CN106085574A - 用于钢板冷轧镀锌的可生物降解光整液 - Google Patents
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
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Abstract
用于钢板冷轧镀锌的可生物降解光整液，配方为：去离子水：88‑92％，脂肪酸酰胺：5‑10％，植物型油酸：2‑5％，改性嵌段聚醚：0.2‑0.6％；有优良的润湿、清洗性，有较好的防锈效果，无毒，有生物降解功能，节能环保，安全可靠，并且耐腐蚀，有绝缘性，产品稳定并且抗硬水，光整后的镀锌板表面清洁光滑，可以有效消除或减轻光整亮点缺陷，几乎没有镀层云纹缺陷。使用范围更广，有一定的防腐抗菌作用，适合在水质硬的地区使用。
Description
技术领域
本发明涉及IPC分类中C10M润滑组合物，尤其是用于钢板冷轧镀锌的可生物降解光整液。
背景技术
钢铁工业热镀锌板生产技术发展很快，其中包括钢板轧制的后处理工程CGL，热镀锌产品在汽车、家电领域使用广泛，表面质量与冷轧板和电镀锌板媲美，中国在热镀锌板生产产量上已成为世界第一生产大国。生产热镀锌板时，由于锌液成分、气刀或冷却风机控制不当，带钢表面有时会产生一些白色的镀层云纹，这种缺陷使板面看起来较花，直接影响镀锌板的表面质量，采用适当的光整工艺可以有效的减轻“镀层云纹”的缺陷。
热镀锌板光整工艺主要功能：1、消除低碳钢的屈服平台或使屈服平台不明显，从而防止镀锌板在随后的拉延或深冲加工时出现滑移线；2、改善板形，提高钢板平整度；3、能为热镀锌板表面提供一定的粗糙度，一方面可改善冲压性能，另一方面可提高漆膜的附着力和表面光洁度。
已公开的专利文献例如：
中国专利申请201410485145.5孝感市江雁化工有限公司公开涉及一种热镀锌板用光整液及其制备方法，由下述重量份的组分组成：组分一：水23～33份、二元酸5～8份、三元羧酸8～12份、三乙醇胺54～57份；组分二：水47～68份、碳酸钠4～8份、氢氧化钾3～5份、乙二胺四乙酸二钠2～4份、五水偏硅酸钠6～10份、反向嵌断聚醚8～12份、新癸酸6～8份、苯甲酸钠3～6份。此配方中，含有三乙醇胺，苯甲酸钠和KOH等对身体有毒害且不易生物降解的物质。
目前光整液多为一次性使用，产生大量的废液需要处理，给环境带来危害，也给钢厂增加了很多处理成本。
为了解决上述问题，一些企业进行了相应的研究，例如：
中国专利申请201020118215.0公开了一种镀锌线光整液过滤循环利用装置，包括光整液回收箱、光整液工作箱、过滤器、纸带过滤机、接液槽和喷头，轧机工作辊两侧分别设有光整液喷头和高压水喷头，光整液喷头和高压水喷头分别与光整液工作箱连接，高压水喷头和光整液工作箱之间的管路上设有高压水冲洗泵、纸带过滤机和过滤器，光整液工作箱出口侧设有光整液大流量泵，光整液工作箱与光整液回收箱连接，光整液回收箱出口侧设有补液泵，工作辊下方设有接液槽，接液槽与其下方的光整液回收箱连接。
这些技术仍然未涉及产品的废液污染危害问题。
发明内容
本发明的目的是提供一种用于钢板冷轧镀锌的可生物降解光整液，不但能够满足客户需要的一般润滑，防锈，清洗等加工性能，而且可以生物降解，为钢厂的后处理节约了成本，并保护了环境。
本发明的目的将通过以下技术措施来实现：配方为：
去离子水：88-92％
脂肪酸酰胺：5-10％
植物型油酸：2-5％
改性嵌段聚醚：0.2-0.6％
其中，脂肪酸酰胺为阴离子和非离子表面活性剂，改性嵌段聚醚为非离子表面活性剂；脂肪酸酰胺、植物型油酸和改性嵌段聚醚均可以生物降解。
尤其是，脂肪酸酰胺具有优秀的防锈性能和乳化清洗能力，且可以生物降解；植物型油酸无毒害，具有防锈性和润滑性，可以生物降解；改性嵌段聚醚，极少量添加便能有效提高产品的渗透，乳化和清洗能力，对铁粉等杂质具有优秀的沉降性能，保证清洗后钢板的表面光洁度；以上选用的原料均为有机原料，可以生物降解，且不含有苯环类等毒性物质。
本发明的优点和效果：有优良的润湿、清洗性，有较好的防锈效果，无毒，有生物降解功能，节能环保，安全可靠，并且耐腐蚀，有绝缘性，产品稳定并且抗硬水，光整后的镀锌板表面清洁光滑，可以有效消除或减轻光整亮点缺陷，几乎没有镀层云纹缺陷。使用范围更广，有一定的防腐抗菌作用，适合在水质硬的地区使用。
具体实施方式
