NOx排放浓度50mg/m3的超净排放要求,单纯改造SCR脱硝系统不仅投资和运行费用较高,同时也影响机组的安全性。从技术与经济角度等多方面考虑,在充分利用原SCR装置的基础上增加SNCR脱硝装置是实现W型锅炉氮氧化物超低排放的合理选择。When the W flame boiler is fired with low volatile coal, it has the characteristics of strong low-load stable combustion capability, good combustion stability, strong load performance, and reliable operation. The main furnace type of low-volatile coal such as coal, but there is a problem of high NOx emissions in actual operation. Faced with the ultra-clean emission requirement of NOx emission concentration of 50mg/m 3 , simply transforming the SCR denitrification system not only has high investment and operating costs, but also affects the safety of the unit. Considering many aspects such as technology and economy, adding SNCR denitrification device on the basis of making full use of the original SCR device is a reasonable choice to achieve ultra-low emission of nitrogen oxides from W-type boilers.
选择性非催化还原法(SNCR)烟气脱硝技术是电站锅炉、流化床锅炉、水泥窑炉和垃圾焚烧烟气脱硝的主流技术。在880℃-1050℃温度范围内、在无催化剂条件下,喷入氨水或尿素等氨基还原剂,烟气中的NOx可选择性地被还原成无害的氮气和水。SNCR工艺以炉膛为反应器,可通过对锅炉的改造实现,建设周期短,投资成本和运行成本与其它烟气脱硝技术相比都是比较低的,适合于对中小型锅炉的改造。现代SNCR技术可控制NOx排放降低20~50%,随着机组容量增加,炉膛尺寸和机组负荷变化范围扩大,增加了反应温度窗口与还原剂均匀混合的控制难度,致使脱硝效率降低。对于600MW机组,在控制氨逃逸浓度小于10μL/L条件下,脱硝效率仅有30%左右。由于燃用无烟煤的W型锅炉NOx初始浓度普遍较高,为保证NOx排放达到50mg/m3,SNCR段的脱硝效率必须达到45%以上,因此研究开发高效的火电厂W型锅炉SNCR脱硝系统迫在眉睫。Selective non-catalytic reduction (SNCR) flue gas denitrification technology is the mainstream technology for power plant boilers, fluidized bed boilers, cement kilns and waste incineration flue gas denitrification. In the temperature range of 880°C-1050°C, under the condition of no catalyst, ammonia or urea and other amino reducing agents are injected, and the NOx in the flue gas can be selectively reduced to harmless nitrogen and water. The SNCR process uses the furnace as the reactor, which can be realized through the transformation of the boiler. The construction period is short, and the investment cost and operation cost are relatively low compared with other flue gas denitrification technologies. It is suitable for the transformation of small and medium-sized boilers. Modern SNCR technology can control NOx emissions to reduce by 20-50%. With the increase of unit capacity, the range of furnace size and unit load changes increases, which increases the difficulty of controlling the reaction temperature window and uniform mixing of reducing agents, resulting in lower denitrification efficiency. For a 600MW unit, the denitrification efficiency is only about 30% under the condition that the ammonia escape concentration is controlled to be less than 10 μL/L. Since the initial NOx concentration of W-type boilers burning anthracite is generally high, in order to ensure that NOx emissions reach 50mg/m 3 , the denitrification efficiency of the SNCR section must reach more than 45%. Therefore, it is imminent to research and develop efficient W-type boiler SNCR denitration systems .
