CN105213213A - A kind of light hair conditioner - Google Patents
A kind of light hair conditioner Download PDFInfo
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- CN105213213A CN105213213A CN201510781166.6A CN201510781166A CN105213213A CN 105213213 A CN105213213 A CN 105213213A CN 201510781166 A CN201510781166 A CN 201510781166A CN 105213213 A CN105213213 A CN 105213213A
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- CN
- China
- Prior art keywords
- sulfonic acid
- acid sodium
- hair conditioner
- alkene
- hair
- Prior art date
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/69—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing fluorine
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a kind of light hair conditioner, it adopts the combination of specific sulfonate surfactants and inner olefin sulfonic acid sodium, and in the process of cleaning hair, lather quickness is fast, and washing is thorough and rear sensation of having had one's hair wash is salubrious.
Description
Technical field
The present invention relates to a kind of hair conditioner, particularly a kind of light hair conditioner.
Background technology
Hair conditioner is also known as Rinsing, and general and shampoo uses in pairs.After hair washing by appropriate hair conditioner uniform application on hair, gently rub about one minute, then use clear water rinsed clean, therefore also have person for rinsing conditioner, belong to hair cosmetic.Send out element and be divided into transparent type and emulsion-type two kinds from mode of appearance, comparatively commonly emulsion type products on market.
It is generally acknowledged, hair is with negative charge.After shampoo (mainly anionic detergent, soap also belongs to this type of) hair washing, hair can be made with more negative charge, thus produce electrostatic, cause combing inconvenience.Employ hair conditioner, main component cation quaternary ammonium salt wherein can neutralize the molecule remaining in hair surface band anion, and leave the uniform monomolecular film of one deck, this layer of marvellous thing can bring a series of benefit to hair: softness, gloss, be easy to combing, antistatic, and the mechanical damage of hair and chemistry scalded, perm, damage that hair dye brings is by reparation to a certain extent.
Hair conditioner is mainly made up of surfactant, cosurfactant, cation opsonizing agent, fatting agent, oil content, chelating agen, antiseptic, pigment, essence and other active component.Wherein, surfactant mainly plays emulsifying, antistatic, bacteriostasis; Cosurfactant can co-emulsifier; Cation opsonizing agent enemy can be initiated to softness, antistatic, moisturizing and opsonic action; Fatting agent can improve hair nutrition situation as lanoline, olive oil, silicone oil etc. in hair conditioner, makes hair light, easy combing; Other active component dandruffs, moistening, sun-proof, vitamin, hydrolyzed protein, plant extraction liquid etc. give hair conditioner various function, market common are dandruff hair conditioner, containing Aloe or the hair conditioner etc. containing Radix Ginseng.
Summary of the invention
The object of the invention is to propose a kind of light hair conditioner, make in the process of cleaning hair, lather quickness is fast, and washing is thorough and rear sensation of having had one's hair wash is salubrious.
For reaching this object, the present invention by the following technical solutions:
A kind of light hair conditioner, it comprises following component by weight percentage:
(1) the octadecyloxypropyl trimethyl ammonium chloride of 8-15%;
(2) stearyl alcohol of 2-7%;
(3) methyl parahydroxybenzoate of 0.1-0.5%;
(4) C of 2-7%
4f
7cH
2cF
2cH
2cH
2sO
3na;
(5) the C12 inner olefin sulfonic acid sodium of 2-7% and the mixture of C18 inner olefin sulfonic acid sodium, its mixing quality ratio is 3:1-1:3, the mass ratio of the hydroxyl body (hydroxyl alkane sulfonic acid sodium)/alkene body (alkene sulfonic acid sodium) in described C12 inner olefin sulfonic acid sodium is the mass ratio of the hydroxyl body (hydroxyl alkane sulfonic acid sodium)/alkene body (alkene sulfonic acid sodium) in 92/8, C18 inner olefin sulfonic acid sodium is 80/20;
(6) water of surplus.
