CN106242452A - ancient building material and preparation method thereof - Google Patents
ancient building material and preparation method thereof Download PDFInfo
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- CN106242452A CN106242452A CN201610765753.0A CN201610765753A CN106242452A CN 106242452 A CN106242452 A CN 106242452A CN 201610765753 A CN201610765753 A CN 201610765753A CN 106242452 A CN106242452 A CN 106242452A
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- Prior art keywords
- slurry
- oil
- vegetable oil
- ground floor
- aggregate
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/10—Lime cements or magnesium oxide cements
- C04B28/105—Magnesium oxide or magnesium carbonate cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/54—Substitutes for natural stone, artistic materials or the like
- C04B2111/547—Imitating ancient compositions, e.g. mediaeval mortars; Compositions specially designed for restauration of ancient buildings or building elements
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of ancient building material and preparation method thereof, including aggregate and slurry, solidification alternately laid by aggregate and slurry, it is characterized in that: by weight percent, described slurry includes the calcium propionate of the aluminium hydroxide of magnesium oxide, 5%～15%, 10%～20%, 5%～15% potassium sorbate, 5%～the sawdust of 15% and the wood wax oil of 30%～50% of 20%～30%.This ancient building material is easy to the phenomenon occurring becoming fragile and cause premature breakdown under rugged environment.
Description
Technical field
The present invention relates to building material technical field, more specifically, it relates to a kind of ancient building material and preparation side thereof
Method.
Background technology
At present, architectural style progressively occurs returning ancient tendency, occurs in that the various ancient building material for building in the style of the ancients on the market
Material.The current ancient building material for building in the style of the ancients mostly uses cement or uses the materials such as wood materials to manufacture.
The weight of the unit volume of cement material is big, brings the biggest challenge to construction in architectural process.And wood materials there is also
Affected by environment greatly, need to make substantial amounts of surface and process to extend the life-span of wood materials.And use the cost height of pure wood, nothing
Shape improves building cost.And using composite wood, it needs to use binding agent adhesion-molded, and containing a large amount of in binding agent
Organic substance, has certain injury, not environmentally to human body.Therefore, it is badly in need of have developed a kind of novel ancient building material, solves existing
The weight of the unit volume that ancient building material exists is big, technical problem not environmentally.
The Chinese patent of Publication No.: CN105601219A discloses a kind of novel ancient building material and preparation method thereof,
Aggregate and slurry are alternately laid in mould solidification and obtain by described ancient building material；By weight percent, described
Slurry includes the sawdust of the aluminium hydroxide of magnesium oxide, 10%～20%, 5%～15% of 35%～50% and 30%～50%
Wood wax oil；Described aggregate uses fiber cloth.Although above-mentioned construction material to some extent solves existing ancient building material and deposits
The weight of unit volume big, technical problem not environmentally, but this construction material is easy to occur under rugged environment
Become fragile and cause the phenomenon of premature breakdown.
Summary of the invention
The deficiency existed for prior art, the invention reside in a kind of ancient building material of offer, this ancient building material, is disliking
The phenomenon occurring becoming fragile and cause premature breakdown it is easy in the environment of bad.
For achieving the above object, the technical scheme is that a kind of ancient building material, including aggregate and slurry
Material, aggregate and slurry alternately lay solidification, by weight percent, described slurry include 20%～30% magnesium oxide, 5%～
The calcium propionate of aluminium hydroxide, 10%～20% of 15%, 5%～15% potassium sorbate, 5%～the sawdust of 15% and 30%～
The wood wax oil of 50%.
By using technique scheme, the construction material structure comparison that this formula of size is allotted is stable, severe
It is difficult under environment that the phenomenon degenerated of getting rusty occurs so that it is the firmest, improves its service life.
The present invention is further arranged to: described aggregate is gauze.
By using technique scheme, gauze has good toughness and a rotproofness, and can make the second pulp layer can
To combine through gauze and the first pulp layer, the internal structure making construction material is more stable.
