CN106281054A - Microporous acrylic emulsion - Google Patents
Microporous acrylic emulsion Download PDFInfo
- Publication number
- CN106281054A CN106281054A CN201610724335.7A CN201610724335A CN106281054A CN 106281054 A CN106281054 A CN 106281054A CN 201610724335 A CN201610724335 A CN 201610724335A CN 106281054 A CN106281054 A CN 106281054A
- Authority
- CN
- China
- Prior art keywords
- parts
- acrylic acid
- acrylate
- acrylic emulsion
- microporous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims abstract description 15
- 239000000839 emulsion Substances 0.000 title claims abstract description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 12
- -1 phenyl ester Chemical class 0.000 claims abstract description 7
- 239000002253 acid Substances 0.000 claims abstract description 6
- UZFMBTHANHHTEK-UHFFFAOYSA-N 1-benzylnaphthalene;sodium Chemical compound [Na].C=1C=CC2=CC=CC=C2C=1CC1=CC=CC=C1 UZFMBTHANHHTEK-UHFFFAOYSA-N 0.000 claims abstract description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 4
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims abstract description 4
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims abstract description 4
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 4
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims abstract description 4
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims abstract description 4
- 229920001577 copolymer Polymers 0.000 claims abstract description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims abstract description 4
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910000077 silane Inorganic materials 0.000 claims abstract description 4
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims abstract description 4
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims abstract description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 4
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims abstract description 4
- AQZSPJRLCJSOED-UHFFFAOYSA-M trimethyl(octyl)azanium;chloride Chemical compound [Cl-].CCCCCCCC[N+](C)(C)C AQZSPJRLCJSOED-UHFFFAOYSA-M 0.000 claims abstract description 4
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims abstract 4
- UPHWVVKYDQHTCF-UHFFFAOYSA-N octadecylazanium;acetate Chemical compound CC(O)=O.CCCCCCCCCCCCCCCCCCN UPHWVVKYDQHTCF-UHFFFAOYSA-N 0.000 claims abstract 2
- 230000008901 benefit Effects 0.000 abstract description 3
- KWABLUYIOFEZOY-UHFFFAOYSA-N dioctyl butanedioate Chemical compound CCCCCCCCOC(=O)CCC(=O)OCCCCCCCC KWABLUYIOFEZOY-UHFFFAOYSA-N 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 abstract description 3
- 235000011152 sodium sulphate Nutrition 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- RZJRJXONCZWCBN-UHFFFAOYSA-N octadecane Chemical compound CCCCCCCCCCCCCCCCCC RZJRJXONCZWCBN-UHFFFAOYSA-N 0.000 description 4
- 238000004026 adhesive bonding Methods 0.000 description 2
- FSEUPUDHEBLWJY-HWKANZROSA-N diacetylmonoxime Chemical compound CC(=O)C(\C)=N\O FSEUPUDHEBLWJY-HWKANZROSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000004702 methyl esters Chemical class 0.000 description 2
- 229940038384 octadecane Drugs 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The microporous acrylic emulsion of the present invention, it is characterised in that: its formula by weight, by 6 vinyl tributyl ketoximyl silane 13 parts, ethylene glycol 34 parts, sodium hexameta phosphate 34 parts, 35 parts of acrylic acid methyl ester .s of acrylic acid cationic acrylate copolymer 125 150 parts, Hydroxypropyl acrylate 16 20 parts, ethyl acrylate 360 400 parts, 19 25 parts of acrylic acid, octadecylamine acetate 1～2 parts, octyltrimethylammonium chloride 1～2 parts, methyl sodiosul foaliphatate 1～2 parts, benzyl naphthalene sodium sulfonate 1～2 parts；Dioctyl succinate sodium sulfate 1～2 parts, carboxymethyl cellulose 1～2 parts, adjacent acid front three phenyl ester 1～2 parts of compositions；There is raw material be easy to get, low cost, environmental protection, advantage easy to use, effective.
Description
Technical field
The invention belongs to a kind of adhesive.
