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CN104974620A - Aqueous colorful paint - Google Patents

Aqueous colorful paint Download PDF

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Publication number
CN104974620A
CN104974620A CN201410143997.6A CN201410143997A CN104974620A CN 104974620 A CN104974620 A CN 104974620A CN 201410143997 A CN201410143997 A CN 201410143997A CN 104974620 A CN104974620 A CN 104974620A
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parts
revs
rotating speed
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CN201410143997.6A
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Chinese (zh)
Inventor
封海
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WUXI SEVEN POINT BUILDING MATERIAL Co Ltd
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WUXI SEVEN POINT BUILDING MATERIAL Co Ltd
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Priority to CN201410143997.6A priority Critical patent/CN104974620A/en
Publication of CN104974620A publication Critical patent/CN104974620A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/28Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for wrinkle, crackle, orange-peel, or similar decorative effects
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/29Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • C09D7/62Additives non-macromolecular inorganic modified by treatment with other compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

An aqueous colorful paint is prepared through a method comprising: (1) preparation of a protective liquid aqueous solution: filling a reaction kettle with deionized water, and adding modified bentonite into the reaction kettle with stirring and dispersion; (2) preparation of a basic paint: adding hydrophobically-modified hydroxyethyl cellulose to the deionized water, adding an additive 1 and mixing the mixture uniformly, feeding a pigment filling material to enable the particle size of the mixture to be less than 60 [mu]m, adding an emulsion and stirring and mixing the mixture uniformly, adding an additive 2 and mixing the mixture uniformly, feeding the protective liquid aqueous solution with dispersion, and feeding a pigment color slurry and stirring the mixture uniformly; (3) preparation of a wrapping gloss oil: adding successively alcohol ester-12, an NXZ defoaming agent and a BIT bactericide to a silicone acrylic emulsion with uniform stirring; and (4) granulation and synthesis: mixing the protective liquid with the basic paint, carrying out cut-granulation, and mixing the wrapping gloss oil with the protective liquid and the basic paint to obtain the aqueous colorful paint. The aqueous colorful paint is strong in decorative effect, is high in elasticity, stain resistance and weather resistance, is abundant in color and is thin and light in coating.

