CN106368408A - Manufacturing method of reinforced floorboard with high surface brightness - Google Patents
Manufacturing method of reinforced floorboard with high surface brightness Download PDFInfo
- Publication number
- CN106368408A CN106368408A CN201610781197.6A CN201610781197A CN106368408A CN 106368408 A CN106368408 A CN 106368408A CN 201610781197 A CN201610781197 A CN 201610781197A CN 106368408 A CN106368408 A CN 106368408A
- Authority
- CN
- China
- Prior art keywords
- abrasion
- parts
- manufacture method
- steel plate
- hot pressing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/02—Flooring or floor layers composed of a number of similar elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/24—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/52—Two layers
- B05D7/54—No clear coat specified
- B05D7/544—No clear coat specified the first layer is let to dry at least partially before applying the second layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/08—Impregnating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2203/00—Other substrates
- B05D2203/22—Paper or cardboard
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2451/00—Type of carrier, type of coating (Multilayers)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2506/00—Halogenated polymers
- B05D2506/20—Chlorinated polymers
- B05D2506/25—PVC
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2602/00—Organic fillers
Landscapes
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Floor Finish (AREA)
Abstract
The invention discloses a manufacturing method of a reinforced floorboard with the high surface brightness. The manufacturing method comprises the following steps that a steel plate is treated, specifically, the surface of the steel plate is polished to obtain a chrome-plated steel plate; an abrasion-resisting layer is treated, specifically, abrasion-resisting paper is dipped into abrasion-resisting paper dipping glue, taken out and made 10-40% dried; composite aluminum oxide powder is uniformly poured and sprayed on the surface of the dipped abrasion-resisting paper, and an abrasion-resisting layer is obtained; patterned paper and balance paper are dipped with composite melamine resin; the dipped patterned paper and the abrasion-resisting layer are sequentially laid on a fiberboard; and the dipped balance paper is laid under the fiberboard, hot pressing is conducted through the chrome-plated steel plate, and the reinforced floorboard with the high surface brightness is obtained. The surface brightness of the floorboard manufactured through the manufacturing method can reach up to 100+/-10 degree, and the floorboard is obviously superior to ordinary floorboards. The floorboard is firm, high in corrosion resistance and long in service life, and the brightness is not prone to weakening in the use process.
Description
Technical field
Patent of the present invention is related to a kind of floor, more particularly, to a kind of manufacture method of the consolidated floor of highlight surface degree.
Background technology
Consolidated floor is also referred to as impregnated-paper laminated wood floor/laminated flooring, is to impregnate heat with one or more layers dedicated paper
Solidity amino resins, mat formation on artificial board substrate top layer, the back side adds balance layer, front adds wearing layer, the ground through hot pressing, molding
Plate.Consolidated floor has the advantages that wear-resisting, shock resistance, resistance to deformation, anti-pollution, is extensively made in daily life
With.
But, consolidated floor is surface-treated everybody and habitually simply emphasizes surface abrasion resistance and pattern effect, consumption
Person does not often note the brightness on surface very much.Consolidated floor Producer is also in that the consolidated floor production cost of highlight surface degree
Height, complex manufacturing and be unwilling to set foot in.
A kind of accordingly, it is desirable to provide good stability, and the consolidated floor of highlight surface degree.
Content of the invention
It is an object of the invention to provide a kind of manufacture method of highlight surface degree consolidated floor, improve the surface light on floor
Degree, the abrasion resistance increasing floor and anti-corrosive properties, corrosion protection.
The technical scheme that the present invention provides:
A kind of manufacture method of the consolidated floor of highlight surface degree, comprises the following steps:
Steel plate is processed: surface steel sheet is polished, obtains chromium plating steel plate；
Wearing layer is processed: by abrasion-proof paper immersion abrasion-proof paper dipping glue, takes out natural air drying 10～20 minutes；Three oxygen will be combined
Change the abrasion-proof paper surface after two aluminium powders are uniformly sprayed onto dipping from lower to upper, obtain wearing layer；
Hot-pressing processing: with compound melmac, pattern layer and balance layer are impregnated respectively；With chromium plating steel plate to from upper
The wearing layer, pattern layer, substrate layer and the balance layer that are down sequentially overlapped carry out hot pressing, obtain the strengthening of described highlight surface degree
Floor.
