CN105272372B - A kind of binding agent and its compound method for burning till preceding incrustation suitable for glazed tile - Google Patents
A kind of binding agent and its compound method for burning till preceding incrustation suitable for glazed tile Download PDFInfo
- Publication number
- CN105272372B CN105272372B CN201510665378.8A CN201510665378A CN105272372B CN 105272372 B CN105272372 B CN 105272372B CN 201510665378 A CN201510665378 A CN 201510665378A CN 105272372 B CN105272372 B CN 105272372B
- Authority
- CN
- China
- Prior art keywords
- binding agent
- bentonite
- glaze
- potassium feldspar
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000011230 binding agent Substances 0.000 title claims abstract description 20
- 238000000034 method Methods 0.000 title abstract description 14
- 150000001875 compounds Chemical class 0.000 title abstract description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 36
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000000440 bentonite Substances 0.000 claims abstract description 22
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 22
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 22
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 235000013312 flour Nutrition 0.000 claims abstract description 12
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 12
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 12
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 11
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 11
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 11
- 239000002689 soil Substances 0.000 claims 1
- 235000009508 confectionery Nutrition 0.000 abstract description 25
- 238000004519 manufacturing process Methods 0.000 abstract description 20
- 230000000694 effects Effects 0.000 abstract description 7
- 238000010304 firing Methods 0.000 abstract description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract description 7
- 238000000498 ball milling Methods 0.000 abstract description 5
- 238000007664 blowing Methods 0.000 abstract description 5
- 239000004615 ingredient Substances 0.000 abstract description 2
- 238000001035 drying Methods 0.000 description 8
- 230000008569 process Effects 0.000 description 5
- 230000008859 change Effects 0.000 description 4
- 238000002386 leaching Methods 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000035800 maturation Effects 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 239000011449 brick Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 210000003298 dental enamel Anatomy 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 235000021552 granulated sugar Nutrition 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- -1 quartzy ratio Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Compositions Of Oxide Ceramics (AREA)
- Adornments (AREA)
Abstract
The present invention disclose a kind of binding agent and compound method for burning till preceding incrustation suitable for glazed tile, by weight percentage for：Bentonite 2 ~ 5, potassium feldspar 5 ~ 10, silica flour 2 ~ 5, methyl 1.5 ~ 2.5, ethylene glycol 25, remaining is the proportion ingredient of water, adds ball mill ball milling 10 hours, fineness reaches 320 mesh screen residues《After 0.5%, blowing is crossed 160 mesh reciprocating sieves and reached the standard grade use.The present invention is mainly changed to adjust the glaze slip performance of binding agent by the ratio of bentonite and methyl, is allowed to meet production stamp requirement.Bentonite is adjusted, potassium feldspar, quartzy ratio, controls binding agent high temperature firing temperature, is allowed to while cold stage keeps sticky, and candy glaze effect and transparency are not interfered with after high temperature is burnt till；Binding agent of the present invention effectively overcomes the winged dry granular problem in existing production simultaneously.
Description
Technical field
This new construction is related to a kind of Building Ceramics Industry glaze paint brick product dry granular binding agent in incrustation before burning till.
Background technology
Candy glaze be in recent years Spain's glaze company exploitation new glaze kind, have it is wear-resisting antifouling, have gorgeous take by force under light
Purpose gloss, there is special decorative effect.In other areas, the maturation process of use is Spray glaze -- stamp（Ink-jet）-- leaching sugar
Fruit glaze -- drying -- enter klining into.After drying, candy glaze dry granular is secured firmly to candy glaze by the reticular substance in stamp-pad ink
Adobe surface, it would not be influenceed to produce defect by kiln interior air-flow when burning till into kiln.But the technique must be burnt
Into preceding drying, production line will have this equipment of dry kiln before kiln.But in general ceramic production line, it is dry kiln before no kiln
, therefore production candy glaze can not use existing maturation process.If must be produced using existing process, one can only be built
Dry kiln before individual kiln, construction cost 500,000 need to be invested, plus left to the indirect loss of Influence of production, input 2,000,000 during putting up a kiln
Right can normally produce.Therefore, the maturation process produces candy glaze product for the ceramic production line built up, product be present
Reach the standard grade transformation cycle length, improvement of manufacturing line input is big, formed sale bring benefits process it is long the problem of.
