CN106420518A - Skin cleaning product containing cereal and ginseng fruit shells, and preparation method thereof - Google Patents

Abstract

The present invention relates to the fermentation products of cereal and ginseng fruit shells, and the application thereof in a skin cleaning product. According to the method, firstly, a culture medium containing cereal and ginseng fruit shells is heated and sterilized. After that, a microbe is inoculated into the culture medium, and then the culture medium is fermented and sterilized to obtain fermentation products containing a bacterium, a fermentation filtrate and solid particles. The fermentation products are applied to the cleaning product. The cleaning product has the effects of removing grease on the surface of the skin, smoothing the skin, preventing inflammation, removing acnes and the like. Meanwhile, the cleaning product nourishes the skin and gently removes the skin cutin, which is low in irritation, safe and mild.

Description

Cleaning products containing cereal ginseng shell and preparation method thereof

Technical field

The present invention relates to a kind of skin cleansing compositions, the particularly skin clean containing cereal ginseng shell tunning Composition.

Technical background

In the cleaning products commonly used at present, no alveolitoid cleaning products contain appropriate oil content typically in formula, Sometimes also contain a small amount of surfactant, it is characterized by foam is less, relatively gentleer, with the foam containing exhibiting high surface activating agent Type mildy wash is compared, and has low irritant, does not result in excessive cleaning, the spy of suitable Dry and sensitive use Levy.But a disadvantage is that less to skin clean dynamics, do not possess removal epidermis unnecessary cutin function simultaneously.

Frosted type cleaning products are widely used in household chemicals field.Frosted type cleaning products its mainly form into Part it is：Abrasive particle, surfactant and other additives.Abrasive particle therein can be largely classified into organic abrasive particle and Inorganic abrasive particle.Wherein organic abrasive particle includes natural shell particle, fruit stone particle, oyster shell whiting, pearl powder.Inorganic frosted Particle has bamboo charcoal, kaolin, salt particle, quartz sand, calcium carbonate etc..The decontamination that its main feature is in addition to cleaning agent in formula is made With outer, unnecessary cutin, dust and bag spot etc. can also be removed by abrasive particle mechanical friction effect.But if abrasive particle Composition is really up to the mark or improper use can cause skin friction to damage, excessively thin acceleration skin exfoliation (particularly dryness and the neutrality of cuticula Skin consumer).

Nowadays, advocate natural Never Ending Fashion to have swept the globe, beauty and skin care circle also can not make an exception, start people to natural peace The upsurge that full skin care item are pursued, some natural, safe skin care item Effect raw materials pour in the visual field.The health to human body for the five cereals Play very favorable effect, in five cereals, contain rich in protein, carbohydrate, fat, mineral matter and multivitamin, These nutritions are quite helpful to skin nursing.Cereal especially by fermentable is used in skin nursing thering is guarantor Hold moisture content of skin, strengthen skin elasticity, strengthen skin furan barrier, promote subcutaneous collagen albumen to produce and certain anti-oxidation efficacy..

KR20130019192A discloses plum, pomegranate, citrus, rice pulverizing, adds lactic acid bacteria culture, and centrifugation obtains Obtain filtrate, for Exfoliating Scrub, but the cleaning products of the method preparation have no good report for the removal of skin oil and fat.

KR20090115844A discloses Chinese herbal medicine (the particularly root of Dahurain angelica), red bean, rice bran addition lactobacillus-fermented, filtration Filtrate, the substitute for washing agent or soap cleans vagina, has the growth preventing vagina mucosa harmful bacteria, removes different Effect of taste.But the cleaning products of the method preparation are to have no skin surface oil stain removing is reported.

JP2001271096A discloses rice bran as the application of cleaning agent, and described bran powder passes through to add lactic acid bacteria, 58 DEG C Cultivation and fermentation 6 hours, adds citric acid 5%, is dried, acquisition of sieving.The document compares ferment rice bran powder with azymic rice Bran powder cleaning skin effect, result display ferment rice bran more can improve skin hydration degree.But this powder cleaning agent makes With front need to mix with liquid or egg liquid in advance size mixing after smear skin, using cumbersome, and the battalion in short time mixed-powder Foster material can not cmpletely discharge, and causes nutrition can not fully be absorbed by the skin.

CN103211749A discloses the method preparing shampoo by fermentable glutinous rice flour, but it selects bacterium Strain fermentation time is up to 15 days, can have impact on the granular sensation that glutinous rice flour script carries after fermentation.Weaken the effect of its frosted cleaning Really.

Therefore there is still a need for finding a kind of method being suitably used for cleaning products.