Preferably, described fall spray angle be to be 30～60 degree with the angle of vertical direction.Applicant's research finds, sprays
Angle when being 30～60 degree, spraying the parabola that compound aluminium sesquioxide formed can make material uniformly be sprayed to abrasion-proof paper
On, be conducive to attachment and the distribution of compound aluminium sesquioxide, reduce the waste of material, and make wear-resisting layer surface more smooth, equal
Even.
Preferably, described fall spray angle be to be 45 degree with the angle of vertical direction.When the angle of spray is and Vertical Square
To when differing 45 degree, compound aluminium sesquioxide can farthest be attached on abrasion-proof paper, reduces the waste of material.
Preferably, described abrasion-proof paper dipping glue includes, by weight, 45～75 parts of polrvinyl chloride three type resin；Dichloro
7～12 parts of benzophenone, 8～25 parts of melamine, 20～30 parts of fatty acid alkyd resin, 4～7 parts of butyl acetate.
Preferably, described abrasion-proof paper and abrasion-proof paper impregnate the weight of glue ratio for 1:1～3.
Preferably, described compound aluminium sesquioxide powder includes: by weight, 70～80 parts of aluminium sesquioxide, carbonization
10～30 parts of silicon, 0～30 part of silica 1,5～10 parts of calcium oxide.
Preferably, described aluminium sesquioxide, carborundum, silicon dioxide, the grain diameter of calcium oxide are 3000～12000
Mesh.
Preferably, the thickness of described wearing layer is 0.02～0.2mm.
Preferably, described steel polishing includes mechanical polishing and chemical polishing, and described chemical polishing is in electrolyte plating
Layers of chrome, wherein voltage are 1000～1600 volts, and the time is 3～4 hours.In traditional chemical polishing, the intensity of voltage is 800
～1000 volts, the time is 1～2 hour；And the present invention, in the process of chemical polishing, increases alive intensity and extends plating
Time, can effectively increase sophistication and the smoothness of electrodeposited chromium layers, make the floor surface of steel plate hot pressing brighter, smooth.
The wearability of coating can also be increased simultaneously and increase the service life, reduce the number of times of chromium plating repeatedly, cost-effective and time.
Preferably, described hot pressing includes two step hot pressing, and hot pressing patch temperature is 180～220 DEG C, and pressure is 20～22mpa,
The time of first time hot pressing veneer is 2～6 seconds, and the time of second hot pressing veneer is 28～36 seconds.
Beneficial effects of the present invention:
The present invention is processed to steel plate, and steel plate is mechanically polished, and improves surface of steel plate flatness, carries out at chemical polishing
Reason, chromium coating, not only improves the flatness of surface of steel plate further, carries out hot pressing to floor, ensured the smooth of floor surface
Degree and brightness.
The anti-wear performance of abrasion-proof paper depends primarily on content and the dispersion of aluminium sesquioxide, three oxidation two in abrasion-proof paper
The content of aluminum is higher, disperse more uniform then wearability better, but traditional aluminium sesquioxide is using dipping or from top to down
Sprinkling, so that aluminium sesquioxide is sprayed uneven, lead to floor surface out-of-flatness, second easily cause aluminium sesquioxide
Gathering and impregnation liquid alluvial, cause the out-of-flatness on surface.The present invention is avoided using the spray technique that falls of aluminium sesquioxide
State problem, not only contribute to the attachment of aluminium sesquioxide, and the larger aluminium sesquioxide of granule can be fallen due to the effect of gravity
Under, it is to avoid it is rough that wearing layer surface particles size inequality causes, and improves the brightness on floor.Ensured wearing layer simultaneously
Adhesion amount and the uniformity, it is to avoid wearing layer is uneven cause rough, have a concavo-convex phenomenon, easily dipping, leaching are dirty
Problem.The present invention improves antiseptic property and the anti-corrosion performance on floor, extends the service life on floor.Additionally, the present invention
Fall spray technique from fall the angle of spray, drying time, raw material consumption considered and optimized, further ensured the product on floor
Matter, moreover it is possible to the use that economizes in raw materials, is easier to control quality and the quality on floor during producing.
