CN105330497A - Colorful firework and preparation method thereof - Google Patents
Colorful firework and preparation method thereof Download PDFInfo
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- CN105330497A CN105330497A CN201510802576.4A CN201510802576A CN105330497A CN 105330497 A CN105330497 A CN 105330497A CN 201510802576 A CN201510802576 A CN 201510802576A CN 105330497 A CN105330497 A CN 105330497A
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- parts
- firework
- varied
- blue light
- preparation
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- 238000002360 preparation method Methods 0.000 title claims description 14
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 25
- 239000000956 alloy Substances 0.000 claims abstract description 25
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 23
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 17
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 17
- AXZAYXJCENRGIM-UHFFFAOYSA-J dipotassium;tetrabromoplatinum(2-) Chemical compound [K+].[K+].[Br-].[Br-].[Br-].[Br-].[Pt+2] AXZAYXJCENRGIM-UHFFFAOYSA-J 0.000 claims abstract description 15
- 229910001487 potassium perchlorate Inorganic materials 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims description 27
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 24
- 239000002245 particle Substances 0.000 claims description 24
- 238000005469 granulation Methods 0.000 claims description 20
- 230000003179 granulation Effects 0.000 claims description 20
- 239000004411 aluminium Substances 0.000 claims description 16
- 229910002651 NO3 Inorganic materials 0.000 claims description 14
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 14
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims description 14
- 229910001864 baryta Inorganic materials 0.000 claims description 14
- 239000002893 slag Substances 0.000 claims description 14
- 229960004643 cupric oxide Drugs 0.000 claims description 12
- 229920003987 resole Polymers 0.000 claims description 8
- 229920000742 Cotton Polymers 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 150000001298 alcohols Chemical class 0.000 claims description 6
- 238000001125 extrusion Methods 0.000 claims description 6
- 238000006396 nitration reaction Methods 0.000 claims description 6
- 235000011837 pasties Nutrition 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 238000005563 spheronization Methods 0.000 claims description 6
- 229910001051 Magnalium Inorganic materials 0.000 claims description 4
- 229910019089 Mg-Fe Inorganic materials 0.000 claims description 4
- 238000004880 explosion Methods 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 2
- IWOUKMZUPDVPGQ-UHFFFAOYSA-N barium nitrate Chemical compound [Ba+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O IWOUKMZUPDVPGQ-UHFFFAOYSA-N 0.000 abstract 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 abstract 1
- 229920001568 phenolic resin Polymers 0.000 abstract 1
- 239000000843 powder Substances 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000003814 drug Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000779 smoke Substances 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- GDDNTTHUKVNJRA-UHFFFAOYSA-N 3-bromo-3,3-difluoroprop-1-ene Chemical compound FC(F)(Br)C=C GDDNTTHUKVNJRA-UHFFFAOYSA-N 0.000 description 1
- 235000017595 Callicarpa japonica Nutrition 0.000 description 1
- 240000003690 Callicarpa japonica Species 0.000 description 1
- 229920002449 FKM Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
Landscapes
- Pens And Brushes (AREA)
Abstract
A colorful firework comprises components in parts by weight as follows: 18-26 parts of potassium perchlorate, 30-40 parts of barium nitrate, 8-14 parts of a blue light agent, 12-20 parts of a special-grade alloy, 10-16 parts of special-grade aluminum dross and 5-10 parts of phenol-formaldehyde resin. The invention further discloses a method for preparing the colorful firework from the components. The prepared colorful firework can display aqua blue light waves in the sky during explosion, the formula is simple, and the ornamental value is higher.
Description
Technical field
The present invention relates to a kind of fireworks and firecrackers composition and preparation method thereof, particularly a kind of varied firework and preparation method thereof.
Background technology
The metal powder such as aluminium powder or magnesium powder is added in the many employings of traditional fireworks in firecrackers.The burning while fireworks blast of these metal powders produces dazzling white light, in order to make the color of fireworks more splendid, often will add other element, as sodium etc.Due to fireworks prepared by traditional method, these metal-powders are particulate state photochromic often just simple mixing when burning, and aesthetic feeling is not strong, is unfavorable for the development of fireworks color diversity.
CN10349077A discloses a kind of formula of multicolored fireworks, consists of the following composition: the bright pearl of 40% ~ 50%, the whistle medicine of 15% ~ 20%, the black powder of 3.5% ~ 4.5%, the unpacking propellant of 10% ~ 15% and
The propelling charge of 15% ~ 22%; Described bright pearl comprises red pearl, green pearl, Japanses beauty-berry, Huang Zhu and Bai Zhu.Production efficiency is high, low cost of manufacture, quality are high, beautiful in colour, fiting effect is good, the feature that overall visual art effect improves greatly to utilize the present invention to realize.