SNCR的脱硝效率受温度、CO浓度、NOx初值、NSR、燃烧条件、煤种、炉型、氨逃逸等因素的影响,其中温度和CO浓度是两个主要影响因素。为提高SNCR工艺脱硝效率,相关研究提出采用控制不同负荷下氨氮比的方法来调节还原剂流量,如中国专利CN105169917A公开的一种基于氨氮摩尔比检测及调控的SNCR-SCR联合脱硝系统和方法,中国专利CN201520543068.4公开的一种选择性非催化还原SNCR反应系统,中国专利CN201510188180.5公开的一种水泥生产中SNCR烟气脱硝系统的喷氨量控制方法,但这种控制方法非常复杂,难以在工程上实现。另外有研究通过测量温度分布来控制喷枪将还原剂喷入到适合SNCR反应的温度区域内,实现对每个SNCR喷枪温度窗口的动态跟踪,如中国专利CN104307347A公开的一种高效SNCR点对点喷射系统,又如中国专利CN104117279A公开的一种电站锅炉SNCR脱硝控制系统及其控制方法,该控制方法的难点在于喷枪数量较多,对每支喷枪进行精确控制将显著增加系统成本。烟气中CO浓度是影响SNCR脱硝效率的重要因素,研究结果表明,当CO浓度低于1000ppm时,SNCR脱硝效率随CO浓度增加而增大;当CO浓度超过1000ppm时,SNCR脱硝效率随CO浓度增加而减小。由于烟气中CO浓度难以实现在线测量,在目前的SNCR控制系统中普遍忽略CO浓度的影响,这也成为制约SNCR脱硝效率的重要原因。The denitrification efficiency of SNCR is affected by factors such as temperature, CO concentration, initial value of NOx, NSR, combustion conditions, coal type, furnace type, and ammonia escape, among which temperature and CO concentration are the two main influencing factors. In order to improve the denitrification efficiency of the SNCR process, related research proposes to adjust the reducing agent flow rate by controlling the ratio of ammonia nitrogen under different loads, such as the SNCR-SCR combined denitrification system and method based on the detection and regulation of ammonia nitrogen molar ratio disclosed in Chinese patent CN105169917A. Chinese patent CN201520543068.4 discloses a selective non-catalytic reduction SNCR reaction system, and Chinese patent CN201510188180.5 discloses a method for controlling the amount of ammonia injection in the SNCR flue gas denitrification system in cement production, but this control method is very complicated. Difficult to implement in engineering. In addition, there are studies that measure the temperature distribution to control the spray gun to spray the reducing agent into the temperature region suitable for SNCR reaction, so as to realize the dynamic tracking of the temperature window of each SNCR spray gun, such as a high-efficiency SNCR point-to-point injection system disclosed in Chinese patent CN104307347A. Another example is a power plant boiler SNCR denitrification control system and its control method disclosed in Chinese patent CN104117279A. The difficulty of this control method lies in the large number of spray guns, and precise control of each spray gun will significantly increase the system cost. The concentration of CO in the flue gas is an important factor affecting the denitration efficiency of SNCR. The research results show that when the concentration of CO is lower than 1000ppm, the denitrification efficiency of SNCR increases with the increase of CO concentration; when the concentration of CO exceeds 1000ppm, the denitration efficiency of SNCR increases with the concentration of CO increase and decrease. Because it is difficult to measure the CO concentration in the flue gas online, the influence of the CO concentration is generally ignored in the current SNCR control system, which has also become an important reason restricting the denitrification efficiency of the SNCR.
发明内容Contents of the invention
针对现有技术中存在的问题,本发明提供一种火电厂W型锅炉SNCR脱硝系统及其控制方法,脱销效率高,控制简单,改造方便。Aiming at the problems existing in the prior art, the present invention provides a W-type boiler SNCR denitrification system of a thermal power plant and a control method thereof, which have high denitrification efficiency, simple control and convenient modification.
本发明是通过以下技术方案来实现:The present invention is achieved through the following technical solutions:
一种火电厂W型锅炉SNCR脱硝系统,包括设置在W型锅炉水平烟道区域的长喷枪,在W型锅炉折焰角区域分多层设置的多个短喷枪,以及激光检测系统和依次连接的计量模块和分配模块;分配模块包括输出端连接长喷枪的长喷枪分配模块和输出端连接短喷枪的短喷枪分配模块;用于控制尿素溶液浓度的计量模块输入端分别连接原尿素溶液储罐和除盐水储罐,输出端分别连接长喷枪分配模块和短喷枪分配模块;所述的激光检测系统包括依次连接的中央控制柜、二极管激光器、光纤多路复用器、光纤和多组激光器;中央控制柜用于通过激光器检测烟气温度分布信号和CO浓度信号;其输出端经工程师站分别连接长喷枪分配模块和计量模块;多个长喷枪在水平烟道的横截面上均匀的呈多层布置,长喷枪分配模块根据工程师站的控制信号分别控制每一个长喷枪喷射的尿素溶液流量;每层短喷枪的尿素溶液管道入口设置一个电动阀门,短喷枪分配模块根据W型锅炉的机组负荷和NSR值控制每层的电动阀门开度。A W-shaped boiler SNCR denitrification system in a thermal power plant, including a long spray gun installed in the horizontal flue area of the W-shaped boiler, a plurality of short spray guns arranged in multiple layers in the deflection angle area of the W-shaped boiler, and a laser detection system and sequentially connected The metering module and distribution module; the distribution module includes a long spray gun distribution module whose output end is connected to a long spray gun and a short spray gun distribution module whose output end is connected to a short spray gun; the input ends of the metering module used to control the concentration of urea solution are respectively connected to the original urea solution storage tank and a desalinated water storage tank, the output ends of which are respectively connected to the long spray gun distribution module and the short spray gun distribution module; the laser detection system includes a central control cabinet, a diode laser, an optical fiber multiplexer, an optical fiber and multiple groups of lasers connected in sequence; The central control cabinet is used to detect the flue gas temperature distribution signal and CO concentration signal through the laser; its output end is respectively connected to the long spray gun distribution module and the metering module through the engineer station; multiple long spray guns are evenly distributed in the cross section of the horizontal flue. Layer layout, the long spray gun distribution module controls the flow of urea solution sprayed by each long spray gun according to the control signal of the engineer station; an electric valve is set at the entrance of the urea solution pipeline of each short spray gun, and the short spray gun distribution module is based on the unit load of the W-type boiler and NSR value to control the electric valve opening of each floor.
