CN106183514A - A kind of thermal dye sublimation transfer film and preparation method thereof - Google Patents
A kind of thermal dye sublimation transfer film and preparation method thereof Download PDFInfo
- Publication number
- CN106183514A CN106183514A CN201610526998.8A CN201610526998A CN106183514A CN 106183514 A CN106183514 A CN 106183514A CN 201610526998 A CN201610526998 A CN 201610526998A CN 106183514 A CN106183514 A CN 106183514A
- Authority
- CN
- China
- Prior art keywords
- transfer film
- thermal dye
- dye sublimation
- sublimation transfer
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000859 sublimation Methods 0.000 title claims abstract description 22
- 230000008022 sublimation Effects 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title abstract description 8
- 238000007639 printing Methods 0.000 claims abstract description 18
- 239000000049 pigment Substances 0.000 claims description 10
- 239000000654 additive Substances 0.000 claims description 6
- 230000000996 additive effect Effects 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 238000004090 dissolution Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 5
- 239000010408 film Substances 0.000 description 35
- 238000010023 transfer printing Methods 0.000 description 8
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical group CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- 229920002635 polyurethane Polymers 0.000 description 6
- 239000004814 polyurethane Substances 0.000 description 6
- 229920000139 polyethylene terephthalate Polymers 0.000 description 5
- 239000005020 polyethylene terephthalate Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 238000013518 transcription Methods 0.000 description 3
- 230000035897 transcription Effects 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 229920002301 cellulose acetate Polymers 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- -1 polyethylene terephthalate Polymers 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- QQZOPKMRPOGIEB-UHFFFAOYSA-N 2-Oxohexane Chemical compound CCCCC(C)=O QQZOPKMRPOGIEB-UHFFFAOYSA-N 0.000 description 1
- 210000000577 adipose tissue Anatomy 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
The invention belongs to heat transfer film technical field, be specifically related to a kind of thermal dye sublimation transfer film and preparation method thereof.This thermal dye sublimation transfer film includes base film layer, and the surface-coated of base film layer has printing layer.Thermal dye sublimation transfer film light resistance, resistance to water and the scratch-proofness of the present invention highlights, and uses thermal dye sublimation transfer film of the present invention the easiest when transferring, and the requirement to transfer condition is extremely low.
Description
Technical field
The invention belongs to heat transfer film technical field, be specifically related to a kind of thermal dye sublimation transfer film and preparation method thereof.
Background technology
In general, utilize existing transfer film, be to be transferred by vac sorb and high temperature (200 DEG C ~ 240 DEG C),
Or transfer under High Temperature High Pressure.Above-mentioned existing technology needs air vacuum, ratio more complicated, and is limited to one and is transferred film
Carrying out transcription, working performance is the lowest, and productivity is restricted.Furthermore, it is desirable to the equipment needed for possessing air vacuum and equipment,
Cost is high, when carrying out transcription by vac sorb and high temperature, film damage often occurs, and transcription face deforms, texture etc.
Concentration class and definition decline, and fraction defective is high.Especially when transfer printing body is aluminum metallic material, after pickling, washing, at conversion
That manages is implemented thermal transfer primary coat and drying course by injection method on print face, by the contact of processed through sublimation heat transfer printing film vacuum
Under the state of squeezing, long-time heating the method compressed realize printing, in order to protect the heat of sublimation of above-mentioned processed through sublimation heat transfer printing to turn
Print layer, uses injection method to carry out strengthening application.Above-mentioned existing transfer film is the thin film of PET material, and these heat transfer films exist
In the thermal transfer stage, need to fall bonding layer by High Temperature High Pressure instant melting, so with the High Temperature High Pressure heating sheet back side.Therefore,
The shortcoming of heat transfer film that above-mentioned PET thin slice makes is: the problem not only existing PET thin slice melt-off under high temperature action, also needs
Protect the particularity being transferred film made by various physical property to exempt from damage, deformation and breakage, carry out instantaneous heat transfer, by force
Under big adhesion strength, printing effect is unstable, utilize existing heat transfer film, just cannot physical property different there is particularity
Applied heat hectographic printing product on transfer printing body, uses existing heat transfer film, it is necessary to just can be transferred to by High Temperature High Pressure by
Transfer article, it is impossible to avoid being printed the damage in face, deformation and breakage, especially, the problem of limited mass production.