At present, it is mainly used in field of food using fermentable bread basket.CN101164428A discloses fermentation Corn flour, the method for preparing biological feedstuff such as dregs of beans, the food of the viscous corn flour of CN103404779A lactobacillus-fermented, Wang Zhi Big grade " research of lactic acid bacteria fermented grain food acid congee zymotechnique, processing of farm products, 2010.2,27～30 " disclose It is cut as raw material with glutinous rice, millet, rotten rice, corn, using the excellent lactobacillus-fermented of proterties, after recording fermentation, sample amino acid contains Amount and total amount showed increased." the Hypolipidemic effects of lactic acid bacteria such as Immaculata Fermented cereal in rats " .Banjoko et al.Lipids in Health and Disease, 2012.11, 170 disclose lactobacillus acidophilus, Bifidobacterium and Lactobacillus helveticus mixed fermentation corn flour, well-grown in corn flour, send out After ferment, corn flour reaches acceptable taste.And find this mixed fermentation food play the role of suppress fat absorption^[2]. " the Lactic acid bacteria producing B-group vitamins such as Vittorio：a great potential For functional cereals products ", Appl Microbiol Biotechnol, 2012,96：1383-1394 Disclose the screening that can pass through microorganism and the different contents improving VB race in fermented cereal of fermentation condition, exploitation is in cereal Fermented product micro-organisms vitamin.Wu little Yan etc. " Agricultural University of the Inner Mongol, master's knowledge paper, 2013 " report with breast Acid bacteria fermentation coix seed, polysaccharide in fermentation liquid, content of peptides do not ferment and increase 4～8 times, and zymotic fluid has good antioxygen The property changed.Fu Liang etc. " development of fermented type rice milk, food and machinery, 2006,5：103～105. " with rice as raw material, through gelatinization Access a certain amount of lactic acid bacteria and fermented Deng after pretreatment, obtain sense organ and the good fermented type rice milk of structural state.Gong Yuan Raw etc. " development of millet fermented beverage, Journal of Zhengzhou Grain College, 1999,3：41～43. " koji and saccharomycete two are adopted Step fermentation obtains the good millet fermented beverage of taste.As can be seen here, microorganism is in using cereal while nutriment, from Body produces some metabolites, makes the macromolecular in cereal be decomposed into the material of molecular weight it is easier to absorb.Also will simultaneously The nutriment being difficult in cereal discharge discharges.In addition through fermentable can produce distinctive material for example lactic acid, polysaccharide, Antibiotic, polyphenoils and bioconversion product make product have more high bioactivity it is easy to body absorption etc. acts on.But It is that the application that fermented grain product is used in cleaning products have not been reported.

Ginseng belongs to the plant of Araliaceae Panax, and the effect reported up to now has：The work of Central nervous system With, antitumaous effect, immunoregulation effect, strengthen liver function function, cardiovascular disorder improvement, resistance to compression, antifatigue effect, anti-oxidant work Property and anti-aging suppression function.

Ginseng physiologically active composition is ginsenoside.What application was most is the underground position of ginseng at present, but ginseng Also ginsenoside composition is contained in leaf, flower, fruit, seed.Different parts in ginseng plant, the content of ginsenoside has significantly Difference.

In recent years, ginseng is widely studied as the skin function raw material of cosmetics, and wherein most all make use of ginseng Root, mainly use panaxan and ginsenoside composition.But the skin function effect disquisition being brought using ginseng shell Very few, the research that particularly fermented rear ginseng shell extract is used for skin has no report.

Inventor finds, fermented grain product is applied in Cleasing compositions, because fermented grain product contains in a large number Starch and dextrin, have good adsorption removal effect, secondly, fermented grain product is applied to cleaning products to skin oil and fat In, remain the granular sensation of cereal and gentle frosted sense, the abrasive action during cooperation cleaning can gently remove skin Surface aging cutin.In addition nutriment such as thalline, lactic acid, polypeptide, amino acid, polysaccharide, the vitamin in fermented grain product Impart cleaning products nourish skin Deng also, prevent from cleaning the scaly dry skin excessively brought, the sense of discomfort such as tight.Further Existing, the tunning that ginseng shell is mixed with cereal is used for preparing and enhances its anti-inflammatory, moisturizing, antioxygen in Cleasing compositions Change, the effect of Sage Extract, and composition obtains the low irritant of raising, the gentle feature of safety.

Therefore, the present invention relates to cereal and ginseng shell tunning are applied in Cleasing compositions, it is in composition In remain cereal and ginseng shell Dare nutrition and granular sensation, can gently remove skin surface aging cutin, remove table Face grease, skin nutrition, skin irritatin of releiving, there is low irritant, safety temperature simultaneously.

Content of the invention

The present invention relates to application in Cleasing compositions for the cereal ginseng shell tunning.

