CN106278383A - A kind of manufacture the method that surface has Z-Correct bump mapping Z-correct Ceramic Tiles - Google Patents
A kind of manufacture the method that surface has Z-Correct bump mapping Z-correct Ceramic Tiles Download PDFInfo
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- CN106278383A CN106278383A CN201610641042.2A CN201610641042A CN106278383A CN 106278383 A CN106278383 A CN 106278383A CN 201610641042 A CN201610641042 A CN 201610641042A CN 106278383 A CN106278383 A CN 106278383A
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- correct
- charity
- adobe
- ceramic tiles
- binding agent
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- 238000000034 method Methods 0.000 title claims abstract description 39
- 239000000919 ceramic Substances 0.000 title claims abstract description 38
- 238000013507 mapping Methods 0.000 title claims abstract description 36
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 30
- 239000008187 granular material Substances 0.000 claims abstract description 68
- 239000011230 binding agent Substances 0.000 claims abstract description 54
- 239000011449 brick Substances 0.000 claims abstract description 16
- 238000007664 blowing Methods 0.000 claims abstract description 10
- 238000007688 edging Methods 0.000 claims abstract description 6
- 238000012545 processing Methods 0.000 claims abstract description 6
- 238000001035 drying Methods 0.000 claims abstract description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 28
- 239000011241 protective layer Substances 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 17
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 16
- 238000004144 decalcomania Methods 0.000 claims description 16
- 239000010410 layer Substances 0.000 claims description 16
- 229910052681 coesite Inorganic materials 0.000 claims description 10
- 229910052593 corundum Inorganic materials 0.000 claims description 10
- 229910052906 cristobalite Inorganic materials 0.000 claims description 10
- 239000000377 silicon dioxide Substances 0.000 claims description 10
- 229910052682 stishovite Inorganic materials 0.000 claims description 10
- 229910052905 tridymite Inorganic materials 0.000 claims description 10
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 10
- 238000007639 printing Methods 0.000 claims description 9
- 239000004575 stone Substances 0.000 claims description 9
- 238000007641 inkjet printing Methods 0.000 claims description 5
- 238000007650 screen-printing Methods 0.000 claims description 4
- 239000002994 raw material Substances 0.000 abstract description 9
- 238000002360 preparation method Methods 0.000 abstract description 4
- 238000005498 polishing Methods 0.000 abstract description 3
- 238000001354 calcination Methods 0.000 abstract description 2
- 230000000694 effects Effects 0.000 description 22
- 230000000052 comparative effect Effects 0.000 description 18
- 239000004744 fabric Substances 0.000 description 12
- 239000002002 slurry Substances 0.000 description 9
- 238000005516 engineering process Methods 0.000 description 8
- 239000004576 sand Substances 0.000 description 8
- 239000004579 marble Substances 0.000 description 7
- 239000007921 spray Substances 0.000 description 7
- 239000003086 colorant Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 238000005245 sintering Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000000758 substrate Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000000498 ball milling Methods 0.000 description 4
- 239000004567 concrete Substances 0.000 description 4
- 238000010304 firing Methods 0.000 description 4
- 239000012634 fragment Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 description 3
- 239000004927 clay Substances 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229910010293 ceramic material Inorganic materials 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 238000009738 saturating Methods 0.000 description 2
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 2
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 235000012222 talc Nutrition 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 241000220479 Acacia Species 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 235000010643 Leucaena leucocephala Nutrition 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 description 1
- 229910052925 anhydrite Inorganic materials 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 125000003636 chemical group Chemical group 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000007499 fusion processing Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000007517 polishing process Methods 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Finishing Walls (AREA)
Abstract
The invention discloses and a kind of manufacture the method that surface has Z-Correct bump mapping Z-correct Ceramic Tiles, comprise the following steps: (1) is at the part surface charity binding agent of adobe；(2) at the adobe surface charity frit granule of charity binding agent；(3) after drying frit granule not glued for adobe surface is blown away；(4) it is polished after burning till processing with edging, obtains surface and there is the Ceramic Tiles of Z-Correct bump mapping Z-correct.After the present invention is by using binding agent that the frit granule on base brick carries out viscous sticking, by blowing process not by stick frit granule blow off, calcining polishing obtains the Ceramic Tiles of required uneven texture, the preparation method of the present invention, simple to operate, raw material is easy to get, with low cost, process controllability is strong, is suitable for the ceramic tile production market demand.
Description
Technical field
The present invention relates to ceramic tile production technical field, particularly relate to a kind of surface that manufactures and there is Z-Correct bump mapping Z-correct Ceramic Tiles
Method.