优选的,长喷枪共设置有六个,且在水平烟道的横截面上均匀的呈三层布置,长喷枪所在截面上均匀设置四组激光器;激光器与长喷枪间隔设置;每组激光器包括一个发射端和一个接收端,发射端连接光纤,接收端连接中央控制柜。Preferably, there are six long spray guns, and they are evenly arranged in three layers on the cross section of the horizontal flue, and four groups of lasers are evenly arranged on the section where the long spray guns are located; the lasers are arranged at intervals from the long spray guns; each group of lasers includes a The transmitting end and a receiving end, the transmitting end is connected to the optical fiber, and the receiving end is connected to the central control cabinet.
优选的,长喷枪冷却端入口连接除盐水储罐的输出端,冷却端出口连接除盐水储罐的输入端。Preferably, the inlet of the cooling end of the long lance is connected to the output end of the desalinated water storage tank, and the outlet of the cooling end is connected to the input end of the desalinated water storage tank.
优选的,还包括压缩空气储罐,压缩空气储罐的输出端分别用于冷却空气连接在短喷枪的冷却端入口,用于雾化空气连接在计量模块和分配模块之间。Preferably, a compressed air storage tank is also included, and the output ends of the compressed air storage tanks are respectively used for cooling air to be connected to the inlet of the cooling end of the short spray gun, and for atomizing air to be connected between the metering module and the distribution module.
优选的,所述的计量模块包括混合器,以及分别设置在混合器两个入口的控制阀和流量计;原尿素溶液储罐和除盐水储罐的输出端分别通过加液泵与对应的混合器入口连接。Preferably, the metering module includes a mixer, and control valves and flowmeters respectively arranged at the two inlets of the mixer; the output ends of the original urea solution storage tank and the desalted water storage tank are respectively mixed with the corresponding Inlet connection to the device.
优选的,每支短喷枪设置一个手动阀门,所有手动阀门开度保持一致。Preferably, each short spray gun is provided with a manual valve, and the openings of all manual valves are consistent.
一种火电厂W型锅炉SNCR脱硝控制方法,基于本发明所述的一种火电厂W型锅炉SNCR脱硝系统上,包括,A thermal power plant W-type boiler SNCR denitrification control method, based on a thermal power plant W-type boiler SNCR denitrification system of the present invention, comprising:
根据激光检测系统得到的CO浓度信号通过计量模块调节尿素溶液浓度的步骤;A step of adjusting the concentration of the urea solution through the metering module according to the CO concentration signal obtained by the laser detection system;
根据激光检测系统得到的温度分布信号通过长喷枪分配模块调节每个长喷枪喷射的尿素溶液流量的步骤;The step of adjusting the flow rate of the urea solution sprayed by each long spray gun through the long spray gun distribution module according to the temperature distribution signal obtained by the laser detection system;
根据机组负荷区间和NSR值控制短喷枪投运层数和每层尿素溶液总流量的步骤。Steps for controlling the number of layers of short spray guns in operation and the total flow rate of each layer of urea solution according to the unit load range and NSR value.