Described tunning passes through, by the culture medium heat sterilization containing the cereal pulverized and ginseng shell, to be followed by giving birth in a subtle way Thing, fermentation, sterilizing, the cereal ginseng shell tunning of thalline, ferment filtrate and solid particle must be comprised.Described cereal ginseng The product that shell tunning is obtained after fermentable by cereal and ginseng shell particle, it has 0.02mm～1mm, The particle diameter of preferably 0.05mm～0.4mm, more preferably 0.15mm～0.25mm.

Further, described cereal is selected from one or more of rice, millet, corn, black rice, Chinese sorghum, adlay.

Further, the present invention relates to the skin cleansing compositions containing corn ginseng shell tunning.

Further, Cleasing compositions of the present invention are essentially free of surfactant.

The tunning of the present invention, it is prepared by following step：

1st, culture medium heat sterilization

2nd, access the fermented bacterium having activated

3rd, ferment

4th, adjust pH

5th, sterilize

Wherein, culture medium is that cereal-granules, ginseng shell particle and pure water are prepared.Granulate mixture content in its culture medium For 3%～30 weight %, preferably 5%～25%, more select 10%～15%, wherein cereal-granules and ginseng shell particle weight Than for 70: 30-99: 1, preferably 80: 20-95: 5, more preferably 90: 10, its sterilising temp is 50 DEG C～120 DEG C, and the time is 10min～30min.

Microbial inoculant amount is 0.1%～20% volume.

Fermentation temperature is 25 DEG C～45 DEG C

Adjusting pH scope is 4.0～7.0.

The further pH scope that adjusts is 5.0～6.0.

Sterilising temp is 65 DEG C～120 DEG C.Sterilization time is controlled to 15min～60min.

Further, nutriment can be added in culture medium.Described nutriment be selected from glucose, lactose, sucrose and/or Maltose, preferably glucose.

Described microorganism, selected from brewer's yeast (Saccharomyces cerevisiae), candida utili Saccharomycete such as (Candida utilis), or lactobacillus acidophilus (Lactobacillus acidophilus), Lactobacillus paracasei (Lactobacillus paracasei), Lactobacillus rhamnosus (Lactobacillus rhamnosus), Lactobacillus brevis (Lactobacillus brevis), lactobacillus bulgaricus (Lactobacillus bulgaricus), lactobacillus reuteri (Lactobacillus reuteri), Lactobacillus salivarius (Lactobacillus salivarius), streptococcus thermophilus (Streptococcus thermophilus), Leuconostoc mesenteroides (Leuconostoc mesenteroides), Lactococcus lactis The lactic acid bacterias such as bacterium (Lactococcus lactis), or the mixture of one or more microorganisms of root enzyme bacterium or Aspergillus.

Be suitable for the present invention Cleasing compositions can be washing cream, mildy wash, face cleaning curry, face cleaning Mu Si, bath foam, The arbitrary forms such as bath oil, hand cleanser, it can be applicable to facial cleansing and clean body.

In one particular embodiment, described emulsion Cleasing compositions contain：

Oily matter 1%～20 weight %, preferably 2%～15 weight %, particularly 3%～10 weight %；

Tunning 10%～80 weight %, preferably 20%～70 weight %, particularly 30%～50 weight %；

Emulsifying agent 1%～10 weight %, preferably 2%～8 weight %, particularly 3%～5 weight %,

Viscosity modifier 0.01%～5 weight %, preferably 0.05%～3 weight %, particularly 0.1%～1 weight %,

Pure water 10%～80 weight %, preferably 15%～60 weight %, particularly 20%～40 weight %.

In one particular embodiment, described curry Cleasing compositions contain：

Tunning 10%～80 weight %, preferably 20%～70 weight %, particularly 30%～50 weight %

Gel 0.01%～5 weight %, preferably 0.05%～3 weight %, particularly 0.1%～1 weight %.

Water 10%～80 weight %, preferably 15%～60 weight %, particularly 20%～40 weight %.

Oily matter

Siloxanes, and also aryl-, the polymethyl siloxane of alkyl-or alkoxyl-replacement and ring first siloxanes.

The grease being applied to the present invention also includes straight chain and/or side chain unitary and/or the binary with 2-44 carbon atom The unitary of carboxylic acid and the saturation with 1-22 carbon atom or undersaturated straight chain and/or branched-chain alcoho and binary esters.Similarly, As the grease for the present invention, it is possible to use there is difunctional aliphatic's alcohol of 2-36 carbon atom with to have 1-22 carbon former The ester of monofunctional aliphatic's carboxylic acid of son.

As the grease for the present invention, can also specifically preferably use the ester of the aliphatic acid with 12-22 carbon atom Class, such as methyl esters and isopropyl ester, such as methyl laurate, methyl stearate, methyl oleate, methyl erucate, isopropyl palmitate, Isopropyl myristate, isopropyl stearate and/or acid isopropyl.

