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CN105220213A - Neutral salt electrolysis groove - Google Patents

Neutral salt electrolysis groove Download PDF

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Publication number
CN105220213A
CN105220213A CN201510697658.7A CN201510697658A CN105220213A CN 105220213 A CN105220213 A CN 105220213A CN 201510697658 A CN201510697658 A CN 201510697658A CN 105220213 A CN105220213 A CN 105220213A
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CN
China
Prior art keywords
cell body
neutral salt
salt electrolysis
roller
steel strip
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510697658.7A
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Chinese (zh)
Inventor
王鲁宁
郭立合
朱银利
郭沿军
高维才
王飞
金宇
王勇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Benxi Steel Stainless Steel Cold Rolling Dandong Co Ltd
Original Assignee
Benxi Steel Stainless Steel Cold Rolling Dandong Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Benxi Steel Stainless Steel Cold Rolling Dandong Co Ltd filed Critical Benxi Steel Stainless Steel Cold Rolling Dandong Co Ltd
Priority to CN201510697658.7A priority Critical patent/CN105220213A/en
Publication of CN105220213A publication Critical patent/CN105220213A/en
Pending legal-status Critical Current

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Abstract

本发明公开一种中性盐电解槽,包括槽体、槽盖,槽体的两侧设置挤干辊,槽体的底部设置多处凸起部,槽体内部还设置多个浸没辊,浸没辊高度不同;带钢由挤干辊驱动沿浸没辊运动;在钢带两侧设置多处电极板,所述电极板与电源连接。本发明可以更深层地清理带钢表面,使生产出的带钢表面光滑无杂质,从而得到更优质的带钢表面。

The invention discloses a neutral salt electrolytic cell, which comprises a cell body and a cell cover. Squeezing rollers are arranged on both sides of the cell body, a plurality of protrusions are arranged at the bottom of the cell body, and a plurality of immersion rollers are arranged inside the cell body. The height of the rollers is different; the strip steel is driven by the squeeze roller to move along the immersion roller; multiple electrode plates are arranged on both sides of the steel strip, and the electrode plates are connected to the power supply. The invention can clean the surface of the steel strip in a deeper layer, so that the surface of the produced steel strip is smooth and free of impurities, thereby obtaining a better surface of the steel strip.

Description

中性盐电解槽Neutral salt electrolyzer

技术领域technical field

本发明涉及化学领域,具体说是一种电解槽。The invention relates to the field of chemistry, in particular to an electrolytic cell.

背景技术Background technique

在不锈钢的冷轧钢带的表面上,由于氧化退火工艺会生成氧化皮,因此,需要去除带钢表面氧化铁皮等杂质;在生产实践中,一般采用中性盐电解槽来解决该技术问题,通常的电解槽结构为一个平底的槽体,钢带由一端向另外一端运动,而在此过程中,槽内注入的中性盐(硫酸钠)溶液,电极板、和带钢形成电化学回路,从而去除带钢表面氧化铁皮等杂质。该结构的缺点是:一方面由于该电解槽长度较大,需要非常大的空间;另一方面,槽体长度有限,钢带经过槽体的时间较短,往往效果不好。为解决该技术问题,中国专利申请号01101288.9,申请人为株式会社日立制作所公开了“一种中性盐电解液的处理装置,该装置为不锈钢的电解中所用的电解液的中性盐水溶液的处理装置,其特征在于具有向所说的电解液中添加还原剂的还原槽;向所说的还原槽中供给酸和碱中至少一种的酸和碱供给机构;向所说的还原槽中供给还原剂的还原剂供给机构;向所说的添加还原剂后的电解液中添加碱的中和槽;向所说的中和槽中供给碱的中和槽用碱供给机构和除去从所说的添加碱后的电解液中析出的析出物的过滤机构,所说的还原剂供给机构供给的还原剂为次硫酸、亚连二硫酸、亚硫酸、焦亚硫酸、焦硫酸、硫代硫酸、卡罗酸、过焦硫酸、连多硫酸和连二亚硫酸中的至少一种或其盐。”该专利不仅结构复杂,而且增加了许多新工序,显而易见增加了生产成本。On the surface of the cold-rolled steel strip of stainless steel, since the oxidation annealing process will generate scale, it is necessary to remove impurities such as scale on the surface of the strip steel; in production practice, a neutral salt electrolytic cell is generally used to solve this technical problem. The usual electrolytic cell structure is a flat-bottomed cell, and the steel strip moves from one end to the other. During this process, the neutral salt (sodium sulfate) solution injected into the cell, the electrode plate, and the strip steel form an electrochemical circuit. , so as to remove impurities such as iron oxide scale on the surface of the strip. The disadvantages of this structure are: on the one hand, due to the large length of the electrolytic cell, a very large space is required; on the other hand, the length of the cell body is limited, and the time for the steel strip to pass through the cell body is relatively short, so the effect is often not good. In order to solve this technical problem, Chinese patent application number 01101288.9, the applicant discloses " a kind of processing device of neutral salt electrolyte for Co., Ltd. Hitachi Manufacturing Co., Ltd., and this device is the neutral salt solution of electrolyte used in the electrolysis of stainless steel. A treatment device characterized by having a reduction tank for adding a reducing agent to the electrolytic solution; an acid and base supply mechanism for supplying at least one of acid and base to the reduction tank; A reducing agent supply mechanism for supplying a reducing agent; a neutralization tank for adding alkali to the electrolytic solution after adding the reducing agent; a neutralization tank for supplying alkali to the neutralization tank with an alkali supply mechanism and removing The filtering mechanism for the precipitates precipitated in the electrolyte after the addition of alkali, the reducing agent supplied by the reducing agent supply mechanism is hyposulfuric acid, dithionous acid, sulfurous acid, pyrosulfurous acid, pyrosulfuric acid, and thiosulfuric acid , Caroic acid, perpyrosulfuric acid, polythionic acid and dithionous acid at least one or its salt." This patent not only has a complex structure, but also adds many new processes, which obviously increases the production cost.

