CN105524407A - PEEK composite material with high heat resistance and preparation method thereof - Google Patents
PEEK composite material with high heat resistance and preparation method thereof Download PDFInfo
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- CN105524407A CN105524407A CN201510736966.6A CN201510736966A CN105524407A CN 105524407 A CN105524407 A CN 105524407A CN 201510736966 A CN201510736966 A CN 201510736966A CN 105524407 A CN105524407 A CN 105524407A
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Abstract
The invention discloses a PEEK composite material with high heat resistance. The PEEK composite material is characterized by comprising the following raw materials by weight: 77 to 85 parts of PEEK, 6 to 8 parts of silicon carbide ceramic micro powder, 3 to 5 parts of magnesium oxide ceramic micro powder and 6 to 10 parts of zinc oxide ceramic micro powder. The invention also discloses a preparation method for the PEEK composite material. Through filling of PEEK with ceramic micro powder, high temperature resistance of PEEK can be substantially improved, melting temperature increases to 387 DEG C and PEEK can be used for a long time in an environment with a temperature of 330 DEG C and has improved wear resistance and hardness with other mechanical properties barely changed; and the prepared PEEK composite material can be used for a long time in a high temperature environment.
Description
Technical field
The present invention relates to high heat resistance PEEK matrix material and preparation method thereof, belong to field of compound material.
Background technology
Polyether-ether-ketone (PEEK) is the linear aromatic race macromolecular compound containing chain link in molecular backbone chain, is a kind of high temperature resistant, high performance thermoplastic special engineering plastic.PEEK has the performance such as good mechanical property and chemicals-resistant, wear-resistant, hydrolysis; Light specific gravity, self-lubricating property is good, there is extraordinary processing characteristics, the high-tech industrial circles such as aviation, machinery, electronics, chemical industry, automobile can be applied to, especially the component of machine of the speed of being used in up to the high request on the High Speed Railway Trains of 350KM/h can be manufactured, as gear, bearing, piston ring, support ring, wear ring (letter), valve block, wear-resisting ring etc., there is the trend replacing traditional metal materials.The melt temperature of pure PEEK is at about 330 DEG C, and use temperature need control, below 250 DEG C, to use restricted under hot environment, need carry out modification to it.
Summary of the invention
The object of this invention is to provide a kind of high heat resistance PEEK matrix material, there is higher second-order transition temperature and melt temperature, can use for a long time in the environment more than 300 DEG C, and there is good wear resistance.
For achieving the above object, the technical solution used in the present invention is: a kind of high heat resistance PEEK matrix material, it is characterized in that being made up of following raw material:
PEEK77-85 part;
Silicon carbide ceramics micro mist 6-8 part;
Magnesia ceramics micro mist 3-5 part;
Zinc oxide ceramics micro mist 6-10 part.
Preferably, described silicon carbide ceramics grain size of micropowder is 0.02-0.10 μm.
Preferably, the particle diameter of described zinc oxide ceramics micro mist is 0.01-0.04 μm.
Preferably, the particle diameter of described magnesia ceramics micro mist is 0.3-1.0 μm.
The invention also discloses the preparation method of above-mentioned high heat resistance PEEK matrix material, its step comprises:
A, silicon carbide ceramics micro mist, magnesia ceramics micro mist and zinc oxide ceramics micro mist to be added in ethanol in proportion, ultrasonic disperse after ball milling, obtained dispersion liquid;
B, in dispersion liquid, add PEEK powder, heated and stirred, ethanol is volatilized, obtain mixed powder;
Sinter after 50-70MPa compression molding after C, mixed powder drying, sintering temperature is 400-430 DEG C, obtains finished product.
Silicon carbide ceramics micro mist, zinc oxide ceramics micro mist and magnesia ceramics micro mist is filled in PEEK, its resistance to elevated temperatures can be significantly improved, melt temperature brings up to 387 DEG C, can under 330 DEG C of environment life-time service, and its wear resistance and hardness can be improved, and other mechanical propertys are without large change, obtained PEEK matrix material can use under long term high temperature environment.