优选的,调节尿素溶液浓度的步骤具体如下,Preferably, the step of adjusting the concentration of urea solution is as follows,
激光检测系统采用TDLAS测量方法得到水平烟道内的CO浓度信号,CO浓度信号在工程师站中被转化为一路阀门开度信号并送入计量模块中,调节除盐水回路的控制阀的开度,从而控制长喷枪喷射的尿素溶液浓度;The laser detection system uses the TDLAS measurement method to obtain the CO concentration signal in the horizontal flue. The CO concentration signal is converted into a valve opening signal in the engineer station and sent to the metering module to adjust the opening of the control valve of the desalinated water circuit. Control the concentration of urea solution sprayed by the long spray gun;
随着CO浓度升高,增大除盐水流量;随着CO浓度降低,减小除盐水流量。As the CO concentration increases, the desalinated water flow increases; as the CO concentration decreases, the desalinated water flow decreases.
优选的,调节每个长喷枪喷射的尿素溶液流量的步骤具体如下,Preferably, the steps of adjusting the flow rate of the urea solution sprayed by each long spray gun are as follows,
激光检测系统采用TDLAS测量方法得到水平烟道内烟气的温度分布信号,温度分布信号在工程师站中被转化为多路阀门开度信号并送入长喷枪分配模块中,调节每个长喷枪控制阀的开度,从而控制每支长喷枪喷射的尿素溶液流量。The laser detection system uses the TDLAS measurement method to obtain the temperature distribution signal of the flue gas in the horizontal flue. The temperature distribution signal is converted into a multi-way valve opening signal in the engineer station and sent to the long spray gun distribution module to adjust the control valve of each long spray gun. The opening degree, thereby controlling the flow of urea solution sprayed by each long spray gun.
优选的,控制短喷枪投运层数和每层尿素溶液总流量的步骤具体如下,Preferably, the steps of controlling the number of layers of the short spray gun to be put into operation and the total flow rate of each layer of urea solution are as follows,
短喷枪分两层设置在W型锅炉折焰角区域,从下往上依次是第一层短喷枪和第二层短喷枪;The short spray guns are arranged in two layers in the deflection angle area of the W-shaped boiler, from bottom to top there are the first layer of short spray guns and the second layer of short spray guns;
当W型锅炉的机组为低负荷时,投运第一层短喷枪,第二层短喷枪关闭,并根据NSR值调节第一层阀门的开度;When the unit of the W-type boiler is under low load, the first layer of short spray guns is put into operation, the second layer of short spray guns is closed, and the opening of the first layer of valves is adjusted according to the NSR value;
当W型锅炉的机组为中负荷时,同时投运两层喷枪,并根据NSR值调节两层阀门的开度;When the unit of the W-type boiler is at medium load, put into operation two layers of spray guns at the same time, and adjust the opening of the two layers of valves according to the NSR value;
当W型锅炉的机组为高负荷时,投运第二层喷枪,第一层短喷枪关闭,并根据NSR值调节第二层阀门的开度。When the unit of the W-type boiler is under high load, the second layer of spray guns is put into operation, the first layer of short spray guns is closed, and the opening of the second layer of valves is adjusted according to the NSR value.
与现有技术相比,本发明具有以下有益的技术效果:Compared with the prior art, the present invention has the following beneficial technical effects:
本发明通过设置多个喷嘴的长喷枪伸入烟道中部,长喷枪喷射的尿素溶液可完全覆盖烟道截面,保证尿素溶液与烟气充分、均匀混合,提高脱硝效率;长喷枪采用除盐水进行冷却,冷却水可循环利用,降低运行成本。同时在长喷枪所在区域布置多组激光探测器,同时测量烟气温度分布及CO浓度,并根据温度分布信号实时调整每支长喷枪尿素溶液流量,根据CO浓度信号实时调整除盐水流量,从而保证喷入的脱硝还原剂处于最佳反应条件,提高SNCR系统脱硝效率。短喷枪尿素溶液流量采用每层集中控制,根据机组负荷区间控制投运层数和每层尿素溶液总流量,并平均分配到每支喷枪,控制方式简单、易实现。In the present invention, a long spray gun with a plurality of nozzles extends into the middle of the flue, and the urea solution sprayed by the long spray gun can completely cover the cross section of the flue, ensuring that the urea solution and the flue gas are fully and uniformly mixed, and the denitrification efficiency is improved; Cooling, cooling water can be recycled to reduce operating costs. At the same time, multiple sets of laser detectors are arranged in the area where the long spray gun is located, and the flue gas temperature distribution and CO concentration are measured at the same time, and the urea solution flow rate of each long spray gun is adjusted in real time according to the temperature distribution signal, and the desalted water flow is adjusted in real time according to the CO concentration signal, so as to ensure The sprayed denitrification reducing agent is in the best reaction condition, which improves the denitrification efficiency of the SNCR system. The urea solution flow rate of the short spray gun is controlled centrally on each floor, and the number of layers in operation and the total flow rate of each layer of urea solution are controlled according to the load range of the unit, and are evenly distributed to each spray gun. The control method is simple and easy to implement.