Background technology
Along with improving constantly of people's living standard, people are increasingly higher for the cosmetic requirement of architectural pottery,
The ceramic tile decoration demand people in the places such as household especially like in styles such as partially naturally stone of marbles, but if use Dali
The materials such as stone are manufactured into fragment of brick and lay, and either material exploitation still manufactures in fragment of brick aspect, is all to consume more people
Power material resources, cost intensive.
Simultaneously because the architectural pottery market competition is growing more intense, producer, in order to extend volume growth, is reducing cost, increase
While product pattern, the comparison also put in terms of high-tech product is many (as current underglaze colour throws glazed brick, inkjet printing
The products such as crystallite composite brick are burnt Deng secondary), this product technology comparative maturity, but production cost is the highest, and finished product can not
Reach texture or the concave-convex effect of stone material.
Thus, how to produce a kind of production cost low, in terms of space of a whole page pattern texture, material and production technology, there is leather
The Ceramic Tiles product of the parian surface irregularity of the breakthrough of life property is the hot issue that Building Ceramics Industry is paid close attention to.
Summary of the invention
Present invention aims to weak point of the prior art, it is provided that a kind of surface that manufactures has Z-Correct bump mapping Z-correct
The method of Ceramic Tiles, preparation process is easy, low production cost, the striped color of prepared Ceramic Tiles out and concave-convex surface
Injustice is unanimous on the whole with stone of marble, and simulated effect is high.
For reaching this purpose, the present invention by the following technical solutions:
A kind of manufacture the method that surface has Z-Correct bump mapping Z-correct Ceramic Tiles, comprise the steps:
(1) at the part surface charity binding agent of adobe；
(2) at the adobe surface charity frit granule of charity binding agent；
(3) after drying frit granule not glued for adobe surface is blown away；
(4) it is polished after burning till processing with edging, obtains surface and there is the Ceramic Tiles of Z-Correct bump mapping Z-correct.
In prior art, for obtaining the Ceramic Tiles with Z-Correct bump mapping Z-correct, the method generally used is to use the modes such as punching press
Obtain Z-Correct bump mapping Z-correct in brick face, but the Z-Correct bump mapping Z-correct that this mode obtains is the most single.And the solution of the present invention, use in adobe
The mode of part surface charity binding agent, then charity frit granule, so have the position of binding agent will be molten in charity
Block is adhesively fixed, and the position of non-charity binding agent, frit only dispenses in adobe surface, is not adhesively fixed.Blowing, can be by
These not glued fixing frit granules blow away, and retain the part of bonding, the most after sintering, remain with the part of frit granule
Raised textural can be formed, so can form natural Z-Correct bump mapping Z-correct in brick face, after polishing and edging are processed, can obtain into
Product.
Illustrating further, in described step (1), the charity mode of charity binding agent is silk screen printing, cylinder printing and spray
At least one in ink printing.Using can make the binding agent shape of charity to control with upper type, i.e. can form decoration
Pattern.Here binding agent is the most relatively conventional, is typically Organic substance or its solution of viscosity, such as, contains carboxylic first
The aqueous solution of base cellulose, stamp-pad ink etc., relatively conventional because of it, the most it is not developed in details in explanation.
Illustrating further, described adobe is the imitative stone material adobe with the embedded texture of entire body, on described adobe surface
Executing protected glaze, have ornamental decalcomania on described protection glaze surface, described binding agent charity is on decalcomania.
Using the imitative stone material adobe with the embedded texture of entire body is to obtain the grain effect with natural marble, because obtaining this
The mode planting texture is that common technology, such as employing multiple color powder use magic distributing technique to obtain in the industry with technique
Obtain corresponding base substrate.Executing protection glaze in billet surface can make decalcomania relatively sharp.Protection glaze has relatively Gao Bai known to being
The opacifying property glaze of degree.
Illustrating further, the fineness of described frit granule is that 100 mesh are to 250 mesh.Use the frit granule of above fineness
Primarily to convenient by the frit granule removal for bonding in subsequent treatment, for example with the mode blown away can avoid because of
Wind speed is crossed the frit of senior general bonding part and can also be blown away.
Illustrating further, between described decalcomania and binding agent, also charity has the layer protective layer, described protective layer to be
Clear frit or transparent ink.Protective layer Main Function is to protect decalcomania, it is to avoid binding agent and frit granule are to print
Flower layer destruction, it can be clear frit or transparent ink, clear frit mentioned here or transparent ink refer to its burn after in thoroughly
Bright shape or can burn does not remains.