Embodiment
Embodiment 1
The preparation method of this high heat resistance PEEK matrix material, its step comprises:
A, 6 parts of silicon carbide ceramics micro mists, 3 parts of magnesia ceramics micro mists and 6 parts of zinc oxide ceramics micro mists to be added in ethanol in proportion, ultrasonic disperse after ball milling, obtained dispersion liquid;
B, in dispersion liquid, add 85 parts of PEEK powder, heated and stirred, ethanol is volatilized, obtain mixed powder;
C, mixed powder, 150 DEG C of dryings 4 hours, then sinter after 50MPa compression molding, and sintering temperature is 400 DEG C, obtains finished product.
Carry out performance test to obtained high heat resistance PEEK matrix material, test result is in table 1.
Embodiment 2
The preparation method of this high heat resistance PEEK matrix material, its step comprises:
A, 8 parts of silicon carbide ceramics micro mists, 5 parts of magnesia ceramics micro mists and 10 parts of zinc oxide ceramics micro mists to be added in ethanol in proportion, ultrasonic disperse after ball milling, obtained dispersion liquid;
B, in dispersion liquid, add 77 parts of PEEK powder, heated and stirred, ethanol is volatilized, obtain mixed powder;
C, mixed powder, 120 DEG C of dryings 8 hours, then sinter after 70MPa compression molding, and sintering temperature is 430 DEG C, obtains finished product.
Carry out performance test to obtained high heat resistance PEEK matrix material, test result is in table 1.
Embodiment 3
The preparation method of this high heat resistance PEEK matrix material, its step comprises:
A, 7 parts of silicon carbide ceramics micro mists, 4 parts of magnesia ceramics micro mists and 8 parts of zinc oxide ceramics micro mists to be added in ethanol in proportion, ultrasonic disperse after ball milling, obtained dispersion liquid;
B, in dispersion liquid, add 81 parts of PEEK powder, heated and stirred, ethanol is volatilized, obtain mixed powder;
C, mixed powder, 130 DEG C of dryings 5 hours, then sinter after 60MPa compression molding, and sintering temperature is 420 DEG C, obtains finished product.
Carry out performance test to obtained high heat resistance PEEK matrix material, test result is in table 1.
The performance test results of table 1 high heat resistance PEEK matrix material
Remarks: friction-wear test condition: initial load 196N, rotating speed 200r/min, metal to-metal contact 2h.To emery wheel: 45 steel, 42-45HRC.
Claims (5)
1. a high heat resistance PEEK matrix material, is characterized in that being made up of following raw material:
PEEK77-85 part;
Silicon carbide ceramics micro mist 6-8 part;
Magnesia ceramics micro mist 3-5 part;
Zinc oxide ceramics micro mist 6-10 part.
2. high heat resistance PEEK matrix material according to claim 1, is characterized in that: described silicon carbide ceramics grain size of micropowder is 0.02-0.10 μm.
3. high heat resistance PEEK matrix material according to claim 1, is characterized in that: the particle diameter of described zinc oxide ceramics micro mist is 0.01-0.04 μm.
4. high heat resistance PEEK matrix material according to claim 2, is characterized in that: the particle diameter of described magnesia ceramics micro mist is 0.3-1.0 μm.
