CN106342872A - Composition containing mefenoxam, azoxystrobin and clothianidin, seed coating agent and application - Google Patents
Composition containing mefenoxam, azoxystrobin and clothianidin, seed coating agent and application Download PDFInfo
- Publication number
- CN106342872A CN106342872A CN201610767131.1A CN201610767131A CN106342872A CN 106342872 A CN106342872 A CN 106342872A CN 201610767131 A CN201610767131 A CN 201610767131A CN 106342872 A CN106342872 A CN 106342872A
- Authority
- CN
- China
- Prior art keywords
- metalaxyl
- clothianidin
- fluoxastrobin
- seed coat
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- ZQEIXNIJLIKNTD-GFCCVEGCSA-N metalaxyl-M Chemical compound COCC(=O)N([C@H](C)C(=O)OC)C1=C(C)C=CC=C1C ZQEIXNIJLIKNTD-GFCCVEGCSA-N 0.000 title claims abstract description 75
- PGOOBECODWQEAB-UHFFFAOYSA-N (E)-clothianidin Chemical compound [O-][N+](=O)\N=C(/NC)NCC1=CN=C(Cl)S1 PGOOBECODWQEAB-UHFFFAOYSA-N 0.000 title claims abstract description 66
- 239000005888 Clothianidin Substances 0.000 title claims abstract description 66
- 239000000203 mixture Substances 0.000 title claims abstract description 24
- 239000011248 coating agent Substances 0.000 title claims abstract description 14
- 239000005730 Azoxystrobin Substances 0.000 title abstract description 5
- WFDXOXNFNRHQEC-GHRIWEEISA-N azoxystrobin Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1OC1=CC(OC=2C(=CC=CC=2)C#N)=NC=N1 WFDXOXNFNRHQEC-GHRIWEEISA-N 0.000 title abstract 3
- 201000010099 disease Diseases 0.000 claims abstract description 27
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims abstract description 27
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 8
- 244000061456 Solanum tuberosum Species 0.000 claims abstract description 6
- 235000002595 Solanum tuberosum Nutrition 0.000 claims abstract description 6
- 235000012015 potatoes Nutrition 0.000 claims abstract description 4
- 239000005808 Metalaxyl-M Substances 0.000 claims description 72
- 239000005784 Fluoxastrobin Substances 0.000 claims description 64
- UFEODZBUAFNAEU-NLRVBDNBSA-N fluoxastrobin Chemical compound C=1C=CC=C(OC=2C(=C(OC=3C(=CC=CC=3)Cl)N=CN=2)F)C=1C(=N/OC)\C1=NOCCO1 UFEODZBUAFNAEU-NLRVBDNBSA-N 0.000 claims description 63
- 239000003795 chemical substances by application Substances 0.000 claims description 44
- 239000002270 dispersing agent Substances 0.000 claims description 16
- 210000000582 semen Anatomy 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 238000002360 preparation method Methods 0.000 claims description 13
- 239000000945 filler Substances 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 11
- 239000000725 suspension Substances 0.000 claims description 11
- 239000000080 wetting agent Substances 0.000 claims description 11
- 230000000844 anti-bacterial effect Effects 0.000 claims description 10
- 239000008187 granular material Substances 0.000 claims description 10
- 239000002552 dosage form Substances 0.000 claims description 9
- 239000013530 defoamer Substances 0.000 claims description 7
- 241000894006 Bacteria Species 0.000 claims description 6
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- 241000238631 Hexapoda Species 0.000 claims description 5
- 239000002562 thickening agent Substances 0.000 claims description 5
- 230000000361 pesticidal effect Effects 0.000 claims description 4
- 238000009331 sowing Methods 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 3
- 239000004615 ingredient Substances 0.000 claims description 3
- 229930192474 thiophene Natural products 0.000 claims description 3
- 239000000375 suspending agent Substances 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 17
- 230000002265 prevention Effects 0.000 abstract description 13
- 244000105624 Arachis hypogaea Species 0.000 abstract description 7
- 240000008042 Zea mays Species 0.000 abstract description 7
- 235000002017 Zea mays subsp mays Nutrition 0.000 abstract description 7
- 235000020232 peanut Nutrition 0.000 abstract description 7
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 abstract description 4
- 235000005822 corn Nutrition 0.000 abstract description 4
- 238000002474 experimental method Methods 0.000 abstract description 2
- 208000003643 Callosities Diseases 0.000 abstract 1
- 206010020649 Hyperkeratosis Diseases 0.000 abstract 1
- 241000209140 Triticum Species 0.000 abstract 1
- 235000021307 Triticum Nutrition 0.000 abstract 1
- 238000000034 method Methods 0.000 description 29
- -1 2- Methoxyacetyl Chemical group 0.000 description 15
- 239000003814 drug Substances 0.000 description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
- 239000012467 final product Substances 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- 241000196324 Embryophyta Species 0.000 description 9
- 238000011835 investigation Methods 0.000 description 9
- 206010039509 Scab Diseases 0.000 description 8
- 235000013399 edible fruits Nutrition 0.000 description 8
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Natural products O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 8
- 239000004576 sand Substances 0.000 description 8
- 230000003449 preventive effect Effects 0.000 description 7
- 235000017060 Arachis glabrata Nutrition 0.000 description 6
- 235000010777 Arachis hypogaea Nutrition 0.000 description 6
- 235000018262 Arachis monticola Nutrition 0.000 description 6
- 235000013339 cereals Nutrition 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- 230000006378 damage Effects 0.000 description 4
- 238000004898 kneading Methods 0.000 description 4
- 230000003902 lesion Effects 0.000 description 4
- 238000003801 milling Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000012216 screening Methods 0.000 description 4
- 230000007226 seed germination Effects 0.000 description 4
- 230000001988 toxicity Effects 0.000 description 4
- 231100000419 toxicity Toxicity 0.000 description 4
- UHPMCKVQTMMPCG-UHFFFAOYSA-N 5,8-dihydroxy-2-methoxy-6-methyl-7-(2-oxopropyl)naphthalene-1,4-dione Chemical compound CC1=C(CC(C)=O)C(O)=C2C(=O)C(OC)=CC(=O)C2=C1O UHPMCKVQTMMPCG-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 241000223218 Fusarium Species 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 3
