CN105038645A - Good-liquidity harmful-gas-free environmentally-friendly hot melt adhesive - Google Patents
Good-liquidity harmful-gas-free environmentally-friendly hot melt adhesive Download PDFInfo
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- CN105038645A CN105038645A CN201510461959.XA CN201510461959A CN105038645A CN 105038645 A CN105038645 A CN 105038645A CN 201510461959 A CN201510461959 A CN 201510461959A CN 105038645 A CN105038645 A CN 105038645A
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- 239000004831 Hot glue Substances 0.000 title claims abstract description 26
- 229920005989 resin Polymers 0.000 claims abstract description 32
- 239000011347 resin Substances 0.000 claims abstract description 32
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 239000004342 Benzoyl peroxide Substances 0.000 claims abstract description 7
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims abstract description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920002472 Starch Polymers 0.000 claims abstract description 7
- 235000019400 benzoyl peroxide Nutrition 0.000 claims abstract description 7
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 claims abstract description 7
- 229920001568 phenolic resin Polymers 0.000 claims abstract description 7
- 239000005011 phenolic resin Substances 0.000 claims abstract description 7
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 7
- 239000004417 polycarbonate Substances 0.000 claims abstract description 7
- 229920002379 silicone rubber Polymers 0.000 claims abstract description 7
- 235000019698 starch Nutrition 0.000 claims abstract description 7
- 239000008107 starch Substances 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000010881 fly ash Substances 0.000 claims abstract description 4
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims abstract description 4
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims abstract description 4
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000002131 composite material Substances 0.000 claims description 16
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 11
- 239000002699 waste material Substances 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 10
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 claims description 9
- 239000000796 flavoring agent Substances 0.000 claims description 9
- 235000019634 flavors Nutrition 0.000 claims description 9
- 230000004048 modification Effects 0.000 claims description 9
- 238000012986 modification Methods 0.000 claims description 9
- 239000002893 slag Substances 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 239000004246 zinc acetate Substances 0.000 claims description 9
- -1 alkyl phenolic resin Chemical compound 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 239000012634 fragment Substances 0.000 claims description 7
- 238000009830 intercalation Methods 0.000 claims description 7
- 230000002687 intercalation Effects 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- DMYOHQBLOZMDLP-UHFFFAOYSA-N 1-[2-(2-hydroxy-3-piperidin-1-ylpropoxy)phenyl]-3-phenylpropan-1-one Chemical compound C1CCCCN1CC(O)COC1=CC=CC=C1C(=O)CCC1=CC=CC=C1 DMYOHQBLOZMDLP-UHFFFAOYSA-N 0.000 claims description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 5
- 239000003963 antioxidant agent Substances 0.000 claims description 4
- 230000003078 antioxidant effect Effects 0.000 claims description 4
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 3
- 229920003987 resole Polymers 0.000 claims description 3
- 238000000926 separation method Methods 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 229920001971 elastomer Polymers 0.000 abstract description 3
- 239000000654 additive Substances 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 230000003712 anti-aging effect Effects 0.000 abstract 1
- 239000004945 silicone rubber Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 5
- 239000003471 mutagenic agent Substances 0.000 description 4
- 231100000707 mutagenic chemical Toxicity 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000006136 alcoholysis reaction Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000004513 sizing Methods 0.000 description 2
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000010685 fatty oil Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
Abstract
The invention discloses a good-liquidity harmful-gas-free environmentally-friendly hot melt adhesive which is prepared from the following raw materials in parts by weight: 35-45 parts of EVA, 1-2 parts of dodecyl trimethyl ammonium chloride, 10-15 parts of nano fly ash, 10-20 parts of kieselguhr, 1-3 parts of tetraethylenepentamine, 4-8 parts of polycarbonate, 5-8 parts of starch, 0.1-0.5 part of benzoyl peroxide, 10-15 parts of octyl-phenolic curing resin, 1-2 parts of an anti-aging agent NBC, 1-2 parts of sodium polyacrylate, 10-18 parts of silicone rubber, 3-9 parts of phenolic resin and 10-20 parts of modified tackifying resin. According to the invention, resin and additives are reasonably compounded, so that the hot melt adhesive is good in liquidity, and high in softness and viscidity; through intercalated modifying, the mechanical property of rubber can be improved, thermal deformation temperature is increased, and water absorption is low, and thus when the rubber is used for preparing the hot melt adhesive, compatibility of all raw materials of the hot melt adhesive can be increased and viscosity and water resistance are improved.