Summary of the invention
The goal of the invention of the present invention is to provide a kind of thermal dye sublimation transfer film and preparation method thereof, this transfer film fast light
Property, resistance to water and scratch-proofness highlight.The present invention is by the following technical solutions: thermal dye sublimation transfer film, including base film layer, base film layer
Surface-coated has printing layer.The thickness of described base film layer is 25-50 μm, and the thickness of printing layer is 2-3 μm.The material of described base film layer
Matter is polyethylene terephthalate.Described printing layer is formed by pigment, resin, solvent and additive mixed dissolution, pigment,
Resin, solvent are 20-25:25-45:39-45:0.1-2 with the weight ratio of additive.Described pigment is inorganic pigment or organic face
Material, the granularity of pigment is 5-100nm；Described resin is polyurethane or acrylic；Described solvent is butanone, toluene, dimethylbenzene, ring
One in hexanone；Described additive is Ployethylene Wax, paraffin, cellulose acetate, polyurethane, acrylic, polyurethane acroleic acid
In one.The granularity of described pigment is 20-30nm.The preparation method of thermal dye sublimation transfer film, comprises the following steps: preparation printing
Layer, then by the surface of printing layer printing to base film layer.
By pigment, resin, solvent and additive mixed dissolution during the preparation of described printing layer.Utilize the distillation of the present invention
Transfer film to quoted body transfer when, comprise the following steps: heat sublimation, according to being quoted the size of body, is turned by (1)
Die is fabricated to base film layer in interior cylindrical conduit；(2) application transfer printing body, in the surface-coated polyurethane tree of transfer printing body
Fat, then dries 3-5 minute at a temperature of 180-200 DEG C, and the thickness of polyurethane resin coating is 70-100 μm；(3) by application
After the cylindrical conduit be made up of thermal dye sublimation transfer film of transfer printing body inserting step (1) in；(4) first at a temperature of 40-60 DEG C
The preheating 30-60 second, finally heat at a temperature of 160-180 DEG C and complete for 3-5 minute.The thermal dye sublimation transfer film light resistance of the present invention,
Resistance to water and scratch-proofness highlight, and use thermal dye sublimation transfer film of the present invention the easiest when transferring, and the requirement to transfer condition is extremely low.
Advantages below is there is: first, it is not necessary to vacuum, high temperature, condition of high voltage, Ke Yi when using the thermal dye sublimation transfer film transfer of the present invention
Under the conditions of low temperature (160 DEG C ~ 180 DEG C), transfer printing body is transferred, do not cause the loss of base film layer, can be with carrying out easily
Batch production, efficiency is more than 25-35 times of traditional method；Second, printing is clear, and fast light, resistance to water, scratch-proofness etc. highlight,
It is exposed in strong ultraviolet also variable color.
Detailed description of the invention
Thermal dye sublimation transfer film, including the base film layer of polyethylene terephthalate material, the surface-coated of base film layer has
Printing layer, the thickness of base film layer is 25 μm, and the thickness of printing layer is 2 μm, and printing layer is fine by pigment, polyurethane, butanone and acetic acid
Dimension element mixing, immersion, high speed dispersion are dissolved and are formed, and pigment, polyurethane, butanone are 20:25 with the weight ratio of cellulose acetate:
39:0.1.The light resistance of this transfer film, resistance to water and scratch-proofness reach following result after testing, and light resistance detects at 60 DEG C,
QUV fadometer tun is used to measure, it is desirable to transfer film can be tested by exposure in 200 hours and flawless appearance, delamination, fade or color
Become.Sample after 200 hours reaches 4 grades of standards of comparison of grey scale: ISOGreyScaleForCoiourChange；Water-fast
Property test according to GB-T1733-1993 standard, occur without loss of gloss, variable color, bubble, wrinkling, come off phenomenon of getting rusty；Scratch-proofness BY
Type pencil hardometer detection hardness reaches >=2H.