Additionally, as the grease for the present invention, also specifically preferably the just own ester of BS, laurate, oleic acid is being just Last of the ten Heavenly stems ester, Ethylhexyl stearate, palmitic acid different nonyl ester, isononyl isononanoate, palmitic acid 2- ethylhexyl, laurate 2- ethyl hexyl Base ester, stearic acid 2- hexyl decyl ester, palmitic acid 2- octyldodecyl, oleic oil alkene ester, erucic acid oil alkene ester and/or oleic acid Mustard ester.

As the grease for the present invention, be also particularly suitable is dicarboxylic acids esters, for example Di-n-butyl Adipate, the last of the ten Heavenly stems two Sour di-n-butyl, adipic acid two (2- ethylhexyl) ester, butanedioic acid two (2- hexyl decyl) ester and/or the different tridecane of azelaic acid two Base ester.As the grease for the present invention, be also particularly suitable is diol-lipid, such as two oleic acid glycol esters, two different 13 The sad DOPCP of alkanoic acid glycol ester, two (2 ethyl hexanoic acid) propylene glycol ester, two isostearic acid butanediol esters and/or two.

As the grease for the present invention, carbonic diester class can also be used, such as carbonic acid two (2- ethylhexyl) ester.

Equally applicable is the triglyceride of long-chain relatively, i.e. triple esters of glycerine and three acid molecules, these acid In molecule, at least one is the acid molecule of a relative long-chain.Here by way of example it is mentioned that fatty acid glycerine Three esters, this include synthesize the triglyceride of the mixture of caprylic/capric, the triglyceride of industrial oleic acid, different tristearin The triglycerides of acid and the triglyceride of palm/oleic acid mixture.Straight or branched fatty alcohol additionally can be used Class, such as oleyl alcohol or octyldodecanol, and also fatty alcohol ethers, such as dicaprylyl ether etc..

As the grease for the present invention, equally applicable is crude vegetal, for example olive oil, sunflower oil, soybean Oil, peanut oil, rapeseed oil, apricot kernel oil, palm oil and/or jojoba oil, and also coconut oil or palm shell oil liquid Part, and also animal oil, such as the liquid part of sperm oil, neat's foot oil or butter.

As the grease for the present invention, squalene extracting, particularly atoleine and isoparaffin can also be used.Can With use squalene extracting example be paraffin oil, White Mineral Oil, isohexadecane, poly decene, petroleum jelly, light liquid paraffin and/or Saualane.Additionally, the esters of aryl carboxylic acid are also suitable, such as benzoic esters, for example there is the full of 1-22 carbon atom And/or the benzoic ether that undersaturated straight or branched alcohol is formed with benzoic acid, such as benzoic acid iso stearyl ester and benzoic acid 2- Octyldodecyl, preferably benzoic acid C12-15 Arrcostab.

In a preferred embodiment of Cleasing compositions of the present invention, oily matter can be white oil, laurate, Pork and beans One or more of cool acid, stearic acid, isobutyl palmitate are combined.

Emulsifying agent

In the still skin cleansing compositions of the present invention, further comprises emulsifying agent, it is nonionic emulsifier.It is applied to The oil-in-water nonionic emulsifier of the present invention is selected from the Hydrophilic nonionic surface work having polyoxyethylene chain as hydrophilic group Property agent, polyglyceryl fatty acid ester, polyglycereol fatty alcohol ether, sucrose fatty ester.

In a preferred embodiment of the invention, described have polyoxyethylene chain as hydrophilic group hydrophily non-from Sub- surfactant is selected from the group：Polyoxyethylene fatty acid ester, polyoxyethylene aliphatic alcohol ether, polyoxyethylene glycerol mono fatty acid Ester, Crodaret and Crodaret mono fatty acid ester.

As polyoxyethylene fatty acid ester, preferably polyoxyethylene caprylic ester, polyoxyethylene 2 ethyl hexanoic acid ester, polyoxyethylene Decylate, polyoxyethylene laurate, polyoxyethylene myristinate, polyoxyethylene palmitate, polyoxyethylene isostearic acid Ester, Myrj 45, polyoxyethylene oleate, polyoxyethylene behenic acid ester etc..

As polyoxyethylene aliphatic alcohol ether, preferably polyoxyethylene octyl ether, polyoxyethylene decyl ethers, polyoxyethylene laural base Ether, polyoxyethylene myristyl ether, polyoxyethylene palmityl ether, polyoxyethylene iso stearyl ether, polyoxyethylene stearyl base ether, poly- Oxygen ethene oleyl ether, polyoxyethylene mountain base ether etc..