Description

A kind of water-soluble colorful coating
Technical field
The present invention relates to technical field of coatings, especially relate to a kind of environment-friendly type aqueous multicolor finish and preparation method thereof.
Background technology
Water-soluble colorful coating in water-based basic coating, is mixed into the two or more different colours of liquid or gel, size and different band look particulate, the suspended dispersion coating of a kind of compound of composition.There is dispersion and multiple color effect of decorative patterns can be obtained after coating, also can have uneven, stereoscopic sensation is strong, the excellent young relief-type appearance tactile impression effect of gloss.
Water-soluble colorful coating had both had decorative pattern and the color of the high-grade finishing material such as natural granite stone, wallpaper, also have surmount nature and back to nature hommization, personalized pattern, have more the perfectly application characteristic such as the incomparable snappiness of common coating, high resistance crackle.But water-soluble colorful coating poor storage stability at present, water tolerance, alkali resistance, abrasion resistance, weatherability are poor, cover crack ability.
Summary of the invention
For the problems referred to above that prior art exists, the applicant provides a kind of water-soluble colorful coating.This coatings decoration is strong, has snappiness, high resistance is stain and high-weatherability, rich color, and coating is thin and light.
Technical scheme of the present invention is as follows:
A kind of water-soluble colorful coating, its preparation method is as follows:
(1) preparation of liquid aqueous solution is protected:
90 ~ 97.5 parts of deionized waters are added reactor, under the rotating speed of 500 revs/min, 5 ~ 8.5 parts of modified alta-mud powder are dropped into reactor, then dispersed with stirring under the rotating speed of 1500 revs/min, until mixture becomes transparent in particle solution, can obtain protecting liquid aqueous solution;
(2) preparation of auxiliary agent 1: 15 ~ 20 parts of propylene glycol, 5 ~ 8 parts of dispersion agent SN-5040,3 ~ 4 parts of NXZ defoamers are mixed; The preparation of auxiliary agent 2: 9 ~ 13 parts of alcohol esters, 12,4 ~ 6 parts of BIT series bactericidal agents, 1 ~ 2 part of AMP-95,2 ~ 3 parts of silicone-based defoamers SN-345 are mixed;
(3) preparation of base paint:
4 ~ 12 parts of Natrosol Pluss are added in 350 ~ 450 parts of deionized waters, disperse 10 minutes under the rotating speed of 2500 revs/min, then add 23 ~ 32 parts of auxiliary agents 1 and mix;
Then 180 ~ 205 parts of color filters are dropped into, disperse 20 ~ 30 minutes under the rotating speed of 2500 revs/min, make the grain diameter of mixture below 60 microns;
Then 200 ~ 350 parts of emulsions are added, and be uniformly mixed, 8 ~ 11 parts of auxiliary agents 2 are added, then stir under the rotating speed of 300 ~ 800 revs/min, make the PH of mixture be 8 ~ 9;
Then protection liquid aqueous solution 50 ~ 60 parts input prepared by step (1), disperse under the rotating speed of 1500 ~ 2000 revs/min after 15 ~ 20 minutes, then by painted mill base 0 ~ 30 part input, stir under the rotating speed of 500 ~ 800 revs/min and can obtain base paint;
(4) preparation of coated gloss oil:
After 850 ~ 1000 parts of organosilicon crylic acid latex RS-3788A are ready to, add 45 ~ 50 parts of alcohol esters, 12,1 ~ 3 part of NXZ defoamer, 2 ~ 3 parts of BIT series bactericidal agents successively, after stirring under the rotating speed of 200 ~ 500 revs/min, coated gloss oil can be obtained;
(5) granulation synthesis:
Granulation is cut after base paint 300 ~ 400 parts prepared by the protection liquid 300 ~ 400 parts step (1) prepared and step (3) mixes under the rotating speed of 200 ~ 1200 revs/min; Poured into coated gloss oil 400 ~ 480 parts prepared by step (4), under the rotating speed of 100 ~ 300 revs/min, mixing can obtain this water-soluble colorful coating again.
Described color filters be calcined kaolin, rutile titanium white powder, coarse whiting, superfine alumina silicate powder one or more.Described emulsion is the one in pure third RS-6733A or organosilicon crylic acid latex RS-3788A.Described painted mill base is one or more in UTI iron oxide red, UTI iron oxide yellow, UTI iron oxide black.The use number of described each raw material is parts by weight.
The technique effect that the present invention is useful is:
This water-soluble colorful coating adopts same base paint formulation, and the needs according to client are mixed colours, different colours colored paint again with protection liquid mixing, match colors simple and convenient.
Gained coating has following excellent properties:
1, by force ornamental: color can imitate natural granite stone and wallpaper, stereoscopic sensation is strong, and the application for exterior wall has extremely strong artistic effect; Application for interior wall can be compared wallpaper, and decorative pattern seamless is then better than wallpaper.
2, snappiness: for different metopes, all has excellent binding ability, effectively can hide the fine cracks on metope, keeps the firm and smooth of coating.
3, high anti-stain characteristic: there is stronger defensive ability/resistance ability, special salt water resistance to acid and basic cpd, be the desirable coating material of seashore skin, even if after being polluted, also only need use clean-out system to remove easily, can not painting effect be affected.
4, high-weatherability: no matter in normal circumstances, or under the severe environment such as acid-rain corrosion, coating all has extremely strong adaptive faculty and resistibility.
5, rich color: though color decorative pattern comes from natural granite, be better than granite, the color depth is followed one's inclinations, decorative pattern size random, can create the artistic state that natural granite is incomparable.
6, coating is thin and light: compared with the external wall decorative materials such as granite, wall brick and glass curtain wall, and water-thinned color exterior coating coating is thin, from heavy and light, do not affect the load-bearing of buildings.
Embodiment
Embodiment 1
(1) preparation of liquid aqueous solution is protected:
90 parts of deionized waters are added reactor, under the rotating speed of 500 revs/min, 5 parts of modified alta-mud powder are dropped into reactor, then dispersed with stirring under the rotating speed of 1500 revs/min, until mixture becomes transparent in particle solution, can obtain protecting liquid aqueous solution;
(2) preparation of auxiliary agent 1: 15 parts of propylene glycol, 5 parts of dispersion agent SN-5040,3 parts of NXZ defoamers are mixed; The preparation of auxiliary agent 2: 9 parts of alcohol esters, 12,4 parts of BIT series bactericidal agents, 1 part of AMP-95,2 parts of silicone-based defoamers SN-345 are mixed;
(3) preparation of base paint:
4 parts of Natrosol Pluss are added in 350 parts of deionized waters, disperse 10 minutes under the rotating speed of 2500 revs/min, then add 23 parts of auxiliary agents 1 and mix;
Then 180 parts of color filters are dropped into, disperse 20 minutes under the rotating speed of 2500 revs/min, make the grain diameter of mixture below 60 microns;
Then 200 parts of emulsions are added, and be uniformly mixed, 8 parts of auxiliary agents 2 are added, then stir under the rotating speed of 300 revs/min, make the PH of mixture be 8;
Then protection liquid aqueous solution 50 parts input step (1) prepared, disperses after 15 minutes, stirs and can obtain base paint under the rotating speed of 500 revs/min under the rotating speed of 1500 revs/min;
(4) preparation of coated gloss oil:
After 850 parts of organosilicon crylic acid latex RS-3788A are ready to, add 45 parts of alcohol esters, 12,1 part of NXZ defoamer, 2 parts of BIT series bactericidal agents successively, after stirring under the rotating speed of 200 revs/min, coated gloss oil can be obtained;
(5) granulation synthesis:
Granulation is cut after base paint 300 parts prepared by the protection liquid 300 parts step (1) prepared and step (3) mixes under the rotating speed of 200 revs/min; Poured into coated gloss oil 400 parts prepared by step (4), under the rotating speed of 100 revs/min, mixing can obtain this water-soluble colorful coating again.
Described color filters is calcined kaolin.Described emulsion is pure third RS-6733A.The use number of described each raw material is parts by weight.
Embodiment 2
(1) preparation of liquid aqueous solution is protected:
97.5 parts of deionized waters are added reactor, under the rotating speed of 500 revs/min, 8.5 parts of modified alta-mud powder are dropped into reactor, then dispersed with stirring under the rotating speed of 1500 revs/min, until mixture becomes transparent in particle solution, can obtain protecting liquid aqueous solution;
