CN105280800A - Semiconductor diode chip - Google Patents
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- 239000004065 semiconductor Substances 0.000 title claims abstract description 133
- 229910052751 metal Inorganic materials 0.000 claims abstract description 78
- 239000002184 metal Substances 0.000 claims abstract description 75
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 239000010949 copper Substances 0.000 claims description 5
- 230000004888 barrier function Effects 0.000 claims 14
- 238000003466 welding Methods 0.000 abstract description 9
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 238000011282 treatment Methods 0.000 abstract description 2
- 238000005476 soldering Methods 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 230000017525 heat dissipation Effects 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910000679 solder Inorganic materials 0.000 description 2
- 239000004642 Polyimide Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
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- H—ELECTRICITY
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- H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
- H10H20/80—Constructional details
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- H—ELECTRICITY
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- H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
- H10H20/80—Constructional details
- H10H20/85—Packages
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
- H10H20/80—Constructional details
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- H10H20/8585—Means for heat extraction or cooling being an interconnection
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Abstract
一种半导体二极管芯片,属于半导体生产技术领域,第一导电层设置于第一半导体层上,第一导电层与第一半导体层欧姆接触;第一绝缘层覆盖由第二半导体层、半导体发光层、第一半导体层和第一导电层组成的半导体层侧壁,第一绝缘层还延伸覆盖部分透明载体,本发明的以上两种技术方案都是通过第一金属焊盘对半导体有源区的全覆盖,更好地改善对半导体芯片热传导,不同平台的第一和第二金属焊盘设计也利于正负电极焊接时的不同处理来提高焊接的合格率。
A semiconductor diode chip, belonging to the technical field of semiconductor production, the first conductive layer is arranged on the first semiconductor layer, the first conductive layer is in ohmic contact with the first semiconductor layer; the first insulating layer is covered by the second semiconductor layer, the semiconductor light-emitting layer 1, the side wall of the semiconductor layer composed of the first semiconductor layer and the first conductive layer, the first insulating layer also extends to cover part of the transparent carrier, the above two technical solutions of the present invention are all connected to the semiconductor active region by the first metal pad Full coverage, better heat conduction to the semiconductor chip, the design of the first and second metal pads on different platforms is also conducive to different treatments when welding the positive and negative electrodes to improve the qualified rate of welding.
Description
技术领域 technical field
本发明属于半导体生产技术领域,具体涉及用于倒装焊接的半导体二极管芯片。 The invention belongs to the technical field of semiconductor production, and in particular relates to a semiconductor diode chip for flip-chip welding.
技术背景 technical background
在半导体二极管领域,LED作为重要的光电子二极管,LED技术正逐步取代传统照明技术和荧光技术进入到照明领域,同时LED芯片也因其同时具备电子器件的特性,除了照明应用,更开辟了许多全新的应用领域。在对流明值得更高追求和对产业制造成本的不断压缩的过程中,发光二极管的倒装应用,已被普遍认为是行业趋势。倒装发光二极管芯片是利于大电流来获取更高的流明值,并用热沉更接近半导体有源区的焊接方式来改善芯片的热传导,传统的正装结构LED技术被慢慢淘汰,取而代之的是可靠性更好,流明密度更大的倒装结构的LED技术。 In the field of semiconductor diodes, LED is an important photoelectric diode. LED technology is gradually replacing traditional lighting technology and fluorescent technology and entering the lighting field. At the same time, LED chips also have the characteristics of electronic devices. field of application. In the pursuit of higher lumens and the continuous compression of industrial manufacturing costs, the flip-chip application of light-emitting diodes has been generally considered to be an industry trend. Flip-chip light-emitting diode chips are beneficial to large currents to obtain higher lumens, and the heat conduction of the chips is improved by welding the heat sink closer to the active area of the semiconductor. The traditional LED technology of the positive structure is gradually eliminated and replaced by reliable Better performance, higher lumen density flip-chip LED technology.