5. the preparation method of the high heat resistance PEEK matrix material according to any one of a claim 1-4, its step comprises:
A, silicon carbide ceramics micro mist, magnesia ceramics micro mist and zinc oxide ceramics micro mist to be added in ethanol in proportion, ultrasonic disperse after ball milling, obtained dispersion liquid;
B, in dispersion liquid, add PEEK powder, heated and stirred, ethanol is volatilized, obtain mixed powder;
Sinter after 50-70MPa compression molding after C, mixed powder drying, sintering temperature is 400-430 DEG C, obtains finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201510736966.6A CN105524407B (en) | 2015-11-03 | 2015-11-03 | High-fire resistance PEEK composites and preparation method thereof |
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| CN201510736966.6A CN105524407B (en) | 2015-11-03 | 2015-11-03 | High-fire resistance PEEK composites and preparation method thereof |
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| CN105524407A true CN105524407A (en) | 2016-04-27 |
| CN105524407B CN105524407B (en) | 2018-02-02 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106334215A (en) * | 2016-08-22 | 2017-01-18 | 苏州聚冠复合材料有限公司 | Method for preparing medical grade 3D printing PEEK composite material |
| CN106751443A (en) * | 2016-11-23 | 2017-05-31 | 大连路阳科技开发有限公司 | The corrosion-resistant friction-resistant composite material of metallic plastic-lining and preparation method and application |
| CN107474478A (en) * | 2017-09-22 | 2017-12-15 | 南京肯特复合材料股份有限公司 | Wear-resisting anti-rotation cross slip-ring PEEK resin composite materials and preparation method thereof |
| CN107474479A (en) * | 2017-09-22 | 2017-12-15 | 南京肯特复合材料股份有限公司 | Anti- rotation cross slip-ring PEEK resin composite materials of high intensity and preparation method thereof |
| CN111888530A (en) * | 2020-04-20 | 2020-11-06 | 上海交通大学医学院附属仁济医院 | Zinc oxide-polyether-ether-ketone composite material, preparation method and application thereof, and artificial joint formed by zinc oxide-polyether-ether-ketone composite material |
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| CN1150958A (en) * | 1996-04-22 | 1997-06-04 | 中国科学院兰州化学物理研究所 | Nanoparticle filled wear-resistant material and preparation method thereof |
| CN1270188A (en) * | 2000-04-17 | 2000-10-18 | 中国科学院兰州化学物理研究所 | Water-proof antiwear self-lubricating material and preparing process thereof |
| CN101220196A (en) * | 2008-01-22 | 2008-07-16 | 南京肯特复合材料有限公司 | Poly(ether-ether-ketone) composite material, production method and application of sealing member |
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2015
- 2015-11-03 CN CN201510736966.6A patent/CN105524407B/en active Active
Patent Citations (3)
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| CN1150958A (en) * | 1996-04-22 | 1997-06-04 | 中国科学院兰州化学物理研究所 | Nanoparticle filled wear-resistant material and preparation method thereof |
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| CN101220196A (en) * | 2008-01-22 | 2008-07-16 | 南京肯特复合材料有限公司 | Poly(ether-ether-ketone) composite material, production method and application of sealing member |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106334215A (en) * | 2016-08-22 | 2017-01-18 | 苏州聚冠复合材料有限公司 | Method for preparing medical grade 3D printing PEEK composite material |
| CN106751443A (en) * | 2016-11-23 | 2017-05-31 | 大连路阳科技开发有限公司 | The corrosion-resistant friction-resistant composite material of metallic plastic-lining and preparation method and application |
| CN106751443B (en) * | 2016-11-23 | 2019-02-22 | 大连路阳科技开发有限公司 | The corrosion-resistant friction-resistant composite material of metallic plastic-lining and preparation method and application |
| CN107474478A (en) * | 2017-09-22 | 2017-12-15 | 南京肯特复合材料股份有限公司 | Wear-resisting anti-rotation cross slip-ring PEEK resin composite materials and preparation method thereof |
| CN107474479A (en) * | 2017-09-22 | 2017-12-15 | 南京肯特复合材料股份有限公司 | Anti- rotation cross slip-ring PEEK resin composite materials of high intensity and preparation method thereof |
| CN111888530A (en) * | 2020-04-20 | 2020-11-06 | 上海交通大学医学院附属仁济医院 | Zinc oxide-polyether-ether-ketone composite material, preparation method and application thereof, and artificial joint formed by zinc oxide-polyether-ether-ketone composite material |
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| CN105524407B (en) | 2018-02-02 |
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Address after: 211162 Jiangsu, Jiangning District, Binjiang Development Zone, No., Copper Road, No. 18 Applicant after: Nanjing Kent composites Limited by Share Ltd Applicant after: Nanjing CompTECH New Material Co., Ltd. Address before: 211162 Nanjing City, Jiangning Province town, the town of copper, Copper Road, No. 18 Applicant before: Nanjing Kente Composite Material Co., Ltd. Applicant before: Nanjing CompTECH New Material Co., Ltd. |
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