- 238000000205 computational method Methods 0.000 description 3
- 239000007859 condensation product Substances 0.000 description 3
- 230000000857 drug effect Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 230000000749 insecticidal effect Effects 0.000 description 3
- 235000009973 maize Nutrition 0.000 description 3
- 239000000575 pesticide Substances 0.000 description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 238000005070 sampling Methods 0.000 description 3
- 230000009885 systemic effect Effects 0.000 description 3
- ZFNYKZIQYSIJMK-UHFFFAOYSA-N C(#N)C1=CC=CC=C1.[O] Chemical compound C(#N)C1=CC=CC=C1.[O] ZFNYKZIQYSIJMK-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- 239000005807 Metalaxyl Substances 0.000 description 2
- 206010067482 No adverse event Diseases 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 2
- 235000011130 ammonium sulphate Nutrition 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical group O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 235000013877 carbamide Nutrition 0.000 description 2
- 210000002615 epidermis Anatomy 0.000 description 2
- 238000013401 experimental design Methods 0.000 description 2
- 230000000855 fungicidal effect Effects 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- 230000035784 germination Effects 0.000 description 2
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 2
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- ZQEIXNIJLIKNTD-UHFFFAOYSA-N methyl N-(2,6-dimethylphenyl)-N-(methoxyacetyl)alaninate Chemical compound COCC(=O)N(C(C)C(=O)OC)C1=C(C)C=CC=C1C ZQEIXNIJLIKNTD-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000017074 necrotic cell death Effects 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229920002401 polyacrylamide Polymers 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229940068984 polyvinyl alcohol Drugs 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 239000000230 xanthan gum Substances 0.000 description 2
- 235000010493 xanthan gum Nutrition 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- 229940082509 xanthan gum Drugs 0.000 description 2
- SAJGCUXAHBJVRH-VFQQELCFSA-N (2r,3r,4r,5s)-hexane-1,2,3,4,5,6-hexol;hydrate Chemical compound O.OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO SAJGCUXAHBJVRH-VFQQELCFSA-N 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- MTXSIJUGVMTTMU-JTQLQIEISA-N (S)-anabasine Chemical compound N1CCCC[C@H]1C1=CC=CN=C1 MTXSIJUGVMTTMU-JTQLQIEISA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- KLEYVGWAORGTIT-UHFFFAOYSA-N 2-chlorothiazole Chemical class ClC1=NC=CS1 KLEYVGWAORGTIT-UHFFFAOYSA-N 0.000 description 1
- YYYARFHFWYKNLF-UHFFFAOYSA-N 4-[(2,4-dimethylphenyl)diazenyl]-3-hydroxynaphthalene-2,7-disulfonic acid Chemical compound CC1=CC(C)=CC=C1N=NC1=C(O)C(S(O)(=O)=O)=CC2=CC(S(O)(=O)=O)=CC=C12 YYYARFHFWYKNLF-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000272525 Anas platyrhynchos Species 0.000 description 1
- KXDAEFPNCMNJSK-UHFFFAOYSA-N Benzamide Chemical compound NC(=O)C1=CC=CC=C1 KXDAEFPNCMNJSK-UHFFFAOYSA-N 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- RZXLPPRPEOUENN-UHFFFAOYSA-N Chlorfenson Chemical compound C1=CC(Cl)=CC=C1OS(=O)(=O)C1=CC=C(Cl)C=C1 RZXLPPRPEOUENN-UHFFFAOYSA-N 0.000 description 1
- 241001272567 Hominoidea Species 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 208000031888 Mycoses Diseases 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 241000233679 Peronosporaceae Species 0.000 description 1
- 241000233614 Phytophthora Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 241000195474 Sargassum Species 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical group [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 239000004141 Sodium laurylsulphate Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 241001544321 Thanatephorus cucumeris Species 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 235000009392 Vitis Nutrition 0.000 description 1
- 241000219095 Vitis Species 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- ZRXADTFMGYNRKV-UHFFFAOYSA-N [S].C1=CC=CC2=CC=CC=C21 Chemical compound [S].C1=CC=CC2=CC=CC=C21 ZRXADTFMGYNRKV-UHFFFAOYSA-N 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000001785 acacia senegal l. willd gum Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 1
- 229930014345 anabasine Natural products 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 235000012216 bentonite Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 1
- 235000012730 carminic acid Nutrition 0.000 description 1
- 235000019994 cava Nutrition 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 238000005213 imbibition Methods 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000010977 jade Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical group O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 230000002147 killing effect Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 229940100486 rice starch Drugs 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01C—PLANTING; SOWING; FERTILISING
- A01C1/00—Apparatus, or methods of use thereof, for testing or treating seed, roots, or the like, prior to sowing or planting
- A01C1/06—Coating or dressing seed
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01C—PLANTING; SOWING; FERTILISING
- A01C1/00—Apparatus, or methods of use thereof, for testing or treating seed, roots, or the like, prior to sowing or planting
- A01C1/08—Immunising seed
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/46—N-acyl derivatives
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Environmental Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Agronomy & Crop Science (AREA)
- Soil Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a composition containing mefenoxam, azoxystrobin and clothianidin and a seed coating agent. The mass ratio of mefenoxam to azoxystrobin to clothianidin (effective components) is (1-20):(1-20):(1-40). An experiment proves that the seed coating agent can effectively improve the rate of emergence of seeds and has a good prevention effect in such crops as peanuts, corns, wheat and potatoes against pests and diseases.