And there are some old factories to be also possible to, because production line place problem can not increase dry kiln before kiln, Spray can only be used
Glaze -- stamp（Ink-jet) -- leaching candy glaze -- enter klining into.And just enter klining into being burnt till in kiln convection drying without drying
It can break through the netted fixed bed that the special stamp-pad ink of candy glaze is formed because moisture drastically volatilizees in glaze, cause glaze destrengthening,
Candy glaze dry granular is taken away by kiln interior air-flow, finished surface does not have candy glaze to turn into waste product.Normal production does not have in actual production
It is problematic, but after the empty kiln of appearance, air-flow changes, and the existing larger fluctuation of temperature, causes glaze rate of drying to change, glaze before kiln
The problem of material intensity is affected, and candy glaze dry granular is blown away, referred to as flies dry granular phenomenon.Shadow is caused to the yield rate of product
Ring, also increase the cost of product.
Some factories certainly flies dry granular problem using glue spraying hydrolysis after leaching candy glaze, but this method because the glue of spray to candy glaze
Surface forms other influences, causes dry granular particle thick, feels without the exquisiteness of granulated sugar, product effect is undesirable.
The content of the invention
In order to solve problem, before being used in leaching candy glaze it is an object of the invention to provide one kind, dry and burnt till in glaze
Cheng Zhong, increase the adhesion strength between cover-coat enamel and candy glaze, suitable for the binding agent for burning till preceding incrustation of glazed tile.
The technical solution adopted by the present invention is：A kind of binding agent for burning till preceding incrustation suitable for glazed tile, it is special
Sign is：Formed by bentonite, bentonite, potassium feldspar, silica flour, sodium carboxymethylcellulose, ethylene glycol, water modulation, it is described each
The percentage by weight of component is：Bentonite 2 ~ 5, potassium feldspar 5 ~ 8, silica flour 2 ~ 5, sodium carboxymethylcellulose 1.5 ~ 2.5, ethylene glycol
25, remaining is water.
The compound method of binding agent of the present invention：It is by weight percentage：Bentonite 2 ~ 5, potassium feldspar 5 ~ 10, silica flour 2 ~ 5,
Sodium carboxymethylcellulose 1.5 ~ 2.5, ethylene glycol 25, remaining is the proportion ingredient of water, adds ball mill ball milling 10 hours, fineness reaches
To 320 mesh screen residues《After 0.5%, blowing is crossed 160 mesh reciprocating sieves and reached the standard grade use.
It has been found that existing production line enters brick again in candy glaze after empty kiln, and because air-flow changes, kiln
The existing larger fluctuation of stokehold temperature, causes glaze rate of drying to change, and glaze intensity is affected, and then candy glaze occurs and is blown away
The problem of.And it can change in kiln height case interface airstream in kiln because of sectional area, change in flow, can also blow away adhesion strength
Not high dry granular.Up to 600 degree, now conventional organic binder bond decomposes kiln temperature, it is impossible to provides required bonding at this
Intensity.And below, at flashboard, temperature is up to 1000 degree, and a small amount of liquid phase produces candy glaze, plays cementation, can expire
The normal production of foot, illustrates only to need somewhat to increase glaze intensity, changes glaze rate of drying, add different binding agents, avoid
Adhesion strength disappears simultaneously, changes water evaporation rate, flies dry granular so as to solve the problems, such as to produce hollow kiln.
The present invention is used in combination using raw mineral materials bentonite and sodium carboxymethylcellulose, fine by bentonite and carboxymethyl
Plain sodium is tieed up to adjust the glaze slip performance of binding agent, is allowed to meet production stamp requirement.So the present invention is just entering kiln
Normal temperature is to before 270 degree of temperature, and sodium carboxymethylcellulose can play cementation, and bentonite also has cementation；In temperature height
After crossing 270 degree, carboxymethyl cellulose has burnt, bentonitic to continue to play cementation, avoids winged dry granular problem.And carboxylic
Sodium carboxymethylcellulose pyce and bentonite dry dehydrating speed difference, time cause different in size, avoid glaze in narrow humidity province
Intensity is lost in short time, causes to fly dry granular phenomenon after fluctuation.After adding bentonite, glaze can influence because becoming high temperature
Transparency, if adjustment glaze temperature is too low, candy glaze surface effect can be influenceed again, therefore add potassium feldspar, quartz, so as to control
The transparency and firing temperature of enamel frit makeing material, it is allowed to while cold stage keeps sticky, and will not shadow after high temperature is burnt till
Ring candy glaze effect and transparency.
