CN105886123A - Extraction technique of lavender essential oil - Google Patents
Extraction technique of lavender essential oil Download PDFInfo
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- CN105886123A CN105886123A CN201610325255.4A CN201610325255A CN105886123A CN 105886123 A CN105886123 A CN 105886123A CN 201610325255 A CN201610325255 A CN 201610325255A CN 105886123 A CN105886123 A CN 105886123A
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- oil
- water
- lavandula angustifolia
- extraction
- quintessence oil
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- 244000178870 Lavandula angustifolia Species 0.000 title claims abstract description 32
- 235000010663 Lavandula angustifolia Nutrition 0.000 title claims abstract description 32
- 238000000605 extraction Methods 0.000 title claims abstract description 21
- 238000000034 method Methods 0.000 title claims abstract description 20
- 239000001102 lavandula vera Substances 0.000 title claims abstract description 7
- 235000018219 lavender Nutrition 0.000 title claims abstract description 7
- 239000000341 volatile oil Substances 0.000 title abstract description 7
- 239000003921 oil Substances 0.000 claims abstract description 50
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 29
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 19
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 14
- 239000010779 crude oil Substances 0.000 claims abstract description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000004821 distillation Methods 0.000 claims abstract description 8
- 238000001179 sorption measurement Methods 0.000 claims abstract description 8
- 238000000926 separation method Methods 0.000 claims abstract description 7
- 239000011780 sodium chloride Substances 0.000 claims abstract description 7
- 238000009835 boiling Methods 0.000 claims abstract description 6
- 235000019198 oils Nutrition 0.000 claims description 49
- 239000000284 extract Substances 0.000 claims description 11
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 238000009833 condensation Methods 0.000 claims description 6
- 230000005494 condensation Effects 0.000 claims description 6
- 238000004137 mechanical activation Methods 0.000 claims description 6
- 235000019476 oil-water mixture Nutrition 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 230000008569 process Effects 0.000 claims description 5
- FGUUSXIOTUKUDN-IBGZPJMESA-N C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 Chemical compound C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 FGUUSXIOTUKUDN-IBGZPJMESA-N 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 244000025254 Cannabis sativa Species 0.000 claims description 2
- 239000000779 smoke Substances 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims 1
- 239000003960 organic solvent Substances 0.000 abstract description 5
- 239000002537 cosmetic Substances 0.000 abstract description 4
- 239000003814 drug Substances 0.000 abstract description 4
- 238000004140 cleaning Methods 0.000 abstract description 3
- 238000005406 washing Methods 0.000 abstract description 2
- 230000003213 activating effect Effects 0.000 abstract 1
- 229940079593 drug Drugs 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 230000009931 harmful effect Effects 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 238000010298 pulverizing process Methods 0.000 abstract 1
- 239000006228 supernatant Substances 0.000 abstract 1
- 231100000331 toxic Toxicity 0.000 abstract 1
- 230000002588 toxic effect Effects 0.000 abstract 1
- -1 washing supplies Substances 0.000 abstract 1
- 239000005418 vegetable material Substances 0.000 description 14
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 12
- 239000000463 material Substances 0.000 description 8
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 6
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 229930007744 linalool Natural products 0.000 description 6
- 125000003118 aryl group Chemical group 0.000 description 4
- 238000001256 steam distillation Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 3
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 2
- 241000723346 Cinnamomum camphora Species 0.000 description 2
- 241000207923 Lamiaceae Species 0.000 description 2
- 230000000507 anthelmentic effect Effects 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 238000002386 leaching Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 244000251953 Agaricus brunnescens Species 0.000 description 1
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 1
- 244000166652 Cymbopogon martinii Species 0.000 description 1
- 235000018793 Cymbopogon martinii Nutrition 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241001529749 Lavandula Species 0.000 description 1
- 235000002997 Lavandula Nutrition 0.000 description 1
- 241000337007 Oceania Species 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 231100000957 no side effect Toxicity 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 239000013557 residual solvent Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/02—Recovery or refining of essential oils from raw materials
- C11B9/027—Recovery of volatiles by distillation or stripping
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/02—Recovery or refining of essential oils from raw materials
- C11B9/022—Refining
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/02—Recovery or refining of essential oils from raw materials
- C11B9/025—Recovery by solvent extraction
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
The invention provides an extraction technique of lavender essential oil. The technique comprises the following steps: picking and cleaning, naturally drying in the shade, activating and pulverizing; adding a sodium chloride solution, and immersing; carrying out atmospheric distillation, and boiling the extracting solution; obtaining a condensate; carrying out oil-water separation; adding an ethanol solution into an activated carbon adsorption column to extract oil in the activated carbon adsorption column, thereby obtaining crude oil; and extracting, stratifying, and separating out the supernatant, thereby obtaining the lavender essential oil. The organic solvent for extraction is the ethanol solution which can be thoroughly volatilized in the extraction process, so the product does not have ethanol residues and does not have any toxic or harmful effect on the human body. The lavender essential oil can be used for preparing cosmetics, washing supplies, medicines and the like, and thus, has wide application range.