The present invention is further arranged to: described wood wax oil uses aqueous wood wax oil；By weight, described aqueous wood wax oil bag
Include 76 parts of vegetable oil wax composite water soluble oil phases, 6 parts of aqueous terpene resins, 3 parts of nano zine oxides, 1 part of nertralizer, 0.6 part of aqueous
Drying aids, 2 parts of anti-yellowing agent, 3 parts of ultraviolet-resistant absorbent, 1 part of crosslinking Hardening agent, 0.4 part of thickening leveling agent and 13 parts of water；
Described vegetable oil wax composite water soluble oil phase is prepared by adding water after emulsifying by vegetable oil and vegetable wax, Qi Zhongzhi
The mass ratio of thing oil and vegetable wax is 10～12 1.
The present invention is further arranged to: the step of preparation process of described vegetable oil wax composite water soluble oil phase is as follows:
Step one, vegetable oil heat pre-treatment is carried out remove impurity；By the vegetable oil after remove impurity in nitrogen atmosphere, 260～280
At a temperature of DEG C, it is incubated 16 hours, obtains polymeric vegetable oil；Then polymeric vegetable oil is decoloured, after bleaching, must refine poly-
Close vegetable oil；
Step 2, the refined polymeric vegetable oil of step one being mixed with vegetable wax, heating ultrasonic disperse, obtaining fineness is 30 μm
Dispersion；
Step 3, in the dispersion of step 3 add emulsifying agent, heated and stirred, then add water, obtain solid content and reach
To the aqueous oil phase of more than 50%；The consumption controlling emulsifying agent is the 1%～3% of dispersion quality.
It is a further object to provide the preparation method of a kind of ancient building material, through the following steps that realize
:
A, according to the component of slurry described in the claims 1 to 4 and consumption, prepare each component, first wood wax oil be heated to
90-100 DEG C, then pour calcium propionate into, stir 5-10 minute, pour aluminium hydroxide, potassium sorbate, sawdust and oxidation the most successively into
Magnesium, is 1-2 minute, and constantly stirs the interval time poured into；Aggregate described in the claims 1 to 4 is entered simultaneously
Row cutting, is cut to the size adapted with mould.
B, coat releasing agent on the face of the die, then brush ground floor slurry at die surface, mould is added rapidly
It is 1-2mm that heat makes ground floor slurry curing, the thickness of ground floor slurry to 100～120 DEG C；
C, watering in the ground floor pulp surface of solidification, shakeout aggregate and be filled with the ground floor pulp surface of water,
Rolled smooth with roller；
D, paving Wangue material ground floor slurry on perfuse the sand grains that particle diameter is 0.1-0.5mm, according to the size every square of mould
Centimetre sprinkle the sand grains of 0.5-1.5 gram, and pushed away with scraper plate even；
E, perfuse sand grains after ground floor slurry is carried out heat treated again, temperature is 70-80 DEG C, and the time controls, at 1-5 minute, to make
Gauze and sand grains can stably be positioned on ground floor slurry；
After F, heat treated, then brushing second layer slurry on ground floor aggregate, the thickness controlling second layer slurry is 1～2mm,
By that analogy, lay to last layer of slurry to mould laying is filled full；
G, will fill full slurry in mould and aggregate carries out a total heat treated, heating-up temperature is 120-150 DEG C, heating
Time is 1-2 minute；
H, heated after place cold closet again in carry out cooling process, cooling is divided into two steps, carries out a pre-cooling for the first time
But, temperature controls at 50-60 DEG C, and the time controlled at 2-5 minute；Chilling temperature controls at 0-10 DEG C for the second time, and the time controls
5-10 minute.
By using technique scheme, proportioning slurry when, in advance wood wax oil is carried out heat treated the most again
Adding raw material one by one, and stir continuously, so that the slurry associativity that proportioning is out is more preferable, structure is more stable；
After having brushed one layer of slurry, it is heating and curing every time, brushes the second layer the most again, so that the slurry of every layer of solidification is more
For smooth, and can be carried out an inspection after each solidification, can in time it be entered if where is it goes wrong
Row is studied for a second time courses one has flunked, by sprinkling water on slurry in advance and passing through heating so that aggregate can the most smooth stably paste spreading aggregate when
Being combined on slurry, the setting of sand grains makes the mouldability of construction material more preferably, and structure is more stable；After having filled in mould, it is entered
One total heating of row, then in the cooling through two processes, makes the construction material manufactured the hardest, and structure is more
Stable, weatherability is more preferably.
