CN105504966B - A kind of offset printing ink - Google Patents
A kind of offset printing ink Download PDFInfo
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- CN105504966B CN105504966B CN201610093677.3A CN201610093677A CN105504966B CN 105504966 B CN105504966 B CN 105504966B CN 201610093677 A CN201610093677 A CN 201610093677A CN 105504966 B CN105504966 B CN 105504966B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract
一种平版胶印油墨,不仅可以长期释放空气负离子,净化空气,利于人体健康;还对葡萄球菌、大肠杆菌、革兰阳性细菌等多种病菌和真菌有一定的抑制、杀灭作用;同时气味芳香,清新怡神,舒缓压力,使用后可留下持久的香气,具有提神醒脑、消除疲劳的保健功效,适用于各个年龄人群,具有非常广泛的应用前景。A lithographic offset printing ink can not only release negative air ions for a long time to purify the air and benefit human health; it also has a certain inhibitory and killing effect on various pathogens and fungi such as Staphylococcus, Escherichia coli, and Gram-positive bacteria; at the same time, it has a fragrant smell, is refreshing and invigorating, and relieves stress. After use, it can leave a long-lasting fragrance, has the health benefits of refreshing the mind and relieving fatigue, is suitable for people of all ages, and has very broad application prospects.
Description
技术领域technical field
本发明涉及一种墨水,特别涉及一种平版胶印油墨。The invention relates to an ink, in particular to a lithographic offset printing ink.
背景技术Background technique
墨水是一种常用的耗材,可用于日常办公或纺织印刷领域,但传统的一般墨水只有书写功能,不具有提神和产生负离子等保健效果,使用者在长时使用用产生倦怠感,由于传统墨水的功能单一,已不能满足人们的多元需求。Ink is a commonly used consumable, which can be used in daily office or textile printing fields, but traditional general ink only has the function of writing, and does not have health effects such as refreshing and negative ions. Users will feel tired after long-term use. The single function of the system can no longer meet the diverse needs of people.
发明内容Contents of the invention
针对现有技术存在的不足,本发明为墨水的使用者提供一种气味清新,具有提神作用及负离子保健效果的墨水,它不仅可以长期释放空气负离子,净化空气,利于人体健康;还对葡萄球菌、大肠杆菌、革兰阳性细菌等多种病菌和真菌有一定的抑制、杀灭作用;同时气味芳香,清新怡神,舒缓压力,还可驱赶蚊虫,不会对人体产生不良影响,具有非常广泛的应用前景。Aiming at the deficiencies in the prior art, the present invention provides ink users with a fresh smell, refreshing effect and negative ion health-care effects. It can not only release air negative ions for a long time, purify the air, and be beneficial to human health; , Escherichia coli, Gram-positive bacteria and other bacteria and fungi have a certain inhibitory and killing effect; at the same time, the smell is fragrant, fresh and refreshing, relieves stress, and can also repel mosquitoes without adverse effects on the human body. application prospects.
本发明的目的是通过如下技术方案实现的:The purpose of the present invention is achieved through the following technical solutions:
一种平版胶印油墨,其特征在于:由下列组份按照重量份数组成:颜料色浆23重量份,双酚A19重量份,甘油4.5重量份,无水硫酸钠2.3重量份,三乙醇胺2.7重量份,三乙胺3.3重量份,丙酮3.6重量份,双硫代氨基甲酸酯0.25重量份,活性矿物质粉1.7重量份,表面活性剂复配物1.2重量份,缓释剂0.55重量份,中药精油3.85重量份,去离子水62重量份,所述色浆的颜料为高色素炭黑,所述颜料色浆的平均粒径为75nm,所述的活性矿物质粉为锗石、萤石、电气石、锌尖晶石按重量比2.5:3:3.7:2的混合物,其中电气石为镁电气石和锂电气石按重量比5:3的混合物,所述活性矿物质粉的粒径≤13μm,其中所述的中药精油通过如下步骤制备而成,A lithographic offset printing ink, characterized in that it consists of the following components in parts by weight: 23 parts by weight of pigment paste, 19 parts by weight of bisphenol A, 4.5 parts by weight of glycerin, 2.3 parts by weight of anhydrous sodium sulfate, and 2.7 parts by weight of triethanolamine Parts, 3.3 parts by weight of triethylamine, 3.6 parts by weight of acetone, 0.25 parts by weight of dithiocarbamate, 1.7 parts by weight of active mineral powder, 1.2 parts by weight of surfactant compound, 0.55 parts by weight of slow-release agent, 3.85 parts by weight of traditional Chinese medicine essential oil, 62 parts by weight of deionized water, the pigment of the color paste is high-pigment carbon black, the average particle diameter of the pigment color paste is 75nm, and the active mineral powder is germanite, fluorite A mixture of tourmaline and gahnite at a weight ratio of 2.5:3:3.7:2, wherein tourmaline is a mixture of magnesium tourmaline and lithium tourmaline at a weight ratio of 5:3, and the particle size of the active mineral powder is ≤ 13 μm, wherein the traditional Chinese medicine essential oil is prepared by the following steps,
S1、取逐蝇梅35重量份洗净,自然晾干,然后置于90℃炒锅中炒至有香味逸出,然后喷淋去离子水17重量份,置于恒温烘箱中60℃以下烘干,含水量≤6.5%;S1. Take 35 parts by weight of chrysanthemum, wash it, dry it naturally, and then fry it in a frying pan at 90°C until the fragrance escapes, then spray 17 parts by weight of deionized water, and dry it in a constant temperature oven below 60°C. Dry, moisture content ≤ 6.5%;
S2、将紫苏叶21重量份洗净,放入盐水中浸泡3.5小时,盐水量为所浸泡药料质量的3.7倍,放入锅中蒸透,取出,晾干,盐水的浓度为27%;S2. Wash 21 parts by weight of perilla leaves, put them in salt water and soak for 3.5 hours, the amount of salt water is 3.7 times of the quality of the soaked medicinal material, put it in a pot and steam it thoroughly, take it out, dry it, the concentration of salt water is 27% ;