The present invention, using the formula of compound aluminium sesquioxide, can not only increase the fineness on surface, and can also improve ground
The Corrosion Protection of plate surface, increases the wearability of floor surface, improves the using effect on floor.Wherein, aluminium sesquioxide with
Carborundum, silicon dioxide form the framing structure of glass under conditions of high temperature, and calcium oxide mentions the effect fluxed, on floor
Glass layer formed on surface, not only contributes to improve the glossiness on floor, increases surface strength, improve impact resistance and load-bearing energy
Power.
The abrasion-proof paper dipping glue that the present invention uses has very high glue-joint strength, and heat stability is high, and low-temperature setting ability is relatively
By force, hardness is high, excellent in abrasion resistance.Meanwhile, abrasion-proof paper impregnates color and the gloss that glue also protects floor, and curing rate is fast, carries
The physical and mechanical property on high strengthening floor, improves presentation quality, makes floor have the performances such as wear-resisting, resistance to deformation and anti-pollution.
The brightness of the floor surface that the present invention makes reaches 100 degree ± 10 degree hence it is evident that being better than common floor.The present invention's
Floor is firm, have higher antiseptic property and anti-corrosion performance, and service life is longer, and brightness is difficult to subtract in use
Weak.
Specific embodiment
Embodiment 1
A kind of manufacture method of the consolidated floor of highlight surface degree, comprises the following steps:
Steel plate is processed: surface mechanical polishing is carried out to steel plate, and chromium coating chemical polishing, obtain chromium plating steel plate；Described chemistry is thrown
Light is in electrolyte chromium coating, and wherein voltage is 1000 volts, and the time is 4 hours.
Wearing layer is processed: by abrasion-proof paper immersion abrasion-proof paper dipping glue, wherein abrasion-proof paper and abrasion-proof paper impregnate the weight of glue
For 1:1, the composition that described abrasion-proof paper impregnates glue includes ratio, by weight, 45 parts of polrvinyl chloride three type resin；Dichloro first
7 parts of ketone, 8 parts of melamine, 20 parts of fatty acid alkyd resin, 4 parts of butyl acetate.Abrasion-proof paper after dipping is taken out to be dried and does to 1 one-tenth；
Compound aluminium sesquioxide powder is uniformly sprayed onto the abrasion-proof paper surface after dipping, obtains wearing layer；Described fall spray angle be
Angle with vertical direction is 30 degree, and the composition of described compound aluminium sesquioxide powder includes: by weight, aluminium sesquioxide
70 parts, 10 parts of carborundum, 0 part of silica 1,5 parts of calcium oxide；Described aluminium sesquioxide, carborundum, silicon dioxide, calcium oxide
Grain diameter be 3000 mesh；The thickness of the wearing layer obtaining is 0.02mm.
Hot-pressing processing: with compound melmac, color paper and balance paper are impregnated respectively；With chromium plating steel plate pair
The wearing layer, pattern layer, substrate layer and the balance layer that are sequentially overlapped from top to bottom carry out hot pressing, obtain described highlight surface degree
Consolidated floor.Wherein, described hot pressing includes two step hot pressing, and hot pressing patch temperature is 180 DEG C, and pressure is 20mpa, first time hot pressing
The time of veneer is 2 seconds, and the time of second hot pressing veneer is 28 seconds.
Embodiment 2
A kind of manufacture method of the consolidated floor of highlight surface degree, comprises the following steps:
Steel plate is processed: surface mechanical polishing is carried out to steel plate, and chromium coating chemical polishing, obtain chromium plating steel plate；Described chemistry is thrown
Light is in electrolyte chromium coating, and wherein voltage is 1600 volts, and the time is 3 hours.