Description
Technical field
The invention belongs to binding agent field, particularly relate to a kind of Environmental-friendhot hot melt adhesive not containing obnoxious flavour of good fluidity.
Background technology
EVA hot-melt adhesive is formulated by EVA resin, tackifier, softening agent, antioxidant, filler etc.In society now, EVA hot-melt adhesive applied range, consumption are maximum.It has excellent adhesiveproperties, nearly all has hot sticky relay to various material; Excellent electric property; And its melt viscosity is low, applying glue is convenient; With the feature such as the consistency of other Synergist S-421 95s is good.EVA hot-melt adhesive has been widely used in shaping, many fields such as automobile and building materials of the bookbinding of books, bonding, ceramic etc. the reparation of the packaging, plastics etc. of food, mounting, clothes and shoes and hats.Because EVA resin is a kind of thermoplastic resin, high and low temperature resistance is limited, softening temperature is low, and main auxiliary material tackifier are all the polymkeric substance of molecular weight mostly, just play reduction melt viscosity, improve the effect of wetting ability and initial cohesiveness, itself is high-low temperature resistant not, causes the shortcoming of EVA hot-melt adhesive not high-low temperature resistant; Simultaneously also there is lower, the not resistance to fatty oil of adhesiveproperties, easily produce skinning and be not suitable for the shortcomings such as big area coating is bonding in EVA hot-melt adhesive.
At present, along with developing rapidly of PET industry, waste PET quantity also increases thereupon, thus brings serious pollution to environment.How to recycle waste PET, become one of focus of research at present.PET reclaims and mainly comprises physiochemical mutagens and chemical recovery two kinds of methods, physiochemical mutagens method cost is lower, but after physiochemical mutagens, the Mr(relative molecular mass of material) and limiting viscosity all reduce, the PET product be made up of physiochemical mutagens material can not be reused this way and recycle; Chemical recovery makes PET generate micromolecular compound by chemical reaction, and the performance of this method products therefrom is more excellent.Chemical recovery technique can be divided into hydrolysis, ammonia solution and alcoholysis etc. (wherein alcoholysis process is chemical recovery technique relatively more conventional at present), as Pereira etc. utilizes the polyester of degraded to make tensio-active agent.
Summary of the invention
The object of this invention is to provide a kind of Environmental-friendhot hot melt adhesive not containing obnoxious flavour of good fluidity.
The present invention adopts following technical scheme to achieve these goals:
A kind of Environmental-friendhot hot melt adhesive not containing obnoxious flavour of good fluidity, it is characterized in that, it is obtained by the raw material of following weight parts: EVA35-45, Dodecyl trimethyl ammonium chloride 1-2, nano flyash 10-15, diatomite 10-20, tetraethylene pentamine 1-3, polycarbonate 4-8, starch 5-8, benzoyl peroxide 0.1-0.5, Octylphenolic Curing Resin 10-15, antioxidant NBC 1-2, sodium polyacrylate 1-2, silicon rubber 10-18, resol 3-9, modified tacky resin 10-20;
Described modified tacky resin is obtained by the raw material of following weight parts:
Waste PET fragment 40-50, zinc acetate 3-4, thiorubber 10-15, chloroprene rubber 5-7, alkyl phenolic resin 20-30, styrene resin 5-10, trimethyloctadecyl ammonium chloride 1-2, carbide slag 10-20, gac 2-4;
The preparation method of described modified tacky resin is:
(1) by after carbide slag, gac mixing, ultraviolet irradiation 8-12h, then in concentration be 5-8% hydrochloric acid soln in soak 10-12h, solid-liquid separation is carried out to soak solution, dry, obtain the composite powder of modification for subsequent use;
(2) washing, dried waste PET fragment are joined in reactor in proportion, then add zinc acetate; Slowly be warming up to zinc acetate under nitrogen protection when dissolving completely, warming while stirring to 230-250 DEG C, insulation reaction 3-4h; Be cooled to 200-210 DEG C, then add thiorubber, chloroprene rubber, alkyl phenolic resin, styrene resin, stirring reaction 10-20min; Add the composite powder of modification and all the other raw materials again, after stirring 1-2h, discharging cooling stripping and slicing.