The present invention is further arranged to: described releasing agent is polyurethane water-based release agent.
By using technique scheme, polyurethane water-based release agent is with water as dispersion phase, and the hydrotrope of formation both possessed
Making the function of the polyurethane foam demoulding, possess again biological degradability, the harmful substance such as VOC free produces, and the feature of environmental protection is strong；And water is made
For diluent, pollution-free it is easy to get, low cost.
In sum, the method have the advantages that the manufacture method of the proportioning by slurry and construction material, from
And the construction material manufactured can be made, under rugged environment, it is easy to the phenomenon occurring becoming fragile and cause premature breakdown,
There is good weatherability.
Accompanying drawing explanation
Fig. 1 is the flow process chart of the present invention.
Detailed description of the invention
Below in conjunction with accompanying drawing, the present invention is described in further detail.
This specific embodiment is only explanation of the invention, and it is not limitation of the present invention, people in the art
The present embodiment can be made after reading this specification by member as required does not has the amendment of creative contribution, but as long as at this
All protected by Patent Law in the right of invention.
Embodiment 1:
A kind of ancient building material, alternately lays solidification including aggregate and slurry, aggregate and slurry, it is characterized in that: by percent mass
Number, described slurry include 20%～30% the calcium propionate of the aluminium hydroxide of magnesium oxide, 5%～15%, 10%～20%, 5%
～15% potassium sorbate, 5%～the sawdust of 15% and the wood wax oil of 30%～50%；Described aggregate is gauze.
Described wood wax oil uses aqueous wood wax oil；By weight, described aqueous wood wax oil includes that 76 parts of vegetable oil waxes are combined
Aqueous oil phase, 6 parts of aqueous terpene resins, 3 parts of nano zine oxides, 1 part of nertralizer, 0.6 part of aqueous drying aids, 2 parts of yellowing-resistant
Agent, 3 parts of ultraviolet-resistant absorbent, 1 part of crosslinking Hardening agent, 0.4 part of thickening leveling agent and 13 parts of water；Described vegetable oil wax Compound Water
Property oil phase prepared by adding water after emulsifying by vegetable oil and vegetable wax, wherein vegetable oil and the quality of vegetable wax
Ratio is 10～12 1.
The step of preparation process of vegetable oil wax composite water soluble oil phase is as follows:
Step one, vegetable oil heat pre-treatment is carried out remove impurity；By the vegetable oil after remove impurity in nitrogen atmosphere, 260～280
At a temperature of DEG C (temperature is 260 degree, 270 degree or 280 degree), it is incubated 16 hours, obtains polymeric vegetable oil；Then to polymeric vegetable oil
Carry out decolouring, after bleaching, obtain refined polymeric vegetable oil；
Step 2, the refined polymeric vegetable oil of step one being mixed with vegetable wax, heating ultrasonic disperse, obtaining fineness is 30 μm
Dispersion；
Step 3, in the dispersion of step 3 add emulsifying agent, heated and stirred, then add water, obtain solid content and reach
To the aqueous oil phase of more than 50%；Control the consumption of emulsifying agent be dispersion quality 1%～3% (consumption of emulsifying agent is
The 1% of dispersion quality, 2% or 3%).