附图说明Description of drawings
图1为本发明所述W型锅炉SNCR脱硝系统。Fig. 1 is a W-type boiler SNCR denitrification system according to the present invention.
图2为本发明所述脱硝系统中长喷枪控制回路。Fig. 2 is the control circuit of the long spray gun in the denitrification system of the present invention.
图中:长喷枪1,短喷枪2,尿素溶液储罐3,除盐水储罐4,计量模块6,混合器61,分配模块7,长喷枪分配模块71,中央控制柜81,二极管激光器82,光纤多路复用器83,光纤84,发射端85,接收端86,工程师站9,W型锅炉10。In the figure: long spray gun 1, short spray gun 2, urea solution storage tank 3, demineralized water storage tank 4, metering module 6, mixer 61, distribution module 7, long spray gun distribution module 71, central control cabinet 81, diode laser 82, Optical fiber multiplexer 83, optical fiber 84, transmitting end 85, receiving end 86, engineer station 9, W-type boiler 10.
具体实施方式detailed description
下面结合具体的实施例对本发明做进一步的详细说明,所述是对本发明的解释而不是限定。The present invention will be further described in detail below in conjunction with specific embodiments, which are explanations of the present invention rather than limitations.
本发明一种火电厂W型锅炉SNCR脱硝系统,如图1所示,其包括设置在W型锅炉10水平烟道区域的长喷枪1,在W型锅炉10折焰角区域分多层设置的多个短喷枪2,以及激光检测系统和依次连接的计量模块6和分配模块7;分配模块7包括输出端连接长喷枪1的长喷枪分配模块71和输出端连接短喷枪2的短喷枪分配模块;用于控制尿素溶液浓度的计量模块6输入端分别连接原尿素溶液储罐3和除盐水储罐4,输出端分别连接长喷枪分配模块71和短喷枪分配模块72;所述的激光检测系统包括依次连接的中央控制柜81、二极管激光器82、光纤多路复用器83、光纤84和多组激光器;中央控制柜81用于通过激光器检测烟气温度分布信号和CO浓度信号;其输出端经工程师站9分别连接长喷枪分配模块71和计量模块6;多个长喷枪1在水平烟道的横截面上均匀的呈多层布置,长喷枪分配模块71根据工程师站9的控制信号分别控制每一个长喷枪1喷射的尿素溶液流量;每层短喷枪2的尿素溶液管道入口设置一个电动阀门,短喷枪分配模块72根据W型锅炉10的机组负荷和NSR值控制每层的电动阀门。其中,还包括压缩空气储罐5,压缩空气储罐5的输出端分别用于冷却空气连接在短喷枪2的冷却端入口,用于雾化空气连接在计量模块6和分配模块7之间。中央控制柜81用于检测和处理激光信号;光纤多路复用器83用于两个波段激光信号的耦合;二极管激光器82生成激光信号;光纤84传输激光信号;优选的激光检测装置还包括用于吹扫和气动除焦的保护装置。A kind of W-type boiler SNCR denitrification system of the present invention, as shown in Figure 1, it comprises the long spray gun 1 that is arranged on W-type boiler 10 horizontal flue areas, divides multi-layer arrangement in W-type boiler 10 flame angle areas A plurality of short spray guns 2, and a laser detection system and a metering module 6 and a distribution module 7 connected in sequence; the distribution module 7 includes a long spray gun distribution module 71 whose output end is connected to the long spray gun 1 and a short spray gun distribution module whose output end is connected to the short spray gun 2 The input end of the metering module 6 used to control the concentration of urea solution is respectively connected to the original urea solution storage tank 3 and the desalted water storage tank 4, and the output end is respectively connected to the long spray gun distribution module 71 and the short spray gun distribution module 72; the laser detection system It includes a central control cabinet 81, a diode laser 82, an optical fiber multiplexer 83, an optical fiber 84 and multiple sets of lasers connected in sequence; the central control cabinet 81 is used to detect the flue gas temperature distribution signal and CO concentration signal through the laser; its output terminal The long spray gun distribution module 71 and the metering module 6 are respectively connected via the engineer station 9; a plurality of long spray guns 1 are uniformly arranged in multiple layers on the cross section of the horizontal flue, and the long spray gun distribution modules 71 are respectively controlled according to the control signals of the engineer station 9 The flow of urea solution sprayed by each long spray gun 1; an electric valve is set at the inlet of the urea