CN105038642A - Waterproof hot melt adhesive containing butyl rubber - Google Patents
Waterproof hot melt adhesive containing butyl rubber Download PDFInfo
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- CN105038642A CN105038642A CN201510461819.2A CN201510461819A CN105038642A CN 105038642 A CN105038642 A CN 105038642A CN 201510461819 A CN201510461819 A CN 201510461819A CN 105038642 A CN105038642 A CN 105038642A
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- melt adhesive
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- 239000004831 Hot glue Substances 0.000 title abstract description 17
- 229920005549 butyl rubber Polymers 0.000 title abstract 4
- 229920005989 resin Polymers 0.000 claims abstract description 23
- 239000011347 resin Substances 0.000 claims abstract description 23
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 229960000892 attapulgite Drugs 0.000 claims abstract description 7
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 claims abstract description 7
- 229910052625 palygorskite Inorganic materials 0.000 claims abstract description 7
- 239000004593 Epoxy Substances 0.000 claims abstract description 4
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 4
- OEIWPNWSDYFMIL-UHFFFAOYSA-N dioctyl benzene-1,4-dicarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C=C1 OEIWPNWSDYFMIL-UHFFFAOYSA-N 0.000 claims abstract description 4
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims abstract description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000944 linseed oil Substances 0.000 claims abstract description 4
- 235000021388 linseed oil Nutrition 0.000 claims abstract description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims abstract description 4
- 239000008117 stearic acid Substances 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920001971 elastomer Polymers 0.000 claims description 17
- VHOQXEIFYTTXJU-UHFFFAOYSA-N Isobutylene-isoprene copolymer Chemical group CC(C)=C.CC(=C)C=C VHOQXEIFYTTXJU-UHFFFAOYSA-N 0.000 claims description 16
- 239000002131 composite material Substances 0.000 claims description 16
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 11
- 239000002699 waste material Substances 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 10
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 claims description 9
- 239000012943 hotmelt Substances 0.000 claims description 9
- 230000004048 modification Effects 0.000 claims description 9
- 238000012986 modification Methods 0.000 claims description 9
- 239000002893 slag Substances 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 239000004246 zinc acetate Substances 0.000 claims description 9
- -1 alkyl phenolic resin Chemical compound 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 239000012634 fragment Substances 0.000 claims description 7
- 238000009830 intercalation Methods 0.000 claims description 7
- 230000002687 intercalation Effects 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- DMYOHQBLOZMDLP-UHFFFAOYSA-N 1-[2-(2-hydroxy-3-piperidin-1-ylpropoxy)phenyl]-3-phenylpropan-1-one Chemical compound C1CCCCN1CC(O)COC1=CC=CC=C1C(=O)CCC1=CC=CC=C1 DMYOHQBLOZMDLP-UHFFFAOYSA-N 0.000 claims description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- YQHLDYVWEZKEOX-UHFFFAOYSA-N cumene hydroperoxide Chemical compound OOC(C)(C)C1=CC=CC=C1 YQHLDYVWEZKEOX-UHFFFAOYSA-N 0.000 claims description 6
- YQLZOAVZWJBZSY-UHFFFAOYSA-N decane-1,10-diamine Chemical compound NCCCCCCCCCCN YQLZOAVZWJBZSY-UHFFFAOYSA-N 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 229920001568 phenolic resin Polymers 0.000 claims description 6
- 239000005011 phenolic resin Substances 0.000 claims description 6
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 4
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 238000000926 separation method Methods 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- MRIZMKJLUDDMHF-UHFFFAOYSA-N cumene;hydrogen peroxide Chemical compound OO.CC(C)C1=CC=CC=C1 MRIZMKJLUDDMHF-UHFFFAOYSA-N 0.000 abstract 1
- OWEZJUPKTBEISC-UHFFFAOYSA-N decane-1,1-diamine Chemical compound CCCCCCCCCC(N)N OWEZJUPKTBEISC-UHFFFAOYSA-N 0.000 abstract 1
- 229910052622 kaolinite Inorganic materials 0.000 abstract 1
- 238000000034 method Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 5
- 239000003471 mutagenic agent Substances 0.000 description 4
- 231100000707 mutagenic chemical Toxicity 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000006136 alcoholysis reaction Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000004513 sizing Methods 0.000 description 2
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000010685 fatty oil Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a waterproof hot melt adhesive containing butyl rubber. The waterproof hot melt adhesive is prepared from the following raw materials in parts by weight: 45-50 parts of EVA, 30-40 parts of modified tackifying resin, 2-3 parts of cumene hydrogen peroxide, 1-3 parts of di-aminodecane, 0.5-0.9 part of citric acid, 0.5-1 part of stearic acid, 1-2 parts of sodium dodecyl benzene sulfonate, 1-3 parts of dioctyl terephthalate, 12-15 parts of butyl rubber, 1-2 parts of dodecyl trimethyl ammonium chloride, 10-20 parts of attapulgite, 40-55 parts of kaolinite and 1-3 parts of epoxy linseed oil. The raw materials of the EVA hot melt adhesive containing butyl rubber are excellent in dispersibility, and the high water tightness and the mechanical property are maintained.
