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CN106118081A - A kind of low rolling resistance tire tread compound - Google Patents

A kind of low rolling resistance tire tread compound Download PDF

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Publication number
CN106118081A
CN106118081A CN201610683228.4A CN201610683228A CN106118081A CN 106118081 A CN106118081 A CN 106118081A CN 201610683228 A CN201610683228 A CN 201610683228A CN 106118081 A CN106118081 A CN 106118081A
Authority
CN
China
Prior art keywords
parts
tire tread
rolling resistance
white carbon
low rolling
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610683228.4A
Other languages
Chinese (zh)
Inventor
刘先春
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sichuan Yuanxing Rubber Co Ltd
Original Assignee
Sichuan Yuanxing Rubber Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sichuan Yuanxing Rubber Co Ltd filed Critical Sichuan Yuanxing Rubber Co Ltd
Priority to CN201610683228.4A priority Critical patent/CN106118081A/en
Publication of CN106118081A publication Critical patent/CN106118081A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0016Compositions of the tread
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/80Technologies aiming to reduce greenhouse gasses emissions common to all road transportation technologies
    • Y02T10/86Optimisation of rolling resistance, e.g. weight reduction 

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Tires In General (AREA)

Abstract

The present invention relates to a kind of low rolling resistance tire tread compound, belong to tyre stock formula technique field.The tire tread compound of the present invention includes: natural rubber 25 parts, 36 points of butadiene-styrene rubber, 0.1 0.5 parts of phenolic resin, epoxy resin 12 parts, stearic acid 24 parts, 24 parts of wax, 13 parts of age resistor, white carbon black N330 21 35 parts, white carbon 27 parts, 0.5 1 parts of sulfur, accelerator 1.5 2.5 parts, aromatic naphtha 15 35 parts, hard (china) clay 4 15 parts.The present invention, by rational formula combination, reduces white carbon black ratio in system, it is possible to tire finished product resistance to rolling in use is greatly lowered, and does not interferes with the anti-wear performance of tire tread.

