CN105273859A - Liquid laundry detergent capable of removing grease dirt - Google Patents
Liquid laundry detergent capable of removing grease dirt Download PDFInfo
- Publication number
- CN105273859A CN105273859A CN201510783582.XA CN201510783582A CN105273859A CN 105273859 A CN105273859 A CN 105273859A CN 201510783582 A CN201510783582 A CN 201510783582A CN 105273859 A CN105273859 A CN 105273859A
- Authority
- CN
- China
- Prior art keywords
- sulfonic acid
- acid sodium
- sodium
- laundry detergent
- alkene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 17
- 239000003599 detergent Substances 0.000 title abstract description 4
- 239000004519 grease Substances 0.000 title abstract 3
- 239000011734 sodium Substances 0.000 claims abstract description 27
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 25
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 23
- 238000005406 washing Methods 0.000 claims abstract description 21
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 19
- 150000001336 alkenes Chemical class 0.000 claims description 29
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 20
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 8
- 238000005238 degreasing Methods 0.000 claims description 7
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 claims description 5
- 239000002453 shampoo Substances 0.000 claims description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 5
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 4
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 3
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 claims description 3
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 claims description 3
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 claims description 3
- 229960005323 phenoxyethanol Drugs 0.000 claims description 3
- 239000004744 fabric Substances 0.000 abstract description 9
- 239000004094 surface-active agent Substances 0.000 abstract description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- -1 alkene sulfonate Chemical class 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000006277 sulfonation reaction Methods 0.000 description 3
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000012043 crude product Substances 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical group [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011973 solid acid Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention discloses liquid laundry detergent capable of removing grease dirt. According to the liquid laundry detergent, a specific combination of sodium sulfonate surfactants and internal olefin sulphonates is adopted, and in the process of removing the grease dirt immersed in a fabric, washing is thorough and the fabric is soft and smooth.
Description
Technical field
The present invention relates to a kind of washing liquid, particularly a kind of degreasing washing liquid.
Background technology
Washing liquid is emerging detergent in recent years, its principle of work and traditional washing powder, soap kind with, effective constituent is all tensio-active agent.Difference is: traditional washing powder, and what soap adopted is aniorfic surfactant, is based on alkyl sodium sulfonate and sodium stearate, alkalescence comparatively strong (washing powder PH is generally greater than 12), so in use to the stimulation of skin and injury larger.And washing liquid many employings nonionic surface active agent, PH is close to neutral, gentle to skin, and after entering nature, comparatively washing powder of degrading is fast, so become the washing composition of a new generation.
The effective constituent mainly nonionic surface active agent of washing liquid, its structure comprises water-wet side and hydrophobic end, and wherein hydrophobic end is combined with spot, then by physical motion (as hand rubbing, machine movement), spot is separated with fabric.Tensio-active agent reduces the tension force of water simultaneously, enables water reach fabric face, effective constituent is played a role.
Summary of the invention
The object of the invention is to propose a kind of degreasing washing liquid, its degreasing is thorough, and rapid-action.
For reaching this object, the present invention by the following technical solutions:
A kind of degreasing washing liquid, it comprises following component by weight percentage:
(1) dimethyl dodecyl amine oxide of 8-15%;
(2) sodium carbonate of 2-7%;
(3) phenoxyethyl alcohol of 0.1-0.5%;
(4) methyl p-hydroxybenzoate of 0.1-0.5%;
(5) C of 2-7%
4f
7cH
2cF
2cH
2cH
2sO
3na;
(6) the C18 inner olefin sulfonic acid sodium of 2-7%, the mass ratio of the hydroxyl body (hydroxyl alkane sulfonic acid sodium)/alkene body (alkene sulfonic acid sodium) in described inner olefin sulfonic acid sodium is 80/20;
(7) water of surplus.
In described washing liquid, preferably, the content of dimethyl dodecyl amine oxide is preferably 9-12%, further preferred 10-11.5%.
Preferably, the content of described sodium carbonate is 3-5%, preferably 4%.
Preferably, described inner olefin sulfonic acid sodium and C
4f
7cH
2cF
2cH
2cH
2sO
3the content of Na is 3-6%, and further preferably 5%.
Degreasing washing liquid of the present invention, it adopts the combination of specific sulfonate surfactants and inner olefin sulfonic acid sodium, in the process of the greasy dirt flooded in cleaning fabric, washs thoroughly and fabric softening.
Embodiment
The present invention is described shampoo of the present invention by following embodiment.
Embodiment 1
A kind of light shampoo, it comprises following component by weight percentage:
The dimethyl dodecyl amine oxide of (1) 10%;
The sodium carbonate of (2) 5%;
The phenoxyethyl alcohol of (3) 0.3%;
The methyl p-hydroxybenzoate of (4) 0.3%;
The C of (5) 3%
4f
7cH
2cF
2cH
2cH
2sO
3na;
The C18 inner olefin sulfonic acid sodium of (6) 5%, the mass ratio of the hydroxyl body (hydroxyl alkane sulfonic acid sodium)/alkene body (alkene sulfonic acid sodium) in described inner olefin sulfonic acid sodium is 80/20;
(7) water of surplus.