S3、将薰衣草17重量份,打破碗花花4重量份,麝香1.5重量份,甜马郁兰2重量份,龙涎香1重量份去杂质,与步骤S1和S2所制原料药一起投入超微粉碎机中粉碎至60目,制得原料药粉末,备用;S3, 17 parts by weight of lavender, 4 parts by weight of broken bowl flowers, 1.5 parts by weight of musk, 2 parts by weight of sweet marjoram, 1 part by weight of ambergris to remove impurities, and put into the ultrafine pulverizer together with the raw materials prepared in steps S1 and S2 Grinding to 60 orders in medium to obtain raw material drug powder, for subsequent use;
S4、将步骤S3中制得的原料药粉末投入超临界二氧化碳萃取装置的萃取釜中,调节萃取压力27.65MPa,萃取温度45.10℃,二氧化碳流量为0.6m3/h,动态萃取2.5h,直接在分离釜出口用三角瓶收集挥发油A,备用;S4. Put the crude drug powder prepared in step S3 into the extraction kettle of the supercritical carbon dioxide extraction device, adjust the extraction pressure to 27.65MPa, the extraction temperature to 45.10°C, the flow rate of carbon dioxide to 0.6m 3 /h, dynamic extraction for 2.5h, directly in the Collect volatile oil A with a triangular flask at the outlet of the separation kettle for subsequent use;
S5、将榆树皮7重量份, 鱼腥草5重量份,苦地丁4.5重量份,沉香3.5重量份,樟木11重量份,菖蒲3重量份,薄荷1.75重量份洗净烘干,一起投入超微粉碎机中粉碎至70目,然后加去离子水浸泡6小时,加水量为所浸泡原料药质量的6.5倍,搅拌分散调匀,制得中药混合物,备用;S5. Wash and dry 7 parts by weight of elm bark, 5 parts by weight of Houttuynia cordata, 4.5 parts by weight of kudiding, 3.5 parts by weight of agarwood, 11 parts by weight of camphor wood, 3 parts by weight of calamus, and 1.75 parts by weight of mint. Pulverize to 70 mesh in an ultrafine pulverizer, then soak in deionized water for 6 hours, the amount of water added is 6.5 times the quality of the soaked raw material drug, stir, disperse and mix thoroughly to obtain a Chinese medicine mixture, which is set aside;
S6、将步骤S5制得的中药混合物于80℃煎煮2小时,收集蒸馏液,并加入乙醚萃取,蒸馏液与乙醚的体积比为2:1,取上层油相,然后加无水硫酸钠干燥,即制得挥发油B,备用;S6. Decoct the Chinese medicine mixture prepared in step S5 at 80°C for 2 hours, collect the distillate, and add diethyl ether for extraction. The volume ratio of the distillate to diethyl ether is 2:1, take the upper oil phase, and then add anhydrous sodium sulfate After drying, the volatile oil B is obtained for subsequent use;
S7、将步骤S4和S6所制挥发油A和挥发油B混合调匀制得混合油,再边搅拌边依次加入小麦芽精油、天竺葵精油、雪莲花精油、柠檬精油和葡萄柚精油,充分搅拌35分钟,静置30分钟,充分搅拌调匀,过滤除杂,即得中药精油,其中,所述混合油与小麦芽精油、天竺葵精油、雪莲花精油、柠檬精油和葡萄柚精油的质量比为1.3:0.4:0.75:0.6:0.5:0.3。S7. Mix the volatile oil A and volatile oil B prepared in steps S4 and S6 and mix thoroughly to obtain a mixed oil, then add wheat germ essential oil, geranium essential oil, snow lotus essential oil, lemon essential oil and grapefruit essential oil in turn while stirring, and fully stir for 35 minutes. Let stand for 30 minutes, fully stir and mix thoroughly, filter to remove impurities, and obtain Chinese medicine essential oil, wherein the mass ratio of the mixed oil to wheat germ essential oil, geranium essential oil, snow lotus essential oil, lemon essential oil and grapefruit essential oil is 1.3:0.4: 0.75:0.6:0.5:0.3.
在一较佳实施例中,在步骤S3的原料药粉末中还包含有牛至油1.3重量份和白花除虫菊1.5重量份。In a preferred embodiment, the bulk drug powder in step S3 also contains 1.3 parts by weight of oregano oil and 1.5 parts by weight of pyrethrum diffusa.
在一较佳实施例中,在步骤S5的中药混合物中还包含有冰片0.6重量份和荷叶0.4重量份。In a preferred embodiment, the traditional Chinese medicine mixture in step S5 also contains 0.6 parts by weight of borneol and 0.4 parts by weight of lotus leaves.
在一较佳实施例中,在步骤S7的中药精油中还包含有桉树油0.3重量份。In a preferred embodiment, the traditional Chinese medicine essential oil in step S7 also contains 0.3 parts by weight of eucalyptus oil.
本发明所涉及的设备、原料及方法,均为本行业惯常使用的设备、原料及方法,在此不再赘述。The equipment, raw materials and methods involved in the present invention are all commonly used equipment, raw materials and methods in this industry, and will not be repeated here.
其中各精油组分必须和表面活性剂、缓释剂充分混合,以达到缓释效果,各精油及负离子天然矿物质粉的添加量一定要适量,不仅抗菌杀菌,还能安定情绪,所以对失常的心理状态有正面的效果,能净化、安抚心灵,可减轻愤怒和筋疲力竭的感觉,使人可以心平气和地面对生活,因为它能平衡中枢神经,所以对惊慌和沮丧的状态很有帮助,也有明显的平静与舒缓功能,对失眠者有相当好的舒放与精神抚慰,对于安抚躁进或心情不稳的脾气有相当好的效果,可提高工作效率。Among them, each essential oil component must be fully mixed with surfactants and slow-release agents to achieve a slow-release effect. The amount of each essential oil and negative ion natural mineral powder must be added in an appropriate amount. It is not only antibacterial and sterilizing, but also calms emotions. It can purify and soothe the mind, relieve the feeling of anger and exhaustion, and enable people to face life calmly. Because it can balance the central nervous system, it is very effective for the state of panic and depression. Helping, it also has obvious calming and soothing functions, which is very good for insomniacs to relax and comfort the spirit, and has a very good effect on appease impetuous or unstable temper, and can improve work efficiency.
本发明参考现代中药药理研究,从现有中药的药物筛选和反复验证,充分发挥各组重量份协同作用,其中各中药组分简介如下。The present invention refers to the pharmacological research of modern Chinese medicines, screens and repeatedly verifies existing Chinese medicines, and fully exerts the synergistic effect of each component by weight. The brief introduction of each Chinese medicine component is as follows.