Description
Technical field
The present invention relates to technical field of pesticide combination and in particular to a kind of containing Metalaxyl-M and Fluoxastrobin and clothianidin
Compositionss and seed coat agent.
Background technology
Seed coat agent be a kind of for crop seed process, there are the pesticidal preparations of film forming characteristicss, it can be in the surface of the seed
The film containing referred to as kind of the clothing of pesticide active ingredient for the solidification.Seed coat agent in soil imbibition but be not dissolved, do not affect plant
The required moisture of the normal germination of son and air pass through, and contained pesticide efficacy composition can slowly discharge, and protects seed not by ground
Lower insect and the injury of various pathogenic bacteria, have preventing and treating sprout term disease and insect pest, improve percentage of seedgermination, promote crops seedling stage to be good for
The effects such as Kang Shengchang.
Metalaxyl-M, Chinese nickname: n- (2- Methoxyacetyl)-n- (2,6- xylyl)-d- methyl lactamine;n-
(2,6- xylyl)-n- (Methoxyacetyl)-d- alanine methyl ester.Belong to the wide spectrum systemic fungicide of phenylamide.Medicine
Thing mainly passes through with, stem, and leaf absorbs, and can make cauline leaf process, seed treatment and soil treatment, to downy mildew, phytophthora, rotten mould
The crop pest that bacterium etc. causes has significant prevention effect.
Fluoxastrobin, Chinese nickname: (e)-[2- [6- (2- cyano-benzene oxygen) pyrimidine-4-yl oxygen] phenyl] -3- methoxy propyl
E pioic acid methyl ester;Amici reaches;(e) -2- { 2- [6 (2- cyano-benzene oxygen) pyrimidine-4-yl oxygen] phenyl } -3- methoxy acrylic acid first
Ester.It is new and effective, wide spectrum, systemic fungicide. can be used for stem and leaf spraying, seed treatment, also can carry out scholar's earth process.To many
Kind of fungal disease all has good activity, and with have antibacterial no interactions resistance at present.For corn, Oryza sativa L., Fructus Vitis viniferae, Ma Ling
Potato, vegetable, fruit tree and other crop, to these crop safeties.
Clothianidin, Chinese nickname: (e) -1- (2- chloro- 1,3-thiazoles -5- ylmethyl) -3- methyl -2- nitroguanidine;1-(2-
Chloro- 5- benzothiazolylmethyl) -3- methyl -2- nitroguanidine;Clothianadin.It is one of anabasine insecticide, highly effective and safe, choosing
Selecting property is high, has and tags, stomach toxicity and systemic activity.
Content of the invention
It is an object of the present invention to provide a kind of compositionss containing Metalaxyl-M and Fluoxastrobin and clothianidin, there is bactericidal effect
Have insecticidal effect simultaneously concurrently, improve percentage of seedgermination, cover crop is not endangered by pest and disease damage, its active component Metalaxyl-M and phonetic
The mass ratio of bacterium ester and clothianidin is 1-20:1-20:1-40.
Further, in the composition, Metalaxyl-M, the mass ratio of Fluoxastrobin is 1:10-10:1, Metalaxyl-M and
The quality of Fluoxastrobin and the mass ratio with clothianidin are 1:1-1:20.
It is a further object of the present invention to provide a kind of seed coat agent containing Metalaxyl-M and Fluoxastrobin and clothianidin, for planting
Attached bag clothing uses, and has bactericidal effect and has insecticidal effect simultaneously concurrently, improve percentage of seedgermination, cover crop is not endangered by pest and disease damage
Evil.For realizing the object of the invention, the present invention adopts the following technical scheme that
A kind of seed coat agent containing Metalaxyl-M and Fluoxastrobin and clothianidin it is characterised in that: effective ingredient be Metalaxyl-M, phonetic
Bacterium ester, clothianidin, effective ingredient Metalaxyl-M, Fluoxastrobin, the mass ratio of clothianidin is respectively 1-20:1-20:1-40.
Further technical scheme is: has the Metalaxyl-M of bactericidal activity, the mass ratio of Fluoxastrobin is 1:10-10:
1, there is the Metalaxyl-M of bactericidal activity, Fluoxastrobin is 1:1-1:20 with the clothianidin mass ratio with insecticidal activity.
The pesticidal preparations dosage form that described seed coat agent can be configured to is suspension seed-coating agent, and seed treatment dispersibles powder,
Seed treatment dispersibles granule.