Description
Technical field
The invention belongs to binding agent field, particularly relate to a kind of waterproof hot melt containing isoprene-isobutylene rubber.
Background technology
EVA hot-melt adhesive is formulated by EVA resin, tackifier, softening agent, antioxidant, filler etc.In society now, EVA hot-melt adhesive applied range, consumption are maximum.It has excellent adhesiveproperties, nearly all has hot sticky relay to various material; Excellent electric property; And its melt viscosity is low, applying glue is convenient; With the feature such as the consistency of other Synergist S-421 95s is good.EVA hot-melt adhesive has been widely used in shaping, many fields such as automobile and building materials of the bookbinding of books, bonding, ceramic etc. the reparation of the packaging, plastics etc. of food, mounting, clothes and shoes and hats.Because EVA resin is a kind of thermoplastic resin, high and low temperature resistance is limited, softening temperature is low, and main auxiliary material tackifier are all the polymkeric substance of molecular weight mostly, just play reduction melt viscosity, improve the effect of wetting ability and initial cohesiveness, itself is high-low temperature resistant not, causes the shortcoming of EVA hot-melt adhesive not high-low temperature resistant; Simultaneously also there is lower, the not resistance to fatty oil of adhesiveproperties, easily produce skinning and be not suitable for the shortcomings such as big area coating is bonding in EVA hot-melt adhesive.
At present, along with developing rapidly of PET industry, waste PET quantity also increases thereupon, thus brings serious pollution to environment.How to recycle waste PET, become one of focus of research at present.PET reclaims and mainly comprises physiochemical mutagens and chemical recovery two kinds of methods, physiochemical mutagens method cost is lower, but after physiochemical mutagens, the Mr(relative molecular mass of material) and limiting viscosity all reduce, the PET product be made up of physiochemical mutagens material can not be reused this way and recycle; Chemical recovery makes PET generate micromolecular compound by chemical reaction, and the performance of this method products therefrom is more excellent.Chemical recovery technique can be divided into hydrolysis, ammonia solution and alcoholysis etc. (wherein alcoholysis process is chemical recovery technique relatively more conventional at present), as Pereira etc. utilizes the polyester of degraded to make tensio-active agent.
Summary of the invention
The object of this invention is to provide a kind of waterproof hot melt containing isoprene-isobutylene rubber.
The present invention adopts following technical scheme to achieve these goals:
A kind of waterproof hot melt containing isoprene-isobutylene rubber, it is characterized in that, it is obtained by the raw material of following weight parts: EVA45-50, modified tacky resin 30-40, isopropyl benzene hydroperoxide 2-3, decamethylene diamine 1-3, citric acid 0.5-0.9, stearic acid 0.5-1, Sodium dodecylbenzene sulfonate 1-2, dioctyl terephthalate 1-3, isoprene-isobutylene rubber 12-15, Dodecyl trimethyl ammonium chloride 1-2, attapulgite 10-20, kaolin 40-55, epoxy linseed oil 1-3;
Described modified tacky resin is obtained by the raw material of following weight parts:
Waste PET fragment 40-50, zinc acetate 3-4, thiorubber 10-15, chloroprene rubber 5-7, alkyl phenolic resin 20-30, styrene resin 5-10, trimethyloctadecyl ammonium chloride 1-2, carbide slag 10-20, gac 2-4;
The preparation method of described modified tacky resin is:
(1) by after carbide slag, gac mixing, ultraviolet irradiation 8-12h, then in concentration be 5-8% hydrochloric acid soln in soak 10-12h, solid-liquid separation is carried out to soak solution, dry, obtain the composite powder of modification for subsequent use;
(2) washing, dried waste PET fragment are joined in reactor in proportion, then add zinc acetate; Slowly be warming up to zinc acetate under nitrogen protection when dissolving completely, warming while stirring to 230-250 DEG C, insulation reaction 3-4h; Be cooled to 200-210 DEG C, then add thiorubber, chloroprene rubber, alkyl phenolic resin, styrene resin, stirring reaction 10-20min; Add the composite powder of modification and all the other raw materials again, after stirring 1-2h, discharging cooling stripping and slicing.