发明内容Contents of the invention

为解决上述技术问题,本发明的目的是提供一种电解效果更好的电解槽,并且相对占用空间较小,具体技术方案是:In order to solve the above-mentioned technical problems, the purpose of the present invention is to provide an electrolytic cell with better electrolysis effect, and relatively less occupied space, the specific technical solution is:

一种中性盐电解槽,包括槽体、槽盖,槽体的两侧设置挤干辊,槽体的底部设置多处凸起部,槽体内部还设置多个浸没辊,浸没辊高度不同;带钢由挤干辊驱动沿浸没辊运动;在钢带两侧设置多处电极板,所述电极板与电源连接。A neutral salt electrolytic cell, comprising a cell body and a cell cover, squeeze rollers are arranged on both sides of the cell body, a plurality of protrusions are arranged at the bottom of the cell body, and a plurality of immersion rollers are arranged inside the cell body, and the immersion rollers have different heights The steel strip is driven by the squeeze roller to move along the immersion roller; multiple electrode plates are arranged on both sides of the steel strip, and the electrode plates are connected to the power supply.

所述凸起部为不规则的三棱锥型。The raised part is irregular triangular pyramid.

所述槽体沿钢带运动方向分为两部分,两部分的交界处设置调流板。The tank body is divided into two parts along the moving direction of the steel belt, and a flow regulating plate is arranged at the junction of the two parts.

所述槽体底板设置紊流叶片。The bottom plate of the tank is provided with turbulent blades.

本发明的优点是:The advantages of the present invention are:

由于浸没辊高度不同,因此,增加了钢带在电解液中的行程;槽体底部设置了多处凸起部,并且增加了紊流叶片,使得中性盐溶液形成局部旋转,更加有利于中性盐溶液的均匀,避免浓度的不均匀,以便更好地进行电化学反应;而槽体的两部分设置,是保证由开始的剧烈反应逐渐变成后来的比较平缓的反应,提高了钢带的表面质量。Due to the different heights of the immersion rollers, the stroke of the steel strip in the electrolyte is increased; the bottom of the tank is provided with multiple protrusions, and turbulent blades are added to make the neutral salt solution form a local rotation, which is more conducive to neutralization. The uniformity of the salt solution avoids the uneven concentration so that the electrochemical reaction can be carried out better; and the two parts of the tank are set to ensure that the initial violent reaction gradually changes to the later relatively gentle reaction, which improves the steel strip. surface quality.

附图说明Description of drawings

图1为本发明的结构示意图。Fig. 1 is a structural schematic diagram of the present invention.

具体实施方式detailed description

下面结合附图具体说明本发明,如图1所示,本发明包括槽体2、槽盖8,槽体2的两侧设置挤干辊1,槽体2的底部设置多处凸起部3,槽体2内部还设置多个浸没辊6,浸没辊6高度不同;带钢7由挤干辊1驱动沿浸没辊6运动;在钢带7两侧设置多处电极板4,所述电极板4与电源连接。The present invention is specifically described below in conjunction with accompanying drawing, as shown in Figure 1, the present invention comprises tank body 2, tank cover 8, the two sides of tank body 2 are provided with squeezing roller 1, and the bottom of tank body 2 is provided with a plurality of protrusions 3 A plurality of immersion rollers 6 are also arranged inside the tank body 2, and the heights of the immersion rollers 6 are different; the strip steel 7 is driven by the squeeze roller 1 to move along the immersion rollers 6; a plurality of electrode plates 4 are arranged on both sides of the steel strip 7, and the electrodes Board 4 is connected to the power supply.

所述凸起部3为不规则的三棱锥型。The raised portion 3 is an irregular triangular pyramid.

所述槽体2沿钢带7运动方向分为两部分,两部分的交界处设置调流板9。The tank body 2 is divided into two parts along the moving direction of the steel belt 7, and a flow regulating plate 9 is arranged at the junction of the two parts.

所述槽体2底板设置紊流叶片5。The bottom plate of the tank body 2 is provided with turbulent blades 5 .

本发明的主要部件的作用如下:The effect of main part of the present invention is as follows:

挤干辊1:支撑带钢7传动、密封槽体和挤干带钢表面液体的作用。Squeeze roller 1: support the transmission of strip steel 7, seal the groove body and squeeze the liquid on the surface of strip steel.