Description
Technical field
The present invention relates to extraction of essential oil technique, particularly relate to the extraction process of a kind of Herba Lysimachiae foenum-graeci quintessence oil.
Background technology
Lavandula angustifolia (Lavandula angustifolia Mill) is that Labiatae (Labiatae) lavandula angustifolia belongs to
(Lavandula Linn) plant, perennial herb or partly fill this, have the good reputation of " after rosha ".
Originate in Mediterranean and Oceania archipelago.Equal China, Russia, Australia, the U.S. and South America
There is distribution, there is long plantation and applicating history.China introduces lavandula angustifolia as far back as nineteen fifty-two, is mainly distributed
In Xinjiang, Shaanxi, the ground such as Jiangsu.Lavandula angustifolia leaf, stem, flower Herb all have fragrance, and the fragrance of You Yihua is dense
Strongly fragrant and soft, stingless excitation, have no side effect, be therefore widely used in medicine, champignon, cosmetics,
Washing, food service industry, be also commonly used as aromatic, anthelmintic and the raw material of preparation essence.
The vegetable oil extracted from lavandula angustifolia contains multiple aromatic compound, is important natural perfume material.Smoke
In clothing grass, essential oil content is higher, because of its fragrant odour, is commonly used for the former of aromatic, anthelmintic and preparation essence
Material.Extract Herba Lysimachiae foenum-graeci quintessence oil and generally use steam distillation, it is also possible to make extractum with solvent method.Water steams
The yield ratio of steam distillation method is relatively low, and solvent method not only needs to remove extracting solvent, also can make to have in product a large amount of
Residual solvent.And use CO_2 supercritical technology to extract Herba Lysimachiae foenum-graeci quintessence oil and be not also widely used.
After traditional dewaxing treatment method typically uses the organic solvent such as petroleum ether, ether to extract crude oil, put
Cold analysis a period of time at low ambient temperatures, last concentrating under reduced pressure extractum, reclaims organic solvent, to produce quintessence oil.
Use this method to produce quintessence oil, waxiness can be removed well, but when distillation and concentration, easily cause point
The rearrangement of son, aoxidize, hydrolyze, polymerization etc., cause derived essential oil to be destroyed, simultaneously it is also possible to cause molten
Agent remains, and have impact on the quality of quintessence oil.
Summary of the invention
The present invention proposes the extraction process of a kind of Herba Lysimachiae foenum-graeci quintessence oil, it is possible to efficiently accurately extract Herba Lysimachiae foenum-graeci quintessence oil,
And protection effective ingredient.
The technical scheme is that and be achieved in that: the extraction process of a kind of Herba Lysimachiae foenum-graeci quintessence oil, including following
Step:
Step a. wins fresh lavandula angustifolia, and clear water is cleaned, and lavandula angustifolia branch, leaf is naturally dried in the shade, is subsequently adding
In agitating ball mill, under rotating speed is 300-500r/min, mechanical activation 5-10min, obtains lavender powder;
Step b. adds sodium chloride solution in the ratio that mass ratio is 1:5 of powder with water, soaks 4-5 little
Time;Wherein, the concentration of sodium chloride solution is 20%-25%;
Step c. proceeds to distilling apparatus and carries out air-distillation, is passed through steam to extracting solution from the bottom of alembic
Heat, be warming up to 110 DEG C-125 DEG C, extract 1.5-2h after extracting solution boiling, obtain mixed vapour;
To condensing droplet on a glass, obtaining oil water mixture after condensation, oil-free oozes and stops distillation now;
Step d. oil-water separation: the oil water mixture that condensation obtains carries out oil-water separation through oil water separator,
Obtain lavandula angustifolia crude oil and water;
Step e. adds ethanol solution with the oil in extraction active carbon adsorption column in described active carbon adsorption column
Point, obtain crude oil;Extracting times is 4 times, and the time of extraction is 5-8 hour every time;
Step f. extracts: the lavandula angustifolia crude oil obtained extracts through extractor again, after layering, separates
Layer is Herba Lysimachiae foenum-graeci quintessence oil.