在倒装二极管芯片焊接过程中因为电极面朝下,芯片与焊接点的对准是需要更精准的封装设备投入。而且同平面、小间隔的正负电极排布,在焊接中也容易出现焊料互溢导致的芯片短路。 During the soldering process of the flip-chip diode chip, because the electrode faces downward, the alignment of the chip and the soldering point requires more precise packaging equipment investment. Moreover, the positive and negative electrodes arranged on the same plane and with small intervals are also prone to chip short circuit caused by solder overflow during soldering.
发明内容 Contents of the invention
本发明目的在于制造一种用于倒装焊接的半导体二极管芯片结构,以利于芯片电极的识别和倒装焊接;同时更好的解决二极管芯片散热问题。 The purpose of the present invention is to manufacture a semiconductor diode chip structure for flip-chip welding, so as to facilitate identification of chip electrodes and flip-chip welding; meanwhile, it can better solve the heat dissipation problem of the diode chip.
本发明的第一种技术方案是整个半导体二极管芯片为一组半导体单元构成:包括依次设置在透明载体上的第二半导体层、半导体发光层和第一半导体层;其特点是:第一导电层设置于第一半导体层上,第一导电层与第一半导体层欧姆接触;第一绝缘层覆盖由第二半导体层、半导体发光层、第一半导体层和第一导电层组成的半导体层侧壁,第一绝缘层还延伸覆盖部分透明载体;在第一绝缘层外侧设置第二导电层,并且,第二导电层与第二半导体层形成欧姆接触,第二导电层在半导体层侧壁还延伸至裸露的透明载体上;在第二导电层外设置第二绝缘层;第二金属焊盘与延伸至透明载体上的第二导电层欧姆接触;第一金属焊盘设置在第二绝缘层上,第一金属焊盘覆盖整个发光层,并经过第二绝缘层和第一绝缘层的通孔与第一导电层欧姆接触。 The first technical solution of the present invention is that the whole semiconductor diode chip is composed of a group of semiconductor units: including the second semiconductor layer, the semiconductor light-emitting layer and the first semiconductor layer arranged on the transparent carrier in sequence; its characteristic is: the first conductive layer Set on the first semiconductor layer, the first conductive layer is in ohmic contact with the first semiconductor layer; the first insulating layer covers the side wall of the semiconductor layer composed of the second semiconductor layer, the semiconductor light emitting layer, the first semiconductor layer and the first conductive layer , the first insulating layer also extends to cover part of the transparent carrier; a second conductive layer is arranged outside the first insulating layer, and the second conductive layer forms an ohmic contact with the second semiconductor layer, and the second conductive layer also extends on the side wall of the semiconductor layer To the exposed transparent carrier; the second insulating layer is arranged outside the second conductive layer; the second metal pad is in ohmic contact with the second conductive layer extending to the transparent carrier; the first metal pad is arranged on the second insulating layer , the first metal pad covers the entire light-emitting layer, and is in ohmic contact with the first conductive layer through the through holes of the second insulating layer and the first insulating layer.
