CN106085562B - 一种注塑机润滑油 - Google Patents
一种注塑机润滑油 Download PDFInfo
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- CN106085562B CN106085562B CN201610402823.6A CN201610402823A CN106085562B CN 106085562 B CN106085562 B CN 106085562B CN 201610402823 A CN201610402823 A CN 201610402823A CN 106085562 B CN106085562 B CN 106085562B
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- parts
- lubricating oil
- injection molding
- molding machine
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- 239000010687 lubricating oil Substances 0.000 title claims abstract description 50
- 238000001746 injection moulding Methods 0.000 title claims abstract description 41
- 239000000843 powder Substances 0.000 claims abstract description 36
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229910052845 zircon Inorganic materials 0.000 claims abstract description 21
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 18
- GTCAXTIRRLKXRU-UHFFFAOYSA-N methyl carbamate Chemical compound COC(N)=O GTCAXTIRRLKXRU-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 15
- 238000002360 preparation method Methods 0.000 claims abstract description 15
- VYMPLPIFKRHAAC-UHFFFAOYSA-N 1,2-ethanedithiol Chemical compound SCCS VYMPLPIFKRHAAC-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 12
- 239000011707 mineral Substances 0.000 claims abstract description 12
- 239000002199 base oil Substances 0.000 claims abstract description 11
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical class C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims abstract description 11
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 7
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 claims abstract description 6
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 6
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 30
- 238000000034 method Methods 0.000 claims description 18
- 238000012545 processing Methods 0.000 claims description 15
- 239000000243 solution Substances 0.000 claims description 15
- 235000021355 Stearic acid Nutrition 0.000 claims description 14
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 14
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 14
- 239000008117 stearic acid Substances 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 11