Illustrating further, described frit granule is clear frit granule, and it is calculated in parts by weight, including following group
Point: Al2O3: 10-20 part, SiO2: 55-60 part, CaO:12-18 part, K2O:3-5 part, MgO:5-12 part and Ba2O3: 4-10 part.This
Frit is high calcareous frit, and magnesium therein and barium can make it have more preferably elastic and anti-wear performance, and this proportioning
Frit, has higher viscosity under Ceramic Tiles sintering temperature at 1150-1250 DEG C, thus without being spread to whole brick face, because of
This Acacia crassicarpaA is more preferably.
Illustrating further, the charity thickness of described frit granule is 0.5-2mm.Select this thickness, mainly consider
The effect of Z-Correct bump mapping Z-correct, crosses thin concavo-convex texture poor, and blocked up, then easy drawout also can make concavo-convex texture be deteriorated.
Illustrating further, on adobe surface, the described protective layer thickness in the position of charity binding agent is more than not having cloth
Execute the thickness of the position of binding agent.So select, mainly for because in high-temperature sintering process, there is the position of frit
Can melt, it also can be warm with protective layer, in this fusion process, protective layer thickness variant, both contact
Angle of wetting on face frit can be suppressed melted after spread out.
Illustrating further, described in step (3), the wind direction of blowing is less than with the angle on the surface of adobe charity frit
In 20 ° of these effects that mainly consideration is dried, if wind direction is vertical with adobe, then wind-force is pressed under frit, it is difficult to blow away.
Illustrating further, the blow-time of monolithic adobe is the 2-4 second.
After the present invention is by using binding agent that the frit granule on base brick carries out viscous sticking, processed not sticked by blowing
Frit granule blow off, calcining polishing obtains the Ceramic Tiles of required uneven texture, in the base substrate body prepared and table
The color and vein in face is unanimous on the whole with marmorean, and there is the rough natural effect of marble surface on surface, it appears more certainly
The most attractive in appearance, it is suitable for the ceramic tile production market demand.
The preparation method of the present invention, simple to operate, raw material is easy to get, with low cost, and process controllability is strong, can produce
State parian surface irregularity all-body tile.
Detailed description of the invention
Below by some specific embodiments, the present invention program is described in detail.Those skilled in the art should manage
Solving, following be embodied as preferred embodiment, the present invention program is only explained by it, and wherein there may be known skill
The suitable omission of art, the present invention should be understood by those skilled in the art in conjunction with the explanation of known technology Yu embodiment.
A kind of manufacture the method that surface has Z-Correct bump mapping Z-correct Ceramic Tiles, comprise the steps:
Step 1, at the part surface charity binding agent of adobe；
Using known Ceramic Material to prepare adobe, the Ceramic Material that the adobe of this programme uses is washing white clay, cunning
Stone mud, Dongxing sand and high alumina potassium sand these four mud sand material are that primary raw material is prepared from, and these components are the mud in nature
Sand.
The described adobe of this programme calculates by weight, including following component: Al2O315-22 part, SiO2 60-70
Part, Fe2O30.2-1.0 part, TiO20.01-0.08 part, CaO 0.1-0.3 part, K2O 2-5 part, MgO 0.1-1 part and Na2O
2-5 part.
It should be noted that the most only make exemplary illustration, the raw material of adobe and chemical group branch because of the place of production or product type and
It is slightly different, it will be appreciated by those skilled in the art that known Ceramic Tiles adobe formula is applicable to the present invention program.
Specifically comprising the following steps that of step 1
1.1, washing white clay, Talcum mud, Dongxing sand and high alumina potassium sand carry out mixing to be equipped with, obtain mixture A, described
Mixture A, water, sodium carboxymethyl cellulose and sodium tripolyphosphate carried out mixed grinding after 12-13 hour in adding ball mill, obtain
Slurry, mixes colours by adding industrial chemicals, obtains mill base B；
1.2, it is dried by mill base B injection in the spray drying tower, pelletize, obtains colorant C, different colours
Colorant C adds stamping machine and carries out cloth, punch forming, dried, obtains adobe D；
Generally, each processing step can be tested in concrete production, and suitably adjust, with this programme be
Example, aborning, it usually needs note following some: (1), by the slurry after above-mentioned deployed ball milling, its slurry properties after testing
Whether can meet production requirement；
(2) if undesirable, use distinct methods to process according to different condition, make slurry meet production requirement；
(3) if slurry meets production requirement, add described chemical industry colorant to slurry and mix colours, the color of slurry is adjusted
Become the color of the marble surface conforming to production.