电极板4:通电后与槽内中性盐溶液和带钢形成电化学回路。Electrode plate 4: After electrification, it forms an electrochemical circuit with the neutral salt solution in the tank and the steel strip.

浸没辊6:使带钢浸没在槽内液体中。Immersion roller 6: to immerse the steel strip in the liquid in the tank.

凸起部3及紊流叶片5:使中性盐溶液在槽体内形成旋转运动,便于浓度的均匀,提高反应效率。Protruding part 3 and turbulent blade 5: make the neutral salt solution form a rotating motion in the tank, which facilitates the uniform concentration and improves the reaction efficiency.

本发明可以更深层地清理带钢表面,使生产出的带钢表面光滑无杂质,从而得到更优质的带钢表面。The invention can clean the surface of the steel strip in a deeper layer, so that the surface of the produced steel strip is smooth and free of impurities, thereby obtaining a better surface of the steel strip.

Claims (4)

1. a neutral salt electrolysis groove, comprises cell body, groove lid, it is characterized in that: the both sides of cell body arrange squeezing roller, and the bottom of cell body arranges many places lug boss, and cell body inside also arranges multiple submergence roller, and submergence roller height is different; Band steel is driven by squeezing roller and moves along submergence roller; Arrange many places battery lead plate in steel band both sides, described battery lead plate is connected with power supply.
2. neutral salt electrolysis groove according to claim 1, is characterized in that: described lug boss is irregular triangular pyramid type.
3. neutral salt electrolysis groove according to claim 1, it is characterized in that: described cell body is divided into two portions along steel band direction of motion, two-part intersection arranges adjusting-flow board.
4. neutral salt electrolysis groove according to claim 1, is characterized in that: described cell body base plate arranges turbulent blade.
CN201510697658.7A 2015-10-24 2015-10-24 Neutral salt electrolysis groove Pending CN105220213A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510697658.7A CN105220213A (en) 2015-10-24 2015-10-24 Neutral salt electrolysis groove

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510697658.7A CN105220213A (en) 2015-10-24 2015-10-24 Neutral salt electrolysis groove

Publications (1)

Publication Number Publication Date
CN105220213A true CN105220213A (en) 2016-01-06

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Family Applications (1)

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CN201510697658.7A Pending CN105220213A (en) 2015-10-24 2015-10-24 Neutral salt electrolysis groove

Country Status (1)

Country Link
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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2234365A1 (en) * 1972-07-13 1974-01-24 Kalle Ag DEVICE FOR CONTINUOUS ELECTROCHEMICAL TREATMENT OF A METAL STRIP
WO2000044964A1 (en) * 1999-01-26 2000-08-03 Nippon Steel Corporation Method and device for removing and suppressing scale of metal material
CN1313411A (en) * 1994-07-28 2001-09-19 株式会社日立制作所 Neutral salt electrolytic liquid for treating device of stainless steel, and method and apparatus for descaling stainless steel
IT1318919B1 (en) * 2000-09-22 2003-09-19 Danieli Hi Tech Gmbh PROCESS AND DEVICE FOR SURFACE ELECTROLYTIC TREATMENT OF METAL TAPES.
CN101052752A (en) * 2004-07-19 2007-10-10 西门子Vai金属科技有限责任公司 Method and device for processing acid washing to metal
CN102713023A (en) * 2009-09-30 2012-10-03 特诺恩股份公司 Surface preparation unit for metal strips processing lines
CN204602828U (en) * 2015-02-13 2015-09-02 中冶南方工程技术有限公司 A kind of Novel cold rolling strip cleaning electrolytic cell
CN205046222U (en) * 2015-10-24 2016-02-24 本钢不锈钢冷轧丹东有限责任公司 Neutral salt electrolysis trough

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2234365A1 (en) * 1972-07-13 1974-01-24 Kalle Ag DEVICE FOR CONTINUOUS ELECTROCHEMICAL TREATMENT OF A METAL STRIP
CN1313411A (en) * 1994-07-28 2001-09-19 株式会社日立制作所 Neutral salt electrolytic liquid for treating device of stainless steel, and method and apparatus for descaling stainless steel
WO2000044964A1 (en) * 1999-01-26 2000-08-03 Nippon Steel Corporation Method and device for removing and suppressing scale of metal material
IT1318919B1 (en) * 2000-09-22 2003-09-19 Danieli Hi Tech Gmbh PROCESS AND DEVICE FOR SURFACE ELECTROLYTIC TREATMENT OF METAL TAPES.
CN101052752A (en) * 2004-07-19 2007-10-10 西门子Vai金属科技有限责任公司 Method and device for processing acid washing to metal
CN102713023A (en) * 2009-09-30 2012-10-03 特诺恩股份公司 Surface preparation unit for metal strips processing lines
CN204602828U (en) * 2015-02-13 2015-09-02 中冶南方工程技术有限公司 A kind of Novel cold rolling strip cleaning electrolytic cell
CN205046222U (en) * 2015-10-24 2016-02-24 本钢不锈钢冷轧丹东有限责任公司 Neutral salt electrolysis trough

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