(2) preparation of auxiliary agent 1: 20 parts of propylene glycol, 8 parts of dispersion agent SN-5040,4 parts of NXZ defoamers are mixed; The preparation of auxiliary agent 2: 13 parts of alcohol esters, 12,6 parts of BIT series bactericidal agents, 2 parts of AMP-95,3 parts of silicone-based defoamers SN-345 are mixed;
(3) preparation of base paint:
12 parts of Natrosol Pluss are added in 450 parts of deionized waters, disperse 10 minutes under the rotating speed of 2500 revs/min, then add 32 parts of auxiliary agents 1 and mix;
Then 205 parts of color filters are dropped into, disperse 30 minutes under the rotating speed of 2500 revs/min, make the grain diameter of mixture below 60 microns;
Then 350 parts of emulsions are added, and be uniformly mixed, 11 parts of auxiliary agents 2 are added, then stir under the rotating speed of 800 revs/min, make the PH of mixture be 9;
Then protection liquid aqueous solution 60 parts input step (1) prepared, disperses after 20 minutes, then by painted mill base 30 parts input, stirs and can obtain base paint under the rotating speed of 800 revs/min under the rotating speed of 2000 revs/min;
(4) preparation of coated gloss oil:
After 1000 parts of organosilicon crylic acid latex RS-3788A are ready to, add 50 parts of alcohol esters, 12,3 parts of NXZ defoamers, 3 parts of BIT series bactericidal agents successively, after stirring under the rotating speed of 500 revs/min, coated gloss oil can be obtained;
(5) granulation synthesis:
Granulation is cut after base paint 400 parts prepared by the protection liquid 400 parts step (1) prepared and step (3) mixes under the rotating speed of 1200 revs/min; Poured into coated gloss oil 480 parts prepared by step (4), under the rotating speed of 300 revs/min, mixing can obtain this water-soluble colorful coating again.
Described color filters is the 1:1:1 mixture of calcined kaolin, rutile titanium white powder and superfine alumina silicate powder.Described emulsion is organosilicon crylic acid latex RS-3788A.Described painted mill base is UTI iron oxide red.The use number of described each raw material is parts by weight.
Embodiment 3
(1) preparation of liquid aqueous solution is protected:
95 parts of deionized waters are added reactor, under the rotating speed of 500 revs/min, 7 parts of modified alta-mud powder are dropped into reactor, then dispersed with stirring under the rotating speed of 1500 revs/min, until mixture becomes transparent in particle solution, can obtain protecting liquid aqueous solution;
(2) preparation of auxiliary agent 1: 18 parts of propylene glycol, 7 parts of dispersion agent SN-5040,3.5 parts of NXZ defoamers are mixed; The preparation of auxiliary agent 2: 11 parts of alcohol esters, 12,5 parts of BIT series bactericidal agents, 1 part of AMP-95,3 parts of silicone-based defoamers SN-345 are mixed;
(3) preparation of base paint:
8 parts of Natrosol Pluss are added in 400 parts of deionized waters, disperse 10 minutes under the rotating speed of 2500 revs/min, then add 27 parts of auxiliary agents 1 and mix;
Then 190 parts of color filters are dropped into, disperse 25 minutes under the rotating speed of 2500 revs/min, make the grain diameter of mixture below 60 microns;
Then 270 parts of emulsions are added, and be uniformly mixed, 10 parts of auxiliary agents 2 are added, then stir under the rotating speed of 500 revs/min, make the PH of mixture be 8;
Then protection liquid aqueous solution 55 parts input step (1) prepared, disperses after 20 minutes, then by painted mill base 15 parts input, stirs and can obtain base paint under the rotating speed of 600 revs/min under the rotating speed of 1700 revs/min;
(4) preparation of coated gloss oil:
After 900 parts of organosilicon crylic acid latex RS-3788A are ready to, add 48 parts of alcohol esters, 12,2 parts of NXZ defoamers, 2 parts of BIT series bactericidal agents successively, after stirring under the rotating speed of 300 revs/min, coated gloss oil can be obtained;
(5) granulation synthesis:
Granulation is cut after base paint 350 parts prepared by the protection liquid 350 parts step (1) prepared and step (3) mixes under the rotating speed of 800 revs/min; Poured into coated gloss oil 450 parts prepared by step (4), under the rotating speed of 150 revs/min, mixing can obtain this water-soluble colorful coating again.
Described color filters is the mixture of the 1:1 of rutile titanium white powder and coarse whiting.Described emulsion is pure third RS-6733A.Described painted mill base is the 1:1 mixture of UTI iron oxide red and UTI iron oxide yellow.The use number of described each raw material is parts by weight.