Production requirement mentioned here is allowed to the internal control index of technique, relates generally to the fineness of slurry, proportion, flow velocity etc.,
Because being conventional treatment mode above, it is not described in detail.
1.3, protected glaze is executed on adobe D surface, ink-jet printed so that on described protection glaze surface, to there is ornamental print
Floral pattern；
1.4, continuing charity layer protective layer in adobe, described protective layer is clear frit or transparent ink；
Note: the transparent ink that this programme uses is the light ink of market sale, and the Main Function of light ink is: protection
Pattern after ink-jet printed, does not allow operation below affect decalcomania.
1.5, at the part surface charity binding agent of adobe；Note: binding agent is the glue ink of commercial type, has notable
Viscous glutinous effect；The Main Function of binding agent is: in order to operation below being wanted the frit granule of charity be sticky in adobe.When
So, binding agent here can also select such as carboxymethyl cellulose aqueous solution etc., it is well known to plays bonding, and was burning till
In journey the most applicable without the binding agent of Special Influence to printed layer and frit.
From step 1.4 and 1.5, the present invention uses ink-jetting style to spray binding agent and transparent ink, concrete according to design
Require as follows:
(1), spray transparent ink is on the surface of adobe, it is desirable to have transparent ink after sprinkling, but the diverse location of adobe
Transparent ink amount different, some position quantity is few, and some position quantity is many；
(2), spray binding agent is continued on the adobe surface after spray transparent ink, it is desirable to the position that transparent ink amount is few is not sprayed
Binding agent, the position spray binding agent that transparent ink amount is many.
Step 2, at the adobe surface charity frit granule of charity binding agent；Use waterfall type that described frit granule is carried out
Cloth.
Using the cloth of described waterfall type, effect is cloth as waterfall, and concrete mode is to arrange on the source of equipment
Having switch, allow it often carve the frit granule flowing out equivalent, described frit granule is to carrying out charity in adobe so that described frit
Grain is distributed to compare uniform ground.
Step 3, after drying frit granule not glued for adobe surface is blown away；
Detailed process is: owing on the surface of adobe, binding agent is not sprayed in some position, therefore frit granule will not glue glutinous
On the position not spraying binding agent, but described frit granule is then clung in the place having sprayed binding agent, by hair-dryer to base
The surface of brick blows, and the frit granule being not bonded on adobe surface can be blown off after blowing.
Step 4, burn till after be polished and edging processing, obtain surface and there is the Ceramic Tiles of Z-Correct bump mapping Z-correct, be a warp
After above-mentioned steps, gained adobe is dried, obtains after high-temperature calcination and polishing process the Ceramic Tiles of required Z-Correct bump mapping Z-correct.
The present invention passes through above-mentioned steps, uses at the viscous glutinous frit granule of base brick part charity binding agent part, by blowing
The frit granule not clung is blown away, forms the adobe surface of uneven texture, fire i.e. available required marble grain
Color, rough surface effect.
Illustrating further, in described step 1, the charity mode of charity binding agent is silk screen printing, cylinder printing and ink-jet
At least one in printing.
Silk screen printing belongs to orifice plate printing, makes binding agent can transfer to brick by the eyelet of orifice plate by certain pressure
On base, it is suitable for small lot operation；Use cylinder print efficient and convenient, be evenly distributed, energy consumption is longer, inkjet printing use shower nozzle from
Moving in adobe after drawing binding agent on microwell plate, by ejector, binding agent is ejected on adobe surface, which is grasped
Making process simple, operating speed block, cheap, above-mentioned three kinds of charity modes can need to make a choice according to production technology.
Illustrating further, described adobe is the imitative stone material adobe with the embedded texture of entire body, on described adobe surface
Execute protected glaze, on described protection glaze surface, there is ornamental decalcomania, described binding agent charity on decalcomania,
In order to thus adobe surface obtains color grain effect natural on marble, pattern is more rich.
Illustrating further, the fineness of described frit granule is that 100 mesh are to 250 mesh.Use the frit granule of different fineness
Carrying out charity, mobility and ductility during its charity all produce different effect, and the fineness of described frit granule is more
Carefully, mobility is the best, and frit granule spreads to surrounding, and the scope causing charity is the biggest；Compared with the frit granule that fineness is big,
Upper cloth of equal time, the height of the frit particle packing that fineness is little is the highest.The fineness of described frit granule is 100
Mesh is in the value range of 250 mesh so that it is finer and smoother, more vividly that adobe forms Z-Correct bump mapping Z-correct effect.