As polyoxyethylene glycerol mono fatty acid ester, preferably polyoxyethylene glycerol list caprylate, the polyoxyethylene glycerol list last of the ten Heavenly stems Acid esters, polyoxyethylene glycerol monolaurate, polyoxyethylene glycerol list myristinate, polyoxyethylene glycerol monopalmitate, Polyoxyethylene glycerol list isostearate, polyoxyethylene glycerol monostearate, TMGO 5, polyoxyethylene Glycerol monobehenate etc..

As Crodaret, polyoxyethylene structure division preferably wherein averagely comprise 20-80, preferably Those Crodarets of 30-60 ethylene oxide repeating units.

As Crodaret mono fatty acid ester, preferably Crodaret list caprylate, polyoxy Ethylene hydrogenation castor oil monkey cell, Crodaret monolaurate, Crodaret list Pork and beans Cool acid esters, Crodaret monopalmitate, Crodaret list isostearate, polyoxyethylene hydrogen Change castor oil monostearate, Crodaret monoleate, Crodaret list behenic acid ester etc..

As polyglyceryl fatty acid ester, the preferably list of polyglycereol-and many caprylates, the list-of polyglycereol and many 2- ethyl hexyl Acid esters, the list-of polyglycereol and many decylates, the list-of polyglycereol and many laurates (as Natrulon H-10 five laurate), poly- The list of glycerine-and many myristinates, the list-of polyglycereol and many palmitates, the list-of polyglycereol and many isostearates, poly- The list of glycerine-and many stearates (as polyglycereol -3 distearate), the list-of polyglycereol and many oleates are (as polyglycereol -2 Dioleate), the list-of polyglycereol and many behenic acids ester etc..

As above-mentioned polyglycereol fatty alcohol ether, formed preferably wherein this polyglycereol fatty alcohol ether fatty alcohol be saturation or Undersaturated and there is 8-22 carbon atom and polyglycerol moiety averagely comprises the poly- sweet of 2-60 glycerine repetitive Oil and fat alcohol ether.As the example, it can be mentioned：Polyglycereol Octyl Ether, polyglycereol decyl ethers, polyglycereol lauryl ether, poly- sweet Oily myristyl ether, polyglycereol palmityl ether, polyglycereol iso stearyl ether, polyglycereol stearyl ether, polyglycereol oleyl ether, poly- sweet Oily mountain base ether etc..The fatty alcohol particularly preferably wherein forming this polyglycereol fatty alcohol ether is saturated or unsaturated and has There is 8-18 carbon atom and polyglycerol moiety averagely comprises the polyglycereol fatty alcohol ether of 3-15 glycerine repetitive, especially It is that the fatty alcohol wherein forming this polyglycereol fatty alcohol ether is saturated or unsaturated and has 10-14 carbon atom and gather Glycerine structure division averagely comprises the polyglycereol fatty alcohol ether of 3-5 glycerine repetitive, such as polyglycereol -4 lauryl ether.

As sucrose fatty ester, the list-of preferably sucrose and many caprylates, the list-of sucrose and many 2 ethyl hexanoic acids ester, sugarcane The list of sugar-and many decylates, the list-of sucrose and many laurates (as sucrose dilaurate), the list-of sucrose and many nutmegs Acid esters, the list-of sucrose and many palmitates (as sucrose six palmitate), the list-of sucrose and many isostearates, sucrose Single-and many stearates, the list-of sucrose and many oleates, the list-of sucrose and many behenic acids ester etc..

Viscosity-controlling agent and gel can be contained, it is hydroaropic substance, described aqueous materials in the composition of the present invention Matter is selected from water-soluble polymer.

As water-soluble polymer, can be natural polysaccharide class, such as xanthans, Arabic gum, guar gum, crust Plain derivative (for example quaternized hydroxypropyl chitin), hyaluronic acid, xanthan gum etc..

As water-soluble polymer, can also be semi synthetic polymer, such as modified cellulose class, it is fine that it includes methylol Dimension element, hydroxyethyl cellulose, hydroxypropyl cellulose, quaternized cellulose etc..

Further, the composition of the present invention can contain polyalcohol, and the polyalcohol that can be used for the present invention is that have 1 to 6 The polyalcohol of individual carbon atom, including propane diols, hexylene glycol, glycerine and propane diols.

Annexing ingredient

The plot composition of the present invention can comprise annexing ingredient, these annexing ingredients can by technical staff according to required The characteristic of finished product is selected, and these annexing ingredients of the moon are suitable to make said composition more attractive or make it have additional use Beneficial effect.

The independent consumption of annexing ingredient is usually 0.001% to 10 weight % by weight of the composition, preferably 0.01-5 weight %.

Various other annexing ingredients can be formulated in the composition of the present invention.These components but be not limited to moisturizing The compositions such as agent, whitening agent, antioxidant, conditioner, preservative, pH adjusting agent, colouring agent, spices, chelating agent.

Foaming surfactant

The present composition is substantially free of foaming surfactant, and described foaming surfactant is selected from anion and foams Surfactant, nonionic lather surfactants, both sexes foaming surfactant and their mixture.