Description

A kind of low rolling resistance tire tread compound
Technical field
The present invention relates to a kind of tyre stock, it is more particularly related to a kind of low rolling resistance tire tread compound, belong to In tyre stock formula technique field.
Background technology
Tire is the annular elastic rubber product rolled at various vehicles or the ground connection mechanically assembled.It is typically mounted on On metal wheel hub, vehicle body can be supported, buffer foreign impacts, it is achieved with the driving performance contacting and ensureing vehicle on road surface.Tire Often using under exacting terms complicated, it subjects various deformation, load, power and high/low temperature effect in motion, because of This must have higher load-carrying properties, hauling ability, shock-absorbing capacity.Meanwhile, also require possess high-wearing feature and flexible resistance, And low resistance to rolling and heat generation.The world consumes the half of rubber mass for tire production, it is seen that tire consumes rubber Ability.
Tire drag is the least, and automobile resistance to be resisted is the least, it is possible to reduce oil consumption.Low rolling resistance is on the one hand Can start with from the structure of tire tread, on the other hand can also start with from the formula of tire tread is optimized, to realize wheel The performance of tire low rolling resistance.
State Intellectual Property Office discloses Publication No. CN105778177A in 2016.7.20, entitled " a kind of super Tread mix and preparation method thereof of low rolling resistance passenger vehicle tyre " invention, the tyre surface of this invention ultralow rolling resistance passenger vehicle tyre Sizing material and preparation method thereof, in parts by weight, including rare earth cis-butadiene cement 15-25 part, Butadiene-Styrene Rubber 34.5-62 part, Two Butadiene-Styrene Rubber 40-50 parts, white carbon black 20-30 part, white carbon 35-45 part, softening agent 5-9 part, activating agent 5-6 part, age resistor 3-4 part, fall rolling resist 2.8-3.2 part, coupling agent 5.6-7.2 part and vulcanizing agent 3.3-3.5 part.The tread mix of the present invention is selected State-of-the-art double terminal-modified Butadiene-Styrene Rubber SLR, and use in sizing compound formula at high proportion, it is effectively reduced rolling resistance Power;Reinforcement system mainly uses high-performance, high-dispersion white carbon black.Can effectively reduce resistance to rolling;Use special material is anti-slippery Rolling resist, reduces resistance to rolling.Use above-mentioned formula and preparation method, the rolling of prepared tire resistive can A level and more than.
State Intellectual Property Office discloses Publication No. CN104844863A in 2015.8.19, entitled " a kind of high Performance environmental protection half green tire formula " invention, this invention ultralow rolling resistance discloses a kind of high-performance environment-friendly half green tire and joins Side, including the component of following parts by weight: Butadiene-Styrene Rubber SSBR3835,96-120 part;BR9000,15-30 part;High dispersive is white White carbon black, 40-60 part;N220 white carbon black, 20-30 part;Coupling agent TESPT, 6-9 part;Environment-friendly aromatic oil, 9-15 part;Green tire is special Materials, 8-10 part;Stearic acid, 1-3 part;Zinc oxide, 2.5-5 part;Octyl group tackifying resin, 1-3 part;Anti-aging agent RD, 1-2.5 part; Antioxidant 4020,1.5-3 part;Microcrystalline wax, 1-3 part;Accelerator NS, 1.2-2 part;Diphenylguanidine PG, 1-2.5 part;Accelerator DM, 0.5-1.5 part;Common sofril, 1.8-2.5 part, functional master batch for green tires, 8-10 part.The high-performance environment-friendly of the present invention Half green tire, it is possible to realizing grabbing ground safety and the dual excellent specific property of low rolling resistance fuel-economizing, it can overcome and surmount Linesless charcoal Black many technological problemses and performance issue, can significantly improve grasp property of wet and slippery ground and reduce resistance to rolling;Green at car half Applying in colour wheel tire tread, resistance to rolling improves 18.66%, anti-slippery raising 15.52%.
Above two tire formulation can make the rolling resistance of tire reduce to a certain extent, but this performance boost is also Inconspicuous, and while reducing tire rolling resistance, the anti-wear performance of tire tread can be affected.
Summary of the invention
Present invention seek to address that in prior art, the low rolling resistance performance boost of low rolling resistance tire is inconspicuous, and tire can be affected The problem of the anti-wear performance of tyre surface, it is provided that a kind of low rolling resistance tire tread compound, it is possible to tire finished product is greatly lowered and is using Time resistance to rolling, and do not interfere with the anti-wear performance of tire tread.
In order to realize foregoing invention purpose, its concrete technical scheme is as follows:
A kind of low rolling resistance tire tread compound, it is characterised in that: include following raw materials by weight:
Natural rubber 2-5 part
Butadiene-styrene rubber 3-6 divides
Phenolic resin 0.1-0.5 part
Epoxy resin 1-2 part
Stearic acid 2-4 part
Wax 2-4 part
Age resistor 1-3 part
White carbon black N330 21-35 part
White carbon 2-7 part