- ZJCZFAAXZODMQT-UHFFFAOYSA-N 2-methylpentadecane-2-thiol Chemical compound CCCCCCCCCCCCCC(C)(C)S ZJCZFAAXZODMQT-UHFFFAOYSA-N 0.000 claims description 9
- DCQBZYNUSLHVJC-UHFFFAOYSA-N 3-triethoxysilylpropane-1-thiol Chemical class CCO[Si](OCC)(OCC)CCCS DCQBZYNUSLHVJC-UHFFFAOYSA-N 0.000 claims description 9
- 230000005684 electric field Effects 0.000 claims description 7
- CEYYIKYYFSTQRU-UHFFFAOYSA-M trimethyl(tetradecyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[N+](C)(C)C CEYYIKYYFSTQRU-UHFFFAOYSA-M 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000009413 insulation Methods 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 4
- 235000013339 cereals Nutrition 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 235000013312 flour Nutrition 0.000 claims description 3
- 230000033116 oxidation-reduction process Effects 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- 150000003754 zirconium Chemical class 0.000 claims description 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 claims 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims 1
- UBGJVOADXUCALK-UHFFFAOYSA-N C1=CC=CC1.[Cl] Chemical compound C1=CC=CC1.[Cl] UBGJVOADXUCALK-UHFFFAOYSA-N 0.000 claims 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims 1
- 238000002156 mixing Methods 0.000 claims 1
- 239000003921 oil Substances 0.000 abstract description 12
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 230000003749 cleanliness Effects 0.000 abstract description 4
- 238000005494 tarnishing Methods 0.000 abstract description 4
- 239000000853 adhesive Substances 0.000 abstract description 3
- 230000001070 adhesive effect Effects 0.000 abstract description 3
- 230000003254 anti-foaming effect Effects 0.000 abstract description 3
- -1 butyl disulfide aminodithioformic acid Chemical compound 0.000 description 16
- 239000004519 grease Substances 0.000 description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 6
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 6
- BGHCVCJVXZWKCC-UHFFFAOYSA-N tetradecane Chemical compound CCCCCCCCCCCCCC BGHCVCJVXZWKCC-UHFFFAOYSA-N 0.000 description 6
- 239000004033 plastic Substances 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 230000001050 lubricating effect Effects 0.000 description 4
