CN106121604B - It is a kind of to utilize CO2Drive away the method for coal-bed gas and residual gas with modified water - Google Patents
It is a kind of to utilize CO2Drive away the method for coal-bed gas and residual gas with modified water Download PDFInfo
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 238000000034 method Methods 0.000 title claims abstract description 19
- 239000003245 coal Substances 0.000 claims abstract description 66
- 238000000605 extraction Methods 0.000 claims abstract description 30
- 238000002347 injection Methods 0.000 claims description 34
- 239000007924 injection Substances 0.000 claims description 34
- 238000005553 drilling Methods 0.000 claims description 24
- 239000007788 liquid Substances 0.000 claims description 13
- 239000007864 aqueous solution Substances 0.000 claims description 10
- 239000011259 mixed solution Substances 0.000 claims description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 5
- 238000005086 pumping Methods 0.000 claims description 5
- 239000000243 solution Substances 0.000 claims description 2
- 230000037452 priming Effects 0.000 claims 4
- 239000012530 fluid Substances 0.000 claims 1
- 230000002045 lasting effect Effects 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 238000003325 tomography Methods 0.000 claims 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract description 24
- 238000006073 displacement reaction Methods 0.000 abstract description 20
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract description 12
- 239000001569 carbon dioxide Substances 0.000 abstract description 4
- 230000035699 permeability Effects 0.000 abstract description 3
- 239000007789 gas Substances 0.000 description 70
- 239000011261 inert gas Substances 0.000 description 3
- 241000439496 Varanus dumerilii Species 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000005065 mining Methods 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
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- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
- E21B43/164—Injecting CO2 or carbonated water
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- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
- E21B43/20—Displacing by water
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Abstract
本发明公开了一种利用CO2和改性水驱除煤层瓦斯及残余气体的方法,采用三个阶段进行瓦斯及残余气体的驱除分别为:常规瓦斯抽采阶段,气相驱替阶段和水力驱替阶段;先进行瓦斯抽采,然后进行气相驱替阶段,最终水力驱替阶段;这样的方式能有效地提高煤层瓦斯的抽采效率,利用二氧化碳气体扩大了煤层瓦斯驱替的范围,提高了煤层的渗透性为水力驱替提供了便利条件,通过向煤层中注入改性水不仅吸收了煤层中多余的二氧化碳气体,又能深入煤体内部,提高煤层含水率。
The invention discloses a method for removing coal seam gas and residual gas by using CO2 and modified water. The removal of gas and residual gas is carried out in three stages: conventional gas extraction stage, gas phase displacement stage and hydraulic displacement stage; gas drainage is carried out first, followed by the gas phase displacement stage, and finally the hydraulic displacement stage; this method can effectively improve the extraction efficiency of coal seam gas, expand the scope of coal seam gas displacement by using carbon dioxide gas, and improve the coal seam gas displacement. The high permeability provides convenient conditions for hydraulic displacement. By injecting modified water into the coal seam, it not only absorbs the excess carbon dioxide gas in the coal seam, but also penetrates deep into the coal body to increase the water content of the coal seam.
Description
技术领域technical field
本发明涉及一种驱除煤层瓦斯及残余气体的方法,具体是一种利用CO2和改性水驱除煤层瓦斯及残余气体的方法。The invention relates to a method for driving coal seam gas and residual gas, in particular to a method for driving coal seam gas and residual gas by using CO2 and modified water.
背景技术Background technique
目前煤层瓦斯气体是煤层开采中的主要危险源,大量瓦斯气体的聚集容易造成煤与瓦斯突出事故,同时在煤层采掘过程中,煤层中瓦斯气体的逸出也是井下生产的危险因素,因此煤层瓦斯抽采是防治煤层瓦斯灾害的有效手段。At present, coal seam gas is the main source of danger in coal seam mining. The accumulation of a large amount of gas may easily cause coal and gas outburst accidents. Drainage is an effective means to prevent and control coal seam gas disasters.