CN103121886A discloses the agent of a kind of colorful cold smoke flower pesticide and cold firework production method, and its component and weight percentage are: ammoniumper chlorate 20-30%, nitro-cotton 20-30%, silver color titanium valve 30-35%, embedded photoluminescent material 15-20%, viton 5-10%; The cold firework production method of spraying decoration class, comprises fuel granulation, medicament mixing and powder charge packaging; The cold firework production method of aerial waterfall shell, comprises luminescent material granulation, fuel mix, opens the making of quick-fried medicine and display shell filling.The cold smoke flower adopting medicament of the present invention to make can present multiple bright color, greatly improves the sight of cold smoke flower.
CN102515990A discloses a kind of varied firework, is made up of the following component of weight percent: oxygenant 35%-45%, charcoal 18%-22%, SULPHUR POWDER 18%-22%, aluminium powder 4%-6%, magnesium paper tinsel fragment 4%-6%, surplus are tackiness agent.Formula is simple, the track of pyrotechnics spark can be made to become more colourful, and its overall visual art effect will improve greatly.
Although the vision of fireworks, appreciation effect can be made in above three sections of prior aries to improve, above-mentioned three sections of prior aries all can not present the color of certain systematicness, and just simple color is various, and its sight needs to be further improved.
Summary of the invention
The object of the invention is to overcome the above-mentioned deficiency of prior art and a kind of varied firework and preparation method thereof be provided, the varied firework prepared explosion time can on high in show blue light wave, formula is simple, sight is stronger.
Technical scheme of the present invention is: a kind of varied firework, the following component composition according to weight part: potassium perchlorate 18 ~ 26 parts, nitrate of baryta 30 ~ 40 parts, Blue light agent 8 ~ 14 parts, specialty alloys 12 ~ 20 parts, superfine aluminium slag 10 ~ 16 parts, 5 ~ 10 parts, resol.
The further technical scheme of the present invention is: the following component composition according to weight part: potassium perchlorate 22 parts, nitrate of baryta 35 parts, Blue light agent 10 parts, specialty alloys 14 parts, superfine aluminium slag 12 parts, 7 parts, resol.
The present invention further technical scheme is: specialty alloys is one in magnalium, Mg-Fe alloy, ferroaluminium or its combination.
The present invention further technical scheme is: Blue light agent is the mixture of clorafin and cupric oxide.
Further, by weight: clorafin is 50 ~ 62 parts, cupric oxide 15 ~ 20 parts.
A preparation method for varied firework, adopt above-mentioned component, step is as follows:
1) take corresponding feed composition by proportioning, potassium perchlorate, nitrate of baryta, Blue light agent are ground respectively, make its particle diameter all be not more than 60 orders, then specialty alloys and superfine aluminium slag are ground respectively, make its particle diameter be 120 ~ 140 orders;
2) raw material in step 1) is added suitable alcohols and be mixed and made into pasty state, adopt spheronization or extrusion molding to carry out granulation, during granulation, in each particle, be equipped with the cotton thread after nitration treatment;
3) dry under vacuum condition, obtain varied firework.
Further, varied firework is blue light wave shape fireworks.
Further, step 2) in granulation time carry out under vacuum, alcohol used is raw spirit.
Further, step 2) in the diameter of gained particle be 2 ~ 6cm.
The present invention compared with prior art has following features: the varied firework that the present invention obtains explosion time can on high in show blue light wave, formula is simple, sight is stronger.
Below in conjunction with embodiment, detailed construction of the present invention is further described.
Embodiment
embodiment 1:
A kind of varied firework, the following component composition according to weight part: potassium perchlorate 22 parts, nitrate of baryta 35 parts, Blue light agent 10 parts, specialty alloys 14 parts, superfine aluminium slag 12 parts, 7 parts, resol.
Specialty alloys is magnalium.
Blue light agent is the mixture of clorafin and cupric oxide.
By weight: clorafin is 50 parts, cupric oxide 15 parts.
A preparation method for varied firework, adopt above-mentioned component, step is as follows:
1) take corresponding feed composition by proportioning, potassium perchlorate, nitrate of baryta, Blue light agent are ground respectively, make its particle diameter all be not more than 60 orders, then specialty alloys and superfine aluminium slag are ground respectively, make its particle diameter be 120 orders;
2) raw material in step 1) is added suitable alcohols and be mixed and made into pasty state, adopt spheronization or extrusion molding to carry out granulation, during granulation, in each particle, be equipped with the cotton thread after nitration treatment;
3) dry under vacuum condition, obtain varied firework.
