CN106400063A - Wear-resistant type nanocomposite electroplating liquid for photovoltaic backboards - Google Patents
Wear-resistant type nanocomposite electroplating liquid for photovoltaic backboards Download PDFInfo
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- CN106400063A CN106400063A CN201610374997.6A CN201610374997A CN106400063A CN 106400063 A CN106400063 A CN 106400063A CN 201610374997 A CN201610374997 A CN 201610374997A CN 106400063 A CN106400063 A CN 106400063A
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- electroplating liquid
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Abstract
The invention discloses a wear-resistant type nanocomposite electroplating liquid for photovoltaic backboards and relates to the technical field of preparation of photovoltaic materials. The liquid is prepared from raw materials as follows: 6-8 parts of cobalt oxide, 200-300 parts of deionized water, 15-25 parts of a composite activator, 3-5 parts of phosphoric acid, 6-8 parts of cobalt sulfate, 8-10 parts of nickel chloride, 5-7 parts of sodium chloride, 5-7 parts of potassium chloride, 6-8 parts of potassium pyrophosphate, 6-8 parts of sulfuric acid and 2-4 parts of coumarin. The liquid has the beneficial effects as follows: the ratio of the raw materials is reasonable, the prepared electroplating liquid is high in hardness and oxidation resistance, physical and chemical requirements which cannot be met by the photovoltaic materials can be enhanced, the cost is greatly saved for a user, the use effect is obvious, the market value is high, and the liquid is convenient to popularize and use.
Description
Technical field
The present invention relates to photovoltaic material preparing technical field is and in particular to a kind of photovoltaic back wear-resisting type is received
Rice composite plating solution.
Background technology
Solar energy can be directly changed into the material of electric energy by photovoltaic back.Photovoltaic material is also known as solar cell
Material, only semi-conducting material have this function, can do solar cell material material have monocrystalline silicon,
Polysilicon, non-crystalline silicon, GaAs, GaAlAs, InP, CdS, CdTe etc., for space have monocrystalline silicon,
GaAs、InP.There are monocrystalline silicon, polysilicon, non-crystalline silicon for ground batch production, other are still in
Development phase, it is devoted at present reducing material cost and improves conversion efficiency, make the electric power valency of solar cell
Lattice are competed with the power price of thermal power generation, thus creating conditions for more extensive more large-scale application；Photovoltaic
Material when using, in order to ensure that its anti-wear performance all can scribble wearing layer on material sheet material, so guarantor
Demonstrate,prove its corresponding service life, but wearing layer traditional from present's view is all the symbol such as direct brushing paint
Condensation material, the use cost of this material is higher, and useful life is not also permanent simultaneously.
Content of the invention：
The technical problem to be solved is to provide a kind of stable performance, the obvious light of using effect
Volt backboard wear-resisting type nano compound electroplating liquid.
The technical problem to be solved employs the following technical solutions to realize：
A kind of photovoltaic back is with wear-resisting type nano compound electroplating liquid it is characterised in that by following components raw material
It is prepared from：
Cobalt oxide 6-8 part, deionized water 200-300 part, composite reactive agent 15-25 part, phosphoric acid 3-5 part,
Cobaltous sulfate 6-8 part, nickel chloride 8-10 part, sodium chloride 5-7 part, potassium chloride 5-7 part, potassium pyrophosphate 6-8 part,
Sulfuric acid 6-8 part, cumarin 2-4 part.
The preferred deal of each raw material is：
7 parts of cobalt oxide, 250 parts of deionized water, 20 parts of composite reactive agent, phosphatase 24 part, 7 parts of cobaltous sulfate,
9 parts of nickel chloride, 6 parts of sodium chloride, 6 parts of potassium chloride, 7 parts of potassium pyrophosphate, 7 parts of sulfuric acid, 3 parts of cumarin.
Described composite reactive agent by lauryl sodium sulfate with lauryl alcohol, lauroyl monoethanolamine according to
5:1:2 mass ratio compounds and forms, can improve its foaming in electroplate liquid, washing, reduction surface tension,
The performances such as emulsification.
Prepare photovoltaic back of the present invention with the method for wear-resisting type nano compound electroplating liquid it is characterised in that wrapping
Include following steps：
1) nickel chloride in raw material, potassium chloride, sodium chloride, phosphoric acid and water are mixed, stirred
After obtain activating solution, standby；
2) cobalt oxide, cobaltous sulfate and potassium pyrophosphate in raw material are added in ball mill, ball milling one hour, so
Add composite reactive agent to continue ball milling three hours afterwards, be subsequently adding remaining raw material in raw material, continue ball milling
After 1-1.5h, regulation pH is 4-5；
3), after the material in step 1 and step 2 being merged, stir, you can obtain.
The invention has the beneficial effects as follows：Reasonable raw material proportioning of the present invention, the plating liquid energy hardness of configuration, anti-
Oxidation susceptibility is strong, strengthens physics, the requirement of chemistry that photovoltaic material does not reach, is that user greatlys save into
This, substantially, market value is high for using effect, is easy to promote and uses.
Specific embodiment
In order that technological means, creation characteristic, reached purpose and effect that the present invention realizes are readily apparent from
Solution, with reference to specific embodiment, is expanded on further the present invention.
