CN105524305A - Tread rubber for engineering tire - Google Patents
Tread rubber for engineering tire Download PDFInfo
- Publication number
- CN105524305A CN105524305A CN201510947851.1A CN201510947851A CN105524305A CN 105524305 A CN105524305 A CN 105524305A CN 201510947851 A CN201510947851 A CN 201510947851A CN 105524305 A CN105524305 A CN 105524305A
- Authority
- CN
- China
- Prior art keywords
- rubber
- tread rubber
- carbon black
- tire tread
- engineering tire
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to tread rubber for an engineering tire. Under synergistic effect of components in the tread rubber, a rubber material has the advantages of high wear resistance, high fatigue resistance, aging resistance, high tensile strength, high elasticity and high strength and toughness. The tread rubber can enable the tire to effectively buffer impact and swinging during driving, so as to prevent laceration and puncture of a cord layer.
Description
Technical field
The invention belongs to tread rubber technical field, be specifically related to a kind of engineering tire tread rubber.
Background technology
Because natural rubber has best bond properties, and synthetic rubber has outstanding abrasion resistance, thus all-steel radial tyre tread rubber generally adopt natural rubber and synthetic rubber and rubber system.
Off-the-road tyre travel speed is low, load is large, haul distance is short, turning is frequent, its tread rubber general requirement cut resistant, resistance to puncture, anti-collapse use up block, abrasion performance, good springiness, hardness high, be out of shape little, heat-dissipating is low.Based on the over-all properties that natural rubber is good, although the prices of raw and semifnished materials are high, traditional off-the-road tyre tread rubber composition majority still adopts All Pure Nature rubber, or with styrene-butadiene rubber(SBR) in 70/30 ratio and use.In fact, theoretical and test all shows, natural rubber for improving the abrasion performance of tread mix, cut resistant, resistance to puncture, anti-collapsing use up block performance and reduce the aspects such as distortion, contribute not remarkable, its advantage is mainly good processing characteristics and lower hysteresis loss, and these characteristics all by equipment and processing and manufacturing technology and reasonably Design of Tire Structure made up.Although adding of styrene-butadiene rubber(SBR) can provide good belt cutting-resisting property for tread rubber, its heat-dissipating is higher, and speed of response is slow, and wear resisting property is slightly poor.
Summary of the invention
In order to solve above-mentioned technical problem, the invention provides a kind of engineering tire tread rubber.By being optimized the raw material of tire tread glue and ratio and adjusting, meet tire tread cut resistant, anti-collapse use up block while, improve its wear resisting property, improve the work-ing life of tire dramatically.
A kind of engineering tire tread rubber of the present invention is realized by following technical scheme:
Described tread rubber comprises the component of following portions by weight:
Natural rubber 70-90 polybutadiene rubber 10-50
Solution polymerized butadiene styrene rubber 10-50 silane coupling agent Si-691-4
Stearic acid 1-4 sulphur 1-4
Carbon black 10-50 white carbon black 7-15
Plasticizer A 1-4 resol resin 1-4
Zinc oxide 1-8 anti-aging agent 1-10
Anti-recovery agent WK-9011-4 altax 0.5-2
Accelerant CZ 0.5-3.
Described natural rubber is 1# smoke sheet rubber or 3# smoke sheet rubber.
Described carbon black is N115 and N234.
Carbon black N115, N234 mix according to the ratio of weight ratio 1:1.
Described described anti-aging agent is anti-aging agent RD and antioxidant 4020.
Anti-aging agent RD and antioxidant 4020 mix according to the ratio of weight ratio 2:1.
Described described white carbon black is the precipitated silica of particle diameter 20-100nm.
Described a kind of engineering tire tread rubber, is grouped into by following one-tenth by weight:
Natural rubber 70 polybutadiene rubber 10
Solution polymerized butadiene styrene rubber 20 silane coupling agent Si-691.6
Stearic acid 1.5 sulphur 2
Carbon black 50 white carbon black 10
Plasticizer A 2 resol resin 1.5
Zinc oxide 4 anti-aging agent 1.5
Anti-recovery agent WK-9011.2 altax 1.5
Accelerant CZ 1.