Anionic lathering surfactant agent non-limitative example includes sarcosinate, sulfate, isethionate, taurine Salt, phosphate, lactate, glutamate and their mixture.

Nonionic foaming surfactant includes alkyl glucoside, alkyl polyglucoside, polyhydroxy fatty acid amide, alcoxyl Base fatty acid ester, foaming sucrose ester, amine oxide and their mixture.

" both sexes foaming surfactant " includes zwitterionic surfactant, and it is little as amphoteric surfactant one Class is known to the skilled formulator of this area.Can be using quite widely both sexes foam surface work in the present composition Property agent.The non-limitative example of both sexes or zwitterionic surfactant is selected from glycine betaine, sulfobetaines, weight ratio beet Alkali, alkyhminoacetates, iminodiacetic alkanoate, aminoalkanoates and their mixture.

Brief description

Fig. 1 is using the tunning Cleansing Foam of shell containing corn ginseng with rice bran fermentation cleaning powder face cleaning skin transdermal dehydration ratio Relatively scheme.

Fig. 2 is using the tunning Cleansing Foam of shell containing corn ginseng with rice bran fermentation cleaning powder face cleaning skin hydration degree water ratio Relatively scheme.

Fig. 3 is using the tunning mildy wash of shell containing corn ginseng with the non-smooth points amount ratio of glutinous rice yeast powder face cleaning skin Relatively scheme.

Fig. 4 uses the still Cleansing Foam face cleaning of different-grain diameter fermented maize ginseng shell, the non-smooth comparison diagram of counting out of skin.

Fig. 5 uses different-grain diameter fermented maize ginseng shell Cleansing Foam face cleaning, removes grease comparison diagram.

The still Cleansing Foam of Fig. 6 corn ginseng shell tunning compares with several Cleansing Foam excitants.

Fig. 7 difference cereal ginseng shell tunning Cleansing Foam face cleaning removes grease comparison diagram.

Grease comparison diagram removed by the mildy wash of Fig. 8 different strain fermented maize ginseng shell product.

Fig. 9 is compared with fermented maize still Cleansing Foam face cleaning anti-inflammatory using the tunning Cleansing Foam of shell containing corn ginseng Figure.

Figure 10 is removed freely with fermented maize still Cleansing Foam face cleaning using the tunning Cleansing Foam of shell containing corn ginseng Base comparison diagram.

Specific embodiment

For being best understood from present disclosure, it is embodied as example in conjunction with some and further illustrates.

Preparation example 1：Corn and the preparation of ginseng shell tunning

(particle diameter is to take 90g corn quarrel and 10g ginseng shell particle：0.15mm～0.25mm, 60 mesh～80 mesh) and 900ml In drinking water, heat sterilization, sterilising conditions are 105 DEG C, 15min, and cooling room temperature is followed by into Lactobacillus casei, and inoculum concentration is 5% Volume.37 DEG C of fermentation 24h～48h.Adjust PH to 5.5～6.0, inactivate thalline, sterilising conditions are 105 DEG C, 15min.

Preparation example 2：Corn and the preparation of ginseng shell tunning

Identical with preparation example 1 method, difference is that (particle diameter is granulate mixture：0.25mm～0.5mm, 40 mesh～60 Mesh).

Preparation example 3：Corn and the preparation of ginseng shell tunning

Identical with preparation example 1 method, difference is that (particle diameter is 0.1mm～0.15mm to granulate mixture：80 mesh～120 Mesh).

Contrast preparation example 1：Prepared by tunning

Identical with preparation example 1 method, difference is that (particle diameter is granulate mixture：＜ 0.1mm, more than 120 mesh).

Contrast preparation example 2：Prepared by corn fermentation product

Identical with preparation example 1 method, difference is that (particle diameter is granulate mixture：＞ 0.5mm, below 40 mesh).

Contrast preparation example 3：Rice bran ferment particulate with reference to JP2001271096A

Contrast prepares ice-cold 4：Glutinous rice flour tunning with reference to CN103211749A

Contrast preparation example 5：Frosted particle, is walnut frosted particulate, and particle diameter is 0.15mm～0.25mm, 60 mesh～80 mesh.

Fermentation composition preparation example 1-3 and comparative example 1-5 still skin cleansing compositions sensory effects are evaluated

Select 5 expert opinion group members, carry out sensory evaluation in such a way

Respectively using embodiment 1-3 and the still skin cleansing compositions of comparative example 1-5, then using effect makes scoring. Granular sensation is with feeling to make evaluation.Cleaning effect carries out skin oil and fat assay by MPA580 skinanalysis apparatus, according to making With impression comprehensive marking is carried out to composition, standard be use when non-stimulated, use when easy to apply, using rear moisten, use after Clearly, smoothed using rear skin and respectively account for 1 point, have one not meet and deduct 1 point.