逐蝇梅:马鞭草科马缨丹属,属多年生植物,常绿半蔓性灌木,小枝四棱形,长而下垂具有逆向的锐刺,它的枝叶与花朵中挥发出蚊蝇敏感的气味,具有很强的驱逐蚊蝇功效,而对人体无任何伤害,有“驱蚊七变花”美誉。Fly-chasing plum: Verbenaceae Lantana genus, perennial plant, evergreen semi-vine shrub, branchlets quadrangular, long and drooping with reverse sharp thorns, its branches, leaves and flowers emit a mosquito-sensitive smell , has a strong effect of repelling mosquitoes and flies without any harm to the human body, and has the reputation of "mosquito repelling seven flowers".
紫苏叶:为唇形科植物紫苏的干燥叶(或带嫩枝),具有解表散寒,行气和胃的功效,用于风寒感冒,咳嗽呕恶,对葡萄球菌有抑制作用。Perilla leaf: It is the dry leaf (or twigs) of perilla, a plant of the Labiatae family. It has the effects of relieving the exterior and dispelling cold, promoting qi and harmonizing the stomach. It is used for colds, coughs and nausea, and has inhibitory effect on staphylococci.
薰衣草能除蚁、除蟑、除螨,放在衣柜、枕头下的时候,不但能代替樟脑丸,还能留下一股沁人的香味,研究发现,薰衣草有明显的抗菌作用,薰衣草中蕴含的芳樟醇是薰衣草抗菌的主要成分,它能抑制17种细菌(包括革兰阴性细菌和革兰阳性细菌)、10种真菌的生长。Lavender can eliminate ants, cockroaches, and mites. When placed in the wardrobe or under the pillow, it can not only replace mothballs, but also leave a refreshing fragrance. Studies have found that lavender has obvious antibacterial effects. Linalool is the main antibacterial component of lavender, which can inhibit the growth of 17 kinds of bacteria (including Gram-negative bacteria and Gram-positive bacteria) and 10 kinds of fungi.
打破碗花花:①《陕西中草药》:“苦,凉,有小毒。”②《四川常用中草药》:“苦辛,温,有小毒。”解毒,排脓生肌,消肿散瘀,具有杀蛆虫、孑孓,化积,消肿,散瘀,治顽癣,秃疮,疟疾,小儿疳积,痢疾,痈疖疮肿,瘰疬,跌打损伤。Breaking the bowl of flowers: ① "Shaanxi Chinese Herbal Medicine": "Bitter, cool, and slightly toxic." ② "Sichuan Commonly Used Chinese Herbal Medicine": "Bitter, warm, and slightly toxic." It has the functions of killing maggots, larvae, dissolving accumulation, reducing swelling, dispelling blood stasis, treating stubborn ringworm, bald sores, malaria, malnutrition in children, dysentery, carbuncle furuncle sores, scrofula, and traumatic injuries.
榆树皮:为榆科植物的干燥树皮或根皮, 甘、平,无毒;利水,通淋,消肿,用于小便不通,淋浊,水肿,痈疽发背,丹毒,疥癣。Ulmus bark: the dry bark or root bark of Ulmaceae plants, sweet, flat, non-toxic; diuresis, relieving stranguria, reducing swelling, used for urinary obstruction, stranguria, edema, carbuncle on the back, erysipelas, scabies.
鱼腥草:具有抗菌、抗病毒、提高机体免疫力等作用,对各种微生物(尤其是酵母菌和霉菌)均有抑制作用,对溶血性的链球菌、金黄色葡萄球菌、流感杆菌、卡他球菌、肺炎球菌有明显的抑制作用。对大肠杆菌、痢疾杆菌、伤寒杆菌也有作用。Houttuynia cordata: It has the effects of antibacterial, antiviral, and improving the body's immunity, etc., and has inhibitory effects on various microorganisms (especially yeasts and molds). His bacteria, pneumococcus have obvious inhibitory effect. It also has effects on Escherichia coli, Shigella, and typhoid bacillus.
苦地丁:为罂粟科植物地丁紫堇的全草,对甲型链球菌、肺炎球菌、卡他球菌、痢疾杆菌、大肠杆菌、绿脓杆菌有抑制,对副流感仙台病毒亦有抑制作用。Kudiding: It is the whole plant of Viola corydalis of the poppy family plant, which can inhibit Streptococcus A, pneumococcus, catarrhal bacteria, Shigella, Escherichia coli, Pseudomonas aeruginosa, and also inhibit parainfluenza Sendai virus .
沉香:“本草纲目”记载木具有强烈的抗菌效能、香气入脾、清神理气、补五脏、止咳化痰、暖胃温脾、通气定痛、能入药,是上等药材极品。Agarwood: "Compendium of Materia Medica" records that wood has a strong antibacterial effect, aroma enters the spleen, clears the mind and qi, nourishes the five internal organs, relieves cough and phlegm, warms the stomach and spleen, ventilates and relieves pain, and can be used as medicine. It is the best medicinal material.
樟木:常绿乔木,树皮黄褐色,有不规则的纵裂纹,主产长江以南及西南各地。冬季伐树劈碎或锯成块状,晒干或风干。木材块状大小不一,表面红棕色至暗棕色,横断面可见年轮。质重而硬。有强烈的樟脑香气,味清凉,有辛辣感,性温,味辛;能通窍辟秽、温中止痛、利湿杀虫。Camphor wood: Evergreen tree with yellow-brown bark and irregular longitudinal cracks. It is mainly produced in the south of the Yangtze River and in the southwest. In winter, the trees are chopped or sawn into blocks, and dried in the sun or in the air. The wood blocks vary in size, the surface is reddish brown to dark brown, and annual rings can be seen in the cross section. Heavy and hard. It has strong camphor aroma, cool taste, pungent feeling, warm nature, and pungent taste;
菖蒲:其花、茎香味浓郁,具有开窍、祛痰、散风的功效,可祛疫益智、强身健体,可作香料或驱蚊虫。Calamus: Its flowers and stems have a strong fragrance, and have the effects of resuscitating, eliminating phlegm, and dispersing wind.