When described seed coat agent dosage form is suspending agent seed coat agent, in preparation, the mass ratio shared by each composition is Metalaxyl-M 1-
20%, Fluoxastrobin 1-20%, clothianidin 1%-40%, auxiliary element is: dispersant 1-5%, antifreezing agent 1-5%, film former 0.1-5%, increases
Thick dose of 1-5%, defoamer 0.1-2%, warning coloration 1-5%, water supplies 100%.Concrete procedure of processing is: joins above-mentioned by above-mentioned formula
In side, each component is sufficiently mixed, through telling shear-mixed uniformly, sand milling 2-3 hour in sand mill, make particle diameter 5 microns with
Under, obtain final product suspension seed-coating agent.
When described seed coat agent dosage form is to dispersible powder, in preparation, the mass ratio shared by each composition is Metalaxyl-M 1-
20%, Fluoxastrobin 1-20%, clothianidin 1%-40%, auxiliary element is: dispersant 2-8%, wetting agent 1-6%, film former 1-10%, alert
Guard against color 1-5%, filler supplies 100%.Concrete procedure of processing is: by above-mentioned formula by each component mixing in above-mentioned formula, mixed
Close stirrer for mixing to stir, pulverized through jet mill, the seed treatment obtaining final product the present invention after mix homogeneously can
Dispersion powder.
When described seed coat agent dosage form is to dispersible granule, in preparation, the mass ratio shared by each composition is Metalaxyl-M 1-
20%, Fluoxastrobin 1-20%, clothianidin 1%-40%, auxiliary element is: dispersant 1-6%, wetting agent 2-6%, disintegrating agent 1-10%, becomes
Membrane 1-5%, warning coloration 1-5%, filler supplies 100%.Concrete procedure of processing is: mixes all above-mentioned each component by above-mentioned formula
Even, carry out mix homogeneously after comminution by gas stream, be subsequently adding fluidized bed pelletizer pelletize, or carry out extruder grain after the kneading that adds water,
It is dried, through sample analysis after screening, the seed treatment obtaining final product the present invention dispersibles granule.
Described dispersant is selected from lignosulfonates, naphthalene sulfonate, polycarboxylate, Ketohexamethylene formaldehyde condensation products, naphthalene sulphur
Hydrochlorate formaldehyde condensation products, aliphatic amine polyoxyethylene ether, aliphatic acid polyethenoxy ether, aliphatic alcohol polyoxyethylene sulfonate, alkyl
Phenol polyethenoxy ether sulfonate, alkylphenol polyoxyethylene phosphate, APES formaldehyde condensation products sulfat, lose
At least one in water sorbitol polyoxyethylene ether.
Described wetting agent is selected from sodium lauryl sulphate, calcium dodecyl benzene sulfonate, pull open powder, wetting and penetrating agent t, tea soap
Element, fatty alcohol-polyoxyethylene ether, at least one in alkylnaphthalene sulfonate etc..
Described disintegrating agent is selected from bentonite, carbamide, ammonium sulfate, sodium sulfate, at least one in sodium carbonate.
Described thickening agent is selected from xanthan gum, aluminium-magnesium silicate, hydroxymethyl cellulose, hydroxypropyl cellulose, polyvinyl alcohol, Sargassum
Sour sodium, arabic gum, Polyethylene Glycol, Polyvinylpyrrolidone, polyacrylamide, at least one in sodium polyacrylate etc..
Described film former selects xanthan gum, hydroxymethyl cellulose, polyvinyl alcohol, sodium alginate, polyvinyl alcohol, Arab
Glue, polyacrylamide, Polyethylene Glycol, polyvinyl acetate, at least one in starch etc..
Described antifreezing agent be selected from ethylene glycol, propylene glycol, glycerol, carbamide, ammonium sulfate, sodium sulfate, in sodium chloride at least
A kind of.
Described defoamer is selected from silicone defoamer, aliphatic alcohols compound, at least in fatty acid compound
Kind.
Described filler is selected from Kaolin, precipitated calcium carbonate, kieselguhr, bentonite, attapulgite, potter's clay, white carbon, jade
At least one in rice starch.
Described warning coloration is selected from rose violet, rose-red, pinkish red, carmine, at least one in the color such as acid scarlet.
The present invention to Metalaxyl-M, furtherd investigate by Fluoxastrobin and clothianidin, finds Metalaxyl-M, Fluoxastrobin and thiophene worm
Amine carries out compounded combination and has obvious potentiation, not only can prevent and treat kind of a biography, soil-borne disease, and can prevent and treat underground evil simultaneously
Worm, improves germination percentage.The seed coat agent that the present invention provides, uses for seed pelleting, has bactericidal effect and has parasite killing effect simultaneously concurrently
Really, improve percentage of seedgermination, cover crop is not endangered by pest and disease damage.
The seed coat agent containing Metalaxyl-M and Fluoxastrobin and clothianidin of the present invention can be used for Semen arachidis hypogaeae, Semen Maydiss, Semen Tritici aestivi, Ma Ling
During the sowing of the crops such as potato, seed pelleting uses and is used for preventing and treating Semen arachidis hypogaeae, Semen Maydiss, Semen Tritici aestivi, potatoes and other crops sprout term disease and insect pest
In application.
Specific embodiment
Below the technical scheme in the embodiment of the present invention is described in detail, described embodiment does not represent all
Embodiment.The every other embodiment that those skilled in the art are obtained under the premise of not making creative work, all belongs to
In the scope of protection of the invention.
Embodiment 1:
Metalaxyl-M 2%, Fluoxastrobin 10%, clothianidin 30%, dispersant 8%, wetting agent 4%, film former 3%, warning coloration 2%, filler
Supply 100%, mix homogeneously in mixer, through jet mill pulverize after in mixer mix homogeneously, that is, be obtained 42% essence
Metalaxyl Fluoxastrobin clothianidin seed treatment dispersibles powder.