本发明的第二种技术方案是:由多组半导体单元组成为一个半导体二极管芯片。该半导体二极管芯片包括至少两组半导体单元,各组半导体单元在各自的透明载体上依次设置第二半导体层、半导体发光层和第一半导体层;其特点是:第一导电层设置于第一半导体层上,第一导电层与第一半导体层欧姆接触;第一绝缘层覆盖由第二半导体层、半导体发光层、第一半导体层和第一导电层组成的半导体层的一侧的侧壁,第一绝缘层还延伸覆盖部分透明载体;在第一绝缘层外侧设置第二导电层,并且,第二导电层与第二半导体层形成欧姆接触,第二导电层的一端与本组的半导体的第一导电层欧姆接触,第二导电层的另一端与相邻的半导体的第二半导体层欧姆接触,第二导电层还分别延伸至位于各组半导体单元侧壁的裸露的透明载体上;在第二导电层外设置第二绝缘层,各组半导体单元的第二绝缘层覆盖由第二半导体层、半导体发光层、第一半导体层和第一导电层组成的半导体层的另一侧的侧壁;第二金属焊盘与延伸至透明载体上的第二导电层欧姆接触;第一金属焊盘设置在第二绝缘层上,第一金属焊盘覆盖整个发光层,并经过第二绝缘层和第一绝缘层的通孔与第一导电层欧姆接触。 The second technical solution of the present invention is: a semiconductor diode chip is composed of multiple groups of semiconductor units. The semiconductor diode chip includes at least two groups of semiconductor units, and each group of semiconductor units is sequentially provided with a second semiconductor layer, a semiconductor light-emitting layer and a first semiconductor layer on their respective transparent carriers; the feature is: the first conductive layer is arranged on the first semiconductor layer, the first conductive layer is in ohmic contact with the first semiconductor layer; the first insulating layer covers the side wall of one side of the semiconductor layer composed of the second semiconductor layer, the semiconductor light-emitting layer, the first semiconductor layer and the first conductive layer, The first insulating layer also extends to cover part of the transparent carrier; a second conductive layer is arranged outside the first insulating layer, and the second conductive layer forms an ohmic contact with the second semiconductor layer, and one end of the second conductive layer is connected to the semiconductor of the group. The first conductive layer is in ohmic contact, the other end of the second conductive layer is in ohmic contact with the second semiconductor layer of the adjacent semiconductor, and the second conductive layer also extends to the exposed transparent carrier on the side wall of each group of semiconductor units; A second insulating layer is arranged outside the second conductive layer, and the second insulating layer of each group of semiconductor units covers the other side of the semiconductor layer composed of the second semiconductor layer, the semiconductor light-emitting layer, the first semiconductor layer and the first conductive layer. wall; the second metal pad is in ohmic contact with the second conductive layer extending to the transparent carrier; the first metal pad is arranged on the second insulating layer, and the first metal pad covers the entire light-emitting layer and passes through the second insulating layer The through hole of the first insulating layer is in ohmic contact with the first conductive layer.
本发明的以上两种技术方案都是通过第一金属焊盘对半导体有源区的全覆盖,更好地改善对半导体芯片热传导,不同平台的第一和第二金属焊盘设计也利于正负电极焊接时的不同处理来提高焊接的合格率。 The above two technical solutions of the present invention are to better improve the heat conduction of the semiconductor chip through the full coverage of the first metal pad on the semiconductor active area, and the design of the first and second metal pads on different platforms is also beneficial to positive and negative Different treatments during electrode welding to improve the qualified rate of welding.
第二种技术方案中相邻的各半导体单元之间形成串联电路。 In the second technical solution, a series circuit is formed between adjacent semiconductor units.
以上两种技术方案的优选设计是: The preferred design of the above two technical solutions is:
所述第二半导体层、半导体发光层和第一半导体层的总厚度大于5μm。在保证二极管结构完整性前提下,更厚的外延结构在本发明中的优势和益处更明显。 The total thickness of the second semiconductor layer, the semiconductor light-emitting layer and the first semiconductor layer is greater than 5 μm. Under the premise of ensuring the integrity of the diode structure, the advantages and benefits of the thicker epitaxial structure in the present invention are more obvious.
所述第一绝缘层厚度大于1μm。主要是低介电常数的介质层组成,保证绝缘层的绝缘性和抗电击穿性。 The thickness of the first insulating layer is greater than 1 μm. It is mainly composed of a dielectric layer with a low dielectric constant to ensure the insulation and electrical breakdown resistance of the insulating layer.
所述第二绝缘层的厚度大于2μm。保证绝缘层在应用中的机械稳定性及绝缘可靠性。 The thickness of the second insulating layer is greater than 2 μm. Ensure the mechanical stability and insulation reliability of the insulating layer in the application.