Illustrating further, between described decalcomania and binding agent, also charity has the layer protective layer, described protective layer to be
Clear frit or transparent ink.The decalcomania of adobe in step 1.3 can effectively be protected by described protective layer, it is to avoid subsequent handling is destroyed
Pattern.
Illustrating further, the chemical composition of described protection glaze includes SiO2、Al2O3、CaO、MgO、ZnO、K2O、Na2O and
ZrO2One or more combination.Described protection glaze is to form according to formula proportion mix homogeneously, to dry described entire body base
It is to dip in glaze, swing glaze, water glaze, brushing glazing, spill glaze and the one of which drenched in glaze that the surface of body applies the mode of ground-coat enamel.
Can be seen that protection glaze is clear frit, this is because have printed layer under it, right by above component raw material
The known clear frit answering firing temperature interval is the most optional, the most only provides the example of a component, and those skilled in the art can
To select according to actual process demand.
The mode that the present invention uses is to drench glaze, and it can obtain the uniform effect of glaze layer at short notice；Waterfall process simultaneously
More can produce the special-effect with sense of movement, several different color glaze under drenching on base brick, reach casual nature of following one's inclinations
Effect.
Illustrating further, described frit granule is clear frit granule, and it is calculated in parts by weight, including following group
Point: Al2O3: 10-20 part, SiO2: 55-60 part, CaO:12-18 part, K2O:3-5 part, MgO:5-12 part and Ba2O3: 4-10 part.
Described frit granule is fritted glaze, and being prepared as of fritted glaze weighs the raw material of fritted glaze in proportion, and mixing is all
After even, be thrown in Cinker clew furnace or crucible, carry out melted make vitreous humour after, put in water the molten of frustillatum of quenching rapidly
Block, obtains frit granule through broken sieving, but frit raw material is generally potassium feldspar well-known to those skilled in the art, sodium
Anhydrite, dolomite, limestone, sodium carbonate, aluminium oxide etc..
Illustrating further, the charity thickness of described frit granule is 0.5-2mm.To described in adobe charity different-thickness
Frit granule, forms the protrusion of different-thickness, and does not has the adobe position of described frit granule, the protruding concave surface of composition after firing
Uneven visual effect, then frit grain thickness size directly affects the rub proofness of the projection on fragment of brick surface,
If fragment of brick upper protruding block thickness is big, the surface of Ceramic Tiles is more resistant to mill, and vice versa.
Illustrating further, on adobe surface, the described protective layer thickness in the position of charity binding agent is more than not having cloth
Execute the thickness of the position of binding agent.According to the requirement of spray transparent ink amount, on the surface of adobe, the position that transparent ink amount is many
Just charity binding agent, measures few position not charity binding agent.
Illustrating further, described in step 3, the wind direction of blowing is less than or equal to the angle on the surface of adobe charity frit
20 °, it is ensured that the wind power energy of described blowing, not blown away by viscous glutinous frit granule, avoids excessive wind-force there being binding agent simultaneously
Viscous glutinous frit granule together blows away, it is achieved effectively dry.
Illustrating further, the blow-time of monolithic adobe is the 2-4 second, it is achieved quickly dry, and efficiently blows away described frit
Granule, it is to avoid adobe also has described frit granule in the position of not glued dose after completing blowing process, and adobe is formed recessed by enhancing
The surface effect of the most gentle convex uniqueness more straggly.
Embodiment 1:
The present embodiment provides one manufacture surface to have Z-Correct bump mapping Z-correct Ceramic Tiles, comprises the following steps:
Step 1: preparation adobe.Weigh material, specifically, washing white clay 14%, Talcum mud 2%, east by mass percentage
Emerging sand 36% and high alumina potassium sand 48%, add water mixing and ball milling by above material, and the chemical constituent of material is: Al2O3: 15-22 part；
SiO2: 60-70 part；Fe2O3: 0.2-1.0 part；TiO2: 0.01-0.08 part；CaO:0.1-0.3 part；K2O:2-5 part；MgO:0.1-1
Part；Na2O:2-5 part.Also being suitably added known sodium carboxymethyl cellulose and sodium tripolyphosphate in material, the former is to improve thing
That expects is moulding, and the latter is that the mud after making ball milling has preferable thixotropy, it is easy to preserves and uses, certainly, and other additive
(such as water reducer) can also be properly added.In order to obtain the raw material with certain color, can add corresponding in material
Body stain, such as ferrum oxide, titanium oxide, manganese red, chrome green, cobalt black etc., with specific reference to actual base substrate texture color design
Difference, these are all known in the art content, the most additionally repeat.Slurry after ball milling obtains powder after mist projection granulating.?