薄荷:为唇形科植物薄荷的干燥地上部分,疏散风热,清利头目,利咽透疹,疏肝行气。Peppermint: It is the dry aerial part of mint, a plant of the Labiatae family, which dispels wind-heat, clears the head, soothes the throat and clears the rash, soothes the liver and promotes qi.
麝香: 具有开窍,辟秽,通络,散瘀的功效;治中风,痰厥,惊痫,中恶烦闷,心腹暴痛,癥瘕癖积,跌打损伤,痈疽肿毒。《本经》:主辟恶气,温疟,痫痉,去三虫。Musk: It has the effects of resuscitating, warding off filth, dredging collaterals, and dispersing blood stasis; it can treat stroke, phlegm syncope, convulsions, dysphoria, sudden pain in trusted subordinates, abdominal mass accumulation, bruises, carbuncle and swollen toxin. "Herbal Classic": Mainly dispelling bad qi, warming malaria, epileptic spasms, and removing three worms.
甜马郁兰:可以改善心情苦闷和上瘾症,尤其对弘毅紧张症状有效,能扩张血管、降血压、减轻以及负担,帮助消除心悸,有优异的神经安抚与镇定功能。Sweet Marjoram: It can improve depression and addiction, especially effective for Hongyi’s nervous symptoms. It can dilate blood vessels, lower blood pressure, reduce stress, help eliminate heart palpitations, and has excellent nerve soothing and calming functions.
龙涎香:是留香最持久的香料,世界上任何一种香料都不能与之相媲美,素有“龙涎之香与日月共存”的说法。《本草纲目》载:可以活血、益精髓、助阳道、通利血脉、化痰平喘;症瘕积聚;心腹疼痛;神昏;廖永言:利水通淋,散癥结,消气结,逐劳虫。Ambergris: It is the spice with the longest lasting fragrance, which cannot be compared with any spice in the world. It is known as "the fragrance of ambergris coexists with the sun and the moon". "Compendium of Materia Medica" contains: it can promote blood circulation, benefit essence, help yang, unblock blood vessels, reduce phlegm and relieve asthma; accumulation of lumps in the abdomen; pain in trusted subordinates; dizziness; insect.
小麦芽精油:有强烈气味含丰富高单位维他命E,是著名的天然抗氧化剂(防腐剂),能稳定各成分的精油,使香水的效果更加持久。有强烈气味含丰富高单位维他命E,是著名的天然抗氧化剂(防腐剂),能稳定各成分的精油,使香水的效果更加持久。Wheat Germ Essential Oil: It has a strong smell and is rich in high-unit vitamin E. It is a famous natural antioxidant (preservative) that can stabilize the essential oils of each component and make the effect of the perfume more durable. It has a strong smell and is rich in high-unit vitamin E, which is a famous natural antioxidant (preservative), which can stabilize the essential oils of each component and make the effect of the perfume more durable.
天竺葵精油:具有止血,收缩血管,气喘,肝排毒,胆结石,肾排毒,肾结石,利尿,肌肉酸痛,油性皮肤,老化皮肤活化,疱疹,皮肤苍白,减肥,促进结疤,湿疹,灼伤晒伤,癣,月经不顺,乳房充血发炎,减轻忧郁不安,具有除臭,抗菌,杀菌的作用。Geranium essential oil: hemostasis, blood vessel constriction, asthma, liver detoxification, gallstones, kidney detoxification, kidney stones, diuresis, muscle aches, oily skin, revitalization of aging skin, herpes, pale skin, weight loss, promotes scarring, eczema, burns and sunburn Injuries, ringworm, irregular menstruation, breast congestion and inflammation, relieve depression, deodorization, antibacterial, and bactericidal effects.
雪莲花精油:具有生理活性有效成分。其中雪莲花伞形花内酯具有明显的抗菌、降压镇静、解痉作用;东莨菪素具有祛风、抗炎、止痛、祛痰和抗肿瘤作用,临床上汉疗喘急性慢性支气管炎有效率为96.6%芹菜素具有平滑肌解痉和抗胃溃疡作用;对羚基苯酮有明显的利胆作用。Saussurea essential oil: active ingredients with physiological activity. Among them, Saussurea umbelliferin has obvious antibacterial, antihypertensive, sedative, and antispasmodic effects; scopolamine has expelling wind, anti-inflammatory, pain-relieving, expectorant, and anti-tumor effects. The efficiency is 96.6%. Apigenin has antispasmodic and anti-gastric ulcer effects on smooth muscle; it has obvious choleretic effect on phenylphenone.
柠檬精油:具有杀菌功效,是有效的强心剂,通常用于降低血压。它抗菌的特性能减轻喉咙痛、咳嗽、着凉和流行性感冒,可减轻头痛、偏头痛、痛风和关节炎。感觉炙热烦躁时,可带来清新的感受,帮助澄清思绪,有效提高工作效率。Lemon essential oil: has antiseptic properties, is an effective cardiotonic, and is often used to lower blood pressure. Its antibacterial properties relieve sore throats, coughs, colds and flu, and relieve headaches, migraines, gout and arthritis. When feeling hot and irritable, it can bring a refreshing feeling, help clarify thoughts, and effectively improve work efficiency.
葡萄柚精油:气味清新、香甜,有柑橘的果香味,具有清热、止渴之效,能滋养组织细胞,增加体力,舒缓支气管炎,利尿,水肿及淋巴腺系统之疾病,抗感染。葡萄柚精油还可以抗忧郁,尤其在冬天出现的忧郁或昏昏欲睡等症状,可以使人恢复精神,是季节性精神失调的调节剂。Grapefruit essential oil: smells fresh, sweet, with citrus fruity aroma, has heat-clearing and thirst-quenching effects, can nourish tissue cells, increase physical strength, relieve bronchitis, diuresis, edema and lymphatic system diseases, and resist infection. Grapefruit essential oil can also fight depression, especially symptoms such as depression or drowsiness that occur in winter, can refresh people, and is a regulator of seasonal mental disorders.
牛至油:唇形科牛至属植物牛至ORIGZNUM VUL-GAREL.的全草,又名止痢草、野荆芥等地符名,具有清热、化湿、祛暑、解表、理气极强的杀菌、抑菌作用,从牛至中提取的挥发油,对31种常见致肠炎细菌和福氏痢疾杆菌,是最具有广谱抗菌的纯正中药药物添加剂。Oregano oil: the whole herb of Origanum oregano ORIGZNUM VUL-GAREL., a plant of the genus Origanum of the Lamiaceae family. Strong bactericidal and antibacterial effects, the volatile oil extracted from oregano is the most pure traditional Chinese medicine additive with broad-spectrum antibacterial effects on 31 common enteritis-causing bacteria and Shigella flexneri.