Background technology
Glued joint (bonding, bonding, cementing, gluing) and refer to that homogeneity or heterogeneous body surface stick with glue the skill that agent links together
The features such as art, has stress distribution continuous, lightweight, or seals, and most technological temperatures are low.Glued joint and be particularly well-suited to different material
Matter, different-thickness, ultra-thin specification and the connection of complex component.Glueing joint RECENT DEVELOPMENTS the fastest, application industry is extremely wide, and to high-new section
The progressive improvement with people's daily life that learn a skill has significant impact.
Summary of the invention:
It is an object of the invention to；A kind of microporous acrylic emulsion is proposed.
The microporous acrylic emulsion of the present invention, it is characterised in that: its formula by weight, by 6--vinyl three diacetylmonoxime
Base silane 1-3 part, ethylene glycol 3-4 part, sodium hexameta phosphate 3-4 part, acrylic acid-cationic acrylate copolymer 3-5 part propylene
Acid methyl ester 125-150 part, Hydroxypropyl acrylate 16-20 part, ethyl acrylate 360-400 part, acrylic acid 19-25 part, octadecane
Amine acetate 1～2 parts, octyltrimethylammonium chloride 1～2 parts, methyl sodiosul foaliphatate 1～2 parts, benzyl naphthalene sodium sulfonate 1～2
Part；Dioctyl succinate sodium sulfate 1～2 parts, carboxymethyl cellulose 1～2 parts, adjacent acid front three phenyl ester 1～2 parts of compositions.
Compared with prior art it provides the benefit that the present invention: has raw material and is easy to get, and technique simplifies, it is easy to manufacture, cost
Low, environmental protection, easy to use, the advantages such as materials more save, effective.
Detailed description of the invention:
Below in conjunction with embodiment, the invention will be further described, but embodiments of the present invention are not limited to this.
Product of the present invention is raw materials used available commercially.
Embodiment
The microporous acrylic emulsion of the present invention, it is characterised in that: its formula by weight, by 6--vinyl three diacetylmonoxime
Base silane 1-3 part, ethylene glycol 3-4 part, sodium hexameta phosphate 3-4 part, acrylic acid-cationic acrylate copolymer 3-5 part propylene
Acid methyl ester 125-150 part, Hydroxypropyl acrylate 16-20 part, ethyl acrylate 360-400 part, acrylic acid 19-25 part, octadecane
Amine acetate 1～2 parts, octyltrimethylammonium chloride 1～2 parts, methyl sodiosul foaliphatate 1～2 parts, benzyl naphthalene sodium sulfonate 1～2
Part；Dioctyl succinate sodium sulfate 1～2 parts, carboxymethyl cellulose 1～2 parts, adjacent acid front three phenyl ester 1～2 parts of compositions.
Product specification of the present invention, quality: solid content more than 80%, its 1% solution pH value is 7.0-7.5；Viscosity 110-120
Centipoise.
Claims (1)
1. a microporous acrylic emulsion, it is characterised in that: its formula by weight, by 6--vinyl tributyl ketoximyl silane
1-3 part, ethylene glycol 3-4 part, sodium hexameta phosphate 3-4 part, acrylic acid-cationic acrylate copolymer 3-5 part acrylic acid methyl ester.
125-150 part, Hydroxypropyl acrylate 16-20 part, ethyl acrylate 360-400 part, acrylic acid 19-25 part, octadecylamine acetic acid
Salt 1～2 parts, octyltrimethylammonium chloride 1～2 parts, methyl sodiosul foaliphatate 1～2 parts, benzyl naphthalene sodium sulfonate 1～2 parts；Amber
Amber dioctyl phthalate sodium sulfate 1～2 parts, carboxymethyl cellulose 1～2 parts, adjacent acid front three phenyl ester 1～2 parts of compositions.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610724335.7A CN106281054A (en) | 2016-08-19 | 2016-08-19 | Microporous acrylic emulsion |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610724335.7A CN106281054A (en) | 2016-08-19 | 2016-08-19 | Microporous acrylic emulsion |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106281054A true CN106281054A (en) | 2017-01-04 |
Family
ID=57616392
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610724335.7A Pending CN106281054A (en) | 2016-08-19 | 2016-08-19 | Microporous acrylic emulsion |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106281054A (en) |
-
2016
- 2016-08-19 CN CN201610724335.7A patent/CN106281054A/en active Pending
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170104 |