为促进煤层瓦斯的高效抽采,大量技术人员提出了驱替煤层瓦斯,从而提高抽采效率,现行使用最为广泛的是水力驱替和惰性气体驱替。两者各有优缺点,水力驱替不仅能够驱替煤层中瓦斯气体,同时煤层水分增加有提高了煤层的强度同时也可以起到抑尘的作用,但是相比于气体,水分在煤层中的渗入能力较弱,因而水力驱替的有效范围并不理想,应用中钻孔间距较小施工量大。惰性气体(CO2)在驱除煤层瓦斯气体时效果较好,且影响范围较大。但是在瓦斯驱除过程中惰性气体又存留在煤层中,特别是吸附能力较强的CO2,该气体在煤层中吸附能力远超过瓦斯,造成了不可预知的二次隐患。如何高效驱除煤层中瓦斯气体,又不产生二次隐患成为了煤矿灾害防治的重点研究工作。由此可见,既能高效驱替煤层瓦斯又可以避免二次隐患的科学方法,能为煤层瓦斯防治工作提供有效的技术支持。In order to promote the efficient extraction of coal seam gas, a large number of technicians have proposed displacement of coal seam gas to improve the extraction efficiency. Currently, hydraulic displacement and inert gas displacement are the most widely used methods. Both have their own advantages and disadvantages. Hydraulic flooding can not only displace the gas in the coal seam, but also increase the strength of the coal seam and also play a role in dust suppression. However, compared with gas, the amount of water in the coal seam The infiltration capacity is weak, so the effective range of hydraulic displacement is not ideal, and the drilling space is small in the application, and the construction volume is large. Inert gas (CO 2 ) has a better effect in driving coal seam gas, and its influence range is larger. However, inert gas remains in the coal seam during the gas removal process, especially CO 2 , which has a strong adsorption capacity, which far exceeds the gas adsorption capacity in the coal seam, causing unpredictable secondary hidden dangers. How to efficiently drive out gas in coal seams without causing secondary hidden dangers has become a key research work for coal mine disaster prevention and control. It can be seen that scientific methods that can efficiently displace coal seam gas and avoid secondary hidden dangers can provide effective technical support for coal seam gas prevention and control.
发明内容Contents of the invention
针对上述现有技术存在的问题,本发明提供一种利用CO2和改性水驱除煤层瓦斯及残余气体的方法,不仅扩大了煤层瓦斯驱替的范围,提高煤层的渗透性为水力驱替提供便利条件;也通过水力驱替可吸收残余气体,避免二次隐患的发生。Aiming at the problems existing in the above-mentioned prior art, the present invention provides a method for driving coal seam gas and residual gas by using CO2 and modified water, which not only expands the scope of coal seam gas displacement, but also improves the permeability of coal seam to provide water power for hydraulic displacement. Convenient conditions; the residual gas can also be absorbed through hydraulic displacement to avoid the occurrence of secondary hidden dangers.
为了实现上述目的,本发明采用的技术方案是:该种利用CO2和改性水驱除煤层瓦斯及残余气体的方法,具体步骤为:In order to achieve the above object, the technical solution adopted in the present invention is: the method for utilizing CO and modified water to drive away coal seam gas and residual gas, the specific steps are:
A、在煤层中选择无断层及无涌出水的区域,测量该区域煤层内瓦斯原始压力值,向区域煤层内打设至少三个钻孔,各个钻孔之间相隔10m~15m,完成后对各个钻孔连接抽采系统进行瓦斯抽采;A. Select an area without faults and gushing water in the coal seam, measure the original gas pressure value in the coal seam in this area, and drill at least three drill holes into the coal seam in the area, and the distance between each drill hole is 10m~15m. Each borehole is connected to the drainage system for gas drainage;
B、在瓦斯抽采过程中监测并记录抽采出的瓦斯浓度值,当各个钻孔平均抽采瓦斯浓度降低至初始抽采瓦斯浓度的50%时,对各个钻孔间隔停止瓦斯抽采,将停止抽采的钻孔与注CO2装置连接,其余钻孔正常进行瓦斯抽采;B. During the gas drainage process, monitor and record the gas concentration value of the drainage. When the average gas concentration of each borehole is reduced to 50% of the initial gas concentration, stop the gas drainage for each borehole interval. Connect the borehole where the drainage is stopped to the CO 2 injection device, and the remaining boreholes are normally used for gas drainage;