Described internal olefin sulphonates is known compound, and it is typical but non-limiting, and to prepare example as follows:
In with the flask of whipping appts, add 1-Stearyl alcohol 7000g (25.9 moles), solid acid catalyst gama-alumina 700g (be 10 quality %s relative to raw alcohol), under agitation, 280 DEG C, the nitrogen (7000mL/ minute .) that circulates in system is while react 10 hours.Alcohol conversion after reaction terminates is 100%, C18 internal olefin purity is 98.2%.Obtained thick internal olefin is moved in distillation flask, distills with 148-158 DEG C/0.5mmHg, thus, obtain the internal olefin of the carbonatoms 18 of alkene purity 100%.The internal olefin obtained double bond distribution be: C1 position is 0.5 quality %, C2 position is 25.0 quality %, C3 position is 22.8 quality %, C4 position is 19.1 quality %, C5 position is 14.0 quality %, C6 position is 7.4 quality %, C7 position is 5.4 quality %, C8,9 add up to 4.8 quality %.
By described carbonatoms be 18 internal olefin be added in outside and have in the film type sulfonation reactor of chuck, circulate the water coolant of 20 DEG C in reactor external jacket, uses sulfur trioxide gas to carry out sulfonation reaction under this condition.SO during sulfonation reaction
3the mol ratio of/internal alkene is set as 1.09.Obtained sulfonated bodies is made an addition in the aqueous solution prepared with the sodium hydroxide relative to theoretical acid number being 1.5 moles of times amount, carry out stirring at 30 DEG C in and 1 hour.Corrective is heated 1 hour in autoclave at 160 DEG C, is hydrolyzed thus, obtains C18 inner olefin sulfonic acid sodium crude product.This crude product 300g is moved to separating funnel, after adding ethanol 300mL, adds sherwood oil 300mL every 1 time, extract the oil-soluble impurity of removing.Now, because the mineral compound (principal constituent is saltcake) being added on water-oil interface precipitation of ethanol is also separated removing by oily water separation operation from aqueous phase.Carry out three these extractions removing operation.Solid by aqueous phase side is evaporated, obtain C18 inner olefin sulfonic acid sodium.The mass ratio of the hydroxyl body (hydroxyl alkane sulfonic acid sodium)/alkene body (alkene sulfonic acid sodium) in the inner olefin sulfonic acid sodium obtained is 80/20.In addition, the content of the raw material internal alkene in the internal alkene sodium sulfonate obtained is 1.3 quality % lower than 100ppm (lower than GC Monitoring lower-cut), mineral compound.Further, sulfonic group is present in the content of the internal alkene sulfonate of 2 is 9.6 quality %.
Described C
4f
7cH
2cF
2cH
2cH
2sO
3na is similarly known compound, and it is typical but non-limiting, and to prepare example as follows:
Ethene (25g, 0.53 mole) is joined and is filled with C
4f
9cH
2cF
2in the autoclave of I (217g, 0.87 mole) and d-(+)-limonene (1g), reactor is then made to heat 12 hours at 240 DEG C.By vacuum distilling under about 81 to 91 DEG C and 19 to 24mmHg (2533 to 3200Pa), obtain product C
4f
7cH
2cF
2cH
2cH
2i, yield 62%.By C
4f
7cH
2cF
2cH
2cH
2i (140g, 0.33 mole) joins in the mixture of ethanol (165mL) and water (165mL).Add S-WAT (83g, 0.66 mole), then add 8g copper.By reaction mixture vigorous stirring one week under reflux.Add 500mL water, and filter at 75 DEG C.Filtrate is cooled, and by collecting by filtration white solid product C
4f
7cH
2cF
2cH
2cH
2sO
3na (112g, 84%).
By the cotton of one piece of area 1 square metre, big area is infected with soybean oil, ink, to simulate the pollution under ordinary clothing extreme condition.Pour washing liquid of the present invention into washing machine by its guidance amount, normal procedure washs.After having washed, fabric face is bright and clean, is put into through microscope, has no obvious dirt and remains.
Comparative example 1
Only containing component (5), not containing component (6), all the other conditions are constant, and fabric has obvious yellow stain.
Comparative example 2
Only containing component (6), not containing component (5), all the other conditions are constant, and fabric has obvious yellow stain.
Above-described embodiment and comparative example explanation, washing liquid of the present invention, composite by two kinds of dissimilar sodium sulfonates, under same amount prerequisite, its soil removability is better than being used alone of two kinds of components far away, proves to create synergistic effect between two kinds of sodium sulfonates that the present invention adopts.