Beneficial effect of the present invention is, tread rubber of the present invention, tire wear, resistance to deterioration are good, the mixing of the natural rubber adopted, polybutadiene rubber, solution polymerized butadiene styrene rubber, by being optimized the raw material of tire tread glue and ratio and adjusting, meet tire tread cut resistant, anti-collapse use up block while, improve its wear resisting property, improve the work-ing life of tire dramatically.
Embodiment
Below in conjunction with specific embodiment, the present invention is further described, so that those skilled in the art more understands the present invention, but does not therefore limit the present invention.
Embodiment 1
A kind of engineering tire tread rubber, is made up of following component by weight:
Natural rubber 70 polybutadiene rubber 10
Solution polymerized butadiene styrene rubber 20 silane coupling agent Si-691.6
Stearic acid 1.5 sulphur 2
Carbon black 50 white carbon black 10
Plasticizer A 2 resol resin 1.5
Zinc oxide 4 anti-aging agent 1.5
Anti-recovery agent WK-9011.2 altax 1.5
Accelerant CZ 1.
Described natural rubber is 1# smoke sheet rubber or 3# smoke sheet rubber.
Described carbon black is N115 and N234.
Carbon black N115, N234 mix according to the ratio of weight ratio 1:1.
Described described anti-aging agent is anti-aging agent RD and antioxidant 4020.
Anti-aging agent RD and antioxidant 4020 mix according to the ratio of weight ratio 2:1.
Described described white carbon black is the precipitated silica of particle diameter 20-100nm.
After testing, 80 weeks abrasion performance (the Pico)/cm of the tread rubber sizing material in the present embodiment
3for 0.0020-0.0027;
300% stress at definite elongation reaches 32.2Mpa; Hardness is 76 Shao Er; Tensile strength at yield is 26.8MPa; Tensile yield is 590%; Compression heat generation is 34 DEG C; Cut resistant decrement is less than 1.2g.
Claims (8)
1. an engineering tire tread rubber, is characterized in that, described tread rubber comprises the component of following portions by weight:
Natural rubber 20-90 polybutadiene rubber 10-50
Solution polymerized butadiene styrene rubber 10-50 silane coupling agent Si-691-4
Stearic acid 1-4 sulphur 1-4
Carbon black 10-50 white carbon black 7-15
Plasticizer A 1-4 resol resin 1-4
Zinc oxide 1-8 anti-aging agent 1-10
Anti-recovery agent WK-9011-4 altax 0.5-2
Accelerant CZ 0.5-3.
2. a kind of engineering tire tread rubber according to claim 1, is characterized in that, described natural rubber is 1# smoke sheet rubber or 3# smoke sheet rubber.
3. a kind of engineering tire tread rubber according to claim 2, is characterized in that, described carbon black is N115 and N234.
4. a kind of engineering tire tread rubber according to claim 3, is characterized in that, carbon black N115, N234 mix according to the ratio of weight ratio 1:1.
5. a kind of engineering tire tread rubber according to claim 4, is characterized in that, described described anti-aging agent is anti-aging agent RD and antioxidant 4020.
6. a kind of engineering tire tread rubber according to claim 5, is characterized in that, anti-aging agent RD and antioxidant 4020 mix according to the ratio of weight ratio 2:1.
7. a kind of engineering tire tread rubber according to claim 6, is characterized in that, described described white carbon black is the precipitated silica of particle diameter 20-100nm.