Embodiment 2:
Metalaxyl-M 5%, Fluoxastrobin 5%, clothianidin 40%, dispersant 10%, wetting agent 5%, film former 2%, warning coloration 4%, filler
Supply 100%, mix homogeneously in mixer, through jet mill pulverize after in mixer mix homogeneously, that is, be obtained 50% essence
Metalaxyl Fluoxastrobin clothianidin seed treatment dispersibles powder.
Embodiment 3:
Metalaxyl-M 15%, Fluoxastrobin 3%, clothianidin 40%, dispersant 8%, wetting agent 6%, film former 4%, warning coloration 1%, filler
Supply 100%.Mix homogeneously in mixer, after pulverizing through jet mill in mixer mix homogeneously, obtain final product 58% smart first
Frost spirit Fluoxastrobin clothianidin seed treatment dispersibles powder.
Embodiment 4:
By dispersant 4%, antifreezing agent 4%, thickening agent 3%, defoamer 0.5%, film former 1%, warning coloration 3%, water supplies 100%, through height
Fast shear-mixed uniformly, sequentially adds Metalaxyl-M 1%, Fluoxastrobin 5%, clothianidin 20%, sand milling 2-3 hour, makes in sand mill
Particle diameter, below 5 microns, obtains final product 26% Metalaxyl-M Fluoxastrobin clothianidin suspension seed-coating agent.
Embodiment 5:
By dispersant 5%, antifreezing agent 3%, thickening agent 2%, defoamer 0.5%, film former 2%, warning coloration 2%, water supplies 100%, through height
Fast shear-mixed uniformly, sequentially adds Metalaxyl-M 5%, Fluoxastrobin 5%, clothianidin 30%, sand milling 2-3 hour, makes in sand mill
Particle diameter, below 5 microns, obtains final product 40% Metalaxyl-M Fluoxastrobin clothianidin suspension seed-coating agent.
Embodiment 6:
By dispersant 4%, antifreezing agent 5%, thickening agent 1%, defoamer 0.5%, film former 3%, warning coloration 3%, water supplies 100%, through height
Fast shear-mixed uniformly, sequentially adds Metalaxyl-M 10%, Fluoxastrobin 2%, clothianidin 30%, sand milling 2-3 hour in sand mill,
Make particle diameter below 5 microns, obtain final product 42% Metalaxyl-M Fluoxastrobin clothianidin suspension seed-coating agent.
Embodiment 7
Metalaxyl-M 10%, Fluoxastrobin 10%, clothianidin 40%, dispersant 6%, wetting agent 4%, disintegrating agent 15%, film former 4%, alert
Guard against color 3%, filler supplies 100%.Mix homogeneously in mixer, mix homogeneously after jet mill, it is subsequently adding fluid bed
Extruder grain after comminutor or the kneading that adds water, drying, sample analysis after screening, obtain final product 60% Metalaxyl-M Fluoxastrobin clothianidin
Seed treatment dispersibles granule.
Embodiment 8
Metalaxyl-M 20%, Fluoxastrobin 5%, clothianidin 40%, dispersant 6%, wetting agent 4%, disintegrating agent 10%, film former 3%, warning
Color 2%, filler supplies 100%.Mix homogeneously in mixer, mix homogeneously after jet mill, it is subsequently adding fluid bed and make
Extruder grain after grain machine or the kneading that adds water, drying, sample analysis after screening, obtain final product 65% Metalaxyl-M Fluoxastrobin clothianidin kind
Subprocessing dispersibles granule.
Embodiment 9
Metalaxyl-M 5%, Fluoxastrobin 20%, clothianidin 30%, dispersant 8%, wetting agent 2%, disintegrating agent 20%, film former 2%, warning
Color 2%, filler supplies 100%.Mix homogeneously in mixer, mix homogeneously after jet mill, it is subsequently adding fluid bed and make
Extruder grain after grain machine or the kneading that adds water, drying, sample analysis after screening, obtain final product 55% Metalaxyl-M Fluoxastrobin clothianidin kind
Subprocessing dispersibles granule.
The method that this experiment is combined using Toxicity Determination and field test.First pass through Toxicity Determination, determine
Co-toxicity coefficient (ctc) after two kinds of medicaments are compounding by a certain percentage, ctc < 80 is antagonism, and 80≤ctc≤120 are to be added to make
With ctc > 120 be potentiation, on this basis, then carry out field test.
Table 1. Metalaxyl-M, the Fluoxastrobin and clothianidin Toxicity Determination to black scurf of potato
As shown in Table 1, Metalaxyl-M and Fluoxastrobin compound in the range of 10:1-1:10 and all show notable synergistic effect, and 1:
10 synergistic effects are the most obvious, and the addition of clothianidin does not have harmful effect to the bactericidal effect of Metalaxyl-M and Fluoxastrobin, and anti-
Control and while disease, insect is played with certain prevention effect.
Field control effectiveness test (one)
Subjects: fusarium root rot of maize
Test kind: Zheng Dan 958
EXPERIMENTAL DESIGN, sets 5 process altogether:
42% Metalaxyl-M Fluoxastrobin clothianidin seed treatment of embodiment 1 dispersibles powder, and it is 1 that note processes numbering；
40% Metalaxyl-M Fluoxastrobin clothianidin suspension seed-coating agent of embodiment 5, it is 2 that note processes numbering；
65% Metalaxyl-M Fluoxastrobin clothianidin seed treatment of embodiment 8 dispersibles granule, and it is 3 that note processes numbering；
3% Metalaxyl-M suspension seed-coating agent, it is 4 that note processes numbering；
With clear water as blank, it is 5 that note processes numbering.