Applicant states, the present invention illustrates washing liquid of the present invention by above-described embodiment, but the present invention is not limited to above-mentioned special formulation, does not namely mean that the present invention must rely on above-mentioned detailed component and formula could be implemented.Person of ordinary skill in the field should understand, any improvement in the present invention, to equivalence replacement and the interpolation of ancillary component, the concrete way choice etc. of each raw material of product of the present invention, all drops within protection scope of the present invention and open scope.
Claims (4)
1. a degreasing washing liquid, it comprises following component by weight percentage:
(1) dimethyl dodecyl amine oxide of 8-15%;
(2) sodium carbonate of 2-7%;
(3) phenoxyethyl alcohol of 0.1-0.5%;
(4) methyl p-hydroxybenzoate of 0.1-0.5%;
(5) C of 2-7%
4f
7cH
2cF
2cH
2cH
2sO
3na;
(6) the C18 inner olefin sulfonic acid sodium of 2-7%, the mass ratio of the hydroxyl body (hydroxyl alkane sulfonic acid sodium)/alkene body (alkene sulfonic acid sodium) in described inner olefin sulfonic acid sodium is 80/20;
(7) water of surplus.
2. light shampoo as claimed in claim 1, is characterized in that, the content of dimethyl dodecyl amine oxide is preferably 9-12%, further preferred 10-11.5%.
3. light shampoo as claimed in claim 1, the content of described sodium carbonate is 3-5%, preferably 4%.
4. light shampoo as claimed in claim 1, described inner olefin sulfonic acid sodium and C
4f
7cH
2cF
2cH
2cH
2sO
3the content of Na is 3-6%, and further preferably 5%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510783582.XA CN105273859A (en) | 2015-11-14 | 2015-11-14 | Liquid laundry detergent capable of removing grease dirt |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510783582.XA CN105273859A (en) | 2015-11-14 | 2015-11-14 | Liquid laundry detergent capable of removing grease dirt |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105273859A true CN105273859A (en) | 2016-01-27 |
Family
ID=55143703
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510783582.XA Withdrawn CN105273859A (en) | 2015-11-14 | 2015-11-14 | Liquid laundry detergent capable of removing grease dirt |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105273859A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2018066102A (en) * | 2016-10-14 | 2018-04-26 | 花王株式会社 | Finishing agent composition for fiber products |
| JP2018104880A (en) * | 2016-12-26 | 2018-07-05 | 花王株式会社 | Textile processing method |
| EP3680314A4 (en) * | 2017-09-06 | 2021-05-19 | Kao Corporation | Treatment agent composition for textile product |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102216345A (en) * | 2008-11-13 | 2011-10-12 | 纳幕尔杜邦公司 | Fluorosulfonates |
| CN103865671A (en) * | 2014-02-15 | 2014-06-18 | 上海方木精细化工有限公司 | Bactericidal detergent powder |
| CN104661640A (en) * | 2012-09-20 | 2015-05-27 | 花王株式会社 | Cleansing composition for skin or hair |
-
2015
- 2015-11-14 CN CN201510783582.XA patent/CN105273859A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102216345A (en) * | 2008-11-13 | 2011-10-12 | 纳幕尔杜邦公司 | Fluorosulfonates |
| CN104661640A (en) * | 2012-09-20 | 2015-05-27 | 花王株式会社 | Cleansing composition for skin or hair |
| CN103865671A (en) * | 2014-02-15 | 2014-06-18 | 上海方木精细化工有限公司 | Bactericidal detergent powder |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2018066102A (en) * | 2016-10-14 | 2018-04-26 | 花王株式会社 | Finishing agent composition for fiber products |
| CN109863269A (en) * | 2016-10-14 | 2019-06-07 | 花王株式会社 | Fibre finishing agent composition |
| EP3527717A4 (en) * | 2016-10-14 | 2020-05-27 | Kao Corporation | Fiber product finishing agent composition |
| US10829717B2 (en) | 2016-10-14 | 2020-11-10 | Kao Corporation | Finishing agent composition for textile products |
| CN109863269B (en) * | 2016-10-14 | 2021-11-19 | 花王株式会社 | Finishing agent composition for fiber product |
| JP6993836B2 (en) | 2016-10-14 | 2022-01-14 | 花王株式会社 | Finishing agent composition for textile products |
| JP2018104880A (en) * | 2016-12-26 | 2018-07-05 | 花王株式会社 | Textile processing method |
| CN110073051A (en) * | 2016-12-26 | 2019-07-30 | 花王株式会社 | The processing method of fibre |
| EP3561175A4 (en) * | 2016-12-26 | 2020-08-26 | Kao Corporation | Method for processing fiber product |
| JP6993217B2 (en) | 2016-12-26 | 2022-02-04 | 花王株式会社 | How to treat textile products |
| EP3680314A4 (en) * | 2017-09-06 | 2021-05-19 | Kao Corporation | Treatment agent composition for textile product |
| US11332698B2 (en) | 2017-09-06 | 2022-05-17 | Kao Corporation | Treatment agent composition for textile products |
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Application publication date: 20160127 |