C、开启注CO2装置向停止抽采的钻孔内注入CO2气体,其注气压力至少为该煤层瓦斯原始压力值的2倍,其余钻孔正常进行抽采工作;C. Turn on the CO 2 injection device to inject CO 2 gas into the borehole where the drainage is stopped, and the gas injection pressure is at least twice the original pressure value of the coal seam gas, and the remaining boreholes are normally drained;
D、监测并记录各个抽采钻孔中抽出的混合气体浓度值,当抽采出的混合气体中CO2气体浓度和CH4气体浓度比值升高至4:1时,关闭注CO2装置,其余钻孔正常进行抽采工作;D. Monitor and record the mixed gas concentration value extracted from each extraction borehole. When the ratio of CO2 gas concentration to CH4 gas concentration in the extracted mixed gas increases to 4:1, turn off the CO2 injection device. The rest of the boreholes are being drained normally;
E、拆除注CO2装置,将注CO2的钻孔与抽采系统连接后开始抽采工作,各个钻孔持续抽采直至CO2气体和CH4气体混合浓度降至抽采出气体的5%以下时,断开注CO2钻孔与抽采系统的连接,将注液装置与上述断开的钻孔连接,所述注液装置注入的水溶液为碱性混合溶液;E. Remove the CO 2 injection device, connect the CO 2 injection boreholes to the drainage system and start the drainage work, and continue to drain each borehole until the mixed concentration of CO 2 gas and CH 4 gas drops to 5% of the extracted gas When % is below, disconnect the injection CO The borehole is connected with the extraction system, and the liquid injection device is connected with the above-mentioned disconnected borehole, and the aqueous solution injected by the liquid injection device is an alkaline mixed solution;
F、注液装置采用低压缓注方式向钻孔内注水溶液,注水溶液压力为2MPa至4MPa,注水溶液量为该区域煤体质量的4%,所述该区域煤体质量为根据煤层厚度及该区域煤层范围得出该区域煤体体积乘以煤体密度,其余钻孔持续进行抽采工作;F, the liquid injection device adopts the low-pressure slow injection method to inject water into the borehole. The pressure of the water injection is 2MPa to 4MPa, and the water injection volume is 4% of the coal mass in this area. The coal mass in this area is based on the thickness of the coal seam and The range of coal seams in this area is obtained by multiplying the volume of coal in this area by the density of coal, and the remaining boreholes continue to carry out drainage work;
G、当持续抽采的钻孔出现液体渗出时,停止注液装置工作,断开注水溶液钻孔与注液装置的连接,将注水溶液钻孔连入抽采系统,开始进行抽采,所有钻孔持续抽采直至开始采掘该区域煤层时移除抽采系统。G. When liquid seeps out of the drill hole that is continuously pumped, stop the work of the liquid injection device, disconnect the connection between the water injection hole and the liquid injection device, connect the water injection hole to the drainage system, and start the pumping. Drainage continued in all boreholes until the drainage system was removed when mining began to mine the coal seam in the area.
进一步,所述碱性混合溶液为饱和的NaOH水溶液。Further, the alkaline mixed solution is a saturated NaOH aqueous solution.
进一步,所述各个钻孔之间相隔10m。Further, the distances between the various boreholes are 10m.
与现有技术相比,本发明采用三个阶段进行瓦斯及残余气体的驱除:常规瓦斯抽采阶段,气相驱替阶段和水力驱替阶段;先进行瓦斯抽采,然后进行气相驱替阶段,最终水力驱替阶段;这样的方式能有效地提高煤层瓦斯的抽采效率,利用二氧化碳气体扩大了煤层瓦斯驱替的范围,提高了煤层的渗透性为水力驱替提供了便利条件,通过向煤层中注入改性水不仅吸收了煤层中多余的二氧化碳气体,又能深入煤体内部,提高煤层含水率。Compared with the prior art, the present invention adopts three stages to remove gas and residual gas: conventional gas drainage stage, gas phase displacement stage and hydraulic displacement stage; gas drainage is carried out first, then gas phase displacement stage, The final hydraulic displacement stage; this method can effectively improve the extraction efficiency of coal seam gas, use carbon dioxide gas to expand the range of coal seam gas displacement, and improve the permeability of coal seams to provide convenient conditions for hydraulic displacement. Injecting modified water not only absorbs excess carbon dioxide gas in the coal seam, but also penetrates deep into the coal body to increase the water content of the coal seam.
附图说明Description of drawings
图1是本发明的施工位置示意图。Fig. 1 is the construction position schematic diagram of the present invention.
图中:1、煤层,2、岩层。In the figure: 1, coal seam, 2, rock formation.
具体实施方式Detailed ways
下面将对本发明作进一步说明。The present invention will be further described below.