本发明原理在于，优化选择好的优质原料，脂肪酸采用可生物降解的植物型油酸，表面活性剂采用可生物降解型的脂肪酸酰胺和改性聚醚，对比方案经过配方反复进行实验，确保同时兼顾发明目的包含的多项技术指标，而且控制成本最低化。
下面结合实施例对本发明作进一步说明。
实施例1：优选方案为：配方：
去离子水：87.5％
脂肪酸二乙醇酰胺：6.3％
新葵酸：2.0％
十八烯酸：0.7％
脂肪酸酰胺羧酸盐：2.8％
改性嵌段聚醚：0.7％
具体实施方法：
④在容器中加入去离子水44.5％、脂肪酸二乙醇酰胺6.3％、新葵酸酸2％，十八烯酸0.7％，加热搅拌15±5min，温度控制在50±5℃，确认透明；
⑤停止加热，加入去离子水43％，并搅拌10±5min，温度控制在35℃以下，确认透明；
⑥加入脂肪酸酰胺羧酸盐，改性嵌段聚醚0.7％，并搅拌15±5min，温度控制在35℃以下，确认透明，制得所述生物降解型高效光整液；
以上步骤均在常压下操作。
本发明实施例中，该组分制成的光整液，防锈功能、清洗功能、润滑和修复表面的功能，以及抑制泡沫的性能都较好，注重了对环境的保护，而且成本也较合理，有利于产生好的经济效益、社会效益和环境效益。
以上详细说明了本发明的实施方式，但这只是为了便于理解而举的实例，不应被视为是对本发明范围的限制。同样，任何所属技术领域的技术人员均可根据本发明的技术方案及其较佳实施例的描述，做出各种可能的等同改变或替换，但所有这些改变或替换都应属于本发明权利要求的保护范围。
Claims (2)
1.用于钢板冷轧镀锌的可生物降解光整液，其特征在于，配方为：
去离子水：88-92％
脂肪酸酰胺：5-10％
植物型油酸：2-5％
改性嵌段聚醚：0.2-0.6％
其中，选用的两款脂肪酸酰胺分别为阴离子型表面活性剂和非离子型表面活性剂，改性嵌段聚醚为非离子型表面活性剂；脂肪酸酰胺、植物型油酸和改性嵌段聚醚均可以生物降解。
2.如权利要求1所述的用于钢板冷轧镀锌的可生物降解光整液，其特征在于，配方：
去离子水：87.5％
脂肪酸二乙醇酰胺：6.3％
新葵酸：2.0％
十八烯酸：0.7％
脂肪酸酰胺羧酸盐：2.8％
改性嵌段聚醚：0.7％
具体实施方法：
①在容器中加入去离子水44.5％、脂肪酸二乙醇酰胺6.3％、新葵酸酸2％，十八烯酸0.7％，加热搅拌15±5min，温度控制在50±5℃，确认透明；
②停止加热，加入去离子水43％，并搅拌10±5min，温度控制在35℃以下，确认透明；
③加入脂肪酸酰胺羧酸盐，改性嵌段聚醚0.7％，并搅拌15±5min，温度控制在35℃以下，确认透明，制得所述生物降解型高效光整液；
以上步骤均在常压下操作。
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101724502A (zh) * | 2009-12-09 | 2010-06-09 | 彭美东 | 水溶性轧制油 |
| CN102876438A (zh) * | 2011-08-29 | 2013-01-16 | 孝感市江雁化工有限公司 | 一种光整液及其制备方法 |
| CN103589491A (zh) * | 2013-11-29 | 2014-02-19 | 广州机械科学研究院有限公司 | 一种冷轧用润滑材料及其制备方法和应用 |
| CN105567406A (zh) * | 2015-12-10 | 2016-05-11 | 长沙艾森设备维护技术有限公司 | 一种全合成轧制液及其制备方法 |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101724502A (zh) * | 2009-12-09 | 2010-06-09 | 彭美东 | 水溶性轧制油 |
| CN102876438A (zh) * | 2011-08-29 | 2013-01-16 | 孝感市江雁化工有限公司 | 一种光整液及其制备方法 |
| CN103589491A (zh) * | 2013-11-29 | 2014-02-19 | 广州机械科学研究院有限公司 | 一种冷轧用润滑材料及其制备方法和应用 |
| CN105567406A (zh) * | 2015-12-10 | 2016-05-11 | 长沙艾森设备维护技术有限公司 | 一种全合成轧制液及其制备方法 |
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