白花除虫菊:菊蒿属(Tanacetum)数种植物的统称,燥湿杀虫、灭杀阴虱、头虱、体虱、跳蚤、除蚊杀虫的功效。Pyrethrum albiflora: A collective name for several plants of the genus Tanacetum. It has the effects of drying dampness and killing insects, killing pubic lice, head lice, body lice, fleas, mosquitoes and insects.
冰片:辛,苦,凉。具有开窍醒神,清热散毒,明目退翳。主治热病高热神昏,中风痰厥惊痫,暑湿蒙蔽清窍,喉痹耳聋,口疮齿肿,疮痈疳痔,目赤肿痛,翳膜遮睛。Borneol: pungent, bitter, cool. Have one's ideas straightened out refreshing, clear away heat and disperse toxin, improve eyesight and relieve nebula. It is mainly used to treat febrile diseases with high fever and unconsciousness, stroke due to phlegm, convulsions and epilepsy, heat-dampness blinding clear orifices, sore throat and deafness, aphtha and tooth swelling, sores, carbuncles, malnutrition and hemorrhoids, red and swollen eyes, and nebula covering the eyes.
荷叶:为睡莲科植物莲的叶,有清热解毒、凉血、止血的作用。有清暑利湿、升发清阳、凉血止血等功效。Lotus leaf: It is the leaf of the lotus plant in the water lily family, which has the functions of clearing away heat and detoxifying, cooling blood and stopping bleeding. It has the effects of clearing heat and dampness, promoting hair and clearing yang, cooling blood and stopping bleeding.
桉树油:最常见和用途最广泛的精油之一,具有良好的保健作用,帮助集中注意力。能够有效缓解鼻窦感染,流感,支气管炎,伤风鼻塞和其他呼吸系统疾病。具有良好的抗菌和杀菌特性,在一些特定食品中,桉树油还作为香料成分。在旅行时携带这种精油,可以有效抵御蚊叮虫咬,治疗皮肤疹子。是良好的驱蚊剂。与水混合可以成为一种简单有效的消毒剂。Eucalyptus Oil: One of the most common and versatile essential oils, it has good health benefits and helps focus. Can effectively relieve sinus infection, flu, bronchitis, cold nasal congestion and other respiratory diseases. It has good antibacterial and bactericidal properties, and in some specific foods, eucalyptus oil is also used as a spice ingredient. Carry this essential oil on your travels to fight off insect bites and treat skin rashes. Is a good mosquito repellant. Mixed with water it can be a simple and effective disinfectant.
本发明的有益效果:Beneficial effects of the present invention:
本发明为使用者提供一种气味清新,具有提神作用及负离子保健功效的墨水,它不仅可以长期释放空气负离子,净化空气,利于人体健康;还对葡萄球菌、大肠杆菌、革兰阳性细菌等多种病菌和真菌有一定的抑制、杀灭作用;同时气味芳香,清新怡神,舒缓压力,还可驱赶蚊虫,不会对人体产生不良影响,适用于各个年龄人群,其在适量添加其它功能组分后仍能够保持原有的效果和质量。The invention provides users with an ink with fresh smell, refreshing effect and negative ion health care effect. It can not only release air negative ions for a long time, purify the air, and benefit human health; Various germs and fungi have a certain inhibitory and killing effect; at the same time, the smell is fragrant, fresh and refreshing, relieves stress, and can also repel mosquitoes without adverse effects on the human body. It is suitable for people of all ages. The original effect and quality can still be maintained after subdivision.
1、电气石是一种硅酸盐矿物,其化学式为Na(Mg,Fe,Mn,Li,Al)3Al6(Si6O18)(Bo3)3(OH,F)4,它与水分子接触在静电场作用下,便可将水分子电离成氢离子(H+)和氢氧根离子(OH-),氢氧根离子与水分子结合形成碱性羟基负离子(H2O•OH-),即为“空气负离子”,目前科学研究证明:负离子不仅能促成人体合成和储存维生素,强化和激活人体的生理活动,对人体及其他生物的生命活动有着十分重要的影响,被称为″空气维生素″。负离子有效吸附室内有害物质,如甲醛、甲苯等建筑装修有害物质,不仅自身不增加污染,而且清洁净化室内空气,从根本上消除建筑装修综合症,保障人体健康不受影响。1. Tourmaline is a silicate mineral whose chemical formula is Na (Mg, Fe, Mn, Li, Al) 3Al6 (Si6O18) (Bo3) 3 (OH, F) 4. It contacts with water molecules in an electrostatic field Under the action, water molecules can be ionized into hydrogen ions (H+) and hydroxide ions (OH-), and hydroxide ions combine with water molecules to form basic hydroxyl anions (H2O•OH-), which are "air negative ions ", the current scientific research proves that negative ions can not only promote the synthesis and storage of vitamins in the human body, strengthen and activate the physiological activities of the human body, but also have a very important impact on the life activities of the human body and other organisms. They are called "air vitamins". Negative ions effectively adsorb indoor harmful substances, such as formaldehyde, toluene and other harmful substances in building decoration, not only do not increase pollution themselves, but also clean and purify indoor air, fundamentally eliminate building decoration syndrome, and protect human health from being affected.
2、本发明中含有的中药成分,不仅对葡萄球菌、结核杆菌、绿脓杆菌、革兰阴性细菌和革兰阳性细菌等多种病菌和真菌有一定的抑制、杀灭作用;同时气味芳香,性质温和,清新怡神,助荷尔蒙分泌,舒缓焦虑的功效,同时也具有一定的驱蚊虫效果,更为关键的是,长期使用本发明不会对人体产生不良影响,适用于各个年龄人群,具有非常广泛的应用前景。2. The traditional Chinese medicine ingredients contained in the present invention not only have a certain inhibitory and killing effect on various germs and fungi such as Staphylococcus, Mycobacterium tuberculosis, Pseudomonas aeruginosa, Gram-negative bacteria and Gram-positive bacteria; at the same time, the smell is fragrant, It is mild in nature, fresh and refreshing, helps hormone secretion, relieves anxiety, and also has a certain effect of repelling mosquitoes. More importantly, long-term use of the invention will not have adverse effects on the human body, and it is suitable for people of all ages. Very broad application prospects.