Wearing layer is processed: by abrasion-proof paper immersion abrasion-proof paper dipping glue, wherein abrasion-proof paper and abrasion-proof paper impregnate the weight of glue
For 1:2, the composition that described abrasion-proof paper impregnates glue includes ratio, by weight, 75 parts of polrvinyl chloride three type resin；Dichloro
12 parts of ketone, 25 parts of melamine, 30 parts of fatty acid alkyd resin, 7 parts of butyl acetate.Abrasion-proof paper after dipping is taken out and is dried to 4
Cheng Gan；Compound aluminium sesquioxide powder is uniformly sprayed onto the abrasion-proof paper surface after dipping, obtains wearing layer；The angle of described spray
Degree is to be 60 degree with the angle of vertical direction, and the composition of described compound aluminium sesquioxide powder includes: by weight, three oxidations
Two 80 parts of aluminum, 30 parts of carborundum, 30 parts of silicon dioxide, 10 parts of calcium oxide；Described aluminium sesquioxide, carborundum, silicon dioxide, oxygen
The grain diameter changing calcium is 12000 mesh；The thickness of the wearing layer obtaining is 0.2mm.
Hot-pressing processing: with compound melmac, color paper and balance paper are impregnated respectively；With chromium plating steel plate pair
The wearing layer, pattern layer, substrate layer and the balance layer that are sequentially overlapped from top to bottom carry out hot pressing, obtain described highlight surface degree
Consolidated floor.Wherein, described hot pressing includes two step hot pressing, and hot pressing patch temperature is 220 DEG C, and pressure is 22mpa, first time hot pressing
The time of veneer is 6 seconds, and the time of second hot pressing veneer is 36 seconds.
Embodiment 3
A kind of manufacture method of the consolidated floor of highlight surface degree, comprises the following steps:
Steel plate is processed: surface mechanical polishing is carried out to steel plate, and chromium coating chemical polishing, obtain chromium plating steel plate；Described chemistry is thrown
Light is in electrolyte chromium coating, and wherein voltage is 1400 volts, and the time is 4 hours.
Wearing layer is processed: by abrasion-proof paper immersion abrasion-proof paper dipping glue, wherein abrasion-proof paper and abrasion-proof paper impregnate the weight of glue
Than for 1:3；The composition that described abrasion-proof paper impregnates glue includes, by weight, 56 parts of polrvinyl chloride three type resin；Dichloro first
10 parts of ketone, 17 parts of melamine, 24 parts of fatty acid alkyd resin, 6 parts of butyl acetate.Abrasion-proof paper after dipping is taken out and is dried to 3 one-tenth
Dry；Compound aluminium sesquioxide powder is uniformly sprayed onto the abrasion-proof paper surface after dipping, obtains wearing layer；The angle of described spray
It is to be 45 degree with the angle of vertical direction, the composition of described compound aluminium sesquioxide powder includes: by weight, three oxidations two
75 parts of aluminum, 28 parts of carborundum, 27 parts of silicon dioxide, 7 parts of calcium oxide；Described aluminium sesquioxide, carborundum, silicon dioxide, oxidation
The grain diameter of calcium is 10000 mesh；The thickness of the wearing layer obtaining is 0.1 mm.
Hot-pressing processing: with compound melmac, color paper and balance paper are impregnated respectively；With chromium plating steel plate pair
The wearing layer, pattern layer, substrate layer and the balance layer that are sequentially overlapped from top to bottom carry out hot pressing, obtain described highlight surface degree
Consolidated floor.Wherein, described hot pressing includes two step hot pressing, and hot pressing patch temperature is 190 DEG C, and pressure is 21mpa, first time hot pressing
The time of veneer is 5 seconds, and the time of second hot pressing veneer is 27 seconds.
It should be noted that above-described embodiment illustrates rather than to patent of the present invention limiting to patent of the present invention
System, and those skilled in the art can design alternative embodiment without departing from the scope of the appended claims.?
In claim, any reference markss between bracket should not be configured to limitations on claims.Word "comprising"
Do not exclude the presence of element not listed in the claims or step.Word "a" or "an" before element is not excluded for depositing
In multiple such elements.The use of word first, second, and third does not indicate that any order.Can be by these word solutions
It is interpreted as title.