To be manufactured in the present embodiment is a kind of adobe with parian texture, therefore uses multiple color powder known many
The mode of pipe cloth (magic cloth) carries out being layered nested cloth, forms the powder layer with entire body nesting texture, then carries out
Punch forming, it is thus achieved that corresponding base substrate.
Step 2: printing ornament.Protect glaze adobe surface charity one layer, there is known in glaze selection the glaze of higher whiteness
Material, it acts primarily as covering effect, is that subsequent decal effect is more preferable.Then carrying out printing ornament, stamp uses the side of inkjet printing
Formula obtains decalcomania layer, needs exist for explanation, and decalcomania layer can also be prepared by existing any known printing technology,
Such as protect but be not limited to silk screen, cylinder, marble paper transfer etc..Then charity protective layer, what protective layer was selected here is a kind of city
The transparent light ink sold, it is transparent and have certain gloss after burning, and can preferably be presented by decalcomania.Certainly, clear frit
Deng also may be used.
Step 3: charity frit.At billet surface charity one layer binder, binding agent is according to predetermined pattern charity here
In billet surface, it is part overlaid in billet surface, forms certain pattern, then uses waterfall type charity fineness to ask 100
Purpose frit granule, the thickness of charity is 0.5mm.After drying, use duck-beak type blower fan by not glued for billet surface fixing melting
Block blows away.The nozzle of blower fan is 20 ° with the angle on adobe surface, and the blow-time of single-piece adobe is the 2-4 second.Used herein above
Frit is the raw material that chemical constituent is following: Al2O3: 10-20 part, SiO2: 55-60 part, CaO:12-18 part, K2O:3-5 part, MgO:
5-12 part and Ba2O3: 4-10 part is fired after melted rear shrend crushes and is obtained.
Step 4: fire rubbing down.Being sent in kiln by base substrate and burn till, firing temperature is 1150-1250 DEG C, burns till week
Phase is 60-75 minute.Adobe is polished after firing edging processing obtain and finally there is parian texture and surface has
The Ceramic Tiles of Z-Correct bump mapping Z-correct.
Compared to the prior art, the invention provides one on surface by default frit granule, and this frit granule
There is in sintering process higher viscosity, do not sprawl, therefore can form the Ceramic Tiles product with Z-Correct bump mapping Z-correct.At this
In embodiment, the charity thinner thickness of frit granule, although therefore it has Z-Correct bump mapping Z-correct, but texture is general.
Embodiment 2
The problem proposed for embodiment 1, in the present embodiment, is adjusted the thickness correspondence of protective layer, i.e. exists
Spraying the position of binding agent, it is thicker, utilizes this thickness difference, can enrich the effect of Z-Correct bump mapping Z-correct.
Embodiment 3
In the present embodiment, scheme is substantially the same manner as Example 1, and institute's difference is that the charity of frit granule is highly
1mm, the concave-convex effect of texture becomes apparent from.
Embodiment 4
In the present embodiment, scheme is substantially the same manner as Example 1, and institute's difference is that frit can obtain charity and highly ask
2mm, texture there is the concave-convex effect become apparent from, but simultaneously, because the thickness of frit granular layer is thicker, at sintering process
In, it has necessarily sprawls, and the texture after i.e. burning is more than set texture, and this situation needs to control the thickness of frit, otherwise its
After spreading apart, it is impossible to form Z-Correct bump mapping Z-correct.
The certain impact that has on concave-convex effect of the frit fineness, here based on selection embodiment 4, the corresponding contrast of design
Embodiment.
Comparative example 1
In this embodiment, the frit granule of use is 80 mesh.
Comparative example 2, and the frit granule used in this embodiment is 150 mesh.
Comparative example 3: the frit granule used in this embodiment is 250 mesh.
Comparative example 4: the frit granule used in this embodiment is 300 mesh.
Here to when spraying binding agent, adjacent interregional minimum range is 5cm.By test, after burning, frit
The glass state material distance to each other formed after particle fusion and convexity layer are compared compared to the height of base substrate printed layer.
