CN103881627B - Foaming microporous acrylic emulsion - Google Patents
Foaming microporous acrylic emulsion Download PDFInfo
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- CN103881627B CN103881627B CN201410104366.3A CN201410104366A CN103881627B CN 103881627 B CN103881627 B CN 103881627B CN 201410104366 A CN201410104366 A CN 201410104366A CN 103881627 B CN103881627 B CN 103881627B
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Abstract
The foaming microporous acrylic emulsion of the present invention, it is characterized in that: it is filled a prescription by weight, by methyl acrylate 125 150 parts, hydroxypropyl acrylate 16 20 parts, ethyl acrylate 360 400 parts, 19 25 parts of acrylic acid, octadecylamine acetate 1～2 parts, citric acid 2～5 parts, calcium carbonate 10～15 parts, octyltrimethylammonium chloride 1～2 parts, methyl sodiosul foaliphatate 1～2 parts, benzyl naphthalene sodium sulfonate 1～2 parts；Dioctyl succinate sodium sulphate 1～2 parts, carboxymethylcellulose calcium 1～2 parts, adjacent acid front three phenyl ester 1～2 parts of compositions；There is raw material be easy to get, low cost, environmental protection, advantage easy to use, effective.
Description
Technical field
The invention belongs to a kind of adhesive.
Background technology
Glued joint (bonding, bonding, cementing, gluing) and refer to that homogeneity or heterogeneous body surface are used
The technology that adhesive links together, has stress distribution continuous, lightweight, or seals, many
The features such as number technological temperature is low.Glued joint and be particularly well-suited to unlike material, different-thickness, ultra-thin rule
Lattice and the connection of complex component.Glueing joint RECENT DEVELOPMENTS the fastest, application industry is extremely wide, and to high-new
Scientific and technological progress and people's daily life improve significant impact.Therefore, study, develop and
Produce all kinds of adhesive particularly significant.Adhesive (Bonding agent) is most important auxiliary
Help one of material, apply extremely wide in package handling.Adhesive is to have sticking material,
The material that two kinds separate can be linked together by its viscosity.The kind of adhesive is a lot.①
Its material of being taken from nature of natural glue.Including starch, protein, dextrin, move
The bioadhesives such as thing glue, shellac, hide glue, rosin；Also the mineral binders such as pitch are included.
2. artificial adhesive this be to use made material, the inorganic bond such as including waterglass, with
And the organic bond such as synthetic resin, synthetic rubber.Characteristic is used to divide 1. aqueous type adhesive to use
The adhesive of water as solvent, mainly has starch, dextrin, polyvinyl alcohol, carboxymethylcellulose calcium etc..
2. heat-fusible adhesive uses after making adhesive melts by heating, is a kind of solid binder.
General thermoplastic resin all can use, such as polyurethane, polystyrene, polyacrylate, ethene
Acetate ethylene copolymer etc..3. solvent type adhesive is water insoluble and be dissolved in the viscous of certain solvent
Mixture.Such as shellac, butyl rubber etc..4. Emulsion Adhesive many in water in suspension, as
Vinyl acetate resin, acrylic resin, chlorinated rubber etc..5. liquid non-solvent adhesive is often
In thick liquid nano under temperature, such as epoxy resin etc..Adhesive be label material and bonding substrates it
Between medium, play link effect.Permanent and removable property two kinds can be divided into by its characteristic.
It has multiple formulations, is suitable for different face materials and different occasions.Adhesive is adhesive material
Most important composition in technology, is the key of label application technology.Glued joint (bonding, bonding,
Cementing, gluing) refer to that homogeneity or heterogeneous body surface stick with glue the technology that agent links together,
There is stress distribution continuous, lightweight, or seal, the features such as most technological temperatures are low.Glued joint
It is particularly well-suited to unlike material, different-thickness, ultra-thin specification and the connection of complex component.Glued joint
RECENT DEVELOPMENTS is the fastest, and application industry is extremely wide, and life daily to high-and-new science and technology progress and the people
Improvement of living has significant impact.Therefore, study, develop and produce all kinds of adhesive particularly significant.
Through China's publication retrieval, do not find the scheme identical with present patent application.
Summary of the invention:
It is an object of the invention to；One foaming microporous acrylic emulsion is proposed.
The foaming microporous acrylic emulsion of the present invention, it is characterised in that: it is filled a prescription by weight,
By methyl acrylate 125-150 part, hydroxypropyl acrylate 16-20 part, ethyl acrylate
360-400 part, acrylic acid 19-25 part, octadecylamine acetate 1～2 parts, citric acid 2～
5 parts, calcium carbonate 10～15 parts, octyltrimethylammonium chloride 1～2 parts, fatty acid methyl ester sulphur
Acid sodium 1～2 parts, benzyl naphthalene sodium sulfonate 1～2 parts；Dioctyl succinate sodium sulphate 1～2 parts,
Carboxymethylcellulose calcium 1～2 parts, adjacent acid front three phenyl ester 1～2 parts of compositions.