Claims (3)
1. a thermal dye sublimation transfer film, it is characterised in that: including base film layer, the surface-coated of base film layer has printing layer.
2. thermal dye sublimation transfer film as claimed in claim 1, it is characterised in that: the thickness of described base film layer is 25-50 μm, printing
The thickness of layer is 2-3 μm.
3. thermal dye sublimation transfer film as claimed in claim 1 or 2, it is characterised in that: described printing layer is by pigment, resin, solvent
Forming with additive mixed dissolution, pigment, resin, solvent are 20-25:25-45:39-45:0.1-2 with the weight ratio of additive.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610526998.8A CN106183514A (en) | 2016-07-06 | 2016-07-06 | A kind of thermal dye sublimation transfer film and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610526998.8A CN106183514A (en) | 2016-07-06 | 2016-07-06 | A kind of thermal dye sublimation transfer film and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106183514A true CN106183514A (en) | 2016-12-07 |
Family
ID=57464926
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610526998.8A Pending CN106183514A (en) | 2016-07-06 | 2016-07-06 | A kind of thermal dye sublimation transfer film and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106183514A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111169193A (en) * | 2018-11-13 | 2020-05-19 | 苏州赛伍应用技术股份有限公司 | A kind of transfer glue for photovoltaic cell silver paste gravure printing process, transfer film and preparation method and application thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09248973A (en) * | 1996-03-18 | 1997-09-22 | General Kk | Thermal transfer medium, overcoat transfer medium, and printing method |
| CN1383992A (en) * | 2001-04-17 | 2002-12-11 | 韩国化学株式会社 | Hot transfer piece and its making process |
| CN2562976Y (en) * | 2002-08-19 | 2003-07-30 | 澄海市东田转印有限公司 | Transfer printing film |
| EP2010838A2 (en) * | 2006-04-20 | 2009-01-07 | BSH Bosch und Siemens Hausgeräte GmbH | System for securing furniture and implements that risk tilting |
| CN202192865U (en) * | 2011-05-27 | 2012-04-18 | 汕头市丽葵玩具有限公司 | Transfer printing film |
| CN102582310A (en) * | 2012-02-22 | 2012-07-18 | 焦作市卓立烫印材料有限公司 | Thermal dye sublimation transfer film and preparation method thereof |
| CN102795014A (en) * | 2012-08-21 | 2012-11-28 | 曹欣纪 | Stereoscopic thermal transfer membrane and preparation method and thermal transfer method thereof |
-
2016
- 2016-07-06 CN CN201610526998.8A patent/CN106183514A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09248973A (en) * | 1996-03-18 | 1997-09-22 | General Kk | Thermal transfer medium, overcoat transfer medium, and printing method |
| CN1383992A (en) * | 2001-04-17 | 2002-12-11 | 韩国化学株式会社 | Hot transfer piece and its making process |
| CN2562976Y (en) * | 2002-08-19 | 2003-07-30 | 澄海市东田转印有限公司 | Transfer printing film |
| EP2010838A2 (en) * | 2006-04-20 | 2009-01-07 | BSH Bosch und Siemens Hausgeräte GmbH | System for securing furniture and implements that risk tilting |
| CN202192865U (en) * | 2011-05-27 | 2012-04-18 | 汕头市丽葵玩具有限公司 | Transfer printing film |
| CN102582310A (en) * | 2012-02-22 | 2012-07-18 | 焦作市卓立烫印材料有限公司 | Thermal dye sublimation transfer film and preparation method thereof |
| CN102795014A (en) * | 2012-08-21 | 2012-11-28 | 曹欣纪 | Stereoscopic thermal transfer membrane and preparation method and thermal transfer method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111169193A (en) * | 2018-11-13 | 2020-05-19 | 苏州赛伍应用技术股份有限公司 | A kind of transfer glue for photovoltaic cell silver paste gravure printing process, transfer film and preparation method and application thereof |
| CN111169193B (en) * | 2018-11-13 | 2022-05-24 | 苏州赛伍应用技术股份有限公司 | Application of transfer film in transferring silver paste to photovoltaic cell piece through gravure printing |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20161207 |
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| WD01 | Invention patent application deemed withdrawn after publication |