8. a kind of engineering tire tread rubber according to claim 7, is characterized in that, is grouped into by following one-tenth by weight:
Natural rubber 70 polybutadiene rubber 10
Solution polymerized butadiene styrene rubber 20 silane coupling agent Si-691.6
Stearic acid 1.5 sulphur 2
Carbon black 50 white carbon black 10
Plasticizer A 2 resol resin 1.5
Zinc oxide 4 anti-aging agent 1.5
Anti-recovery agent WK-9011.2 altax 1.5
Accelerant CZ 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510947851.1A CN105524305A (en) | 2015-12-17 | 2015-12-17 | Tread rubber for engineering tire |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510947851.1A CN105524305A (en) | 2015-12-17 | 2015-12-17 | Tread rubber for engineering tire |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105524305A true CN105524305A (en) | 2016-04-27 |
Family
ID=55766850
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510947851.1A Pending CN105524305A (en) | 2015-12-17 | 2015-12-17 | Tread rubber for engineering tire |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105524305A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106118081A (en) * | 2016-08-18 | 2016-11-16 | 四川远星橡胶有限责任公司 | A kind of low rolling resistance tire tread compound |
| CN108424552A (en) * | 2018-04-08 | 2018-08-21 | 贾中将 | A kind of rubber absorbers of high anti-reversion behaviour |
| CN110343295A (en) * | 2018-04-02 | 2019-10-18 | 住友橡胶工业株式会社 | Rubber composition for tire tread and tire |
| CN110872400A (en) * | 2018-09-04 | 2020-03-10 | 固特异轮胎和橡胶公司 | Pneumatic tire |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101440176A (en) * | 2008-12-24 | 2009-05-27 | 昊华南方(桂林)橡胶有限责任公司 | Giant engineering tire tread rubber and giant engineering tyre using the same |
| CN101735492A (en) * | 2010-01-22 | 2010-06-16 | 中国化工橡胶桂林有限公司 | Engineering tire tread rubber |
| CN102634088A (en) * | 2012-05-02 | 2012-08-15 | 三角轮胎股份有限公司 | Aging resistant and cracking resistant tread rubber composition of engineering tyre |
| CN103589014A (en) * | 2012-08-16 | 2014-02-19 | 山东玲珑轮胎股份有限公司 | Fully synthetic rubber tread compound for OTR tires |
| CN103980560A (en) * | 2014-03-13 | 2014-08-13 | 中国化工橡胶桂林有限公司 | High-wear-resistant engineering tire tread rubber |
| CN104356442A (en) * | 2014-11-20 | 2015-02-18 | 三角轮胎股份有限公司 | Articulated truck tire tread rubber composition and preparation method thereof |
-
2015
- 2015-12-17 CN CN201510947851.1A patent/CN105524305A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101440176A (en) * | 2008-12-24 | 2009-05-27 | 昊华南方(桂林)橡胶有限责任公司 | Giant engineering tire tread rubber and giant engineering tyre using the same |
| CN101735492A (en) * | 2010-01-22 | 2010-06-16 | 中国化工橡胶桂林有限公司 | Engineering tire tread rubber |
| CN102634088A (en) * | 2012-05-02 | 2012-08-15 | 三角轮胎股份有限公司 | Aging resistant and cracking resistant tread rubber composition of engineering tyre |
| CN103589014A (en) * | 2012-08-16 | 2014-02-19 | 山东玲珑轮胎股份有限公司 | Fully synthetic rubber tread compound for OTR tires |
| CN103980560A (en) * | 2014-03-13 | 2014-08-13 | 中国化工橡胶桂林有限公司 | High-wear-resistant engineering tire tread rubber |
| CN104356442A (en) * | 2014-11-20 | 2015-02-18 | 三角轮胎股份有限公司 | Articulated truck tire tread rubber composition and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106118081A (en) * | 2016-08-18 | 2016-11-16 | 四川远星橡胶有限责任公司 | A kind of low rolling resistance tire tread compound |
| CN110343295A (en) * | 2018-04-02 | 2019-10-18 | 住友橡胶工业株式会社 | Rubber composition for tire tread and tire |
| CN108424552A (en) * | 2018-04-08 | 2018-08-21 | 贾中将 | A kind of rubber absorbers of high anti-reversion behaviour |
| CN108424552B (en) * | 2018-04-08 | 2020-05-12 | 贾中将 | Rubber shock absorber with high reversion resistance |
| CN110872400A (en) * | 2018-09-04 | 2020-03-10 | 固特异轮胎和橡胶公司 | Pneumatic tire |
| CN110872400B (en) * | 2018-09-04 | 2022-03-04 | 固特异轮胎和橡胶公司 | Pneumatic tire |
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| PB01 | Publication | ||
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| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160427 |