The foaming microporous acrylic emulsion preparation method of the present invention, it is characterised in that: its formula
By weight, by methyl acrylate 125-150 part, hydroxypropyl acrylate 16-20 part, propylene
Acetoacetic ester 360-400 part, acrylic acid 19-25 part, octadecylamine acetate 1～2 parts, lemon
Lemon acid 2～5 parts, calcium carbonate 10～15 parts, octyltrimethylammonium chloride 1～2 parts, fat
Acid methyl ester sulfonate 1～2 parts, benzyl naphthalene sodium sulfonate 1～2 parts；Dioctyl succinate sodium sulphate
1～2 part, carboxymethylcellulose calcium 1～2 parts, adjacent acid front three phenyl ester 1～2 parts of compositions；Will be complete
Portion's material adds mixing, reacts 60-90 minute, obtain product at 80-90 DEG C.
Product of the present invention, is suitable for the use of various occasion, and bonding strength reaches prior art
More than 2 times.
Compared with prior art it provides the benefit that the present invention: has raw material and is easy to get, and technique simplifies,
Easily fabricated, low cost, environmental protection, easy to use, the advantages such as materials more save, effective.
Detailed description of the invention:
Below in conjunction with embodiment, the invention will be further described, but embodiments of the present invention are not
It is limited to this.
Product of the present invention is raw materials used available commercially.
Embodiment 1
The foaming microporous acrylic emulsion preparation method of the present invention, it is characterised in that: its formula
By weight, by methyl acrylate 125-150 part, hydroxypropyl acrylate 16-20 part, propylene
Acetoacetic ester 360-400 part, acrylic acid 19-25 part, octadecylamine acetate 1～2 parts, lemon
Lemon acid 2～5 parts, calcium carbonate 10～15 parts, octyltrimethylammonium chloride 1～2 parts, fat
Acid methyl ester sulfonate 1～2 parts, benzyl naphthalene sodium sulfonate 1～2 parts；Dioctyl succinate sodium sulphate
1～2 part, carboxymethylcellulose calcium 1～2 parts, adjacent acid front three phenyl ester 1～2 parts of compositions；Will be complete
Portion's material adds mixing, reacts 60-90 minute, obtain product at 80-90 DEG C.
Embodiment 2
The foaming microporous acrylic emulsion preparation method of the present invention, it is characterised in that: its formula
By weight, by methyl acrylate 125 parts, hydroxypropyl acrylate 16 parts, ethyl acrylate
360 parts, 19 parts of acrylic acid, octadecylamine acetate 1～2 parts, citric acid 2～5 parts,
Calcium carbonate 10～15 parts, octyltrimethylammonium chloride 1～2 parts, methyl sodiosul foaliphatate 1～
2 parts, benzyl naphthalene sodium sulfonate 1～2 parts；Dioctyl succinate sodium sulphate 1～2 parts, carboxymethyl
Cellulose 1～2 parts, adjacent acid front three phenyl ester 1～2 parts of compositions；Whole materials are added mixing,
React 60-90 minute at 80-90 DEG C, obtain product.
Embodiment 3
The foaming microporous acrylic emulsion preparation method of the present invention, it is characterised in that: its formula
By weight, by methyl acrylate 150 parts, hydroxypropyl acrylate 20 parts, ethyl acrylate
400 parts, 25 parts of acrylic acid, octadecylamine acetate 1～2 parts, citric acid 2～5 parts,
Calcium carbonate 10～15 parts, octyltrimethylammonium chloride 1～2 parts, methyl sodiosul foaliphatate 1～
2 parts, benzyl naphthalene sodium sulfonate 1～2 parts；Dioctyl succinate sodium sulphate 1～2 parts, carboxymethyl
Cellulose 1～2 parts, adjacent acid front three phenyl ester 1～2 parts of compositions；Whole materials are added mixing,
React 60-90 minute at 80-90 DEG C, obtain product.
Embodiment 4
The foaming microporous acrylic emulsion preparation method of the present invention, it is characterised in that: its formula
By weight, by methyl acrylate 125 parts, hydroxypropyl acrylate 20 parts, ethyl acrylate
360 parts, 25 parts of acrylic acid, octadecylamine acetate 1～2 parts, citric acid 2～5 parts,
Calcium carbonate 10～15 parts, octyltrimethylammonium chloride 1～2 parts, methyl sodiosul foaliphatate 1～
2 parts, benzyl naphthalene sodium sulfonate 1～2 parts；Dioctyl succinate sodium sulphate 1～2 parts, carboxymethyl
Cellulose 1～2 parts, adjacent acid front three phenyl ester 1～2 parts of compositions；Whole materials are added mixing,
React 60-90 minute at 80-90 DEG C, obtain product.