- 238000005461 lubrication Methods 0.000 description 4
- 239000010445 mica Substances 0.000 description 4
- 229910052618 mica group Inorganic materials 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 230000003078 antioxidant effect Effects 0.000 description 3
- 235000006708 antioxidants Nutrition 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- KXDHJXZQYSOELW-UHFFFAOYSA-N carbonic acid monoamide Natural products NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- KJAMZCVTJDTESW-UHFFFAOYSA-N tiracizine Chemical compound C1CC2=CC=CC=C2N(C(=O)CN(C)C)C2=CC(NC(=O)OCC)=CC=C21 KJAMZCVTJDTESW-UHFFFAOYSA-N 0.000 description 3
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000001506 calcium phosphate Substances 0.000 description 2
- 229910000389 calcium phosphate Inorganic materials 0.000 description 2
- 235000011010 calcium phosphates Nutrition 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 2
- ITRNXVSDJBHYNJ-UHFFFAOYSA-N tungsten disulfide Chemical compound S=[W]=S ITRNXVSDJBHYNJ-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 230000004308 accommodation Effects 0.000 description 1
- 238000012644 addition polymerization Methods 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005662 electromechanics Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- 238000010137 moulding (plastic) Methods 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 230000005180 public health Effects 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- GLFDLEXFOHUASB-UHFFFAOYSA-N trimethyl(tetradecyl)azanium Chemical compound CCCCCCCCCCCCCC[N+](C)(C)C GLFDLEXFOHUASB-UHFFFAOYSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
- C10M2201/041—Carbon; Graphite; Carbon black
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- C—CHEMISTRY; METALLURGY
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/10—Compounds containing silicon
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2211/02—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only
- C10M2211/022—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only aliphatic
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/10—Amides of carbonic or haloformic acids