所述第一金属焊盘和第二金属焊盘的高度差大于8μm。第一金属焊盘和第二金属焊盘之间的高度差能提高焊接识别度,并对不同金属焊盘使用差别化工艺条件。 The height difference between the first metal pad and the second metal pad is greater than 8 μm. The height difference between the first metal pad and the second metal pad can improve welding recognition, and use differentiated process conditions for different metal pads.
所述第一金属焊盘包括铜元素。含铜电极成本低可焊性好,常见金属中导热性仅次与银。 The first metal pad includes copper element. Copper-containing electrodes have low cost and good solderability, and the thermal conductivity of common metals is second only to silver.
所述第一金属焊盘的厚度大于第二金属焊盘71b的厚度。 The thickness of the first metal pad is greater than the thickness of the second metal pad 71b.
所述第一金属焊盘的厚度为5μm,第二金属焊盘的厚度为2μm。更厚的第一金属焊盘能更大程度增加第一金属焊盘和第二金属焊盘间的高度差,降低焊接时焊盘上焊料溢出对可靠性的影响。 The thickness of the first metal pad is 5 μm, and the thickness of the second metal pad is 2 μm. The thicker first metal pad can increase the height difference between the first metal pad and the second metal pad to a greater extent, and reduce the impact of solder overflow on the pad during soldering on reliability.
所述第一金属焊盘的表面积占半导体二极管芯片总表面积的80%以上,更大的金属面利于芯片散热。 The surface area of the first metal pad accounts for more than 80% of the total surface area of the semiconductor diode chip, and the larger metal surface is conducive to chip heat dissipation.
附图说明 Description of drawings
图1为本发明半导体层的剖面结构示意图。 FIG. 1 is a schematic cross-sectional structure diagram of a semiconductor layer of the present invention.
图2为本发明实施例一的剖面示意图。 FIG. 2 is a schematic cross-sectional view of Embodiment 1 of the present invention.
图3为图2的俯向示意图。 FIG. 3 is a schematic top view of FIG. 2 .
图4为本发明实施例二的剖面示意图。 Fig. 4 is a schematic cross-sectional view of Embodiment 2 of the present invention.
图5图4的俯向示意图。 Fig. 5 is a top view of Fig. 4 .
具体实施方式 detailed description
实施例1:是由单一的半导体单元组成为一个半导体二极管芯片的例子。 Embodiment 1: An example in which a semiconductor diode chip is composed of a single semiconductor unit.
如图1所示,在透明载体01上依次设置第二半导体层11、半导体发光层21和第一半导体层31,制成的半导体层总厚度大于5μm。 As shown in FIG. 1 , the second semiconductor layer 11 , the semiconductor light-emitting layer 21 and the first semiconductor layer 31 are sequentially arranged on the transparent carrier 01 , and the total thickness of the manufactured semiconductor layer is greater than 5 μm.
如图2所示,第一导电层(含反射金属元素的金属层)41设置于第一半导体层31上,第二导电层61设置于第一导电层41上,第二导电层61还与第二半导体层11形成欧姆接触,在第一导电层41和第二导电层61之间设置第一绝缘层51a,第一绝缘层51a厚度一般大于1μm。 As shown in Figure 2, the first conductive layer (metal layer containing reflective metal elements) 41 is disposed on the first semiconductor layer 31, the second conductive layer 61 is disposed on the first conductive layer 41, and the second conductive layer 61 is also connected with The second semiconductor layer 11 forms an ohmic contact, and a first insulating layer 51 a is disposed between the first conductive layer 41 and the second conductive layer 61 , and the thickness of the first insulating layer 51 a is generally greater than 1 μm.
第二导电层61的部分延伸至裸露的透明载体01上,延伸的部分或全部与第二金属焊盘71b欧姆接触。 A part of the second conductive layer 61 extends to the bare transparent carrier 01 , and the extended part or all is in ohmic contact with the second metal pad 71b.