具体实施方式Detailed ways
实施例。Example.
一种平版胶印油墨,其特征在于:由下列组份按照重量份数组成:颜料色浆23重量份,双酚A19重量份,甘油4.5重量份,无水硫酸钠2.3重量份,三乙醇胺2.7重量份,三乙胺3.3重量份,丙酮3.6重量份,双硫代氨基甲酸酯0.25重量份,活性矿物质粉1.7重量份,表面活性剂复配物1.2重量份,缓释剂0.55重量份,中药精油3.85重量份,去离子水62重量份,所述色浆的颜料为高色素炭黑,所述颜料色浆的平均粒径为75nm,所述的活性矿物质粉为锗石、萤石、电气石、锌尖晶石按重量比2.5:3:3.7:2的混合物,其中电气石为镁电气石和锂电气石按重量比5:3的混合物,所述活性矿物质粉的粒径≤13μm,其中所述的中药精油通过如下步骤制备而成,A lithographic offset printing ink, characterized in that it consists of the following components in parts by weight: 23 parts by weight of pigment paste, 19 parts by weight of bisphenol A, 4.5 parts by weight of glycerin, 2.3 parts by weight of anhydrous sodium sulfate, and 2.7 parts by weight of triethanolamine Parts, 3.3 parts by weight of triethylamine, 3.6 parts by weight of acetone, 0.25 parts by weight of dithiocarbamate, 1.7 parts by weight of active mineral powder, 1.2 parts by weight of surfactant compound, 0.55 parts by weight of slow-release agent, 3.85 parts by weight of traditional Chinese medicine essential oil, 62 parts by weight of deionized water, the pigment of the color paste is high-pigment carbon black, the average particle diameter of the pigment color paste is 75nm, and the active mineral powder is germanite, fluorite A mixture of tourmaline and gahnite at a weight ratio of 2.5:3:3.7:2, wherein tourmaline is a mixture of magnesium tourmaline and lithium tourmaline at a weight ratio of 5:3, and the particle size of the active mineral powder is ≤ 13 μm, wherein the traditional Chinese medicine essential oil is prepared by the following steps,
S1、取逐蝇梅35重量份洗净,自然晾干,然后置于90℃炒锅中炒至有香味逸出,然后喷淋去离子水17重量份,置于恒温烘箱中60℃以下烘干,含水量≤6.5%;S1. Take 35 parts by weight of chrysanthemum, wash it, dry it naturally, and then fry it in a frying pan at 90°C until the fragrance escapes, then spray 17 parts by weight of deionized water, and dry it in a constant temperature oven below 60°C. Dry, moisture content ≤ 6.5%;
S2、将紫苏叶21重量份洗净,放入盐水中浸泡3.5小时,盐水量为所浸泡药料质量的3.7倍,放入锅中蒸透,取出,晾干,盐水的浓度为27%;S2. Wash 21 parts by weight of perilla leaves, put them in salt water and soak for 3.5 hours, the amount of salt water is 3.7 times of the quality of the soaked medicinal material, put it in a pot and steam it thoroughly, take it out, dry it, the concentration of salt water is 27% ;
S3、将薰衣草17重量份,打破碗花花4重量份,麝香1.5重量份,甜马郁兰2重量份,龙涎香1重量份去杂质,与步骤S1和S2所制原料药一起投入超微粉碎机中粉碎至60目,制得原料药粉末,备用;S3, 17 parts by weight of lavender, 4 parts by weight of broken bowl flowers, 1.5 parts by weight of musk, 2 parts by weight of sweet marjoram, 1 part by weight of ambergris to remove impurities, and put into the ultrafine pulverizer together with the raw materials prepared in steps S1 and S2 Grinding to 60 orders in medium to obtain raw material drug powder, for subsequent use;
S4、将步骤S3中制得的原料药粉末投入超临界二氧化碳萃取装置的萃取釜中,调节萃取压力27.65MPa,萃取温度45.10℃,二氧化碳流量为0.6m3/h,动态萃取2.5h,直接在分离釜出口用三角瓶收集挥发油A,备用;S4. Put the crude drug powder prepared in step S3 into the extraction kettle of the supercritical carbon dioxide extraction device, adjust the extraction pressure to 27.65MPa, the extraction temperature to 45.10°C, the flow rate of carbon dioxide to 0.6m 3 /h, dynamic extraction for 2.5h, directly in the Collect volatile oil A with a triangular flask at the outlet of the separation kettle for subsequent use;
S5、将榆树皮7重量份, 鱼腥草5重量份,苦地丁4.5重量份,沉香3.5重量份,樟木11重量份,菖蒲3重量份,薄荷1.75重量份洗净烘干,一起投入超微粉碎机中粉碎至70目,然后加去离子水浸泡6小时,加水量为所浸泡原料药质量的6.5倍,搅拌分散调匀,制得中药混合物,备用;S5. Wash and dry 7 parts by weight of elm bark, 5 parts by weight of Houttuynia cordata, 4.5 parts by weight of kudiding, 3.5 parts by weight of agarwood, 11 parts by weight of camphor wood, 3 parts by weight of calamus, and 1.75 parts by weight of mint. Pulverize to 70 mesh in an ultrafine pulverizer, then soak in deionized water for 6 hours, the amount of water added is 6.5 times the quality of the soaked raw material drug, stir, disperse and mix thoroughly to obtain a Chinese medicine mixture, which is set aside;
S6、将步骤S5制得的中药混合物于80℃煎煮2小时,收集蒸馏液,并加入乙醚萃取,蒸馏液与乙醚的体积比为2:1,取上层油相,然后加无水硫酸钠干燥,即制得挥发油B,备用;S6. Decoct the Chinese medicine mixture prepared in step S5 at 80°C for 2 hours, collect the distillate, and add diethyl ether for extraction. The volume ratio of the distillate to diethyl ether is 2:1, take the upper oil phase, and then add anhydrous sodium sulfate After drying, the volatile oil B is obtained for subsequent use;
S7、将步骤S4和S6所制挥发油A和挥发油B混合调匀制得混合油,再边搅拌边依次加入小麦芽精油、天竺葵精油、雪莲花精油、柠檬精油和葡萄柚精油,充分搅拌35分钟,静置30分钟,充分搅拌调匀,过滤除杂,即得中药精油,其中,所述混合油与小麦芽精油、天竺葵精油、雪莲花精油、柠檬精油和葡萄柚精油的质量比为1.3:0.4:0.75:0.6:0.5:0.3。S7. Mix the volatile oil A and volatile oil B prepared in steps S4 and S6 and mix thoroughly to obtain a mixed oil, then add wheat germ essential oil, geranium essential oil, snow lotus essential oil, lemon essential oil and grapefruit essential oil in turn while stirring, and fully stir for 35 minutes. Let stand for 30 minutes, fully stir and mix thoroughly, filter to remove impurities, and obtain Chinese medicine essential oil, wherein the mass ratio of the mixed oil to wheat germ essential oil, geranium essential oil, snow lotus essential oil, lemon essential oil and grapefruit essential oil is 1.3:0.4: 0.75:0.6:0.5:0.3.