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
- C10M2215/224—Imidazoles
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/04—Detergent property or dispersant property
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/08—Hydraulic fluids, e.g. brake-fluids
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
Abstract
本发明涉及一种注塑机润滑油，由以下重量份的原料制备而成：矿物基础油85‑95份、壬基酚聚氧乙烯醚15‑25份、六氯环戊二烯3‑5份、乙二硫醇3‑5份、烷基化二苯胺5‑10份、石墨烯10‑15份、改性锆英石粉5‑10份、氨基甲酸甲酯1‑3份与苯并咪唑2‑4份。本发明的润滑油具有良好的抗磨性、抗锈蚀性、热稳定性、抗泡性，密封适应性能好、具有较高清洁度，能满足注塑机液压系统对润滑油的要求。使润滑油本身具有较强附着力以使油不易快速流失，本发明制备方法简单、便于工业化生产、成本低。
Description
技术领域
本发明涉及一种润滑油，尤其涉及一种防锈、抗氧化、极压抗磨性能好的注塑机润滑油。
背景技术
注射成型机，简称注射机或注塑机，是将热塑性塑料或热固性料利用塑料成型模具制成各种形状的塑料制品的主要成型设备。注塑机被广泛应用于国防、机电、汽车、交通运输、建材、包装、农业、文教卫生及人们日常生活各个领域，在塑料工业迅速发展的今天，注塑机不论在数量上或品种上都占有重要地位，其生产总数占整个塑料成型设备的20％--30％，从而成为目前塑料机械中增长最快，生产数量最多的机种之一。目前，我国注塑机制造能力已跃居世界首位，塑料机械主要分布在东南沿海、珠江三角洲一带，其中浙江宁波地区发展势头最猛，现已成为中国最大的注塑机生产基地，年生产量占国内注塑机年总量的1/2以上，占世界注塑机总产量的1/3。
润滑油是一种技术密集型产品，是复杂的碳氢化合物的混合物，而其真正使用性能又是复杂的物理或化学变化过程的综合效应。润滑油的基本性能包括一般理化性能、特殊理化性能和模拟台架试验。每一类润滑油脂都有其共同的一般理化性能，以表明该产品的内在质量。作润滑剂用的油(如石油的蒸馏物或脂肪质)；涂在机器轴承或者人体某个部位等运动部分表面的油状液体。有减少摩擦、避免发热、防止机器磨损以及医学用途等作用。一般是分馏石油的产物，也有从动植物油中提炼的。
对于注塑机关节来说，其对润滑油性能的要求是产品具有特别优异的极压抗磨性能、抗水性、良好的泵送性能，同时具备防锈、抗氧化等特点，能在极高的压力下保护设备不磨损。同时还需重点考虑到注塑机关节的结构特点，其本身的较强附着力使油脂不易快速流失。润滑油的主要功效是润滑和密封，当润滑油起密封作用时，其对于防水性能的要求会更高。在润滑油中添加适合的固体粉末来提高防水性能不失为一种不错的方法，比如发明申请CN01115610.4提供一种用于燃气管道阀门的润滑脂，其组成添加了0-30％的云母粉、碳酸钙或磷酸钙，优选添加的是云母粉，这种润滑脂特点是滴点高、阻燃性和绝缘性好，但是其生产成本高，因此并不适于做注塑机关节专用润滑脂；发明申请CN200610113499公开一种抗水润滑脂，添加了二硫化钼、二硫化钨、鳞片石墨、胶体石油墨、微粉石墨、云母粉、滑石粉、氟化钙、碳酸钙、碳酸钡、硫代锑酸锑、铜粉、铝粉、铅粉、硫化二丁基二硫代氨基甲酸钼中的一种以上，这种润滑油主要是用于水下工况的要求，因此不适宜用做注塑机关节润滑脂；发明申请CN200810057199提供一种开式齿轮润滑脂组合物，其添加了石墨、二硫化钼、聚四氟乙烯、二硫化钨、三聚氰胺、碳酸钙、磷酸钙、硫酸钙、硫酸钡、碳酸钡或云母粉，这种油脂因加聚异丁烯，比较粘稠，泵送不适宜，不能用于集中润滑，因此也不适宜用做注塑机关节润滑脂。
发明内容
本发明针对注塑机的润滑油，提供一种性能良好、具有较高清洁度、防锈、抗氧化、极压抗磨性能好的注塑机润滑油。
为了实现上述目的，本发明采用以下技术方案：
一种注塑机润滑油，由以下重量份的原料制备而成：矿物基础油85-95份、壬基酚聚氧乙烯醚15-25份、六氯环戊二烯3-5份、乙二硫醇3-5份、烷基化二苯胺5-10份、石墨烯10-15份、改性锆英石粉5-10份、氨基甲酸甲酯1-3份与苯并咪唑2-4份。在本技术方案中，本发明以矿物基础油为基础油，并添加了壬基酚聚氧乙烯醚、六氯环戊二烯、乙二硫醇、烷基化二苯胺、氨基甲酸甲酯与苯并咪唑来提高抗磨性、抗锈蚀性、热稳定性、抗泡性，密封适应性能好，满足注塑机润滑油的性能要求，尤其突出的是其添加了纳米级的石墨烯、改性锆英石粉，试验表明纳米级固体粉末的添加不仅增强了润滑油的抗水性能，也令其抗磨性能也有所增强，并且对润滑油的其他性能没有影响。
本发明的润滑油具有良好的抗磨性、抗锈蚀性、热稳定性、抗泡性，密封适应性能好、具有较高清洁度，能满足注塑机液压系统对润滑油的要求。
作为优选，石墨烯的层数为1-20层，粒径为0.5nm-50um，制备方法为氧化还原法、机械剥离法、溶剂剥离法中的一种或者多种混合方法制备。