Claims (5)

1. a water-soluble colorful coating, is characterized in that its preparation method is as follows:
(1) preparation of liquid aqueous solution is protected:
90 ~ 97.5 parts of deionized waters are added reactor, under the rotating speed of 500 revs/min, 5 ~ 8.5 parts of modified alta-mud powder are dropped into reactor, then dispersed with stirring under the rotating speed of 1500 revs/min, until mixture becomes transparent in particle solution, can obtain protecting liquid aqueous solution;
(2) preparation of auxiliary agent 1: 15 ~ 20 parts of propylene glycol, 5 ~ 8 parts of dispersion agent SN-5040,3 ~ 4 parts of NXZ defoamers are mixed; The preparation of auxiliary agent 2: 9 ~ 13 parts of alcohol esters, 12,4 ~ 6 parts of BIT series bactericidal agents, 1 ~ 2 part of AMP-95,2 ~ 3 parts of silicone-based defoamers SN-345 are mixed;
(3) preparation of base paint:
4 ~ 12 parts of Natrosol Pluss are added in 350 ~ 450 parts of deionized waters, disperse 10 minutes under the rotating speed of 2500 revs/min, then add 23 ~ 32 parts of auxiliary agents 1 and mix;
Then 180 ~ 205 parts of color filters are dropped into, disperse 20 ~ 30 minutes under the rotating speed of 2500 revs/min, make the grain diameter of mixture below 60 microns;
Then 200 ~ 350 parts of emulsions are added, and be uniformly mixed, 8 ~ 11 parts of auxiliary agents 2 are added, then stir under the rotating speed of 300 ~ 800 revs/min, make the PH of mixture be 8 ~ 9;
Then protection liquid aqueous solution 50 ~ 60 parts input prepared by step (1), disperse under the rotating speed of 1500 ~ 2000 revs/min after 15 ~ 20 minutes, then by painted mill base 0 ~ 30 part input, stir under the rotating speed of 500 ~ 800 revs/min and can obtain base paint;
(4) preparation of coated gloss oil:
After 850 ~ 1000 parts of organosilicon crylic acid latex RS-3788A are ready to, add 45 ~ 50 parts of alcohol esters, 12,1 ~ 3 part of NXZ defoamer, 2 ~ 3 parts of BIT series bactericidal agents successively, after stirring under the rotating speed of 200 ~ 500 revs/min, coated gloss oil can be obtained;
(5) granulation synthesis:
Granulation is cut after base paint 300 ~ 400 parts prepared by the protection liquid 300 ~ 400 parts step (1) prepared and step (3) mixes under the rotating speed of 200 ~ 1200 revs/min; Poured into coated gloss oil 400 ~ 480 parts prepared by step (4), under the rotating speed of 100 ~ 300 revs/min, mixing can obtain this water-soluble colorful coating again.
2. water-soluble colorful coating according to claim 1, it is characterized in that described color filters be calcined kaolin, rutile titanium white powder, coarse whiting, superfine alumina silicate powder one or more.
3. water-soluble colorful coating according to claim 1, is characterized in that described emulsion is the one in pure third RS-6733A or organosilicon crylic acid latex RS-3788A.
4. water-soluble colorful coating according to claim 1, is characterized in that described painted mill base is one or more in UTI iron oxide red, UTI iron oxide yellow, UTI iron oxide black.
5. water-soluble colorful coating according to claim 1, is characterized in that the use number of described each raw material is parts by weight.
CN201410143997.6A 2014-04-11 2014-04-11 Aqueous colorful paint Pending CN104974620A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410143997.6A CN104974620A (en) 2014-04-11 2014-04-11 Aqueous colorful paint

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Application Number Priority Date Filing Date Title
CN201410143997.6A CN104974620A (en) 2014-04-11 2014-04-11 Aqueous colorful paint

Publications (1)

Publication Number Publication Date
CN104974620A true CN104974620A (en) 2015-10-14

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106833218A (en) * 2016-12-09 2017-06-13 泉州市长兴化工材料有限公司 A kind of 2D planes stone similar paint and preparation method thereof
CN107163700A (en) * 2017-04-07 2017-09-15 河北晨阳工贸集团有限公司 Sealing wax of imitative wallpaper effect and preparation method thereof
CN111807784A (en) * 2020-07-17 2020-10-23 江苏爱富希新型建材股份有限公司 A kind of imitation granite fiber cement board and its preparation method and application

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1124266A (en) * 1994-12-07 1996-06-12 湖南天海林实业股份有限公司 Multi-colour paint
CN102660181A (en) * 2012-05-08 2012-09-12 上海大学 Water-in-water imitation granite multicolor coating and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1124266A (en) * 1994-12-07 1996-06-12 湖南天海林实业股份有限公司 Multi-colour paint
CN102660181A (en) * 2012-05-08 2012-09-12 上海大学 Water-in-water imitation granite multicolor coating and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106833218A (en) * 2016-12-09 2017-06-13 泉州市长兴化工材料有限公司 A kind of 2D planes stone similar paint and preparation method thereof
CN107163700A (en) * 2017-04-07 2017-09-15 河北晨阳工贸集团有限公司 Sealing wax of imitative wallpaper effect and preparation method thereof
CN111807784A (en) * 2020-07-17 2020-10-23 江苏爱富希新型建材股份有限公司 A kind of imitation granite fiber cement board and its preparation method and application

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Application publication date: 20151014