In described hair conditioner, preferably, the content of octadecyloxypropyl trimethyl ammonium chloride is preferably 9-12%, further preferred 10-11.5%.
Preferably, the content of described stearyl alcohol is 3-5%, preferably 4%.
Preferably, described inner olefin sulfonic acid sodium and C
4f
7cH
2cF
2cH
2cH
2sO
3the content of Na is 3-6%, and further preferably 5%.
Light hair conditioner of the present invention, it adopts the combination of specific sulfonate surfactants and inner olefin sulfonic acid sodium, and in the process of cleaning hair, lather quickness is fast, and washing is thorough and rear sensation of having had one's hair wash is salubrious.
Detailed description of the invention
The present invention is described hair conditioner of the present invention by following embodiment.
Embodiment 1
A kind of light hair conditioner, it comprises following component by weight percentage:
The octadecyloxypropyl trimethyl ammonium chloride of (1) 10%;
The stearyl alcohol of (2) 5%;
The methyl parahydroxybenzoate of (3) 0.3%;
The C of (4) 3%
4f
7cH
2cF
2cH
2cH
2sO
3na;
The C12 inner olefin sulfonic acid sodium of (5) 5% and the mixture of C18 inner olefin sulfonic acid sodium, its mixing quality ratio is 1:1, the mass ratio of the hydroxyl body (hydroxyl alkane sulfonic acid sodium)/alkene body (alkene sulfonic acid sodium) in described C12 inner olefin sulfonic acid sodium is the mass ratio of the hydroxyl body (hydroxyl alkane sulfonic acid sodium)/alkene body (alkene sulfonic acid sodium) in 92/8, C18 inner olefin sulfonic acid sodium is 80/20;
(6) water of surplus.
Described internal olefin sulphonates is known compound, and it is typical but non-limiting, and to prepare example as follows:
The preparation of C12 inner olefin sulfonic acid sodium
Add 1-laurylene " Linealene12, Idemitsu Kosen Co., Ltd.'s system " (6000g (35.6 moles), protic beta-zeolite (CP-814E, Zeolyst company) 180g (be 3 quality %s relative to raw material alpha-olefin) as solid acid catalyst in the flask of agitating device, under agitation, at 120 DEG C, reaction 20 hours is carried out.Then, thick internal alkene is moved to distillation flask, distill with 124-136 DEG C/7.5mmHg, obtain the internal alkene of the carbon number 12 of alkene purity 100% thus.The double bond of the internal alkene obtained is distributed as C1 position 0.5 quality %, C2 position 33.1 quality %, C3 position quality 23.7 quality %, C4 position 21.2 quality %, C5 position 15.0 quality %, C6 position 6.6 quality %.
By described carbon number be 12 internal olefin be added in outside and have in the diaphragm type sulfonation reactor of chuck, circulate the cooling water of 20 DEG C in reactor external jacket, uses sulfur trioxide gas to carry out sulfonating reaction under this condition.SO during sulfonating reaction
3the mol ratio of/internal alkene is set as 1.09.Obtained sulfonated bodies is made an addition in the aqueous solution prepared with the sodium hydroxide relative to theoretical acid number being 1.5 moles of times amount, carry out stirring at 30 DEG C in and 1 hour.Corrective is heated 1 hour in autoclave at 160 DEG C, is hydrolyzed thus, obtains C12 inner olefin sulfonic acid sodium crude product.This crude product 300g is moved to separatory funnel, after adding ethanol 300mL, adds petroleum ether 300mL every 1 time, extract the oil-soluble impurity of removing.Now, because the inorganic compound (main constituent is Natrii Sulfas) being added on oil-water interfaces precipitation of ethanol is also separated removing by oil-water separation operation from aqueous phase.Carry out three these extractions removing operation.Solid by aqueous phase side is evaporated, obtain C12 inner olefin sulfonic acid sodium.The mass ratio of the hydroxyl body (hydroxyl alkane sulfonic acid sodium)/alkene body (alkene sulfonic acid sodium) in the inner olefin sulfonic acid sodium obtained is 92/8.In addition, the content of the raw material internal alkene in the internal alkene sodium sulfonate obtained is 0.2 quality % lower than 100ppm (lower than GC Monitoring lower-cut), inorganic compound.Further, sulfonic group is present in the content of the internal alkene sulfonate of 2 is 21.0 quality %.