第一金属焊盘71a置于发光层最上方,在第一金属焊盘71a与第二导电层61重叠的部分设置第二绝缘层51b,第二绝缘层51b的厚度一般厚度大于2μm。 The first metal pad 71a is placed on the top of the light-emitting layer, and the second insulating layer 51b is provided on the overlapping portion of the first metal pad 71a and the second conductive layer 61. The thickness of the second insulating layer 51b is generally greater than 2 μm.
第一金属焊盘71a通过设置在第一绝缘层51a和第二绝缘层51b上的通孔与第一导电层41欧姆接触。 The first metal pad 71a is in ohmic contact with the first conductive layer 41 through the through holes provided on the first insulating layer 51a and the second insulating layer 51b.
第一金属焊盘71a和第二金属焊盘71b同为含金元素的焊盘,两者高度差大于8μm;进一步的,第一金属焊盘71a与第二金属焊盘72b含有不同金属元素,更优化的是第一金属焊盘71a是含铜的焊盘,厚度可以大于第二金属焊盘71b,如第一金属焊盘71a的厚度为5μm,第二金属焊盘的厚度71b为2μm。 The first metal pad 71a and the second metal pad 71b are pads containing gold elements, and the height difference between them is greater than 8 μm; further, the first metal pad 71a and the second metal pad 72b contain different metal elements, More optimally, the first metal pad 71a is a pad containing copper, and its thickness may be greater than that of the second metal pad 71b, for example, the thickness of the first metal pad 71a is 5 μm, and the thickness of the second metal pad 71b is 2 μm.
实施例1中第一金属焊盘71a、第二金属焊盘71b的高度差大于11μm。 In Embodiment 1, the height difference between the first metal pad 71 a and the second metal pad 71 b is greater than 11 μm.
第一金属焊盘71a和第二金属焊盘71b可以如图3所示,第一金属焊盘71a表面积远大于第二金属焊盘71b,且第一金属焊盘71a表面积可以实现占整个芯片总表面积的80%。 The first metal pad 71a and the second metal pad 71b can be shown in Figure 3, the surface area of the first metal pad 71a is much larger than the second metal pad 71b, and the surface area of the first metal pad 71a can be realized to account for the entire chip. 80% of the surface area.
实施例2:是由若干个半导体单元组成为一个半导体二极管芯片的例子。 Embodiment 2: An example in which a semiconductor diode chip is composed of several semiconductor units.
如图4所示,在透明载体01上依次形成第二半导体层11、半导体发光层21和第一半导体层31,制成的半导体层总厚度大于5μm。 As shown in FIG. 4 , the second semiconductor layer 11 , the semiconductor light emitting layer 21 and the first semiconductor layer 31 are sequentially formed on the transparent carrier 01 , and the total thickness of the manufactured semiconductor layer is greater than 5 μm.
通过电隔离形成三组半导体单元后,将第一导电层(含反射金属元素的金属层)41置于每组半导体单元的第一半导体层31上。 After three groups of semiconductor units are formed by electrical isolation, a first conductive layer (a metal layer containing reflective metal elements) 41 is placed on the first semiconductor layer 31 of each group of semiconductor units.
第二导电层61(与第二半导体层能形成欧姆接触的金属层)一端置于一组半导体单元的第二半导体层11上,另一端与相邻的半导体单元的第一导电层41欧姆接触。 One end of the second conductive layer 61 (a metal layer capable of forming ohmic contact with the second semiconductor layer) is placed on the second semiconductor layer 11 of a group of semiconductor units, and the other end is in ohmic contact with the first conductive layer 41 of the adjacent semiconductor unit .