Embodiment 1
Weigh：Cobalt oxide 6kg, deionized water 200kg, composite reactive agent 15kg, phosphoric acid 3kg, cobaltous sulfate
6kg, nickel chloride 8kg, sodium chloride 5kg, potassium chloride 5kg, potassium pyrophosphate 6kg, sulfuric acid 6kg, cumarin
2kg.
Embodiment 2
Weigh：Cobalt oxide 7kg, deionized water 250kg, composite reactive agent 20kg, phosphatase 24 kg, cobaltous sulfate
7kg, nickel chloride 9kg, sodium chloride 6kg, potassium chloride 6kg, potassium pyrophosphate 7kg, sulfuric acid 7kg, cumarin
3kg.
The preparation method of above-described embodiment 1 and 2 is：
1) nickel chloride in raw material, potassium chloride, sodium chloride, phosphoric acid and water are mixed, stirred
After obtain activating solution, standby；
2) cobalt oxide, cobaltous sulfate and potassium pyrophosphate in raw material are added in ball mill, ball milling one hour, so
Add composite reactive agent to continue ball milling three hours afterwards, be subsequently adding remaining raw material in raw material, continue ball milling
After 1-1.5h, regulation pH is 4-5；
3), after the material in step 1 and step 2 being merged, stir, you can obtain.
General principle and principal character and the advantages of the present invention of the present invention have been shown and described above.One's own profession
The technical staff of industry it should be appreciated that the present invention is not restricted to the described embodiments, above-described embodiment and explanation
Merely illustrating the principles of the invention described in book, without departing from the spirit and scope of the present invention,
The present invention also has various changes and modifications, and these changes and improvements both fall within claimed invention model
In enclosing.Claimed scope is by appending claims and its equivalent thereof.
Claims (4)
1. a kind of photovoltaic back with wear-resisting type nano compound electroplating liquid it is characterised in that by with
Lower component raw material is prepared from：
Cobalt oxide 6-8 part, deionized water 200-300 part, composite reactive agent 15-25 part, phosphoric acid
3-5 part, cobaltous sulfate 6-8 part, nickel chloride 8-10 part, sodium chloride 5-7 part, potassium chloride 5-7 part,
Potassium pyrophosphate 6-8 part, sulfuric acid 6-8 part, cumarin 2-4 part.
2. a kind of photovoltaic back according to claim 1 wear-resisting type nano compound electroplating liquid,
It is characterized in that, the preferred deal of each raw material is：7 parts of cobalt oxide, 250 parts of deionized water, multiple
Close 20 parts of activating agent, phosphatase 24 part, 7 parts of cobaltous sulfate, 9 parts of nickel chloride, 6 parts of sodium chloride, chlorination
6 parts of potassium, 7 parts of potassium pyrophosphate, 7 parts of sulfuric acid, 3 parts of cumarin.
3. a kind of photovoltaic back according to claim 1 wear-resisting type nano compound electroplating liquid,
It is characterized in that：Described composite reactive agent by lauryl sodium sulfate with lauryl alcohol, bay
Acyl MEA is according to 5:1:2 mass ratio compounds and forms.
4. photovoltaic back wear-resisting type nano compound electroplating liquid in preparation claim 1 or 2
Method is it is characterised in that comprise the following steps：
1) nickel chloride in raw material, potassium chloride, sodium chloride, phosphoric acid and water are mixed,
Activating solution is obtained after stirring, standby；
2) cobalt oxide, cobaltous sulfate and potassium pyrophosphate in raw material are added in ball mill, ball milling one
Hour, it is subsequently adding composite reactive agent and continues ball milling three hours, be subsequently adding remaining in raw material
Raw material, after continuing ball milling 1-1.5h, regulation pH is 4-5；
3), after the material in step 1 and step 2 being merged, stir, you can obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610374997.6A CN106400063A (en) | 2016-05-26 | 2016-05-26 | Wear-resistant type nanocomposite electroplating liquid for photovoltaic backboards |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610374997.6A CN106400063A (en) | 2016-05-26 | 2016-05-26 | Wear-resistant type nanocomposite electroplating liquid for photovoltaic backboards |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106400063A true CN106400063A (en) | 2017-02-15 |
Family
ID=58005820
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610374997.6A Pending CN106400063A (en) | 2016-05-26 | 2016-05-26 | Wear-resistant type nanocomposite electroplating liquid for photovoltaic backboards |
Country Status (1)
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105018983A (en) * | 2015-06-26 | 2015-11-04 | 安徽西得仪表科技有限公司 | Nanometer composite electroplating type temperature-resistant and wear-resistant thermocouple protection tube and preparation method thereof |
| CN105543912A (en) * | 2016-02-15 | 2016-05-04 | 上海应用技术学院 | Method for preparing compound surfactant/La-Ni-Mo-W codeposited coating on copper matrix |
-
2016
- 2016-05-26 CN CN201610374997.6A patent/CN106400063A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105018983A (en) * | 2015-06-26 | 2015-11-04 | 安徽西得仪表科技有限公司 | Nanometer composite electroplating type temperature-resistant and wear-resistant thermocouple protection tube and preparation method thereof |
| CN105543912A (en) * | 2016-02-15 | 2016-05-04 | 上海应用技术学院 | Method for preparing compound surfactant/La-Ni-Mo-W codeposited coating on copper matrix |
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| C10 | Entry into substantive examination | ||
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170215 |
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| RJ01 | Rejection of invention patent application after publication |