The preparation of C18 inner olefin sulfonic acid sodium
In with the flask of agitating device, add 1-octadecanol 7000g (25.9 moles), solid acid catalyst gama-alumina 700g (be 10 quality %s relative to raw alcohol), under agitation, 280 DEG C, the nitrogen (7000mL/ minute .) that circulates in system is while react 10 hours.Alcohol conversion after reaction terminates is 100%, C18 internal olefin purity is 98.2%.Obtained thick internal olefin is moved in distillation flask, distills with 148-158 DEG C/0.5mmHg, thus, obtain the internal olefin of the carbon number 18 of alkene purity 100%.The internal olefin obtained double bond distribution be: C1 position is 0.5 quality %, C2 position is 25.0 quality %, C3 position is 22.8 quality %, C4 position is 19.1 quality %, C5 position is 14.0 quality %, C6 position is 7.4 quality %, C7 position is 5.4 quality %, C8,9 add up to 4.8 quality %.
By described carbon number be 18 internal olefin be added in outside and have in the diaphragm type sulfonation reactor of chuck, circulate the cooling water of 20 DEG C in reactor external jacket, uses sulfur trioxide gas to carry out sulfonating reaction under this condition.SO during sulfonating reaction
3the mol ratio of/internal alkene is set as 1.09.Obtained sulfonated bodies is made an addition in the aqueous solution prepared with the sodium hydroxide relative to theoretical acid number being 1.5 moles of times amount, carry out stirring at 30 DEG C in and 1 hour.Corrective is heated 1 hour in autoclave at 160 DEG C, is hydrolyzed thus, obtains C18 inner olefin sulfonic acid sodium crude product.This crude product 300g is moved to separatory funnel, after adding ethanol 300mL, adds petroleum ether 300mL every 1 time, extract the oil-soluble impurity of removing.Now, because the inorganic compound (main constituent is Natrii Sulfas) being added on oil-water interfaces precipitation of ethanol is also separated removing by oil-water separation operation from aqueous phase.Carry out three these extractions removing operation.Solid by aqueous phase side is evaporated, obtain C18 inner olefin sulfonic acid sodium.The mass ratio of the hydroxyl body (hydroxyl alkane sulfonic acid sodium)/alkene body (alkene sulfonic acid sodium) in the inner olefin sulfonic acid sodium obtained is 80/20.In addition, the content of the raw material internal alkene in the internal alkene sodium sulfonate obtained is 1.3 quality % lower than 100ppm (lower than GC Monitoring lower-cut), inorganic compound.Further, sulfonic group is present in the content of the internal alkene sulfonate of 2 is 9.6 quality %.
Described C
4f
7cH
2cF
2cH
2cH
2sO
3na is similarly known compound, and it is typical but non-limiting, and to prepare example as follows:
Ethylene (25g, 0.53 mole) is joined and is filled with C
4f
9cH
2cF
2in the autoclave of I (217g, 0.87 mole) and d-(+)-limonene (1g), reactor is then made to heat 12 hours at 240 DEG C.By vacuum distilling under about 81 to 91 DEG C and 19 to 24mmHg (2533 to 3200Pa), obtain product C
4f
7cH
2cF
2cH
2cH
2i, yield 62%.By C
4f
7cH
2cF
2cH
2cH
2i (140g, 0.33 mole) joins in the mixture of ethanol (165mL) and water (165mL).Add sodium sulfite (83g, 0.66 mole), then add 8g copper.By reactant mixture vigorous stirring one week under reflux.Add 500mL water, and filter at 75 DEG C.Filtrate is cooled, and by collecting by filtration white solid product C
4f
7cH
2cF
2cH
2cH
2sO
3na (112g, 84%).