The present invention is changed by the ratio of bentonite and methyl to adjust the glaze slip performance of binding agent, is allowed to meet production print
Flower requirement；Potassium feldspar, quartz are added simultaneously, controls the high temperature firing temperature of binding agent, is allowed to keep viscous in cold stage
While property, and candy glaze effect and transparency are not interfered with after high temperature is burnt till；Binding agent of the present invention is effectively gram simultaneously
The winged dry granular problem in existing production is taken.
Embodiment
In order to preferably illustrate technology disclosed in this invention, it is described further by following case study on implementation：
Embodiment 1：
First weigh bentonite 20Kg, potassium feldspar 55Kg, the 0Kg of silica flour 5, the Kg of methyl 25, the Kg of ethylene glycol 250, water 600
Kg；Above-mentioned raw materials are sequentially added into ball mill ball milling 10 hours, fineness reaches 320 mesh screen residues《After 0.5%, blowing crosses the shake of 160 mesh
It is dynamic to sieve use of reaching the standard grade.
Application method of the present invention：Spent in production line using 100 mesh flower wire mark, then drench candy glaze, kiln-firing is into finished product.
Embodiment 2：
First weigh bentonite 50Kg, potassium feldspar 55Kg, silica flour 30Kg, methyl 15Kg, ethylene glycol 250 Kg, water 600Kg；
Above-mentioned raw materials are sequentially added into ball mill ball milling 10 hours, fineness reaches 320 mesh screen residues《After 0.5%, blowing crosses 160 mesh reciprocating sieves
Reach the standard grade use.
Application method of the present invention：Spent in production line using 100 mesh flower wire mark, then drench candy glaze, kiln-firing is into finished product.
Embodiment 3：
First weigh bentonite 32Kg, potassium feldspar 80Kg, the Kg of silica flour 20, the Kg of methyl 18, the Kg of ethylene glycol 250, water
600Kg；Above-mentioned raw materials are sequentially added into ball mill ball milling 10 hours, fineness reaches 320 mesh screen residues《After 0.5%, blowing crosses 160 mesh
Reciprocating sieve is reached the standard grade use.
Application method of the present invention：Spent in production line using 100 mesh flower wire mark, then drench candy glaze, kiln-firing is into finished product.
The present invention is changed by the ratio of bentonite and methyl to adjust the glaze slip performance of binding agent, can meet to produce stamp
Requirement.By adjusting bentonite, potassium feldspar, quartzy ratio, binding agent high temperature firing temperature is controlled, is allowed in cold stage
While keeping sticky, high temperature does not influence candy glaze effect and transparency after burning till, and effectively overcomes the winged dry granular in production
Problem.
Embodiment of the present invention is only the description carried out to the preferred embodiment of the present invention, not to the present invention
Spirit and scope are defined, and on the premise of design philosophy of the present invention is not departed from, engineers and technicians are to this hair in this area
The all variations and modifications that bright technical scheme is made, protection scope of the present invention, the claimed skill of the present invention all should be fallen into
Art content, all record in detail in the claims.
Claims (4)
1. a kind of application of binding agent, the application burns till preceding incrustation for glazed tile, it is characterised in that：The binding agent by
Bentonite, potassium feldspar, silica flour, sodium carboxymethylcellulose, ethylene glycol, water modulation form, and the percentage by weight of each component is：It is swollen
Profit soil 2 ~ 5%, potassium feldspar 5 ~ 8%, silica flour 2 ~ 5%, sodium carboxymethylcellulose 1.5 ~ 2.5%, ethylene glycol 25%, remaining is water.
2. application according to claim 1, it is characterised in that：The percentage by weight of each component is：Bentonite 2%, potassium
Feldspar 5.5%, silica flour 5%, sodium carboxymethylcellulose 2.5%, ethylene glycol 25%, remaining is water.
3. application according to claim 1, it is characterised in that：The percentage by weight of each component is：Bentonite 5%, potassium
Feldspar 5.5%, silica flour 3%, sodium carboxymethylcellulose 1.5%, ethylene glycol 25%, remaining is water.