相邻的半导体单元之间的侧壁被第一绝缘层51a覆盖,相邻两个半导体单元间形成串联电路,负极端的第二导电层61一端与第二半导体11接触,一端延伸至裸露的透明载体01上,第二金属焊盘71b部分或全部与延伸的第二导电层61接触。插入的第一绝缘层51a厚度一般大于1μm,主要是低介电常数的介质层组成;第二导电层61部分延伸至裸露的透明载体01上,延伸部分或全部与第二金属焊盘71b欧姆接触,第一导电层41和第二导电层61厚度一般小于1μm。第二绝缘层51b可以是类似聚酰亚胺的有机绝缘层厚度可以大于5μm覆盖整个发光区和互联半导体单元的第二导电层。 The side walls between adjacent semiconductor units are covered by the first insulating layer 51a, and a series circuit is formed between two adjacent semiconductor units. One end of the second conductive layer 61 of the negative terminal is in contact with the second semiconductor 11, and one end extends to the exposed On the transparent carrier 01 , part or all of the second metal pad 71 b is in contact with the extended second conductive layer 61 . The thickness of the inserted first insulating layer 51a is generally greater than 1 μm, and it is mainly composed of a dielectric layer with a low dielectric constant; the second conductive layer 61 partially extends to the exposed transparent carrier 01, and part or all of the extension is ohmic with the second metal pad 71b In contact, the thickness of the first conductive layer 41 and the second conductive layer 61 is generally less than 1 μm. The second insulating layer 51b may be an organic insulating layer similar to polyimide, the thickness of which may be greater than 5 μm, covering the entire light emitting region and the second conductive layer interconnecting the semiconductor units.
第一金属焊盘71a置于发光层最上方,第一金属焊盘71a与正极端的第一导电层41通过第一绝缘层51a和第二绝缘层51b的通孔欧姆接触。 The first metal pad 71a is placed on the top of the light-emitting layer, and the first metal pad 71a is in ohmic contact with the first conductive layer 41 at the positive end through the through holes of the first insulating layer 51a and the second insulating layer 51b.
如本实施例中,第一金属焊盘71a是含铜的焊盘,第二焊盘71b为金焊盘,第一金属焊盘71a厚度为5μm,第二金属焊盘71b厚度为2μm,此时实施例中第一第二金属焊盘高度差大于14μm。 As in this embodiment, the first metal pad 71a is a pad containing copper, the second pad 71b is a gold pad, the thickness of the first metal pad 71a is 5 μm, and the thickness of the second metal pad 71b is 2 μm. In this embodiment, the height difference between the first and second metal pads is greater than 14 μm.
金属焊盘面的第一金属焊盘71a和第二金属焊盘71b可以如图5所示,第一金属焊盘71a表面积远大于第二金属焊盘71b,第一金属焊盘71a的表面积占半导体二极管芯片总表面积的80%以上,且第一金属焊盘71a覆盖整个各组半导体单元的有源区。 The first metal pad 71a and the second metal pad 71b on the metal pad surface can be shown in FIG. The total surface area of the diode chip is more than 80%, and the first metal pad 71a covers the entire active area of each group of semiconductor units.
以上各图式与说明仅是对特定实施例的解释,以增加对本发明技术方案的理解。例如金属焊盘正面分布不限于本实施说公开的示意图,虽然本发明已说明如上,然其并非用以闲置本发明的范围、实施顺序、或使用材料与制作方法,对于本发明所作的各种修饰与变更,皆不脱离本发明的精神和范围。 The above drawings and descriptions are only explanations of specific embodiments to enhance the understanding of the technical solution of the present invention. For example, the distribution of the front side of the metal pad is not limited to the schematic diagram disclosed in this implementation statement. Although the present invention has been described above, it is not used to idle the scope of the present invention, the implementation sequence, or the materials and manufacturing methods used. For the various aspects of the present invention Modifications and changes do not depart from the spirit and scope of the present invention.
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CN112802953A (en) * | 2020-12-28 | 2021-05-14 | 厦门三安光电有限公司 | Light-emitting diode and preparation method thereof |
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