10 professional evaluators try out hair conditioner of the present invention, and all evaluate it and bubble fast, washing is thorough and rear sensation of having had one's hair wash is salubrious.
Comparative example 1
Only containing component (4), not containing component (5), all the other conditions are constant, after 10 professional evaluators are on probation, all evaluate its lather quickness slightly slow, feel clouding after having had one's hair wash.
Comparative example 2
Only containing component (5), not containing component (4), all the other conditions are constant, after 10 professional evaluators are on probation, all evaluate its lather quickness slightly slow, feel clouding after having had one's hair wash.
Above-described embodiment and comparative example explanation, hair conditioner of the present invention, composite by two kinds of dissimilar sodium sulfonates, under same amount prerequisite, its lather quickness and salubrious degree are better than being used alone of two kinds of components far away, prove to create cooperative effect between two kinds of sodium sulfonates that the present invention adopts.
Applicant states, the present invention illustrates hair conditioner of the present invention by above-described embodiment, but the present invention is not limited to above-mentioned special formulation, does not namely mean that the present invention must rely on above-mentioned detailed component and formula could be implemented.Person of ordinary skill in the field should understand, any improvement in the present invention, to equivalence replacement and the interpolation of auxiliary element, the concrete way choice etc. of each raw material of product of the present invention, all drops within protection scope of the present invention and open scope.
Claims (4)
1. a light hair conditioner, it comprises following component by weight percentage:
(1) the octadecyloxypropyl trimethyl ammonium chloride of 8-15%;
(2) stearyl alcohol of 2-7%;
(3) methyl parahydroxybenzoate of 0.1-0.5%;
(4) C of 2-7%
4f
7cH
2cF
2cH
2cH
2sO
3na;
(5) the C12 inner olefin sulfonic acid sodium of 2-7% and the mixture of C18 inner olefin sulfonic acid sodium, its mixing quality ratio is 3:1-1:3, the mass ratio of the hydroxyl body (hydroxyl alkane sulfonic acid sodium)/alkene body (alkene sulfonic acid sodium) in described C12 inner olefin sulfonic acid sodium is the mass ratio of the hydroxyl body (hydroxyl alkane sulfonic acid sodium)/alkene body (alkene sulfonic acid sodium) in 92/8, C18 inner olefin sulfonic acid sodium is 80/20;
(6) water of surplus.
2. light hair conditioner as claimed in claim 1, is characterized in that, the content of octadecyloxypropyl trimethyl ammonium chloride is preferably 9-12%, further preferred 10-11.5%.
3. light hair conditioner as claimed in claim 1, the content of described stearyl alcohol is 3-5%, preferably 4%.
4. light hair conditioner as claimed in claim 1, described inner olefin sulfonic acid sodium and C
4f
7cH
2cF
2cH
2cH
2sO
3the content of Na is 3-6%, and further preferably 5%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510781166.6A CN105213213A (en) | 2015-11-14 | 2015-11-14 | A kind of light hair conditioner |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510781166.6A CN105213213A (en) | 2015-11-14 | 2015-11-14 | A kind of light hair conditioner |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105213213A true CN105213213A (en) | 2016-01-06 |
Family
ID=54982741
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510781166.6A Withdrawn CN105213213A (en) | 2015-11-14 | 2015-11-14 | A kind of light hair conditioner |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105213213A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102216345A (en) * | 2008-11-13 | 2011-10-12 | 纳幕尔杜邦公司 | Fluorosulfonates |
| CN104661640A (en) * | 2012-09-20 | 2015-05-27 | 花王株式会社 | Cleansing composition for skin or hair |
-
2015
- 2015-11-14 CN CN201510781166.6A patent/CN105213213A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102216345A (en) * | 2008-11-13 | 2011-10-12 | 纳幕尔杜邦公司 | Fluorosulfonates |
| CN104661640A (en) * | 2012-09-20 | 2015-05-27 | 花王株式会社 | Cleansing composition for skin or hair |
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Application publication date: 20160106 |