Concrete test data are as follows:
Table 1
Being analyzed by above comparison, we draw, the particle diameter of frit granule should be between 100-250 mesh, the most meticulous appearance
Easily adhesion, crosses and slightly is then difficult to be blown away, it is difficult to form the Z-Correct bump mapping Z-correct of predetermined pattern.Cloth height (thickness) at frit granule
Should be at 0.5-2mm, the melt temperature of frit granule can decline with its particle diameter, and the thinnest frit melt temperature is the lowest,
Therefore 100 the thickest mesh frits are selected to test, it can be deduced that the ultimate value of this technique.
Frit can illustrate also by comparative example here with the impact of component.
High calcareous clear frit granule is preferably used in the present invention, and its chemical constituent is as follows: Al2O3: 10-20 part,
SiO2: 55-60 part, CaO:12-18 part, K2O:3-5 part, MgO:5-12 part and Ba2O3: 4-10 part.Saturating as a kind of high temperature sintering
Bright frit, no matter it is at high temperature viscosity, or is better than the conventional frit on market on anti-wear performance.
Here select different clear frits to contrast, comparative example 5-8 is set.
Comparative example 5, other technique such as embodiment 1, and difference is that the fineness of used frit granule is 150
Mesh, fabric thickness is 1.0mm.
Comparative example 6, other technique such as comparative example 5, and institute's difference is, the frit of use is commercially available saturating
Bright high zinc frit.
Comparative example 7, other technique such as comparative example 5, and institute's difference is, the component of the frit of use is:
Al2O3: 10 parts, SiO2: 50 parts, CaO:10 part, K2O:10 part, MgO:15 part and Ba2O3: 5 parts.
Comparative example 8: other technique such as comparative example 5, and institute's difference is, the component of the frit of use is:
Al2O3: 13 parts, SiO2: 50 parts, CaO:2 part, K2O:15 part, MgO:10 part and Ba2O3: 10 parts.
Table 2
| Sequence number | Z-Correct bump mapping Z-correct effect | Texture height of projection | Wearing coefficient | Rupture strength |
| Comparative example 5 | Sharpness of border | 0.7 | 12000 turns | 43MPa |
| Comparative example 6 | Obscurity boundary | — | 6000 turns | 36MPa |
| Comparative example 7 | Sharpness of border | 0.6 | 8000 turns | 39MPa |
| Comparative example 8 | Sharpness of border | 0.55 | 8000 turns | 38MPa |
By above contrast, we can show that the frit granule provided in optimal way of the present invention has higher
High temperature viscosity, can make its pattern have a higher conservation degree, and compared to the clear frit granule of existing routine, its hard
Degree (Mohs' hardness 5) is the highest, and anti-wear performance is more preferable.
The know-why of the present invention is described above in association with specific embodiment.These describe and are intended merely to explain the present invention's
Principle, and limiting the scope of the invention can not be construed to by any way.Based on explanation herein, the technology of this area
Personnel need not pay performing creative labour can associate other detailed description of the invention of the present invention, and these modes fall within
Within protection scope of the present invention.
Claims (10)
1. one kind manufactures the method that surface has Z-Correct bump mapping Z-correct Ceramic Tiles, it is characterised in that comprise the steps:
(1) at the part surface charity binding agent of adobe；
(2) at the adobe surface charity frit granule of charity binding agent；
(3) after drying frit granule not glued for adobe surface is blown away；
(4) it is polished after burning till processing with edging, obtains surface and there is the Ceramic Tiles of Z-Correct bump mapping Z-correct.
The most according to claim 1 a kind of manufacture the method that surface has Z-Correct bump mapping Z-correct Ceramic Tiles, it is characterised in that described
At least one during the charity mode of charity binding agent is silk screen printing, cylinder printing and inkjet printing in step (1).
The most according to claim 1 a kind of manufacture the method that surface has Z-Correct bump mapping Z-correct Ceramic Tiles, it is characterised in that described
Adobe is the imitative stone material adobe with the embedded texture of entire body, executes protected glaze on described adobe surface, at described protection glaze table
Mask has ornamental decalcomania, and described binding agent charity is on decalcomania.
The most according to claim 1 a kind of manufacture the method that surface has Z-Correct bump mapping Z-correct Ceramic Tiles, it is characterised in that described
The fineness of frit granule is that 100 mesh are to 250 mesh.
5. manufacture, according to a kind of described in claim 3 or 4, the method that surface has Z-Correct bump mapping Z-correct Ceramic Tiles, it is characterised in that
Between described decalcomania and binding agent, also charity has layer protective layer, described protective layer to be clear frit or transparent ink.