The preparation method of a kind of ancient building material is as follows:
A, the component of proportioning slurry and consumption, prepare each component, first wood wax oil be heated to 90-100 DEG C, then pour calcium propionate into,
Stirring 5-10 minute, pour aluminium hydroxide, potassium sorbate, sawdust and magnesium oxide the most successively into, the interval time poured into is that 1-2 divides
Clock, and constantly stir；Aggregate described in the claims 1 to 4 is carried out cutting simultaneously, be cut to adapt with mould
Size；
B, coat releasing agent (releasing agent is polyurethane water-based release agent) on the face of the die, then brush the at die surface
One layer of slurry, mould being heated rapidly to 100～120 DEG C and makes ground floor slurry curing, the thickness of ground floor slurry is 1-2mm；
C, watering in the ground floor pulp surface of solidification, shakeout aggregate and be filled with the ground floor pulp surface of water,
Rolled smooth with roller；
D, paving Wangue material ground floor slurry on perfuse the sand grains that particle diameter is 0.1-0.5mm, according to the size every square of mould
Centimetre sprinkle the sand grains of 0.5-1.5 gram, and pushed away with scraper plate even；
E, perfuse sand grains after ground floor slurry is carried out heat treated again, temperature is 70-80 DEG C, and the time controls, at 1-5 minute, to make
Gauze and sand grains can stably be positioned on ground floor slurry；
After F, heat treated, then brushing second layer slurry on ground floor aggregate, the thickness controlling second layer slurry is 1～2mm,
By that analogy, lay to last layer of slurry to mould laying is filled full；
G, will fill full slurry in mould and aggregate carries out a total heat treated, heating-up temperature is 120-150 DEG C, heating
Time is 1-2 minute；
Carrying out cooling process in placing cold closet after having heated again, cooling is divided into two steps, carries out a precooling for the first time,
Temperature controls at 50-60 DEG C, and the time controlled at 2-5 minute；Chilling temperature controls at 0-10 DEG C for the second time, and the time controls at 5-10
Minute.
Table 1, the proportioning of wood wax oil.
| Sequence number | Material | Consumption |
| 1 | Vegetable oil wax composite water soluble oil phase | 76 parts |
| 2 | Aqueous terpene resin | 6 parts |
| 3 | Nano zine oxide | 3 parts |
| 4 | Nertralizer | 1 part |
| 5 | Aqueous drying aids | 0.6 part |
| 6 | Anti-yellowing agent | 2 parts |
| 7 | Ultraviolet-resistant absorbent | 3 parts |
| 8 | Crosslinking Hardening agent | 1 part |
| 9 | Thickening leveling agent | 0.4 part |
| 10 | Water | 13 parts |
Table 2, the preparation method of ancient building material
Embodiment 2:
Table 3, the preparation method of ancient building material
Embodiment 3:
Table 4, the preparation method of ancient building material
Claims (6)
1. an ancient building material, alternately lays solidification including aggregate and slurry, aggregate and slurry, it is characterized in that: by quality hundred
Mark, described slurry include the aluminium hydroxide of magnesium oxide, 5%～15%, 10%～20% of 20%～30% calcium propionate,
5%～15% potassium sorbate, 5%～the sawdust of 15% and the wood wax oil of 30%～50%.
Ancient building material the most according to claim 1, is characterized in that: described aggregate is gauze.
Ancient building material the most according to claim 1, is characterized in that: described wood wax oil uses aqueous wood wax oil；By weight
Part, described aqueous wood wax oil include 76 parts of vegetable oil wax composite water soluble oil phases, 6 parts of aqueous terpene resins, 3 parts of nano zine oxides, 1
Part nertralizer, 0.6 part of aqueous drying aids, 2 parts of anti-yellowing agent, 3 parts of ultraviolet-resistant absorbent, 1 part of crosslinking Hardening agent, 0.4 part
Thickening leveling agent and 13 parts of water；Described vegetable oil wax composite water soluble oil phase is to be added by after emulsifying by vegetable oil and vegetable wax
Water prepares, and wherein the mass ratio of vegetable oil and vegetable wax is 10～12 1.
Ancient building material the most according to claim 3, is characterized in that: the preparation work of described vegetable oil wax composite water soluble oil phase
Skill step is as follows:
Step one, vegetable oil heat pre-treatment is carried out remove impurity；By the vegetable oil after remove impurity in nitrogen atmosphere, 260～280
At a temperature of DEG C, it is incubated 16 hours, obtains polymeric vegetable oil；Then polymeric vegetable oil is decoloured, after bleaching, must refine poly-
Close vegetable oil；
Step 2, the refined polymeric vegetable oil of step one being mixed with vegetable wax, heating ultrasonic disperse, obtaining fineness is 30 μm
Dispersion；
Step 3, in the dispersion of step 3 add emulsifying agent, heated and stirred, then add water, obtain solid content and reach
To the aqueous oil phase of more than 50%；The consumption controlling emulsifying agent is the 1%～3% of dispersion quality.