The Environmental-friendhot hot melt adhesive not containing obnoxious flavour of described a kind of good fluidity, is characterized in that: preparation method comprises the following steps:
(1) diatomite, appropriate amount of deionized water, Dodecyl trimethyl ammonium chloride mixing, fully disperse under 100-200 rev/min, dry after obtained compound size, then mix with silicon rubber, and twin screw extruder is extruded, and cools the composite modified material of intercalation is for subsequent use;
(2) kneader is preheated to wall temperature 190-200 DEG C; Then add EVA, polycarbonate, starch, benzoyl peroxide by weight, Octylphenolic Curing Resin, mediate 10-20min; After add the composite modified material of intercalation and surplus stock by weight, at 180-190 DEG C, mediate 8-10min, take out cool and get final product.
Beneficial effect of the present invention:
(1) each resin of the present invention and additive compound reasonable, good fluidity, soft viscosity is high, through intercalation modifying, can improve the mechanical property of rubber, heat-drawn wire improves, and water-absorbent is low, use it to prepare consistency that hot melt adhesive can increase each raw material of hot melt adhesive, improves viscosity and water-repellancy.
(2) modified tacky resin batching rationally, the composite powder of modification wherein contains carbide slag, turn waste into wealth, can carbide slag sterilization be given by uv irradiation again, the hole of carbide slag, gac can be increased simultaneously, strengthen the avidity with resin, ageing-resistant, resistance to air loss is good, not only significantly improves the properties of hot melt adhesive with the composite powder of modification as the new raw material of hot melt adhesive, and has made new contribution for environmental protection.
(3) waste PET fragment by degraded after, then with all the other tackifying resins and the good melting of the composite powder of modification, obtained tackifying resin viscosity is high, and hardness strength performance satisfies the demands; Composite powder can be better dispersed in PET and remaining resin by modified, can increase the tensile strength of sizing material, hardness, nontoxic pollution-free; The present invention successfully by pet waste for the preparation of in hot melt adhesive, obtained hot melt adhesive can meet the sizing agent demand in each field, environmental protection, economy, useful environment.
Embodiment
A kind of Environmental-friendhot hot melt adhesive not containing obnoxious flavour of good fluidity, it is obtained by the raw material of following weight (kg): EVA38, Dodecyl trimethyl ammonium chloride 1, nano flyash 10, diatomite 20, tetraethylene pentamine 1, polycarbonate 4, starch 8, benzoyl peroxide 0.1, Octylphenolic Curing Resin 10, antioxidant NBC 1, sodium polyacrylate 1, silicon rubber 18, resol 9, modified tacky resin 20;
Described modified tacky resin is obtained by the raw material of following weight (kg):
Waste PET fragment 50, zinc acetate 4, thiorubber 10, chloroprene rubber 5, alkyl phenolic resin 30, styrene resin 10, trimethyloctadecyl ammonium chloride 2, carbide slag 20, gac 4;
The preparation method of described modified tacky resin is:
(1) by after carbide slag, gac mixing, ultraviolet irradiation 9h, then in concentration be 8% hydrochloric acid soln in soak 10h, solid-liquid separation is carried out to soak solution, dry, obtain the composite powder of modification for subsequent use;
Ultraviolet light source in uv irradiation adopts power 1000W, the high voltage mercury lamp fluorescent tube of spectral range 365-450nm, peak value 365nm;
(2) washing, dried waste PET fragment are joined in reactor in proportion, then add zinc acetate; Slowly be warming up to zinc acetate under nitrogen protection when dissolving completely, warming while stirring to 250 DEG C, insulation reaction 4h; Be cooled to 210 DEG C, then add thiorubber, chloroprene rubber, alkyl phenolic resin, styrene resin, stirring reaction 20min; Add the composite powder of modification and all the other raw materials again, after stirring 2h, discharging cooling stripping and slicing.