6. manufacture, according to a kind of described in claim 3 or 4, the method that surface has Z-Correct bump mapping Z-correct Ceramic Tiles, it is characterised in that
Described frit granule is clear frit granule, and it is calculated in parts by weight, including following component: Al2O3: 10-20 part, SiO2:
55-60 part, CaO:12-18 part, K2O:3-5 part, MgO:5-12 part and Ba2O3: 4-10 part.
The most according to claim 6 a kind of manufacture the method that surface has Z-Correct bump mapping Z-correct Ceramic Tiles, it is characterised in that described
The charity thickness of frit granule is 0.5-2mm.
The most according to claim 6 a kind of manufacture the method that surface has Z-Correct bump mapping Z-correct Ceramic Tiles, it is characterised in that at brick
Base surface, the described protective layer thickness in the position of charity binding agent is more than the thickness of the position not having charity binding agent.
The most according to claim 1 a kind of manufacture the method that surface has Z-Correct bump mapping Z-correct Ceramic Tiles, it is characterised in that step
(3) wind direction of blowing described in is less than or equal to 20 ° with the angle on the surface of adobe charity frit.
The most according to claim 9 a kind of manufacture the method that surface has Z-Correct bump mapping Z-correct Ceramic Tiles, it is characterised in that single
The blow-time of block adobe is the 2-4 second.
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| CN108947589A (en) * | 2018-07-03 | 2018-12-07 | 佛山欧神诺陶瓷有限公司 | A kind of preparation method of the Ceramic Tiles of the sagging texture of the controllable noncontinuity of depth |
| CN109293399A (en) * | 2018-11-09 | 2019-02-01 | 蒙娜丽莎集团股份有限公司 | One kind having stone pattern embossing feeling dry granular brick and preparation method thereof |
| CN110128172A (en) * | 2019-04-28 | 2019-08-16 | 东莞市唯美陶瓷工业园有限公司 | A kind of method improving Ceramic Tiles green surface performance of keeping humidity and the Ceramic Tiles using this method preparation |
| CN114394853A (en) * | 2021-12-28 | 2022-04-26 | 福建省德化县聚美陶瓷有限公司 | Ceramic flowerpot with glaze surface imitating brick to stone and preparation method thereof |
| CN114455951A (en) * | 2020-05-20 | 2022-05-10 | 深圳市科思飞科技有限公司 | Organic ceramic precursor and ceramic product |
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| CN108101371A (en) * | 2017-12-18 | 2018-06-01 | 广东永航新材料实业股份有限公司 | A kind of preparation method of non-mold ripple type glazed ceramic brick |
| CN108101371B (en) * | 2017-12-18 | 2021-02-05 | 广东永航新材料实业股份有限公司 | Preparation method of non-mold water ripple type glazed ceramic tile |
| CN108545999A (en) * | 2018-04-13 | 2018-09-18 | 佛山东华盛昌新材料有限公司 | A kind of preparation method of hole material, parian hole brick and preparation method thereof |
| CN108545999B (en) * | 2018-04-13 | 2020-12-01 | 佛山东华盛昌新材料有限公司 | Preparation method of hole material, marble-imitated hole brick and preparation method thereof |
| CN108892540A (en) * | 2018-07-03 | 2018-11-27 | 佛山欧神诺陶瓷有限公司 | A kind of preparation method of the Ceramic Tiles with sagging effect |
| CN108947589A (en) * | 2018-07-03 | 2018-12-07 | 佛山欧神诺陶瓷有限公司 | A kind of preparation method of the Ceramic Tiles of the sagging texture of the controllable noncontinuity of depth |
| CN109293399A (en) * | 2018-11-09 | 2019-02-01 | 蒙娜丽莎集团股份有限公司 | One kind having stone pattern embossing feeling dry granular brick and preparation method thereof |
| CN109293399B (en) * | 2018-11-09 | 2021-05-07 | 蒙娜丽莎集团股份有限公司 | Dry granular brick with stone grain embossed feeling and preparation method thereof |
| CN110128172A (en) * | 2019-04-28 | 2019-08-16 | 东莞市唯美陶瓷工业园有限公司 | A kind of method improving Ceramic Tiles green surface performance of keeping humidity and the Ceramic Tiles using this method preparation |
| CN114455951A (en) * | 2020-05-20 | 2022-05-10 | 深圳市科思飞科技有限公司 | Organic ceramic precursor and ceramic product |
| CN114394853A (en) * | 2021-12-28 | 2022-04-26 | 福建省德化县聚美陶瓷有限公司 | Ceramic flowerpot with glaze surface imitating brick to stone and preparation method thereof |
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