[1] the corn ginseng shell tunning of fermentation composition preparation example 1

[2] the corn ginseng shell tunning of fermentation composition preparation example 2

[3] the corn ginseng shell tunning of fermentation composition preparation example 3

[4] contrast the corn ginseng shell tunning of preparation example 1

[5] contrast the corn ginseng shell tunning of preparation example 2

[6] with reference to the rice bran ferment particulate of JP2001271096A

[7] with reference to the glutinous rice flour tunning of CN103211749A

[8] frosted particle is walnut frosted particulate, and particle diameter is 0.15mm～0.25mm, 60 mesh～80 mesh.

Conclusion：After the corn ginseng shell tunning cleaning of embodiment 1-3, perceptual effect is optimal, and has good grease Elimination effect, the wherein particle sizes of grains of embodiment 1 are in 0.15mm～0.25mm, more excellent with ginseng shell fermentate mixed effect.

Embodiment 1 and comparative example 3 composition effect evaluation

20 volunteers are divided into two groups, are divided into the still mildy wash group of corn ginseng shell tunning and ferment rice bran Powder group, volunteer is twice daily using corn ginseng shell tunning mildy wash and ferment rice bran powder face cleaning, routine use phase With placebo creams skin care.After 8 weeks, MPA580 tests skin hydration degree and transdermal dehydration.

Result shows that corn ginseng shell tunning mildy wash group skin hydration degree is higher than ferment rice bran using after 8 weeks Group, transdermal percentage of water loss is less than ferment rice bran group.Illustrate in the still mildy wash of tunning that nutrition more can fill part to be inhaled by skin Receive, have enhancing skin barrier function more by force simultaneously.

Embodiment 1 and contrast ice-cold 4 still composition effect evaluations

20 volunteers are divided into two groups, are divided into the still Cleansing Foam group of corn ginseng shell tunning and fermentation glutinous rice Powder cleaning agent group, volunteer uses the still Cleansing Foam of corn ginseng shell and fermentation glutinous rice flour cleaning agent face cleaning, VISIA after 5min Full face analysis instrument measures the non-smooth points amount of skin surface.

The result display non-smooth reduced rate of corn ginseng shell tunning still Cleansing Foam group skin surface is significantly high In fermentation glutinous rice flour cleaning agent.Illustrate that the gentle frosted particle effect in the still Cleansing Foam of corn fermentation product removes more by force skin Unnecessary dirt around excess surface cutin and pore.

Embodiment 1-3 and contrast ice-cold 1-2 still Cleansing Foam contrast

30 volunteers are divided into 6 groups, respectively using 5 kinds of different-grain diameter corn ginseng shell Cleansing Foam face cleanings and blank Cleansing Foam.Blank group is the still mildy wash without tunning.Face cleaning dries the facial smoothness of test and face after 5min naturally Portion's grease situation of change.

Result showed that 60 mesh～80 mesh sieve corn particle ginseng shell tunning Cleansing Foam groups reduced in non-smooth point Best results in rate and oil stain removing rate.Particle is excessive cannot to be disperseed very well during face cleaning and rub, the too small funeral of particle Frosted particle sensation and effect are lost.

Embodiment 4

The still Cleansing Foam of corn ginseng shell tunning compares with commercially available several mildy wash excitants

Sample number into spectrum	Cleaning composition
		Embodiment 2	Corn ginseng shell tunning
Sample 1	Sodium lauryl tri(oxyethyl) sulfate, Cocoamidopropyl betaine
		Sample 2	Glycerin monostearate, sodium cocoyl glutamate
Sample 3	Laruyl alcohol sodium sulfovinate, APG
		Sample 4	Odium stearate, Sodium myristate

Take commercially available mildy wash to be measured and corn ginseng shell tunning mildy wash, being made into active material fraction is 10% Solution, adds a certain amount of zeins (zein), stirs 2h at 25 DEG C, then filters.Filtrate is fixed with micro kelvin Nitrogen method records the mass fraction (A) of nitrogen.The quality of nitrogen in the surfactant solution be not added with zein can be recorded with same method Fraction (B).

Zein value=A-B, in zein value solution, institute's nitrogen content mg (or g)/L represents, lives in zein value bigger explanation surface Property agent excitant is bigger.

Result (accompanying drawing 6) shows that commercially available several mildy wash Zein values are far above still corn ginseng shell fermentation and wash one's face Breast, illustrates that several mildy wash excitants containing Common surface activating agent are far above still corn fermentation product mildy wash.