Sulfur 0.5-1 part
Accelerator 1.5-2.5 part
Aromatic naphtha 15-35 part
Hard (china) clay 4-15 part.
Preferably, a kind of low rolling resistance tire tread compound, it is characterised in that: include following in parts by weight former Material:
Natural rubber 4.5 parts
3.5 points of butadiene-styrene rubber
0.2 part of phenolic resin
Epoxy resin 1.3 parts
Stearic acid 2.6 parts
3 parts of wax
1 part of age resistor
White carbon black N330 25 parts
White carbon 6 parts
0.75 part of sulfur
Accelerator 2.1 parts
Aromatic naphtha 33 parts
Hard (china) clay 10 parts.
Age resistor of the present invention is anti-aging agent RD and the antioxidant A W of arbitrary proportion combination.
The ratio of above-mentioned anti-aging agent RD and antioxidant A W is 1:1-6.
Accelerator of the present invention is DTDM.
The Advantageous Effects that the present invention brings:
1, during the present invention solves prior art, the low rolling resistance performance boost of low rolling resistance tire is inconspicuous, and can affect tire tread The problem of anti-wear performance, it is provided that a kind of low rolling resistance tire tread compound, by rational formula combination, reduce white carbon black in system In ratio, it is possible to tire finished product resistance to rolling in use is greatly lowered, and does not interferes with the wearability of tire tread Energy.
2, currently preferred, age resistor of the present invention is anti-aging agent RD and the antioxidant A W of arbitrary proportion combination. The ratio of above-mentioned anti-aging agent RD and antioxidant A W is 1:1-6.Above-mentioned being preferable to provide can improve reduction tire tread further The performance of rolling resistance, and while not affecting anti-wear performance, improve anti-wear performance on the contrary.
3, currently preferred, accelerator of the present invention is DTDM.Above-mentioned being preferable to provide can be improved further Reduce the performance of tire tread rolling resistance, and while not affecting anti-wear performance, improve anti-wear performance on the contrary.
Detailed description of the invention
Embodiment 1
A kind of low rolling resistance tire tread compound, including following raw materials by weight:
Natural rubber 2 parts
3 points of butadiene-styrene rubber
0.1 part of phenolic resin
Epoxy resin 1 part
Stearic acid 2 parts
2 parts of wax
1 part of age resistor
White carbon black N330 21 parts
White carbon 2 parts
0.5 part of sulfur
Accelerator 1.5 parts
Aromatic naphtha 15 parts
Hard (china) clay 4 parts.
Embodiment 2
A kind of low rolling resistance tire tread compound, including following raw materials by weight:
Natural rubber 5 parts
6 points of butadiene-styrene rubber
0.5 part of phenolic resin
Epoxy resin 2 parts
Stearic acid 4 parts
4 parts of wax
3 parts of age resistor
White carbon black N330 35 parts
White carbon 7 parts
1 part of sulfur
Accelerator 2.5 parts
Aromatic naphtha 35 parts
Hard (china) clay 15 parts.
Embodiment 3
A kind of low rolling resistance tire tread compound, including following raw materials by weight:
Natural rubber 3.5 parts
4.5 points of butadiene-styrene rubber
0.3 part of phenolic resin
Epoxy resin 1.5 parts
Stearic acid 3 parts
3 parts of wax
2 parts of age resistor
White carbon black N330 28 parts
White carbon 4.5 parts
0.75 part of sulfur
Accelerator 2 parts
Aromatic naphtha 25 parts
Hard (china) clay 9.5 parts.
Embodiment 4
A kind of low rolling resistance tire tread compound, including following raw materials by weight:
Natural rubber 2.5 parts
4 points of butadiene-styrene rubber
0.22 part of phenolic resin
Epoxy resin 1.78 parts
Stearic acid 3.15 parts
2.2 parts of wax
2.8 parts of age resistor
White carbon black N330 25 parts
White carbon 5.5 parts
0.9 part of sulfur
Accelerator 1.8 parts
Aromatic naphtha 16 parts
Hard (china) clay 13 parts.
Embodiment 5
A kind of low rolling resistance tire tread compound, including following raw materials by weight:
Natural rubber 4.5 parts
3.5 points of butadiene-styrene rubber
0.2 part of phenolic resin
Epoxy resin 1.3 parts
Stearic acid 2.6 parts
3 parts of wax
1 part of age resistor
White carbon black N330 25 parts
White carbon 6 parts
0.75 part of sulfur
Accelerator 2.1 parts
Aromatic naphtha 33 parts
Hard (china) clay 10 parts.
Embodiment 6
On the basis of embodiment 1-5:
Preferably, described age resistor is anti-aging agent RD and the antioxidant A W of arbitrary proportion combination.
Further, the ratio of described anti-aging agent RD and antioxidant A W is 1:1.
Preferably, described accelerator is DTDM.
Embodiment 7
On the basis of embodiment 1-5:
Preferably, described age resistor is anti-aging agent RD and the antioxidant A W of arbitrary proportion combination.
Further, the ratio of described anti-aging agent RD and antioxidant A W is 1:6.
Preferably, described accelerator is DTDM.
Embodiment 8
On the basis of embodiment 1-5:
Preferably, described age resistor is anti-aging agent RD and the antioxidant A W of arbitrary proportion combination.
Further, the ratio of described anti-aging agent RD and antioxidant A W is 1:3.5.
Preferably, described accelerator is DTDM.
Embodiment 9
On the basis of embodiment 1-5:
Preferably, described age resistor is anti-aging agent RD and the antioxidant A W of arbitrary proportion combination.
Further, the ratio of described anti-aging agent RD and antioxidant A W is 1:5.
Preferably, described accelerator is DTDM.