Described a kind of waterproof hot melt containing isoprene-isobutylene rubber, is characterized in that: preparation method comprises the following steps:
(1) attapulgite, appropriate amount of deionized water, Dodecyl trimethyl ammonium chloride mixing, fully disperse under 100-200 rev/min, dry after obtained compound size, then mix with isoprene-isobutylene rubber, and twin screw extruder is extruded, and cools the composite modified material of intercalation is for subsequent use;
(2) kneader is preheated to wall temperature 190-200 DEG C; Then add EVA, isopropyl benzene hydroperoxide by weight, decamethylene diamine, citric acid, mediate 10-20min; After add the composite modified material of intercalation and surplus stock by weight, at 180-190 DEG C, mediate 10-15min, take out cool and get final product.
Beneficial effect of the present invention:
(1) each stock dispersion of EVA hot-melt adhesive containing isoprene-isobutylene rubber of the present invention is good, maintains good watertightness and mechanical property.Through intercalation modifying, can improve the mechanical property of rubber, heat-drawn wire improves, and water-absorbent is low, use it to prepare consistency that hot melt adhesive can increase each raw material of hot melt adhesive, improves viscosity and water-repellancy.
(2) modified tacky resin batching rationally, the composite powder of modification wherein contains carbide slag, turn waste into wealth, can carbide slag sterilization be given by uv irradiation again, the hole of carbide slag, gac can be increased simultaneously, strengthen the avidity with resin, ageing-resistant, resistance to air loss is good, not only significantly improves the properties of hot melt adhesive with the composite powder of modification as the new raw material of hot melt adhesive, and has made new contribution for environmental protection.
(3) waste PET fragment by degraded after, then with all the other tackifying resins and the good melting of the composite powder of modification, obtained tackifying resin viscosity is high, and hardness strength performance satisfies the demands; Composite powder can be better dispersed in PET and remaining resin by modified, can increase the tensile strength of sizing material, hardness, nontoxic pollution-free; The present invention successfully by pet waste for the preparation of in hot melt adhesive, obtained hot melt adhesive can meet the sizing agent demand in each field, environmental protection, economy, useful environment.
Embodiment
A kind of waterproof hot melt containing isoprene-isobutylene rubber, it is obtained by the raw material of following weight (kg): EVA47, modified tacky resin 30, isopropyl benzene hydroperoxide 2, decamethylene diamine 1, citric acid 0.5, stearic acid 1, Sodium dodecylbenzene sulfonate 1, dioctyl terephthalate 1, isoprene-isobutylene rubber 15, Dodecyl trimethyl ammonium chloride 2, attapulgite 10, kaolin 55, epoxy linseed oil 1;
Described modified tacky resin is obtained by the raw material of following weight (kg):
Waste PET fragment 40, zinc acetate 3, thiorubber 10, chloroprene rubber 5, alkyl phenolic resin 30, styrene resin 10, trimethyloctadecyl ammonium chloride 1, carbide slag 15, gac 3;
The preparation method of described modified tacky resin is:
(1) by after carbide slag, gac mixing, ultraviolet irradiation 8h, then in concentration be 5% hydrochloric acid soln in soak 10h, solid-liquid separation is carried out to soak solution, dry, obtain the composite powder of modification for subsequent use;
Ultraviolet light source in uv irradiation adopts power 1000W, the high voltage mercury lamp fluorescent tube of spectral range 365-450nm, peak value 365nm;
(2) washing, dried waste PET fragment are joined in reactor in proportion, then add zinc acetate; Slowly be warming up to zinc acetate under nitrogen protection when dissolving completely, warming while stirring to 250 DEG C, insulation reaction 3h; Be cooled to 210 DEG C, then add thiorubber, chloroprene rubber, alkyl phenolic resin, styrene resin, stirring reaction 20min; Add the composite powder of modification and all the other raw materials again, after stirring 2h, discharging cooling stripping and slicing.
Described a kind of waterproof hot melt containing isoprene-isobutylene rubber, preparation method comprises the following steps:
(1) attapulgite, appropriate amount of deionized water, Dodecyl trimethyl ammonium chloride mixing, fully disperse under 200 revs/min, dry after obtained compound size, then mix with isoprene-isobutylene rubber, and twin screw extruder is extruded, and cools the composite modified material of intercalation is for subsequent use;
(2) kneader is preheated to wall temperature 190 DEG C; Then add EVA, isopropyl benzene hydroperoxide by weight, decamethylene diamine, citric acid, mediate 20min; After add the composite modified material of intercalation and surplus stock by weight, at 180 DEG C, mediate 15min, take out cool and get final product.
The apparent viscosity of the hot melt adhesive of the present embodiment is 5200MPa.s, stripping strength 52N/2.5cm, and initial bonding strength reaches No. 5 steel balls, open hour 42s, and within 24 hours, thermally-stabilised proterties is stablized.