Embodiment 5 prepares the still mildy wash of different cereal ginseng shell ferment particulate

Identical with tunning preparation example 1 method, difference be cereal be rice, millet, black rice, Chinese sorghum, coix seed (grain Footpath is：One of 0.25mm～0.5mm, 40 mesh～60 mesh).Blank control group is the mildy wash without tunning.Its Cleaning effect is shown in accompanying drawing 7：Result display rice, millet, black rice, Chinese sorghum, coix seed tunning and ginseng shell tunning Mildy wash remove grease effect be much better than the blank group without tunning.

Embodiment 6 prepares the still mildy wash of different microorganisms fermented grain particle

Identical with embodiment 1 method, difference is using different microorganisms：Microorganism is respectively adopted saccharomyces cerevisiae (Saccharomyces cerevisiae), Rhizopus javanicus (Rhizopus), the one of aspergillus oryzae (Aspergill us oryzae) Plant and fermented.(particle diameter is：0.25mm～0.5mm, 40 mesh～60 mesh).Blank control group is still without tunning Mildy wash.Its cleaning effect is shown in Fig. 8：Result shows that the still mildy wash cleaning effect of several microbial fermentation product preparations is far excellent In the still mildy wash without fermented grain thing.

Embodiment 7 corn and the ginseng shell still mildy wash of fermentation compare with corn fermentation mildy wash antiphlogistic effects.

20 volunteers for a long time with scytitis and acne recurrent exerbation, are equally divided into two groups, are corn ginseng fruit Shell tunning still Cleansing Foam group and non-fermented maize still Cleansing Foam group, volunteer is twice daily using corn ginseng shell The still Cleansing Foam of tunning and non-fermented maize still Cleansing Foam face cleaning, routine use identical placebo creams skin care.Using 4 Zhou Hou, compares acne and the degree of scytitis, and its result shows scorching using corn and fermented ginseng still mildy wash group face Disease is improved degree and is substantially better than control group.Result is shown in accompanying drawing 9.

Embodiment 8 corn and ginseng shell ferment still mildy wash with corn fermentation mildy wash non-oxidizability effectiveness comparison.

10 dilution respectively of the corn fermentation product mildy wash of the present invention and corn and ginseng shell tunning mildy wash Times.Experiment, with vitamin C as positive control, samples 1ml, adds the DPPH- ethanol solution 3.0ml of 0.04mg/ml, and lucifuge stands 30min, 12000rpm are centrifuged 10min, mensuration absorbance under 517nm.Calculate DPPH clearance rate.Result shows fementative composition Thing mildy wash has more excellent antioxidation activity.Result is shown in accompanying drawing 10.

Claims (9)

1. a kind of cleaning products composition, it contains tunning 10%～80 weight %, and described tunning is by cereal and people Ginseng shell co-fermentation forms, and wherein cereal and the weight of ginseng shell are than for 70: 30-99: 1, preferably 80: 20-95: 5, more excellent Select 90: 10, described tunning is after cereal and ginseng shell are pulverized, the product obtaining through fermentable, it has The particle diameter of 0.02mm～1mm, preferably 0.05mm～0.4mm, more preferably 0.15mm～0.25mm.

2. composition as claimed in claim 1, described cereal be selected from rice, millet, corn, black rice, Chinese sorghum, in adlay one Plant or several.

3. composition as claimed in claim 1 is it is characterised in that composition is washing cream, mildy wash, face cleaning curry, face cleaning Mu This, bath foam, bath oil, hand cleanser.

4. composition as claimed in claim 1, wherein said tunning passes through the method preparation comprising the steps：

(1) culture medium heat sterilization, foster base is cereal-granules and ginseng shell particle,

(2) access the fermented bacterium having activated, inoculum concentration is 0.1%～20% volume,

(3) ferment, temperature is 25 DEG C～45 DEG C,

(4) adjust pH, scope is 4.0～7.0,

(5) sterilize, sterilising temp is 65 DEG C～120 DEG C, sterilization time is 15min～60min.

5. the tunning as described in claim 4 or 5, wherein said microorganism be selected from saccharomycete, lactobacillus, lactic acid bacteria, One or more of root enzyme bacterium, Aspergillus mix.

6. the tunning as described in claim 4 or 5, in described culture medium, adds nutriment, described nutrition further Material is selected from glucose, lactose, sucrose and/or maltose, preferably glucose.

7. composition as claimed in claim 3, it is emulsion, contains：Oily matter 1%～20 weight %, tunning 10%～80 weight %, emulsifying agent 1%～10 weight %, viscosity modifier 0.01%～5 weight %, pure water 10%～80 weight Amount %.

8. composition as claimed in claim 3, it is curry, and it contains：Tunning 10%～80 weight %, gel 0.01%～1 weight %, pure water 10%～80 weight %.

9. application in preparing Cleasing compositions for the tunning as claimed in claim 1, basic in described Cleasing compositions Do not contain foaming surfactant.