As preferably, described lavandula angustifolia branch, leaf being dried in the shade is that lavandula angustifolia dries in the shade to make its water content be 10-15%.
As preferably, described agitating ball mill is agitated ball mill, under whipping process rotating speed 400r/min
Mechanical activation 8min.
Compared with prior art, it is an advantage of the current invention that: extraction organic solvent used is ethanol solution, its
In leaching process, volatilization is thoroughly, remains without ethanol in product, to human non-toxic's evil effect.This lavandula angustifolia essence
Oil can be used in preparing cosmetics, cleaning chemical products, medicine etc., and tool has been widely used.Use steam distillation
When method is extracted and manufactures quintessence oil, vegetable material to be put into distillator, then steam be injected vegetable material
In.Need not add water in this method distillator, the steam that boiler occurs is passed through bottom in distillator, typically exists
Under porous barrier, pot bottom position has the most lacunary ring pipe equipped with one, and steam is directly sprayed by aperture
Go out, be directly entered the bed of material through porous sieve plate.Generally, boiler the steam sent here is to have certain pressure, temperature
Spend higher and that water capacity is relatively low saturated steam, material bed intensification can be made rapidly.The steam of heat contributes to
Aromatic molecules is discharged, because steam can be with quintessence oil storage in force open vegetable material from vegetable material
Oil droplet cell.These volatile quintessence oil molecules discharge among entrance steam from vegetable material.Steam
Temperature need careful regulation and control, be allowed to just to make vegetable material discharge quintessence oil.The hottest meeting is lighted and is planted
Thing material or quintessence oil.Steam containing quintessence oil passes through a cooling system, and steam concentrates, and forms liquid,
So quintessence oil and water is the most separated from each other.The vapour pressure ratio atmospheric pressure used wants big, and therefore steam produces
Boiling temperature time raw, more than 100 DEG C, so can promote that quintessence oil quickly discharges from vegetable material,
Prevent quintessence oil from being destroyed.Herba Lysimachiae foenum-graeci quintessence oil is sensitive to heat.Using this extracting method, quintessence oil is the most not
Can be destroyed, its composition also will not resolve into linalool (linalool, linalool) and acetic acid, such as virtue
Camphor tree ester etc..
Detailed description of the invention
Technical scheme in the embodiment of the present invention will be clearly and completely described below, it is clear that retouched
The embodiment stated is only a part of embodiment of the present invention rather than whole embodiments.Based in the present invention
Embodiment, it is every other that those of ordinary skill in the art are obtained under not making creative work premise
Embodiment, broadly falls into the scope of protection of the invention.
Embodiment:
The extraction process of a kind of Herba Lysimachiae foenum-graeci quintessence oil, comprises the following steps:
Step a. wins fresh lavandula angustifolia, and clear water is cleaned, and lavandula angustifolia branch, leaf is naturally dried in the shade, is subsequently adding
In agitating ball mill, under rotating speed is 300-500r/min, mechanical activation 5-10min, obtains lavender powder;
Step b. adds sodium chloride solution in the ratio that mass ratio is 1:5 of powder with water, soaks 4-5 little
Time;Wherein, the concentration of sodium chloride solution is 20%-25%;
Step c. proceeds to distilling apparatus and carries out air-distillation, is passed through steam to extracting solution from the bottom of alembic
Heat, be warming up to 110 DEG C-125 DEG C, extract 1.5-2h after extracting solution boiling, obtain mixed vapour;
To condensing droplet on a glass, obtaining oil water mixture after condensation, oil-free oozes and stops distillation now;
Step d. oil-water separation: the oil water mixture that condensation obtains carries out oil-water separation through oil water separator,
Obtain lavandula angustifolia crude oil and water;
Step e. adds ethanol solution with the oil in extraction active carbon adsorption column in described active carbon adsorption column
Point, obtain crude oil;Extracting times is 4 times, and the time of extraction is 5-8 hour every time;
Step f. extracts: the lavandula angustifolia crude oil obtained extracts through extractor again, after layering, separates
Layer is Herba Lysimachiae foenum-graeci quintessence oil.
As preferably, described lavandula angustifolia branch, leaf being dried in the shade is that lavandula angustifolia dries in the shade to make its water content be 10-15%.
As preferably, described agitating ball mill is agitated ball mill, under whipping process rotating speed 400r/min
Mechanical activation 8min.