solution pipeline of each short spray gun 2, and the short spray gun distribution module 72 controls the electric valve of each layer according to the unit load and NSR value of the W-type boiler 10. Among them, a compressed air storage tank 5 is also included, and the output ends of the compressed air storage tank 5 are respectively used for cooling air to be connected to the inlet of the cooling end of the short spray gun 2, and for atomizing air to be connected between the metering module 6 and the distribution module 7. The central control cabinet 81 is used for detecting and processing the laser signal; the optical fiber multiplexer 83 is used for the coupling of the laser signals of two bands; the diode laser 82 generates the laser signal; the optical fiber 84 transmits the laser signal; the preferred laser detection device also includes Protective device for purging and pneumatic decoking.
本优选实例中,如图2所示,长喷枪1共设置有六个,且在水平烟道的横截面上均匀的呈三层布置,长喷枪1所在截面上均匀设置四组激光器;激光器与长喷枪1间隔设置;每组激光器包括一个发射端85和一个接收端86,发射端85连接光纤84,接收端86连接中央控制柜81。In this preferred example, as shown in Figure 2, six long spray guns 1 are arranged in total, and are arranged in three layers evenly on the cross section of the horizontal flue, and four groups of lasers are evenly arranged on the cross section where the long spray gun 1 is located; The long spray guns 1 are arranged at intervals; each group of lasers includes a transmitting end 85 and a receiving end 86, the transmitting end 85 is connected to the optical fiber 84, and the receiving end 86 is connected to the central control cabinet 81.
本优选实例中,长喷枪1冷却端入口连接除盐水储罐4的输出端,冷却端出口连接除盐水储罐4的输入端。计量模块6包括混合器61,以及分别设置在混合器61两个入口的控制阀和流量计;原尿素溶液储罐3和除盐水储罐4的输出端分别通过加液泵与对应的混合器61入口连接。In this preferred example, the inlet of the cooling end of the long lance 1 is connected to the output end of the desalted water storage tank 4 , and the outlet of the cooling end is connected to the input end of the desalinated water storage tank 4 . The metering module 6 includes a mixer 61, and control valves and flowmeters respectively arranged at two inlets of the mixer 61; the output ends of the original urea solution storage tank 3 and the desalted water storage tank 4 are connected to the corresponding mixer through a liquid addition pump respectively. 61 entrance connections.
本发明一种火电厂W型锅炉SNCR脱硝控制方法,包括根据激光检测系统得到的CO浓度信号通过计量模块6调节尿素溶液浓度的步骤;根据激光检测系统得到的温度分布信号通过长喷枪分配模块71调节每个长喷枪1喷射的尿素溶液流量的步骤;根据机组负荷区间和NSR值控制短喷枪2投运层数和每层尿素溶液总流量的步骤。优选的,短喷枪2分两层设置在W型锅炉10折焰角区域,从下往上依次是第一层短喷枪和第二层短喷枪。A method for controlling SNCR denitrification of a W-type boiler in a thermal power plant according to the present invention includes the steps of adjusting the concentration of urea solution through the metering module 6 according to the CO concentration signal obtained by the laser detection system; the temperature distribution signal obtained by the laser detection system is passed through the long spray gun distribution module 71 A step of adjusting the flow rate of urea solution sprayed by each long spray gun 1; a step of controlling the number of layers of the short spray gun 2 in operation and the total flow rate of each layer of urea solution according to the load range of the unit and the NSR value. Preferably, the short spray guns 2 are arranged in two layers in the folded flame area of the W-shaped boiler 10, and there are the first layer of short spray guns and the second layer of short spray guns from bottom to top.