Experimental plot arranges, experimental plot random alignment, and experimental plot area is 60m2, is repeated 4 times.
Application method:
Add water in the ratio that 100 kilograms of seed doses convert 2 liters of water in table Chinese medicine consumption before sowing and be tuned into medicinal liquid, then by medicinal liquid
It is sufficiently stirred for seed, so that medicinal liquid is uniformly bonded on seed, sow after airing.
Investigation method:
Disease index is investigated.10d after emergence of corn, the every cell of 30d, 60d takes 5 points of samplings, and each treatment region takes 30 plants
Investigation, record total strain number and diseased plant number at different levels, disease index, calculate prevention effect.
Stage division:
0 grade: plant basal part of stem and master, the equal disease-free spot of fibrous root；
1 grade: a small amount of scab is had on basal part of stem and main root；
3 grades: on basal part of stem and main root, scab is more, lesion area accounts for cervical region and the 1/4-1/2 of the root gross area；
5 grades: on basal part of stem and main root, scab is many and larger, and lesion area accounts for cervical region and the 1/2-3/4 of the root gross area；
7 grades: on basal part of stem and main root, scab in flakes, forms around stem phenomenon, but root system is not dead；
9 grades: root system necrosis, plant above ground portion wilts or dead.
Drug effect computational methods:
Disease index=σ (disease numbers of sheets * at different levels are relative to value of series)/(investigating total leaf book * 9) * 100
Prevention effect (%)=[1- (disease index after disease index * treatment region medicine before blank district medicine)/(blank district medicine
Disease index before disease index * treatment region medicine afterwards)] * 100%
Table 2 Metalaxyl-M Fluoxastrobin clothianidin seed coat agent prevents and treats fusarium root rot of maize result of the test
| Process numbering | Preparation dosage (gram/100kg seed) | After planting 30 days preventive effects (%) | After planting 60 days preventive effects (%) | After planting 90 days preventive effects (%) |
| 1 | 1 | 86.97 | 87.52 | 83.31 |
| 2 | 1 | 87.69 | 88.43 | 82.34 |
| 3 | 1 | 85.69 | 86.97 | 81.36 |
| 4 | 2 | 74.36 | 75.21 | 70.56 |
| 5 | -- | -- | -- | -- |
From table 2 it can be seen that Metalaxyl-M and azoxystrobin compound seed coat agent will be substantially better than to the prevention effect of fusarium root rot of maize
Metalaxyl-M single dose, and the addition of clothianidin has no adverse effects to the field bactericidal effect of Metalaxyl-M and Fluoxastrobin.
Field control effectiveness test (two)
Subjects: Semen arachidis hypogaeae root rot, peanut grub
Test kind: four red
EXPERIMENTAL DESIGN, sets 6 process altogether:
50% Metalaxyl-M Fluoxastrobin clothianidin seed treatment of embodiment 2 dispersibles powder, and it is 1 that note processes numbering；
26% Metalaxyl-M Fluoxastrobin clothianidin suspension seed-coating agent of embodiment 4, it is 2 that note processes numbering；
55% Metalaxyl-M Fluoxastrobin clothianidin seed treatment of embodiment 9 dispersibles granule, and it is 3 that note processes numbering；
3% Metalaxyl-M suspension seed-coating agent, it is 4 that note processes numbering；
20% clothianidin suspension seed-coating agent, it is 5 that note processes numbering:
With clear water as blank, it is 6. that note processes numbering
Experimental plot arranges, experimental plot random alignment, and experimental plot area is 60m2, is repeated 4 times.
Application method:
Add water in the ratio that 100 kilograms of seed doses convert 2 liters of water in table Chinese medicine consumption before sowing and be tuned into medicinal liquid, then by medicinal liquid
It is sufficiently stirred for seed, so that medicinal liquid is uniformly bonded on seed, sow after airing.
Investigation method:
Semen arachidis hypogaeae root rot investigation method
Disease index is investigated.10d after emergence of corn, the every cell of 30d, 60d takes 5 points of samplings, and each treatment region takes 30 plants
Investigation, record total strain number and diseased plant number at different levels, disease index, calculate prevention effect.
Stage division:
0 grade: plant basal part of stem and master, the equal disease-free spot of fibrous root；
1 grade: a small amount of scab is had on basal part of stem and main root；
3 grades: on basal part of stem and main root, scab is more, lesion area accounts for cervical region and the 1/4-1/2 of the root gross area；
5 grades: on basal part of stem and main root, scab is many and larger, and lesion area accounts for cervical region and the 1/2-3/4 of the root gross area；
7 grades: on basal part of stem and main root, scab in flakes, forms around stem phenomenon, but root system is not dead；
9 grades: root system necrosis, plant above ground portion wilts or dead.
Drug effect computational methods:
Disease index=σ (disease numbers of sheets * at different levels are relative to value of series)/(investigation total number of sheets * 9) * 100
Prevention effect (%)=[1- (disease index after disease index * treatment region medicine before blank district medicine)/(blank district medicine
Disease index before disease index * treatment region medicine afterwards)] * 100%
Peanut grub prevention effect investigation method:
Test and investigate 1 time in the harvesting peanut phase.Every 8 points of samplings of cell checkerboard type, do not put 5 caves, investigate peanut grub work borer population, and
By 3 grades of killed fruit numbers of investigation.Calculate prevention effect.