Claims (5)

1. one kind low rolling resistance tire tread compound, it is characterised in that: include following raw materials by weight:
Natural rubber 2-5 part
Butadiene-styrene rubber 3-6 divides
Phenolic resin 0.1-0.5 part
Epoxy resin 1-2 part
Stearic acid 2-4 part
Wax 2-4 part
Age resistor 1-3 part
White carbon black N330 21-35 part
White carbon 2-7 part
Sulfur 0.5-1 part
Accelerator 1.5-2.5 part
Aromatic naphtha 15-35 part
Hard (china) clay 4-15 part.
One the most according to claim 1 low rolling resistance tire tread compound, it is characterised in that: include following according to weight portion The raw material of number meter:
Natural rubber 4.5 parts
3.5 points of butadiene-styrene rubber
0.2 part of phenolic resin
Epoxy resin 1.3 parts
Stearic acid 2.6 parts
3 parts of wax
1 part of age resistor
White carbon black N330 25 parts
White carbon 6 parts
0.75 part of sulfur
Accelerator 2.1 parts
Aromatic naphtha 33 parts
Hard (china) clay 10 parts.
One the most according to claim 1 and 2 low rolling resistance tire tread compound, it is characterised in that: described age resistor is The anti-aging agent RD of arbitrary proportion combination and antioxidant A W.
One the most according to claim 3 low rolling resistance tire tread compound, it is characterised in that: described anti-aging agent RD is old with anti- The ratio of agent AW is 1:1-6.
One the most according to claim 1 and 2 low rolling resistance tire tread compound, it is characterised in that: described accelerator is DTDM。
CN201610683228.4A 2016-08-18 2016-08-18 A kind of low rolling resistance tire tread compound Pending CN106118081A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610683228.4A CN106118081A (en) 2016-08-18 2016-08-18 A kind of low rolling resistance tire tread compound

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610683228.4A CN106118081A (en) 2016-08-18 2016-08-18 A kind of low rolling resistance tire tread compound

Publications (1)

Publication Number Publication Date
CN106118081A true CN106118081A (en) 2016-11-16

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610683228.4A Pending CN106118081A (en) 2016-08-18 2016-08-18 A kind of low rolling resistance tire tread compound

Country Status (1)

Country Link
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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102675694A (en) * 2011-03-17 2012-09-19 住友橡胶工业株式会社 Rubber composition for bead apex, and pneumatic tire
CN103073755A (en) * 2012-12-31 2013-05-01 特拓(青岛)轮胎技术有限公司 Rubber composition for producing wet-skid resistant tire tread
CN104311905A (en) * 2014-11-07 2015-01-28 无锡宝通带业股份有限公司 Wear resistant conveying belt primer with low rolling resistance and preparation method thereof
CN104448425A (en) * 2014-12-25 2015-03-25 北京彤程创展科技有限公司 Rubber composition and tire utilizing same
CN105418994A (en) * 2015-12-17 2016-03-23 山东永泰集团有限公司 Wear resistance tire tread rubber and production method thereof
CN105418993A (en) * 2015-12-17 2016-03-23 山东永泰集团有限公司 Tread rubber of radial tire
CN105524305A (en) * 2015-12-17 2016-04-27 山东永泰集团有限公司 Tread rubber for engineering tire

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102675694A (en) * 2011-03-17 2012-09-19 住友橡胶工业株式会社 Rubber composition for bead apex, and pneumatic tire
CN103073755A (en) * 2012-12-31 2013-05-01 特拓(青岛)轮胎技术有限公司 Rubber composition for producing wet-skid resistant tire tread
CN104311905A (en) * 2014-11-07 2015-01-28 无锡宝通带业股份有限公司 Wear resistant conveying belt primer with low rolling resistance and preparation method thereof
CN104448425A (en) * 2014-12-25 2015-03-25 北京彤程创展科技有限公司 Rubber composition and tire utilizing same
CN105418994A (en) * 2015-12-17 2016-03-23 山东永泰集团有限公司 Wear resistance tire tread rubber and production method thereof
CN105418993A (en) * 2015-12-17 2016-03-23 山东永泰集团有限公司 Tread rubber of radial tire
CN105524305A (en) * 2015-12-17 2016-04-27 山东永泰集团有限公司 Tread rubber for engineering tire

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
张守昌 等: "295/75R22.5低滚动阻力轮胎胎面胶配方的研究", 《橡胶科技》 *

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Application publication date: 20161116