作为优选，改性纳米锆英石粉的制备方法为：将硬脂酸加入到二氯甲烷中，然后加入十四烷基三甲基氯化铵、十六烷基硫醇与3-巯丙基三乙氧基硅烷，制得改性溶液；然后将锆英石粉碎成20-40μm后加入改性溶液中，超声频率60-90KHz下水浴85-95℃加热5-10h，冷却后取出干燥在650-700℃下煅烧2-3h，而后研磨成纳米粉末得到改性纳米锆英石粉。
作为优选，硬脂酸与二氯甲烷的料液比为1g:10mL，硬脂酸与十四烷基三甲基氯化铵、十六烷基硫醇、3-巯丙基三乙氧基硅烷的质量比为3:1:2:1，锆英石与改性溶液的料液比为1g：20mL。
作为优选，所述注塑机润滑油的制备方法为：按配方量取石墨烯、改性锆英石粉、氨基甲酸甲酯加入绝缘袋中进行高压脉冲电场处理35-50min；然后取配方量的矿物基础油，加热到65-75℃，加入壬基酚聚氧乙烯醚、六氯环戊二烯、乙二硫醇、烷基化二苯胺与苯并咪唑，超声搅拌30-45min，然后加入经过高压脉冲电场处理的剩余原料，高速剪切45-60min，得到注塑机润滑油。
作为优选，高压脉冲电场处理的脉冲时间为1s，脉冲频率为55-75Hz，电场强度为45-55kV/cm。
作为优选，超声频率为100-120KHz，高速剪切速度为6500-7500rpm。
本发明的有益效果是本发明的润滑油具有良好的抗磨性、抗锈蚀性、热稳定性、抗泡性，密封适应性能好、具有较高清洁度，能满足注塑机液压系统对润滑油的要求。使润滑油本身具有较强附着力以使油不易快速流失，本发明制备方法简单、便于工业化生产、成本低。
具体实施方式
下面通过具体实施例，对本发明的技术方案作进一步的具体说明。应当理解，本发明的实施并不局限于下面的实施例，对本发明所做的任何形式上的变通和/或改变都将落入本发明保护范围。
在本发明中，若非特指，所有的份、百分比均为重量单位，所采用的设备和原料等均可从市场购得或是本领域常用的。下述实施例中的方法，如无特别说明，均为本领域的常规方法。
石墨烯的层数为1-20层，粒径为0.5nm-50um，制备方法为氧化还原法、机械剥离法、溶剂剥离法中的一种或者多种混合方法制备。
实施例1
一种注塑机润滑油，由以下重量份的原料制备而成：矿物基础油85份、壬基酚聚氧乙烯醚15份、六氯环戊二烯3份、乙二硫醇3份、烷基化二苯胺5份、石墨烯10份、改性锆英石粉5份、氨基甲酸甲酯1份与苯并咪唑2份。
改性纳米锆英石粉的制备方法为：将硬脂酸加入到二氯甲烷中，然后加入十四烷基三甲基氯化铵、十六烷基硫醇与3-巯丙基三乙氧基硅烷，制得改性溶液；然后将锆英石粉碎成20-40μm后加入改性溶液中，超声频率60KHz下水浴85℃加热5h，冷却后取出干燥在650℃下煅烧2h，而后研磨成纳米粉末得到改性纳米锆英石粉；其中，硬脂酸与二氯甲烷的料液比为1g:10mL，硬脂酸与十四烷基三甲基氯化铵、十六烷基硫醇、3-巯丙基三乙氧基硅烷的质量比为3:1:2:1，锆英石与改性溶液的料液比为1g：20mL；
所述注塑机润滑油的制备方法为：按配方量取石墨烯、改性锆英石粉、氨基甲酸甲酯加入绝缘袋中进行高压脉冲电场处理35min，高压脉冲电场处理的脉冲时间为1s，脉冲频率为55Hz，电场强度为45kV/cm；然后取配方量的矿物基础油，加热到65℃，加入壬基酚聚氧乙烯醚、六氯环戊二烯、乙二硫醇、烷基化二苯胺与苯并咪唑，超声搅拌30min，超声频率为100KHz，然后加入经过高压脉冲电场处理的剩余原料，高速剪切45min，高速剪切速度为6500rpm，得到注塑机润滑油。
实施例2
一种注塑机润滑油，由以下重量份的原料制备而成：矿物基础油90份、壬基酚聚氧乙烯醚20份、六氯环戊二烯4份、乙二硫醇4份、烷基化二苯胺7份、石墨烯12份、改性锆英石粉7份、氨基甲酸甲酯2份与苯并咪唑3份。
改性纳米锆英石粉的制备方法为：将硬脂酸加入到二氯甲烷中，然后加入十四烷基三甲基氯化铵、十六烷基硫醇与3-巯丙基三乙氧基硅烷，制得改性溶液；然后将锆英石粉碎成20-40μm后加入改性溶液中，超声频率70KHz下水浴90℃加热7h，冷却后取出干燥在680℃下煅烧2.5h，而后研磨成纳米粉末得到改性纳米锆英石粉；其中，硬脂酸与二氯甲烷的料液比为1g:10mL，硬脂酸与十四烷基三甲基氯化铵、十六烷基硫醇、3-巯丙基三乙氧基硅烷的质量比为3:1:2:1，锆英石与改性溶液的料液比为1g：20mL；
所述注塑机润滑油的制备方法为：按配方量取石墨烯、改性锆英石粉、氨基甲酸甲酯加入绝缘袋中进行高压脉冲电场处理45min，高压脉冲电场处理的脉冲时间为1s，脉冲频率为65Hz，电场强度为50kV/cm；然后取配方量的矿物基础油，加热到70℃，加入壬基酚聚氧乙烯醚、六氯环戊二烯、乙二硫醇、烷基化二苯胺与苯并咪唑，超声搅拌40min，超声频率为110KHz，然后加入经过高压脉冲电场处理的剩余原料，高速剪切55min，高速剪切速度为6800rpm，得到注塑机润滑油。
实施例3
一种注塑机润滑油，由以下重量份的原料制备而成：矿物基础油95份、壬基酚聚氧乙烯醚25份、六氯环戊二烯5份、乙二硫醇5份、烷基化二苯胺10份、石墨烯15份、改性锆英石粉10份、氨基甲酸甲酯3份与苯并咪唑4份。