Claims (2)
1. the waterproof hot melt containing isoprene-isobutylene rubber, it is characterized in that, it is obtained by the raw material of following weight parts: EVA45-50, modified tacky resin 30-40, isopropyl benzene hydroperoxide 2-3, decamethylene diamine 1-3, citric acid 0.5-0.9, stearic acid 0.5-1, Sodium dodecylbenzene sulfonate 1-2, dioctyl terephthalate 1-3, isoprene-isobutylene rubber 12-15, Dodecyl trimethyl ammonium chloride 1-2, attapulgite 10-20, kaolin 40-55, epoxy linseed oil 1-3;
Described modified tacky resin is obtained by the raw material of following weight parts:
Waste PET fragment 40-50, zinc acetate 3-4, thiorubber 10-15, chloroprene rubber 5-7, alkyl phenolic resin 20-30, styrene resin 5-10, trimethyloctadecyl ammonium chloride 1-2, carbide slag 10-20, gac 2-4;
The preparation method of described modified tacky resin is:
(1) by after carbide slag, gac mixing, ultraviolet irradiation 8-12h, then in concentration be 5-8% hydrochloric acid soln in soak 10-12h, solid-liquid separation is carried out to soak solution, dry, obtain the composite powder of modification for subsequent use;
(2) washing, dried waste PET fragment are joined in reactor in proportion, then add zinc acetate; Slowly be warming up to zinc acetate under nitrogen protection when dissolving completely, warming while stirring to 230-250 DEG C, insulation reaction 3-4h; Be cooled to 200-210 DEG C, then add thiorubber, chloroprene rubber, alkyl phenolic resin, styrene resin, stirring reaction 10-20min; Add the composite powder of modification and all the other raw materials again, after stirring 1-2h, discharging cooling stripping and slicing.
2. a kind of waterproof hot melt containing isoprene-isobutylene rubber according to claim 1, is characterized in that: preparation method comprises the following steps:
(1) attapulgite, appropriate amount of deionized water, Dodecyl trimethyl ammonium chloride mixing, fully disperse under 100-200 rev/min, dry after obtained compound size, then mix with isoprene-isobutylene rubber, and twin screw extruder is extruded, and cools the composite modified material of intercalation is for subsequent use;
(2) kneader is preheated to wall temperature 190-200 DEG C; Then add EVA, isopropyl benzene hydroperoxide by weight, decamethylene diamine, citric acid, mediate 10-20min; After add the composite modified material of intercalation and surplus stock by weight, at 180-190 DEG C, mediate 10-15min, take out cool and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510461819.2A CN105038642A (en) | 2015-07-31 | 2015-07-31 | Waterproof hot melt adhesive containing butyl rubber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510461819.2A CN105038642A (en) | 2015-07-31 | 2015-07-31 | Waterproof hot melt adhesive containing butyl rubber |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105038642A true CN105038642A (en) | 2015-11-11 |
Family
ID=54445622
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510461819.2A Pending CN105038642A (en) | 2015-07-31 | 2015-07-31 | Waterproof hot melt adhesive containing butyl rubber |
Country Status (1)
| Country | Link |
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| CN (1) | CN105038642A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4552819A (en) * | 1982-10-12 | 1985-11-12 | Sumitomo Electric Industries, Ltd. | Adhesive and heat recoverable article having a layer of the adhesive |
| CN1222928A (en) * | 1996-06-21 | 1999-07-14 | 阿托芬德利公司 | Hydrophilic hot melt adhesive |
| JP2002173654A (en) * | 2000-12-05 | 2002-06-21 | Taoka Chem Co Ltd | Hot-melt adhesive composition |
| CN103214984A (en) * | 2013-04-17 | 2013-07-24 | 安徽金门工贸有限公司 | Holt melt adhesive containing nanometer iron ore tailing powder |
| CN103571387A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Special hot melt adhesive for automotive upholstery |
| CN104086956A (en) * | 2014-07-08 | 2014-10-08 | 彭朕财 | PET(PETG) (poly(ethylene terephthalate)(polyethylene terephthalate glycol)) tackifying and toughening agent |
-
2015
- 2015-07-31 CN CN201510461819.2A patent/CN105038642A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4552819A (en) * | 1982-10-12 | 1985-11-12 | Sumitomo Electric Industries, Ltd. | Adhesive and heat recoverable article having a layer of the adhesive |
| CN1222928A (en) * | 1996-06-21 | 1999-07-14 | 阿托芬德利公司 | Hydrophilic hot melt adhesive |
| JP2002173654A (en) * | 2000-12-05 | 2002-06-21 | Taoka Chem Co Ltd | Hot-melt adhesive composition |
| CN103214984A (en) * | 2013-04-17 | 2013-07-24 | 安徽金门工贸有限公司 | Holt melt adhesive containing nanometer iron ore tailing powder |
| CN103571387A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Special hot melt adhesive for automotive upholstery |
| CN104086956A (en) * | 2014-07-08 | 2014-10-08 | 彭朕财 | PET(PETG) (poly(ethylene terephthalate)(polyethylene terephthalate glycol)) tackifying and toughening agent |
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