Compared with prior art, it is an advantage of the current invention that: extraction organic solvent used is ethanol solution, its
In leaching process, volatilization is thoroughly, remains without ethanol in product, to human non-toxic's evil effect.This lavandula angustifolia essence
Oil can be used in preparing cosmetics, cleaning chemical products, medicine etc., and tool has been widely used.Use steam distillation
When method is extracted and manufactures quintessence oil, vegetable material to be put into distillator, then steam be injected vegetable material
In.Need not add water in this method distillator, the steam that boiler occurs is passed through bottom in distillator, typically exists
Under porous barrier, pot bottom position has the most lacunary ring pipe equipped with one, and steam is directly sprayed by aperture
Go out, be directly entered the bed of material through porous sieve plate.Generally, boiler the steam sent here is to have certain pressure, temperature
Spend higher and that water capacity is relatively low saturated steam, material bed intensification can be made rapidly.The steam of heat contributes to
Aromatic molecules is discharged, because steam can be with quintessence oil storage in force open vegetable material from vegetable material
Oil droplet cell.These volatile quintessence oil molecules discharge among entrance steam from vegetable material.Steam
Temperature need careful regulation and control, be allowed to just to make vegetable material discharge quintessence oil.The hottest meeting is lighted and is planted
Thing material or quintessence oil.Steam containing quintessence oil passes through a cooling system, and steam concentrates, and forms liquid,
So quintessence oil and water is the most separated from each other.The vapour pressure ratio atmospheric pressure used wants big, and therefore steam produces
Boiling temperature time raw, more than 100 DEG C, so can promote that quintessence oil quickly discharges from vegetable material,
Prevent quintessence oil from being destroyed.Herba Lysimachiae foenum-graeci quintessence oil is sensitive to heat.Using this extracting method, quintessence oil is the most not
Can be destroyed, its composition also will not resolve into linalool (linalool, linalool) and acetic acid, such as virtue
Camphor tree ester etc..
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all at this
Within bright spirit and principle, any modification, equivalent substitution and improvement etc. made, should be included in this
Within bright protection domain.
Claims (3)
1. the extraction process of a Herba Lysimachiae foenum-graeci quintessence oil, it is characterised in that comprise the following steps:
Step a. wins fresh lavandula angustifolia, and clear water is cleaned, and lavandula angustifolia branch, leaf is naturally dried in the shade, is subsequently adding
In agitating ball mill, under rotating speed is 300-500r/min, mechanical activation 5-10min, obtains lavender powder;
Step b. adds sodium chloride solution in the ratio that mass ratio is 1:5 of powder with water, soaks 4-5 little
Time;Wherein, the concentration of sodium chloride solution is 20%-25%;
Step c. proceeds to distilling apparatus and carries out air-distillation, is passed through steam to extracting solution from the bottom of alembic
Heat, be warming up to 110 DEG C-125 DEG C, extract 1.5-2h after extracting solution boiling, obtain mixed vapour;
To condensing droplet on a glass, obtaining oil water mixture after condensation, oil-free oozes and stops distillation now;
Step d. oil-water separation: the oil water mixture that condensation obtains carries out oil-water separation through oil water separator,
Obtain lavandula angustifolia crude oil and water;
Step e. adds ethanol solution with the oil in extraction active carbon adsorption column in described active carbon adsorption column
Point, obtain crude oil;Extracting times is 4 times, and the time of extraction is 5-8 hour every time;
Step f. extracts: the lavandula angustifolia crude oil obtained extracts through extractor again, after layering, separates
Layer is Herba Lysimachiae foenum-graeci quintessence oil.
The extraction process of Herba Lysimachiae foenum-graeci quintessence oil the most according to claim 1, it is characterised in that: described will smoke
It is that lavandula angustifolia dries in the shade to make its water content be 10-15% that clothing grass branch, leaf dry in the shade.
The extraction process of Herba Lysimachiae foenum-graeci quintessence oil the most according to claim 1, it is characterised in that: described stirring
Ball mill is agitated ball mill, mechanical activation 8min under whipping process rotating speed 400r/min.
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CN106914034A (en) * | 2017-04-27 | 2017-07-04 | 广西竟铭三农投资有限公司 | A kind of high-efficiency environment friendly double back receives extraction equipment |
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CN107987968A (en) * | 2017-11-25 | 2018-05-04 | 防城港市润禾农林科技有限公司 | It is a kind of to be used to extract the aromatic oil processing technology that essence processing uses |
CN108456594A (en) * | 2018-05-07 | 2018-08-28 | 南召留山岭南艾叶制品有限公司 | A kind of extracting method of high yield wormwood essential oil |
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CN1710045A (en) * | 2005-07-04 | 2005-12-21 | 上海应用技术学院 | A kind of extraction method of lavender essential oil |
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