Varied firework is blue light wave shape fireworks.
Step 2) in granulation time carry out under vacuum, alcohol used is raw spirit.
Step 2) in the diameter of gained particle be 2cm.
embodiment 2:
A kind of varied firework, the following component composition according to weight part: the following component composition according to weight part: potassium perchlorate 18 parts, nitrate of baryta 30 parts, Blue light agent 8 parts, specialty alloys 12 parts, superfine aluminium slag 10 parts, 5 parts, resol.
Specialty alloys is Mg-Fe alloy.
Blue light agent is the mixture of clorafin and cupric oxide.
By weight: clorafin is 62 parts, cupric oxide 20 parts.
A preparation method for varied firework, adopt above-mentioned component, step is as follows:
1) take corresponding feed composition by proportioning, potassium perchlorate, nitrate of baryta, Blue light agent are ground respectively, make its particle diameter all be not more than 60 orders, then specialty alloys and superfine aluminium slag are ground respectively, make its particle diameter be 140 orders;
2) raw material in step 1) is added suitable alcohols and be mixed and made into pasty state, adopt spheronization or extrusion molding to carry out granulation, during granulation, in each particle, be equipped with the cotton thread after nitration treatment;
3) dry under vacuum condition, obtain varied firework.
Varied firework is blue light wave shape fireworks.
Step 2) in granulation time carry out under vacuum, alcohol used is raw spirit.
Step 2) in the diameter of gained particle be 3cm.
embodiment 3:
A kind of varied firework, the following component composition according to weight part: the following component composition according to weight part: potassium perchlorate 20 parts, nitrate of baryta 35 parts, Blue light agent 9 parts, specialty alloys 18 parts, superfine aluminium slag 14 parts, 8 parts, resol.
Specialty alloys is ferroaluminium.
Blue light agent is the mixture of clorafin and cupric oxide.
By weight: clorafin is 55 parts, cupric oxide 18 parts.
A preparation method for varied firework, adopt above-mentioned component, step is as follows:
1) take corresponding feed composition by proportioning, potassium perchlorate, nitrate of baryta, Blue light agent are ground respectively, make its particle diameter all be not more than 60 orders, then specialty alloys and superfine aluminium slag are ground respectively, make its particle diameter be 130 orders;
2) raw material in step 1) is added suitable alcohols and be mixed and made into pasty state, adopt spheronization or extrusion molding to carry out granulation, during granulation, in each particle, be equipped with the cotton thread after nitration treatment;
3) dry under vacuum condition, obtain varied firework.
Varied firework is blue light wave shape fireworks.
Step 2) in granulation time carry out under vacuum, alcohol used is raw spirit.
Step 2) in the diameter of gained particle be 4cm.
embodiment 4:
A kind of varied firework, the following component composition according to weight part: the following component composition according to weight part: potassium perchlorate 24 parts, nitrate of baryta 36 parts, Blue light agent 12 parts, specialty alloys 18 parts, superfine aluminium slag 12 parts, 7 parts, resol.
Specialty alloys is the mixture of magnalium, Mg-Fe alloy.
Blue light agent is the mixture of clorafin and cupric oxide.
By weight: clorafin is 58 parts, cupric oxide 17 parts.
A preparation method for varied firework, adopt above-mentioned component, step is as follows:
1) take corresponding feed composition by proportioning, potassium perchlorate, nitrate of baryta, Blue light agent are ground respectively, make its particle diameter all be not more than 60 orders, then specialty alloys and superfine aluminium slag are ground respectively, make its particle diameter be 130 orders;
2) raw material in step 1) is added suitable alcohols and be mixed and made into pasty state, adopt spheronization or extrusion molding to carry out granulation, during granulation, in each particle, be equipped with the cotton thread after nitration treatment;
3) dry under vacuum condition, obtain varied firework.
Varied firework is blue light wave shape fireworks.
Step 2) in granulation time carry out under vacuum, alcohol used is raw spirit.
Step 2) in the diameter of gained particle be 6cm.
Claims (9)
1. a varied firework, is characterized in that: the following component composition according to weight part: potassium perchlorate 18 ~ 26 parts, nitrate of baryta 30 ~ 40 parts, Blue light agent 8 ~ 14 parts, specialty alloys 12 ~ 20 parts, superfine aluminium slag 10 ~ 16 parts, 5 ~ 10 parts, resol.
2. varied firework according to claim 1, is characterized in that: the following component composition according to weight part: potassium perchlorate 22 parts, nitrate of baryta 35 parts, Blue light agent 10 parts, specialty alloys 14 parts, superfine aluminium slag 12 parts, 7 parts, resol.