The Environmental-friendhot hot melt adhesive not containing obnoxious flavour of described a kind of good fluidity, preparation method comprises the following steps:
(1) diatomite, appropriate amount of deionized water, Dodecyl trimethyl ammonium chloride mixing, fully disperse under 200 revs/min, dry after obtained compound size, then mix with silicon rubber, and twin screw extruder is extruded, and cools the composite modified material of intercalation is for subsequent use;
(2) kneader is preheated to wall temperature 200 DEG C; Then add EVA, polycarbonate, starch, benzoyl peroxide by weight, Octylphenolic Curing Resin, mediate 20min; After add the composite modified material of intercalation and surplus stock by weight, at 190 DEG C, mediate 10min, take out cool and get final product.
The apparent viscosity of the hot melt adhesive of the present embodiment is 5500MPa.s, stripping strength 55N/2.5cm, and initial bonding strength reaches No. 5 steel balls, open hour 44s, and within 24 hours, thermally-stabilised proterties is stablized.
Claims (2)
1. the Environmental-friendhot hot melt adhesive not containing obnoxious flavour of a good fluidity, it is characterized in that, it is obtained by the raw material of following weight parts: EVA35-45, Dodecyl trimethyl ammonium chloride 1-2, nano flyash 10-15, diatomite 10-20, tetraethylene pentamine 1-3, polycarbonate 4-8, starch 5-8, benzoyl peroxide 0.1-0.5, Octylphenolic Curing Resin 10-15, antioxidant NBC 1-2, sodium polyacrylate 1-2, silicon rubber 10-18, resol 3-9, modified tacky resin 10-20;
Described modified tacky resin is obtained by the raw material of following weight parts:
Waste PET fragment 40-50, zinc acetate 3-4, thiorubber 10-15, chloroprene rubber 5-7, alkyl phenolic resin 20-30, styrene resin 5-10, trimethyloctadecyl ammonium chloride 1-2, carbide slag 10-20, gac 2-4;
The preparation method of described modified tacky resin is:
(1) by after carbide slag, gac mixing, ultraviolet irradiation 8-12h, then in concentration be 5-8% hydrochloric acid soln in soak 10-12h, solid-liquid separation is carried out to soak solution, dry, obtain the composite powder of modification for subsequent use;
(2) washing, dried waste PET fragment are joined in reactor in proportion, then add zinc acetate; Slowly be warming up to zinc acetate under nitrogen protection when dissolving completely, warming while stirring to 230-250 DEG C, insulation reaction 3-4h; Be cooled to 200-210 DEG C, then add thiorubber, chloroprene rubber, alkyl phenolic resin, styrene resin, stirring reaction 10-20min; Add the composite powder of modification and all the other raw materials again, after stirring 1-2h, discharging cooling stripping and slicing.