Embodiment 5
The foaming microporous acrylic emulsion preparation method of the present invention, it is characterised in that: its formula
By weight, by methyl acrylate 150 parts, hydroxypropyl acrylate 16 parts, ethyl acrylate
400 parts, 19 parts of acrylic acid, octadecylamine acetate 1～2 parts, citric acid 2～5 parts,
Calcium carbonate 10～15 parts, octyltrimethylammonium chloride 1～2 parts, methyl sodiosul foaliphatate 1～
2 parts, benzyl naphthalene sodium sulfonate 1～2 parts；Dioctyl succinate sodium sulphate 1～2 parts, carboxymethyl
Cellulose 1～2 parts, adjacent acid front three phenyl ester 1～2 parts of compositions；Whole materials are added mixing,
React 60-90 minute at 80-90 DEG C, obtain product.
Product specification of the present invention, quality: solid content more than 80%, its 1% solution pH value is 7.0
—7.5；Viscosity 110-120 centipoise.
Claims (2)
1. a foaming microporous acrylic emulsion, it is characterised in that: it is filled a prescription by weight,
By methyl acrylate 125-150 part, hydroxypropyl acrylate 16-20 part, ethyl acrylate
360-400 part, acrylic acid 19-25 part, octadecylamine acetate 1～2 parts, citric acid 2～
5 parts, calcium carbonate 10～15 parts, octyltrimethylammonium chloride 1～2 parts, fatty acid methyl ester sulphur
Acid sodium 1～2 parts, benzyl naphthalene sodium sulfonate 1～2 parts；Dioctyl succinate sodium sulphate 1～2 parts,
Carboxymethylcellulose calcium 1～2 parts, tricresyl phosphate 1～2 parts of compositions.
2. one kind foaming microporous acrylic emulsion preparation method, it is characterised in that: its formula with
Weight meter, by methyl acrylate 125-150 part, hydroxypropyl acrylate 16-20 part, acrylic acid
Ethyl ester 360-400 part, acrylic acid 19-25 part, octadecylamine acetate 1～2 parts, lemon
Acid 2～5 parts, calcium carbonate 10～15 parts, octyltrimethylammonium chloride 1～2 parts, aliphatic acid
Methyl ester sulfonate 1～2 parts, benzyl naphthalene sodium sulfonate 1～2 parts；Dioctyl succinate sodium sulphate 1～
2 parts, carboxymethylcellulose calcium 1～2 parts, tricresyl phosphate 1～2 parts of compositions；By whole things
Material adds mixing, reacts 60-90 minute, obtain product at 80-90 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410104366.3A CN103881627B (en) | 2014-03-20 | 2014-03-20 | Foaming microporous acrylic emulsion |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410104366.3A CN103881627B (en) | 2014-03-20 | 2014-03-20 | Foaming microporous acrylic emulsion |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103881627A CN103881627A (en) | 2014-06-25 |
| CN103881627B true CN103881627B (en) | 2016-08-17 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410104366.3A Active CN103881627B (en) | 2014-03-20 | 2014-03-20 | Foaming microporous acrylic emulsion |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102260478A (en) * | 2010-12-14 | 2011-11-30 | 上海凯鑫森产业投资控股有限公司 | Pressure-sensitive adhesive for PET protective film and preparation method thereof |
| CN103172797A (en) * | 2013-03-13 | 2013-06-26 | 华南师范大学 | Polyacrylate/polyester resin prepolymer in interpenetration network structure, method for preparing same and powdery coating with same |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100995509B1 (en) * | 2007-01-18 | 2010-11-19 | 주식회사 엘지화학 | Acrylic pressure-sensitive adhesive composition |
-
2014
- 2014-03-20 CN CN201410104366.3A patent/CN103881627B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102260478A (en) * | 2010-12-14 | 2011-11-30 | 上海凯鑫森产业投资控股有限公司 | Pressure-sensitive adhesive for PET protective film and preparation method thereof |
| CN103172797A (en) * | 2013-03-13 | 2013-06-26 | 华南师范大学 | Polyacrylate/polyester resin prepolymer in interpenetration network structure, method for preparing same and powdery coating with same |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103881627A (en) | 2014-06-25 |
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Effective date of registration: 20190430 Address after: 510000 Room 710, 282 Zhongshan Avenue Middle Road, Tianhe District, Guangzhou City, Guangdong Province Patentee after: Guangzhou Xinri Chemical Technology Co.,Ltd. Address before: 542800 No. 13 Garden Street, eight step area, Hezhou, the Guangxi Zhuang Autonomous Region Patentee before: Yang Yi |
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Effective date of registration: 20230420 Address after: 512400 Pearl Industrial Park, Nanxiong, Shaoguan, Guangdong Patentee after: Nanxiong Qiyuanda New Material Co.,Ltd. Address before: 510000 Room 710, 282 Zhongshan Avenue Middle Road, Tianhe District, Guangzhou City, Guangdong Province Patentee before: Guangzhou Xinri Chemical Technology Co.,Ltd. |
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