Stage division:
0 grade: pod is complete, no killed shape；
1 grade: pod epidermis is killed, killed area accounts for less than 1/3；
2 grades: the killed area of pod epidermis is more than 1/3, or has killed duck eye, but pod is complete, does not affect yield；
3 grades: pod has killed formation hole fruit, kernel is killed, affects yield.
Drug effect computational methods:
Live borer population * 100 for prevention effect (%)=(check plot work borer population-chemicals treatment district work borer population)/check plot
The killed index of pod (%)=
σ (this killed fruit rank of killed fruit number *)/(the investigation killed rank of total fruit number * highest) * 100
Fruit retention effect (%)=
(the killed index of the blank district pod-killed index of chemicals treatment district pod)/blank district pod killed index *
100
Table 3 Metalaxyl-M Fluoxastrobin clothianidin seed coat agent prevents and treats Semen arachidis hypogaeae root rot result of the test
| Process numbering | Preparation dosage (gram/100kg seed) | After planting 30 days preventive effects (%) | After planting 60 days preventive effects (%) | After planting 90 days preventive effects (%) |
| 1 | 1 | 84.68 | 85.04 | 83.49 |
| 2 | 1 | 86.37 | 87.25 | 84.66 |
| 3 | 1 | 85.53 | 85.86 | 82.47 |
| 4 | 2 | 73.63 | 72.65 | 71.48 |
| 5 | 2 | -- | -- | -- |
| 6 | -- | -- | -- | -- |
Table 4 Metalaxyl-M Fluoxastrobin clothianidin seed coat agent prevents and treats peanut grub result of the test
| Process numbering | Preparation dosage (gram/100kg seed) | Larva preventive effect (%) | Foliar symptoms | Fruit retention effect (%) |
| 1 | 1 | 87.85 | 12.45 | 85.68 |
| 2 | 1 | 88.36 | 11.57 | 86.65 |
| 3 | 1 | 87.98 | 12.13 | 86.12 |
| 4 | 2 | -- | -- | -- |
| 5 | 2 | 82.65 | 13.97 | 84.27 |
| 6 | -- | -- | -- | -- |
From table 3, table 4 is as can be seen that Metalaxyl-M and azoxystrobin compound seed coat agent are obvious to the prevention effect of Semen arachidis hypogaeae root rot
Better than Metalaxyl-M single dose, and the addition of clothianidin has no adverse effects to the field bactericidal effect of Metalaxyl-M and Fluoxastrobin.With
When, the addition of clothianidin also shows preferable prevention effect to peanut grub.
Claims (9)
1. a kind of compositionss containing Metalaxyl-M and Fluoxastrobin and clothianidin it is characterised in that active component Metalaxyl-M and
The mass ratio of Fluoxastrobin and clothianidin is 1-20:1-20:1-40.
2. as claimed in claim 1 a kind of compositionss containing Metalaxyl-M and Fluoxastrobin and clothianidin it is characterised in that
In described compositionss, Metalaxyl-M, the mass ratio of Fluoxastrobin is 1:10-10:1, the quality of Metalaxyl-M and Fluoxastrobin and and thiophene
The mass ratio of worm amine is 1:1-1:20.
3. a kind of seed coat agent containing Metalaxyl-M and Fluoxastrobin and clothianidin it is characterised in that: effective ingredient Metalaxyl-M, phonetic
Bacterium ester, the mass ratio of clothianidin is 1-20:1-20:1-40.
4. the seed coat agent containing Metalaxyl-M and Fluoxastrobin and clothianidin according to claim 3 it is characterised in that: tool
The Metalaxyl-M of bactericidal activity and the mass ratio of Fluoxastrobin is had to be 1:10-10:1, the quality of Metalaxyl-M and Fluoxastrobin and and thiophene
The mass ratio of worm amine is 1:1-1:20.
5. the seed coat agent containing Metalaxyl-M and Fluoxastrobin and clothianidin according to claim 3 it is characterised in that: described
The pesticidal preparations dosage form that can be configured to of seed coat agent be suspension seed-coating agent for pesticidal preparations dosage form, seed treatment dispersibles powder
Agent, seed treatment dispersibles granule.
6., according to the arbitrary described seed coat agent containing Metalaxyl-M and Fluoxastrobin and clothianidin of claim 3-5, its feature exists
In: when described seed coat agent dosage form is suspending agent seed coat agent, in preparation, the mass ratio shared by each composition is Metalaxyl-M 1-20%,
Fluoxastrobin 1-20%, clothianidin 1%-40%, auxiliary element is: dispersant 1-5%, antifreezing agent 1-5%, film former 0.1-5%, thickening agent
1-5%, defoamer 0.1-2%, warning coloration 1-5%, water supplies 100%.
7., according to the arbitrary described seed coat agent containing Metalaxyl-M and Fluoxastrobin and clothianidin of claim 3-5, its feature exists
In: when described seed coat agent dosage form is to dispersible powder, in preparation, the mass ratio shared by each composition is Metalaxyl-M 1-20%, phonetic
Bacterium ester 1-20%, clothianidin 1%-40%, auxiliary element is: dispersant 2-8%, wetting agent 1-6%, film former 1-10%, warning coloration 1-
5%, filler supplies 100%.