2. the Environmental-friendhot hot melt adhesive not containing obnoxious flavour of a kind of good fluidity according to claim 1, is characterized in that: preparation method comprises the following steps:
(1) diatomite, appropriate amount of deionized water, Dodecyl trimethyl ammonium chloride mixing, fully disperse under 100-200 rev/min, dry after obtained compound size, then mix with silicon rubber, and twin screw extruder is extruded, and cools the composite modified material of intercalation is for subsequent use;
(2) kneader is preheated to wall temperature 190-200 DEG C; Then add EVA, polycarbonate, starch, benzoyl peroxide by weight, Octylphenolic Curing Resin, mediate 10-20min; After add the composite modified material of intercalation and surplus stock by weight, at 180-190 DEG C, mediate 8-10min, take out cool and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510461959.XA CN105038645A (en) | 2015-07-31 | 2015-07-31 | Good-liquidity harmful-gas-free environmentally-friendly hot melt adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510461959.XA CN105038645A (en) | 2015-07-31 | 2015-07-31 | Good-liquidity harmful-gas-free environmentally-friendly hot melt adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105038645A true CN105038645A (en) | 2015-11-11 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510461959.XA Pending CN105038645A (en) | 2015-07-31 | 2015-07-31 | Good-liquidity harmful-gas-free environmentally-friendly hot melt adhesive |
Country Status (1)
| Country | Link |
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| CN (1) | CN105038645A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105400457A (en) * | 2015-12-28 | 2016-03-16 | 任新界 | Cigarette lap adhesive capable of giving off fragrance and preparation method thereof |
| CN111237728A (en) * | 2020-02-14 | 2020-06-05 | 厦门普为光电科技有限公司 | Protection system for lamp tube |
| CN114190649A (en) * | 2021-12-22 | 2022-03-18 | 广州大草原鞋业有限公司 | Manufacturing process of waterproof climbing shoes |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4552819A (en) * | 1982-10-12 | 1985-11-12 | Sumitomo Electric Industries, Ltd. | Adhesive and heat recoverable article having a layer of the adhesive |
| CN1222928A (en) * | 1996-06-21 | 1999-07-14 | 阿托芬德利公司 | Hydrophilic hot melt adhesive |
| JP2002173654A (en) * | 2000-12-05 | 2002-06-21 | Taoka Chem Co Ltd | Hot-melt adhesive composition |
| CN103214984A (en) * | 2013-04-17 | 2013-07-24 | 安徽金门工贸有限公司 | Holt melt adhesive containing nanometer iron ore tailing powder |
| CN103571387A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Special hot melt adhesive for automotive upholstery |
| CN104086956A (en) * | 2014-07-08 | 2014-10-08 | 彭朕财 | PET(PETG) (poly(ethylene terephthalate)(polyethylene terephthalate glycol)) tackifying and toughening agent |
-
2015
- 2015-07-31 CN CN201510461959.XA patent/CN105038645A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4552819A (en) * | 1982-10-12 | 1985-11-12 | Sumitomo Electric Industries, Ltd. | Adhesive and heat recoverable article having a layer of the adhesive |
| CN1222928A (en) * | 1996-06-21 | 1999-07-14 | 阿托芬德利公司 | Hydrophilic hot melt adhesive |
| JP2002173654A (en) * | 2000-12-05 | 2002-06-21 | Taoka Chem Co Ltd | Hot-melt adhesive composition |
| CN103214984A (en) * | 2013-04-17 | 2013-07-24 | 安徽金门工贸有限公司 | Holt melt adhesive containing nanometer iron ore tailing powder |
| CN103571387A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Special hot melt adhesive for automotive upholstery |
| CN104086956A (en) * | 2014-07-08 | 2014-10-08 | 彭朕财 | PET(PETG) (poly(ethylene terephthalate)(polyethylene terephthalate glycol)) tackifying and toughening agent |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105400457A (en) * | 2015-12-28 | 2016-03-16 | 任新界 | Cigarette lap adhesive capable of giving off fragrance and preparation method thereof |
| CN105400457B (en) * | 2015-12-28 | 2017-07-07 | 任新界 | It is a kind of can be with the cigarette overlapping glue of emanating faint scent and preparation method |
| CN111237728A (en) * | 2020-02-14 | 2020-06-05 | 厦门普为光电科技有限公司 | Protection system for lamp tube |
| CN114190649A (en) * | 2021-12-22 | 2022-03-18 | 广州大草原鞋业有限公司 | Manufacturing process of waterproof climbing shoes |
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Application publication date: 20151111 |