其中,激光检测系统采用TDLAS测量方法得到水平烟道内的CO浓度信号,CO浓度信号在工程师站9中被转化为一路阀门开度信号并送入计量模块6中,调节除盐水回路的控制阀的开度,从而控制长喷枪1喷射的尿素溶液浓度。Among them, the laser detection system uses the TDLAS measurement method to obtain the CO concentration signal in the horizontal flue. The CO concentration signal is converted into a valve opening signal in the engineer station 9 and sent to the metering module 6 to adjust the control valve of the desalinated water circuit. Opening, thereby controlling the concentration of the urea solution sprayed by the long spray gun 1.
其中,激光检测系统采用TDLAS测量方法得到水平烟道内烟气的温度分布信号,温度分布信号在工程师站9中被转化为多路阀门开度信号并送入长喷枪分配模块71中,调节每个长喷枪1控制阀的开度,从而控制每支长喷枪1喷射的尿素溶液流量。Among them, the laser detection system adopts the TDLAS measurement method to obtain the temperature distribution signal of the flue gas in the horizontal flue, and the temperature distribution signal is converted into a multi-way valve opening signal in the engineer station 9 and sent to the long spray gun distribution module 71 to adjust each The opening of the long spray gun 1 controls the valve, thereby controlling the flow rate of the urea solution sprayed by each long spray gun 1 .
本发明中具体布置和控制如下。The specific arrangement and control in the present invention are as follows.
1)如图1所示,六支长喷枪分三层布置在W型锅炉水平烟道区域,向烟气中喷射尿素溶液。长喷枪伸入烟道中心并包含多个喷口,喷射的尿素溶液可覆盖整个烟道截面。长喷枪采用除盐水冷却,冷却水循环利用。1) As shown in Figure 1, six long spray guns are arranged in three layers in the horizontal flue area of the W-shaped boiler, spraying urea solution into the flue gas. The long spray gun extends into the center of the flue and contains multiple nozzles, and the sprayed urea solution can cover the entire flue section. The long spray gun is cooled by demineralized water, and the cooling water is recycled.
2)如图1所示,在W型锅炉折焰角区域分两层布置多支短喷枪,伸入炉内约1米处喷射尿素溶液。短喷枪采用压缩空气进行冷却,冷却空气直接吹入炉膛中。2) As shown in Figure 1, multiple short spray guns are arranged in two layers in the refraction angle area of the W-type boiler, and spray urea solution about 1 meter into the furnace. The short lance is cooled with compressed air, which is blown directly into the furnace.
3)如图2所示,在长喷枪所在截面布置四组激光器,每组激光器包含一个发射端和一个接收端。发射端所发出的特定波长的激光光线穿过锅炉后被接收端采集,然后送入中央控制柜中,由中央控制柜测量未吸收光线与被吸收光线的比例,从而确定烟气温度分布及CO浓度。烟气温度分布信号在工程师站中被转化为六路阀门开度信号并送入长喷枪分配模块,调节每个长喷枪回路中电动阀门的开度,从而控制每支长喷枪喷射的尿素溶液流量。CO浓度信号在工程师站中被转化为一路阀门开度信号并送入计量模块,调节除盐水回路电动阀门的开度,从而控制长喷枪喷射的尿素溶液浓度,具体为随着CO浓度升高,增大除盐水流量;随着CO浓度降低,减小除盐水流量。3) As shown in Figure 2, four sets of lasers are arranged on the section where the long spray gun is located, and each set of lasers includes a transmitting end and a receiving end. The laser light of a specific wavelength emitted by the transmitter passes through the boiler and is collected by the receiver, and then sent to the central control cabinet, where the ratio of unabsorbed light to absorbed light is measured by the central control cabinet to determine the flue gas temperature distribution and CO concentration. The flue gas temperature distribution signal is converted into a six-way valve opening signal in the engineer station and sent to the long spray gun distribution module to adjust the opening of the electric valve in each long spray gun circuit, thereby controlling the flow of urea solution sprayed by each long spray gun. The CO concentration signal is converted into a valve opening signal in the engineer station and sent to the metering module to adjust the opening of the electric valve of the desalinated water circuit, thereby controlling the concentration of the urea solution sprayed by the long spray gun. Specifically, as the CO concentration increases, Increase the flow rate of desalinated water; decrease the flow rate of desalinated water as the CO concentration decreases.