Claims (10)
1. a kind of manufacture method of the consolidated floor of highlight surface degree is it is characterised in that comprise the following steps:
Steel plate is processed: surface of steel plate is polished, obtains chromium plating steel plate；
Wearing layer is processed: by abrasion-proof paper immersion abrasion-proof paper dipping glue, takes out natural air drying 10～20 minutes；Three oxygen will be combined
Change the abrasion-proof paper surface after two aluminium powders are uniformly sprayed onto dipping from lower to upper, obtain wearing layer；
Hot-pressing processing: with compound melmac, pattern layer and balance layer are impregnated respectively；With chromium plating steel plate to from upper
The wearing layer, pattern layer, substrate layer and the balance layer that are down sequentially overlapped carry out hot pressing, obtain the strengthening of described highlight surface degree
Floor.
2. a kind of consolidated floor of highlight surface degree according to claim 1 manufacture method it is characterised in that described fall
The angle of spray is to be 30～60 degree with the angle of vertical direction.
3. a kind of consolidated floor of highlight surface degree according to claim 1 manufacture method it is characterised in that described fall
The angle of spray is to be 45 degree with the angle of vertical direction.
4. a kind of manufacture method of the consolidated floor of highlight surface degree according to claim 1 is it is characterised in that described
Abrasion-proof paper dipping glue includes, by weight, 45～75 parts of polrvinyl chloride three type resin；7～12 parts of dichloro benzophenone, melamine 8
～25 parts, 20～30 parts of fatty acid alkyd resin, 4～7 parts of butyl acetate.
5. a kind of manufacture method of the consolidated floor of highlight surface degree according to claim 1 is it is characterised in that described resistance to
Mill paper and abrasion-proof paper impregnate the weight ratio of glue for 1:1～3.
6. a kind of manufacture method of the consolidated floor of highlight surface degree according to claim 1 is it is characterised in that described
Compound aluminium sesquioxide powder includes: by weight, 70～80 parts of aluminium sesquioxide, 10～30 parts of carborundum, silica 10
～30 parts, 5～10 parts of calcium oxide.
7. a kind of manufacture method of the consolidated floor of highlight surface degree according to claim 6 is it is characterised in that described three
Al 2 O, carborundum, silicon dioxide, the grain diameter of calcium oxide are 3000～12000 mesh.
8. a kind of manufacture method of the consolidated floor of highlight surface degree according to claim 1 is it is characterised in that described resistance to
The thickness of mill layer is 0.02～0.2mm.
9. a kind of manufacture method of the consolidated floor of highlight surface degree according to claim 1 is it is characterised in that described
Steel polishing includes mechanical polishing and chemical polishing, and described chemical polishing is in electrolyte chromium coating, wherein voltage for 1000～
1600 volts, the time is 3～4 hours.
10. a kind of manufacture method of the consolidated floor of highlight surface degree according to claim 1 is it is characterised in that described
Hot pressing include two step hot pressing, hot pressing patch temperature is 180～220 DEG C, and pressure is 20～22mpa, first time hot pressing veneer when
Between be 2～6 seconds, time of second hot pressing veneer is 28～36 seconds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610781197.6A CN106368408A (en) | 2016-08-31 | 2016-08-31 | Manufacturing method of reinforced floorboard with high surface brightness |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610781197.6A CN106368408A (en) | 2016-08-31 | 2016-08-31 | Manufacturing method of reinforced floorboard with high surface brightness |
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| Publication Number | Publication Date |
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| CN106368408A true CN106368408A (en) | 2017-02-01 |
Family
ID=57898678
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| CN201610781197.6A Pending CN106368408A (en) | 2016-08-31 | 2016-08-31 | Manufacturing method of reinforced floorboard with high surface brightness |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108249799A (en) * | 2017-12-29 | 2018-07-06 | 中冶建筑研究总院有限公司 | A kind of concrete corrosion-resistant preservative and its application |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108249799A (en) * | 2017-12-29 | 2018-07-06 | 中冶建筑研究总院有限公司 | A kind of concrete corrosion-resistant preservative and its application |
| CN108249799B (en) * | 2017-12-29 | 2021-06-15 | 中冶建筑研究总院有限公司 | Concrete corrosion-resistant preservative and application thereof |
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