3. varied firework according to claim 1 and 2, is characterized in that: specialty alloys is one in magnalium, Mg-Fe alloy, ferroaluminium or its combination.
4. varied firework according to claim 1 and 2, is characterized in that: Blue light agent is the mixture of clorafin and cupric oxide.
5. varied firework according to claim 4, is characterized in that: by weight: clorafin is 50 ~ 62 parts, cupric oxide 15 ~ 20 parts.
6. a preparation method for varied firework, is characterized in that: adopt the component according to any one of claim 1-5, step is as follows:
1) take corresponding feed composition by proportioning, potassium perchlorate, nitrate of baryta, Blue light agent are ground respectively, make its particle diameter all be not more than 60 orders, then specialty alloys and superfine aluminium slag are ground respectively, make its particle diameter be 120 ~ 140 orders;
2) raw material in step 1) is added suitable alcohols and be mixed and made into pasty state, adopt spheronization or extrusion molding to carry out granulation, during granulation, in each particle, be equipped with the cotton thread after nitration treatment;
3) dry under vacuum condition, obtain varied firework.
7. the preparation method of varied firework according to claim 6, is characterized in that: varied firework is blue light wave shape fireworks.
8. the preparation method of varied firework according to claim 7, is characterized in that: step 2) in granulation time carry out under vacuum, alcohol used is raw spirit.
9. the preparation method of the varied firework according to claim 7 or 8, is characterized in that: step 2) in the diameter of gained particle be 2 ~ 6cm.
Priority Applications (1)
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CN201510802576.4A CN105330497A (en) | 2015-11-19 | 2015-11-19 | Colorful firework and preparation method thereof |
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CN201510802576.4A CN105330497A (en) | 2015-11-19 | 2015-11-19 | Colorful firework and preparation method thereof |
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CN201510802576.4A Pending CN105330497A (en) | 2015-11-19 | 2015-11-19 | Colorful firework and preparation method thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107628918A (en) * | 2016-11-30 | 2018-01-26 | 湖北航天化学技术研究所 | A kind of environment-friendly and low-toxicity bright pearl material of green and its preparation method and application |
CN111763129A (en) * | 2020-07-01 | 2020-10-13 | 肖永日 | Sulfur-free sulfoblue agent and preparation method thereof |
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US3951705A (en) * | 1975-05-14 | 1976-04-20 | The United States Of America As Represented By The Secretary Of The Army | Blue-burning tracer mix |
CN86102788A (en) * | 1986-04-16 | 1987-10-28 | 中山大学 | The fireworks composition of safe blue pyrotechnics |
CN1420109A (en) * | 2002-10-17 | 2003-05-28 | 萧永日 | Blue light agent |
CN102910995A (en) * | 2011-08-02 | 2013-02-06 | 浏阳市五环烟花厂 | Sparkle beads producing cardamon green firework effect, and manufacturing method thereof |
-
2015
- 2015-11-19 CN CN201510802576.4A patent/CN105330497A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3951705A (en) * | 1975-05-14 | 1976-04-20 | The United States Of America As Represented By The Secretary Of The Army | Blue-burning tracer mix |
CN86102788A (en) * | 1986-04-16 | 1987-10-28 | 中山大学 | The fireworks composition of safe blue pyrotechnics |
CN1420109A (en) * | 2002-10-17 | 2003-05-28 | 萧永日 | Blue light agent |
CN102910995A (en) * | 2011-08-02 | 2013-02-06 | 浏阳市五环烟花厂 | Sparkle beads producing cardamon green firework effect, and manufacturing method thereof |
Non-Patent Citations (2)
Title |
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JAI PRAKASH AGRAWAL: "《高能材料——火药、炸药和烟火药》", 31 July 2015, 国防工业出版社 * |
潘功配: "《烟花爆竹原理》", 1 June 2013, 南京大学出版社 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107628918A (en) * | 2016-11-30 | 2018-01-26 | 湖北航天化学技术研究所 | A kind of environment-friendly and low-toxicity bright pearl material of green and its preparation method and application |
CN107628918B (en) * | 2016-11-30 | 2019-07-12 | 湖北航天化学技术研究所 | Environment-friendly and low-toxicity bright pearl material of green of one kind and its preparation method and application |
CN111763129A (en) * | 2020-07-01 | 2020-10-13 | 肖永日 | Sulfur-free sulfoblue agent and preparation method thereof |
CN111763129B (en) * | 2020-07-01 | 2022-02-01 | 肖永日 | Sulfur-free sulfoblue agent and preparation method thereof |
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Application publication date: 20160217 |