4)短喷枪尿素溶液流量采用每层集中控制,根据机组负荷区间控制投运层数和每层尿素溶液总流量,并平均分配到每支短喷枪。具体为每层短喷枪的尿素溶液管道入口设一个电动阀门,阀门开度根据机组负荷调节。当机组为低负荷时,例如达到满负荷的50%,投运第一层短喷枪,第二层短喷枪关闭,并根据NSR值调节第一层阀门的开度;当机组为中负荷时,例如达到满负荷的75%,同时投运两层短喷枪,并根据NSR值调节两层阀门的开度;当机组为高负荷时,例如达到满负荷的100%,投运第二层短喷枪,第一层短喷枪关闭,并根据NSR值调节第二层阀门的开度。每支短喷枪处设置一个手动阀门,所有手动阀门开度保持一致。4) The urea solution flow rate of the short spray guns is centrally controlled on each floor, and the number of layers in operation and the total flow rate of each layer of urea solution are controlled according to the unit load interval, and are evenly distributed to each short spray gun. Specifically, an electric valve is provided for the inlet of the urea solution pipeline of each short spray gun, and the opening of the valve is adjusted according to the load of the unit. When the unit is under low load, for example reaching 50% of full load, the first layer of short spray guns is put into operation, the second layer of short spray guns is closed, and the opening of the first layer valve is adjusted according to the NSR value; when the unit is under medium load, For example, when the unit reaches 75% of full load, put into operation two layers of short spray guns at the same time, and adjust the opening of the two layers of valves according to the NSR value; , the short spray gun of the first layer is closed, and the opening of the valve of the second layer is adjusted according to the NSR value. A manual valve is set at each short spray gun, and the openings of all manual valves are consistent.
其中,激光检测系统采用TDLAS(Tunable Diode Laser AbsorptionSpectroscopy,可调谐二极管激光可吸收光谱)技术,集两个波长激光于一根光纤,然后使发出的光线依次穿过W型锅炉的水平烟道段。接收器采集光线后将其传回中央控制柜,由中央控制柜对穿过锅炉的特定波长的基准光量与被测物质分子所吸收的光量之间的比率进行比较,从而确定各个被测对象的浓度,气体温度则根据两条CO2特征吸收谱线的比值来测量。发射器及接收器能够自动校正,以确保在锅炉扰动时也能获得最佳的光量传输,同时配有仪用气吹扫装置和气动除焦装置,来保证探测孔的畅通。本发明中,在水平烟道的两端装有发射端85和接收端86,当激光从一侧发出时,对应端的接收端86收到后,在水平烟道中形成一条测量路径,这些路径可以同时测量炉膛内CO浓度和炉膛温度。Among them, the laser detection system adopts TDLAS (Tunable Diode Laser Absorption Spectroscopy, Tunable Diode Laser Absorption Spectroscopy) technology, which integrates two wavelengths of laser light into one optical fiber, and then makes the emitted light pass through the horizontal flue section of the W-type boiler in sequence. The receiver collects the light and transmits it back to the central control cabinet, and the central control cabinet compares the ratio between the reference light quantity of a specific wavelength passing through the boiler and the light quantity absorbed by the measured substance molecules, so as to determine the Concentration, gas temperature is measured according to the ratio of two CO 2 characteristic absorption lines. The emitter and receiver can be automatically calibrated to ensure the best light transmission even when the boiler is disturbed. At the same time, it is equipped with an instrument gas purging device and a pneumatic decoking device to ensure the smooth flow of the detection hole. In the present invention, a transmitting end 85 and a receiving end 86 are installed at both ends of the horizontal flue. When the laser light is emitted from one side, after the receiving end 86 of the corresponding end receives it, a measuring path is formed in the horizontal flue. These paths can be Simultaneously measure CO concentration and furnace temperature in the furnace.
TDLAS测量的原理是气体分子对特定频率(波长)的光线具有吸收作用,吸收率与温度、压力、路径长度和气体浓度相关。对于一个已知的路径长度和气体压力,通过收集并分析激光在一个特征吸收频率范围中的吸收率,可以确定烟气的温度和组分浓度。The principle of TDLAS measurement is that gas molecules absorb light of a specific frequency (wavelength), and the absorption rate is related to temperature, pressure, path length and gas concentration. For a known path length and gas pressure, the temperature and component concentration of the flue gas can be determined by collecting and analyzing the absorption rate of the laser light in a characteristic absorption frequency range.
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