改性纳米锆英石粉的制备方法为：将硬脂酸加入到二氯甲烷中，然后加入十四烷基三甲基氯化铵、十六烷基硫醇与3-巯丙基三乙氧基硅烷，制得改性溶液；然后将锆英石粉碎成20-40μm后加入改性溶液中，超声频率60-90KHz下水浴95℃加热10h，冷却后取出干燥在700℃下煅烧3h，而后研磨成纳米粉末得到改性纳米锆英石粉；其中，硬脂酸与二氯甲烷的料液比为1g:10mL，硬脂酸与十四烷基三甲基氯化铵、十六烷基硫醇、3-巯丙基三乙氧基硅烷的质量比为3:1:2:1，锆英石与改性溶液的料液比为1g：20mL；
所述注塑机润滑油的制备方法为：按配方量取石墨烯、改性锆英石粉、氨基甲酸甲酯加入绝缘袋中进行高压脉冲电场处理50min，高压脉冲电场处理的脉冲时间为1s，脉冲频率为75Hz，电场强度为55kV/cm；然后取配方量的矿物基础油，加热到75℃，加入壬基酚聚氧乙烯醚、六氯环戊二烯、乙二硫醇、烷基化二苯胺与苯并咪唑，超声搅拌45min，超声频率为120KHz，然后加入经过高压脉冲电场处理的剩余原料，高速剪切60min，高速剪切速度为7500rpm，得到注塑机润滑油。
对比例1，市场上购买到现有常用的注塑机关节润滑油。
对实施例1-3制备的润滑油与对比例1润滑油进行减摩抗磨性能评价：
实验按照SH/T 0189-92进行，采用厦门天机MS-10J四球摩擦磨损试验机，电机转速1200±50r/min，温度室温，负荷392N，时间60min。
对实施例1-3制备的润滑油与对比例1润滑油进行极压性能评价：
实验按照GB/T 3142-82进行，采用厦门天机MS-10J四球摩擦磨损试验机，电机转速1450±50r/min，温度室温，时间10s，最大无卡咬负荷(PB)越大，表面极压承载性能越好，结果见表1。
润滑油热稳定性测定法SH/T0209；石油和合成液抗乳化性能测定法GB/T7305，结果见表1。
表1、性能结果对比
从表1中可以看出，实施例1-3制备的润滑油与对比例1的润滑油润滑油的承载能力PB(N)值得到了明显提高，最大无卡咬负荷PB越大，表面极压承载性能越好；而摩擦系数(μ)减小，抗磨损性能提高。
应当理解的是，对于本领域普通技术人员来说，可以根据上述说明加以改进或变换，而所有这些改进和变换都应属于本发明所附权利要求的保护范围。
Claims (5)
1.一种注塑机润滑油，其特征在于，由以下重量份的原料制备而成：矿物基础油85-95份、壬基酚聚氧乙烯醚15-25份、六氯环戊二烯3-5份、乙二硫醇3-5份、烷基化二苯胺5-10份、石墨烯10-15份、改性锆英石粉5-10份、氨基甲酸甲酯1-3份与苯并咪唑2-4份；改性锆英石粉的制备方法为：将硬脂酸加入到二氯甲烷中，然后加入十四烷基三甲基氯化铵、十六烷基硫醇与3-巯丙基三乙氧基硅烷，制得改性溶液；然后将锆英石粉碎成20-40μm后加入改性溶液中，超声频率60-90KHz下水浴85-95℃加热5-10h，冷却后取出干燥在650-700℃下煅烧2-3h，而后研磨成纳米粉末，得到改性锆英石粉；硬脂酸与二氯甲烷的料液比为1g:10mL，硬脂酸与十四烷基三甲基氯化铵、十六烷基硫醇、3-巯丙基三乙氧基硅烷的质量比为3:1:2:1，锆英石与改性溶液的料液比为1g：20mL。
2.根据权利要求1所述的一种注塑机润滑油，其特征在于，石墨烯的层数为1-20层，粒径为0.5nm-50um，制备方法为氧化还原法、机械剥离法、溶剂剥离法中的一种或者多种混合方法制备。
3.根据权利要求1或2所述的一种注塑机润滑油，其特征在于，所述注塑机润滑油的制备方法为：按配方量取石墨烯、改性锆英石粉、氨基甲酸甲酯加入绝缘袋中进行高压脉冲电场处理35-50min；然后取配方量的矿物基础油，加热到65-75℃，加入壬基酚聚氧乙烯醚、六氯环戊二烯、乙二硫醇、烷基化二苯胺与苯并咪唑，超声搅拌30-45min，然后加入经过高压脉冲电场处理的剩余原料，高速剪切45-60min，得到注塑机润滑油。
4.根据权利要求3所述的一种注塑机润滑油，其特征在于，高压脉冲电场处理的脉冲时间为1s，脉冲频率为55-75Hz，电场强度为45-55kV/cm。
5.根据权利要求3所述的一种注塑机润滑油，其特征在于，超声频率为100-120KHz，高速剪切速度为6500-7500rpm。
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Address after: No. 19 Yuntaishan Road, Xiapu Modern International Logistics Park, Beilun District, Ningbo City, Zhejiang Province, 315807 Patentee after: Zhejiang Runbei Wanling Lubrication Technology Co.,Ltd. Address before: No. 19 Yuntaishan Road, Xiapu Modern International Logistics Park, Beilun District, Ningbo City, Zhejiang Province, 315807 Patentee before: Zhejiang Run Beiwanling lubricating oil Co.,Ltd. |
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