8., according to the arbitrary described seed coat agent containing Metalaxyl-M and Fluoxastrobin and clothianidin of claim 3-5, its feature exists
In: when described seed coat agent dosage form is to dispersible granule, in preparation, the mass ratio shared by each composition is Metalaxyl-M 1-20%, phonetic
Bacterium ester 1-20%, clothianidin 1%-40%, auxiliary element is: dispersant 1-6%, wetting agent 2-6%, disintegrating agent 1-10%, film former 1-
5%, warning coloration 1-5%, filler supplies 100%.
9. according to the arbitrary described seed coat agent containing Metalaxyl-M and Fluoxastrobin and clothianidin of claim 3-5 be used for Semen arachidis hypogaeae,
When Semen Maydiss, Semen Tritici aestivi, potatoes and other crops sowing, seed pelleting uses and is used for preventing and treating Semen arachidis hypogaeae, Semen Maydiss, Semen Tritici aestivi, potatoes and other crops
Application in sprout term disease and insect pest.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610767131.1A CN106342872A (en) | 2016-08-31 | 2016-08-31 | Composition containing mefenoxam, azoxystrobin and clothianidin, seed coating agent and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610767131.1A CN106342872A (en) | 2016-08-31 | 2016-08-31 | Composition containing mefenoxam, azoxystrobin and clothianidin, seed coating agent and application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106342872A true CN106342872A (en) | 2017-01-25 |
Family
ID=57858071
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610767131.1A Pending CN106342872A (en) | 2016-08-31 | 2016-08-31 | Composition containing mefenoxam, azoxystrobin and clothianidin, seed coating agent and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106342872A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114766480A (en) * | 2022-03-16 | 2022-07-22 | 深圳诺普信农化股份有限公司 | Water dispersible granule and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1604737A (en) * | 2001-11-27 | 2005-04-06 | 辛根塔参与股份公司 | Seed treatment compositions |
| CN101227820A (en) * | 2004-08-17 | 2008-07-23 | 先正达参股股份有限公司 | Anabasine composition containing water for seed processing |
| CN101242739A (en) * | 2005-06-29 | 2008-08-13 | 先正达参股股份有限公司 | Liquid compositions for treating plant propagation materials |
-
2016
- 2016-08-31 CN CN201610767131.1A patent/CN106342872A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1604737A (en) * | 2001-11-27 | 2005-04-06 | 辛根塔参与股份公司 | Seed treatment compositions |
| CN101227820A (en) * | 2004-08-17 | 2008-07-23 | 先正达参股股份有限公司 | Anabasine composition containing water for seed processing |
| CN101242739A (en) * | 2005-06-29 | 2008-08-13 | 先正达参股股份有限公司 | Liquid compositions for treating plant propagation materials |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114766480A (en) * | 2022-03-16 | 2022-07-22 | 深圳诺普信农化股份有限公司 | Water dispersible granule and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106342822A (en) | Fludioxonil, prothioconazole and chlorantraniliprole containing composition and seed coating agent and application of seed coating agent | |
| CN1994082B (en) | A compound fungicide for preventing and controlling anthracnose of fruits and vegetables | |
| CN106376570A (en) | Fludioxonil-containing seed coating agent composition and application thereof | |
| CN106359395A (en) | Bactericidal composition containing benzovindiflupyr | |
| CN102630679B (en) | Pesticide composition containing orysastrobin | |
| CN105961399A (en) | Fungicidal composition and application thereof | |
| CN104273174B (en) | Pesticide granules containing dinotefuran and diazinon | |
| CN102715173B (en) | Bactericidal composition containing phenylate diazole and fluoxastrobin and application of bactericidal composition | |
| CN107372556A (en) | A kind of suspension seed-coating agent containing pyraclostrobin, amino-oligosaccharide and Diacloden | |
| CN106035363A (en) | Suspension seed coating agent containing fipronil and imidacloprid and its preparation method and use | |
| CN117063935A (en) | Sterilization composition and application thereof | |
| CN106342872A (en) | Composition containing mefenoxam, azoxystrobin and clothianidin, seed coating agent and application | |
| CN101836649B (en) | Preparation of N-phenyl-5-substituted aminopyrazole compounds and application thereof | |
| CN108207985A (en) | A kind of rice terrace ternary weeding composition | |
| CN105052995B (en) | A kind of complex composition and preparation containing toxic fluoride phosphate and oxazole series bactericidal agent | |
| CN106942280A (en) | Nematicidal composition containing tioxazafen and Paecilomyces lilacinus | |
| CN105638697B (en) | Composition pesticide and its application containing methoxy acrylic bactericide | |
| CN107279161A (en) | A kind of bactericidal composition containing folpet and fluopyram | |
| CN109430264B (en) | Bactericide composition containing terpene alcohol and chitosan, and preparation method and application thereof | |
| CN107535518A (en) | Seed treatment composition and its application | |
| CN106857584A (en) | A kind of suspension seed-coating agent containing ethiprole and Tebuconazole and preparation method thereof | |
| CN106508969A (en) | Fluazaindolizine-Paecilomyces lilacinus-containing nematicide composition | |
| CN104604883A (en) | Sterilizing composition containing fluxapyroxad and ipconazole as well as application of sterilizing composition | |
| CN108477192A (en) | A kind of efficient bactericidal composite containing folpet and hexaconazole | |
| CN115316394B (en) | Sterilization composition containing fluazinam |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170125 |