5. a preparation method for ancient building material, is characterized in that being realized by following steps:
According to component and the consumption of slurry described in the claims 1 to 4, prepare each component, first wood wax oil is heated to 90-
100 DEG C, then pour calcium propionate into, stir 5-10 minute, pour aluminium hydroxide, potassium sorbate, sawdust and magnesium oxide the most successively into, fall
The interval time entered is 1-2 minute, and constantly stirs；Aggregate described in the claims 1 to 4 is cut out simultaneously
Cut, be cut to the size adapted with mould；
Coat releasing agent on the face of the die, then brush ground floor slurry at die surface, mould is heated rapidly to 100
～120 DEG C to make ground floor slurry curing, the thickness of ground floor slurry be 1-2mm；
The ground floor pulp surface of solidification is sprinkled water, aggregate is shakeout be filled with the ground floor pulp surface of water the most again, use
Roller is rolled smooth；
The ground floor slurry of paving Wangue material perfuses the sand grains that particle diameter is 0.1-0.5mm, according to the size every square li of mould
Rice sprinkles the sand grains of 0.5-1.5 gram, and is pushed away even with scraper plate；
Ground floor slurry carries out after perfusing sand grains heat treated again, and temperature is 70-80 DEG C, and the time controls, at 1-5 minute, to make yarn
Net and sand grains can stably be positioned on ground floor slurry；
After heat treated, then brushing second layer slurry on ground floor aggregate, the thickness controlling second layer slurry is 1～2mm, with
This analogizes, and lays to last layer of slurry full to mould is laid filling；
To fill full slurry in mould and aggregate carries out a total heat treated, heating-up temperature is 120-150 DEG C, during heating
Between be 1-2 minute；
Carrying out cooling process in placing cold closet after having heated again, cooling is divided into two steps, carries out a precooling for the first time,
Temperature controls at 50-60 DEG C, and the time controlled at 2-5 minute；Chilling temperature controls at 0-10 DEG C for the second time, and the time controls at 5-10
Minute.
The preparation method of ancient building material the most according to claim 5, is characterized in that: described releasing agent is polyurethane water
Property releasing agent.
Priority Applications (1)
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| CN201610765753.0A CN106242452A (en) | 2016-08-29 | 2016-08-29 | ancient building material and preparation method thereof |
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| CN201610765753.0A CN106242452A (en) | 2016-08-29 | 2016-08-29 | ancient building material and preparation method thereof |
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ID=57596883
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1090242A (en) * | 1993-10-27 | 1994-08-03 | 周兴和 | Decorative relief sculpture products imitating ancient and European styles and manufacture method thereof |
| CN1884731A (en) * | 2006-06-09 | 2006-12-27 | 北京聚星复合材料技术发展有限公司 | Light archaized architecture production method and product |
| CN101265116A (en) * | 2008-04-14 | 2008-09-17 | 公安部四川消防研究所 | Fireproof board for ancient buildings and preparation method thereof |
| CN105601219A (en) * | 2015-12-25 | 2016-05-25 | 董学明 | Novel antique building material and preparation method thereof |
-
2016
- 2016-08-29 CN CN201610765753.0A patent/CN106242452A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1090242A (en) * | 1993-10-27 | 1994-08-03 | 周兴和 | Decorative relief sculpture products imitating ancient and European styles and manufacture method thereof |
| CN1884731A (en) * | 2006-06-09 | 2006-12-27 | 北京聚星复合材料技术发展有限公司 | Light archaized architecture production method and product |
| CN101265116A (en) * | 2008-04-14 | 2008-09-17 | 公安部四川消防研究所 | Fireproof board for ancient buildings and preparation method thereof |
| CN105601219A (en) * | 2015-12-25 | 2016-05-25 | 董学明 | Novel antique building material and preparation method thereof |
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Application publication date: 20161221 |