实施例:如图1所示,本发明的具体步骤为:Embodiment: as shown in Figure 1, concrete steps of the present invention are:
A、在煤层中选择无断层及无涌出水的区域,测量该区域煤层内瓦斯原始压力值,向煤层内打设三个钻孔,分别为A钻孔、B钻孔和C钻孔,三个钻孔之间相隔10m~15m,完成后对三个钻孔连接抽采系统进行瓦斯抽采;A. Select an area without faults and gushing water in the coal seam, measure the original gas pressure value in the coal seam in this area, and drill three boreholes into the coal seam, namely A borehole, B borehole and C borehole. The distance between the two boreholes is 10m~15m. After completion, the three boreholes are connected to the drainage system for gas drainage;
B、在瓦斯抽采过程中监测并记录抽采出的瓦斯浓度值,当各个钻孔平均抽采瓦斯浓度降低至初始抽采瓦斯浓度的50%时,对A钻孔和C钻孔停止瓦斯抽采,将A钻孔和C钻孔与注CO2装置连接,B钻孔正常进行瓦斯抽采;B. During the process of gas drainage, monitor and record the gas concentration value of the drainage. When the average gas concentration of each drilling hole is reduced to 50% of the initial gas concentration, stop the gas for drilling A and C Drainage, connect borehole A and borehole C to the CO2 injection device, and borehole B is normally used for gas drainage;
C、开启注CO2装置向A钻孔和C钻孔内注入CO2气体,其注气压力至少为该煤层瓦斯原始压力值的2倍,B钻孔正常进行抽采工作;C. Turn on the CO 2 injection device to inject CO 2 gas into boreholes A and C, the gas injection pressure is at least twice the original pressure value of the coal seam gas, and the drainage work is carried out normally in borehole B;
D、监测并记录各个抽采钻孔中抽出的混合气体浓度值,当抽采出的混合气体中CO2气体浓度和CH4气体浓度比值升高至4:1时,关闭注CO2装置,B钻孔正常进行抽采工作;D. Monitor and record the mixed gas concentration value extracted from each extraction borehole. When the ratio of CO2 gas concentration to CH4 gas concentration in the extracted mixed gas increases to 4:1, turn off the CO2 injection device. Borehole B is normally drained;
E、拆除注CO2装置,将A钻孔和C钻孔与抽采系统连接后开始抽采工作,三个钻孔持续抽采直至CO2气体和CH4气体混合浓度降至抽采出气体的5%以下时,断开A钻孔和C钻孔与抽采系统的连接,将注液装置与A钻孔和C钻孔连接,所述注液装置注入的水溶液为碱性混合溶液;E. Remove the CO 2 injection device, connect borehole A and borehole C to the drainage system and start the drainage work, and the three boreholes will continue to drain until the mixed concentration of CO 2 gas and CH 4 gas decreases to the extracted gas When below 5%, disconnect the A borehole and C borehole and the connection of the extraction system, connect the liquid injection device with the A borehole and the C borehole, and the aqueous solution injected by the liquid injection device is an alkaline mixed solution;
F、注液装置采用低压缓注方式向A钻孔和C钻孔内注水溶液,注水溶液压力为2MPa至4MPa,注水溶液量为该区域煤体质量的4%,所述该区域煤体质量为根据煤层厚度及该区域煤层范围得出该区域煤体体积乘以煤体密度,B钻孔持续进行抽采工作;F. The liquid injection device uses a low-pressure slow injection method to inject water into the A borehole and the C borehole. The pressure of the water injection is 2MPa to 4MPa, and the water injection volume is 4% of the coal mass in this area. The coal mass in this area is In order to obtain the coal body volume in the area multiplied by the coal body density according to the thickness of the coal seam and the range of the coal seam in the area, the B borehole continues to carry out drainage work;
G、当B钻孔持续抽采出现液体渗出时,停止注液装置工作,断开A钻孔和C钻孔与注液装置的连接,将A钻孔和C钻孔连入抽采系统,开始进行抽采,三个钻孔持续抽采直至开始采掘该区域煤层时移除抽采系统。G. When the liquid seeps out in the continuous drainage of borehole B, stop the liquid injection device, disconnect the connection between borehole A and borehole C and the liquid injection device, and connect borehole A and borehole C into the drainage system , the drainage was started, and the three boreholes continued to drain until the drainage system was removed when the coal seam in the area began to be mined.
进一步,所述碱性混合溶液为饱和的NaOH水溶液。Further, the alkaline mixed solution is a saturated NaOH aqueous solution.
进一步,所述三个钻孔之间相隔10m。Further, the three boreholes are separated by 10m.
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CN113550784B (en) * | 2021-03-31 | 2022-05-24 | 湖南科技大学 | Method for extracting high-sulfur coal seam gas and treating hydrogen sulfide through acid-base synergy |
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