4. application according to claim 1, it is characterised in that：The percentage by weight of each component is：Bentonite 3.2%,
Potassium feldspar 8%, silica flour 2%, sodium carboxymethylcellulose 1.8%, ethylene glycol 25%, remaining is water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510665378.8A CN105272372B (en) | 2015-10-16 | 2015-10-16 | A kind of binding agent and its compound method for burning till preceding incrustation suitable for glazed tile |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510665378.8A CN105272372B (en) | 2015-10-16 | 2015-10-16 | A kind of binding agent and its compound method for burning till preceding incrustation suitable for glazed tile |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105272372A CN105272372A (en) | 2016-01-27 |
| CN105272372B true CN105272372B (en) | 2017-12-08 |
Family
ID=55142288
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510665378.8A Active CN105272372B (en) | 2015-10-16 | 2015-10-16 | A kind of binding agent and its compound method for burning till preceding incrustation suitable for glazed tile |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105272372B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108191242A (en) * | 2018-01-25 | 2018-06-22 | 广东金牌陶瓷有限公司 | A kind of big plate glued surfaces of ceramics protect color glaze and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101029209A (en) * | 2006-03-01 | 2007-09-05 | 白振福 | Binder for producing building material by building refuse and industrial fag end |
| CN103086732A (en) * | 2013-01-21 | 2013-05-08 | 天津师范大学 | Fiber enhanced silicon carbide porous ceramic and preparation method and application thereof |
| CN104591611A (en) * | 2013-11-01 | 2015-05-06 | 徐小芹 | Binder for production of new building material by utilization of construction waste and industrial waste residue |
-
2015
- 2015-10-16 CN CN201510665378.8A patent/CN105272372B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101029209A (en) * | 2006-03-01 | 2007-09-05 | 白振福 | Binder for producing building material by building refuse and industrial fag end |
| CN103086732A (en) * | 2013-01-21 | 2013-05-08 | 天津师范大学 | Fiber enhanced silicon carbide porous ceramic and preparation method and application thereof |
| CN104591611A (en) * | 2013-11-01 | 2015-05-06 | 徐小芹 | Binder for production of new building material by utilization of construction waste and industrial waste residue |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105272372A (en) | 2016-01-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104829268B (en) | Preparation method and the application of a kind of fast sinter glaze Ceramic Tiles glaze and Ceramic Tiles | |
| CN103351683A (en) | Preparation method of interior wall putty | |
| CN104130032B (en) | A kind of manufacture method of glazed tile and products thereof | |
| RU2013133836A (en) | PRELIMINARY PROCESSING OF RAW MATERIALS FOR PRODUCING BASALT FIBERS | |
| CN104355607A (en) | High-strength semitransparent ceramic sheet and preparation method thereof | |
| CN106278383A (en) | A kind of manufacture the method that surface has Z-Correct bump mapping Z-correct Ceramic Tiles | |
| CN103342467B (en) | Novel nucleated glass ceramic clad plate and preparation method thereof | |
| CN105272372B (en) | A kind of binding agent and its compound method for burning till preceding incrustation suitable for glazed tile | |
| KR101149576B1 (en) | Manufacturing method for clay brick and clay brick | |
| CN107555976A (en) | One-time formed eggshell porcelain and its preparation technology | |
| CN105000865B (en) | A kind of preparation method of large-size ceramic tile | |
| CN102659394A (en) | Production method of glazed ceramic board members | |
| CN104150967A (en) | Method for manufacturing machinable glass ceramic composite board and product thereof | |
| CN106810207A (en) | A kind of ceramic whiteware mud high | |
| CN118495810A (en) | Ridge element-color ceramic tile and preparation method thereof | |
| CN103359930A (en) | Gold pigment for colored glazes and application method of gold pigment | |
| CN106495482A (en) | A kind of ceramic glaze and preparation method thereof | |
| CN105330147A (en) | Preparation method of zinc silicate crystal glaze for bone china | |
| RU2417187C1 (en) | Faience mixture | |
| CN104291877B (en) | A preparation method of one-time fired glass-ceramic composite board | |
| CN107602081A (en) | A kind of porcelain and preparation method thereof | |
| CN107640980A (en) | A kind of natural-like stone throws the formula and manufacture method of in-glaze decoration Imitation Rock Porcelain Tiles entirely | |
| CN104230395B (en) | A kind of adobe of once-firing crystallite glass composite plate | |
| CN107827471A (en) | A kind of Fire-resistant ceramic tile and preparation method thereof | |
| CN104609831A (en) | Method for reducing cutting cracks of ceramic tile |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CP03 | Change of name, title or address |
Address after: 4100 Xinqiang agricultural industrialization Park, Yueyang County, Yueyang City, Hunan Province Patentee after: Tianxin Technology Co.,Ltd. Address before: 414122 Xinqiang agricultural industrialization Park, Yueyang County, Yueyang City, Hunan Province Patentee before: HUNAN TIANXIN TECHNOLOGY CO.,LTD. |
|
| CP03 | Change of name, title or address |