在一较佳实施例中,在步骤S3的原料药粉末中还包含有牛至油1.3重量份和白花除虫菊1.5重量份。In a preferred embodiment, the bulk drug powder in step S3 also contains 1.3 parts by weight of oregano oil and 1.5 parts by weight of pyrethrum diffusa.
在一较佳实施例中,在步骤S5的中药混合物中还包含有冰片0.6重量份和荷叶0.4重量份。In a preferred embodiment, the traditional Chinese medicine mixture in step S5 also contains 0.6 parts by weight of borneol and 0.4 parts by weight of lotus leaves.
在一较佳实施例中,在步骤S7的中药精油中还包含有桉树油0.3重量份。In a preferred embodiment, the traditional Chinese medicine essential oil in step S7 also contains 0.3 parts by weight of eucalyptus oil.
使用空气离子静态测试法测试该上述实施例中的墨水,负离子释放量在430-650个/ m3,而且持续释放空气负离子,更有利于长期净化空气,达到人们健康的基本要求。Using the air ion static test method to test the ink in the above embodiment, the amount of negative ions released is 430-650/ m3 , and the continuous release of air negative ions is more conducive to long-term air purification and meets the basic requirements of people's health.
对照例。Comparative example.
色素炭黑20g,苯酚11g,甘油4g,苯并三氮唑3g,三乙醇胺1g,三乙胺3g,碳酸氢钠5g,聚氧乙烯基醚类非离子型氟碳表面活性剂1.5g,缓释剂0.4g,甜马郁兰精油0.6g,小麦芽精油0.5g,薰衣草精油0.5g,白芍药精油0.4g,丝柏精油0. 4g,尤加利精油0.4g,艾叶精油0. 4g,薄荷精油0.4g,去离子水75g。Pigment carbon black 20g, phenol 11g, glycerin 4g, benzotriazole 3g, triethanolamine 1g, triethylamine 3g, sodium bicarbonate 5g, polyoxyethylene ether nonionic fluorocarbon surfactant 1.5g, slow Release agent 0.4g, sweet marjoram essential oil 0.6g, wheat germ essential oil 0.5g, lavender essential oil 0.5g, white peony essential oil 0.4g, cypress essential oil 0.4g, eucalyptus essential oil 0.4g, mugwort essential oil 0.4g, peppermint essential oil 0.4g, 75g deionized water.
使用空气离子静态测试法测试该上述对照例中的墨水,负离子释放量在0个/ m3,不具有释放空气负离子的功能。The ink in the above-mentioned comparative example was tested by using the air ion static test method, and the negative ion release amount was 0/m 3 , which did not have the function of releasing air negative ions.
(1)对所制得的中药精油进行急性毒性试验,结果如下:(1) Acute toxicity test was carried out on the prepared traditional Chinese medicine essential oil, the results are as follows:
①小鼠口服急性毒性试验:小鼠口服中药精油的LD50 为383.55g/kg,95%的可信限为294.68g/kg~ 499.31g/kg。而空气清新剂的毒性判定标准是:小鼠口服急毒LD50 ≥5g/kg,判定为无毒。本中药精油的LD50 高于无毒标准的76 倍,因此判定为无毒。① Oral acute toxicity test in mice: The LD50 of traditional Chinese medicine essential oil in mice is 383.55g/kg, and the 95% credible limit is 294.68g/kg~499.31g/kg. And the toxicity judging standard of air freshener is: mouse oral acute toxicity LD50 ≥ 5g/kg, it is judged as non-toxic. The LD50 of the essential oil of this traditional Chinese medicine is 76 times higher than the non-toxic standard, so it is judged as non-toxic.
②小鼠急性吸入毒性试验:小鼠急性吸入中药精油的LC50 为24863.99g/m3,95%的可信限为16837.34g/m3 ~ 33387.46g/m3。而空气清新剂的毒性判定标准是:小鼠急性吸入(2h)LC50 > 10000mg/m3,属实际无毒级。本中药精油的LC50 高于无毒标准的2486倍,因此判定为无毒。② Acute inhalation toxicity test in mice: The LC50 of acute inhalation of traditional Chinese medicine essential oil in mice is 24863.99g/m3, and the 95% credible limit is 16837.34g/m3 to 33387.46g/m3. The toxicity judgment standard of air fresheners is: acute inhalation of mice (2h) LC50 > 10000mg/m3, which belongs to the actual non-toxic level. The LC50 of this traditional Chinese medicine essential oil is 2486 times higher than the non-toxic standard, so it is judged as non-toxic.
所制得的中药精油经检验,其香气、色泽、折光指数、相对密度、含砷量、重金属含量、pH 值均符合国家标准的要求。The prepared essential oil of traditional Chinese medicine has been tested, and its aroma, color, refractive index, relative density, arsenic content, heavy metal content, and pH value all meet the requirements of national standards.
(2)检验上述墨水性能测试结果如表1:(2) Check the performance test results of the above inks as shown in Table 1:
(3)对改善精神状态的测试。(3) Tests for improving mental state.
主要方法是墨水使用志愿者实验,招募60人,分别使用上述2种实施例中的墨水,通过SCL-90问卷(即《症状自评量表-SCL90》,是世界上最著名的心理健康测试量表之一),通过连续1周的使用跟踪,来判定本发明在提神方面的实际功效作用,其中3人无感受;7人感受一般;1人认为本品对于提神作用无效;有49人反馈本品具有较好的提神效果,可以使人注意力集中,有效率为81.67%。The main method is the ink use volunteer experiment, recruiting 60 people, respectively using the ink in the above two embodiments, and passing the SCL-90 questionnaire (namely "Symptom Self-Assessment Scale-SCL90", which is the most famous mental health test in the world) One of the scales), through continuous use tracking for 1 week, to determine the actual efficacy of the present invention in terms of refreshing, 3 of them had no experience; 7 felt normal; 1 thought that this product was invalid for refreshing; Feedback This product has a good refreshing effect, can make people concentrate, and the effective rate is 81.67%.
(4)驱蚊效果测试。(4) Mosquito repellent effect test.
依据现有技术中的普通墨水与上述实施例中墨水的驱蚊效果进行对比测试,测试数据见表2。The mosquito repelling effect of the ordinary ink in the prior art and the ink in the above-mentioned embodiments was compared and tested, and the test data are shown in Table 2.
结论:本发明实施例中的墨水具有较好的驱蚊效果。Conclusion: the ink in the embodiment of the present invention has better mosquito repellent effect.
以上所述仅为本发明的较佳实施例,并不用以限制本发明,对于所属领域的普通技术人员来说,在上述说明的基础上还可以做出其它不同形式的变化或变动,这里无需也无法对所有的实施方式予以穷举,凡在本发明的精神和原则之内,所做的任何修改、等同替换、改进等,仍包含在本发明的保护范围之内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention. For those of ordinary skill in the art, other changes or changes in different forms can be made on the basis of the above descriptions. It is also impossible to list all the implementation modes, and any modifications, equivalent replacements, improvements, etc. made within the spirit and principles of the present invention are still included in the protection scope of the present invention.
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| CN106287265A (en) * | 2016-05-23 | 2017-01-04 | 庄可香 | A plug-in formaldehyde-removing environmentally friendly LED lamp |
| CN105802435A (en) * | 2016-05-23 | 2016-07-27 | 庄可香 | LED energy-saving lamp containing graphene composition |
| CN106167665A (en) * | 2016-05-23 | 2016-11-30 | 庄可香 | a lighting fixture |
| CN106189666A (en) * | 2016-05-23 | 2016-12-07 | 庄可香 | A kind of preparation method of multi-purpose antistatic led heat radiation coating |
| CN106280852A (en) * | 2016-05-23 | 2017-01-04 | 庄可香 | LED lamp assembly |
| CN106189658A (en) * | 2016-05-23 | 2016-12-07 | 庄可香 | LED environmental protection decorative lamps with the function of removing formaldehyde and toluene |
| CN106221483A (en) * | 2016-05-23 | 2016-12-14 | 庄可香 | Anion-friendly LED lamp holder |
| CN106189660A (en) * | 2016-05-23 | 2016-12-07 | 庄可香 | LED lamp radiator and LED lamp |
| CN106189656A (en) * | 2016-05-23 | 2016-12-07 | 庄可香 | An energy-saving and environment-friendly LED spotlight |
| CN106280855A (en) * | 2016-05-23 | 2017-01-04 | 庄可香 | An environmentally friendly LED downlight with formaldehyde removal function |
| CN106189668A (en) * | 2016-05-23 | 2016-12-07 | 庄可香 | A kind of preparation method of environment protection type flame-retarding led heat radiation coating |
| CN106221482A (en) * | 2016-05-23 | 2016-12-14 | 庄可香 | A negative ion LED energy-saving environmental protection lamp |
| CN106189667A (en) * | 2016-05-23 | 2016-12-07 | 庄可香 | A graphene environment-friendly LED energy-saving lamp |
| CN106189651A (en) * | 2016-05-23 | 2016-12-07 | 庄可香 | A LED light bulb assembly with high heat dissipation performance |
| CN106189659A (en) * | 2016-05-23 | 2016-12-07 | 庄可香 | A multi-functional aldehyde-removing and benzene-removing environmentally friendly LED candle lamp |
| CN105820701A (en) * | 2016-05-23 | 2016-08-03 | 庄可香 | Environment-friendly phenolic resin heat dissipating paint for decorative LED lamps |
| CN106189662A (en) * | 2016-05-23 | 2016-12-07 | 庄可香 | LED Bulb |
| CN106147499A (en) * | 2016-05-23 | 2016-11-23 | 庄可香 | Led lamp |
| CN106433305A (en) * | 2016-09-24 | 2017-02-22 | 陈建平 | Environmental-friendly diatom ooze ink |
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| JPH09137076A (en) * | 1995-11-13 | 1997-05-27 | Mitsubishi Chem Corp | Aqueous dispersion of colored silk particles, aqueous ink using the same, and ink jet recording liquid |
| CN101787234A (en) * | 2010-04-01 | 2010-07-28 | 北京今鼎新翰文化艺术有限公司 | Antique tusche and new preparation method thereof |
| CN101792624A (en) * | 2010-04-01 | 2010-08-04 | 北京今鼎新翰文化艺术有限公司 | Traditional Chinese medicine decoction additive for water-based ink and preparation method thereof |
| CN104194473B (en) * | 2014-07-28 | 2017-02-15 | 中山菲力特化工有限公司 | Printing ink containing antibacterial Chinese herbal medicinal ingredient |
| CN104212240B (en) * | 2014-08-20 | 2016-03-02 | 杭州天马思宏染织有限公司 | Adopt the ink-jet printer ink of compound botanical extract |
| CN104212236B (en) * | 2014-08-20 | 2016-01-27 | 中山艺展装饰工程有限公司 | A kind of fragrant ink with stimulating effect |
| CN104212238B (en) * | 2014-08-20 | 2016-03-02 | 杭州天马思宏染织有限公司 | A kind of antimicrobial form carbon black ink |
| CN104212237A (en) * | 2014-08-20 | 2014-12-17 | 中山艺展装饰工程有限公司 | Health-care ink that releases negative ions |
| CN104312271A (en) * | 2014-11-10 | 2015-01-28 | 合肥宏图彩印有限公司 | Quick-drying alcohol-based printing ink and preparation method thereof |
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