CN104961244B - A kind of processing method of L arginine fermented waste fluid - Google Patents
A kind of processing method of L arginine fermented waste fluid Download PDFInfo
- Publication number
- CN104961244B CN104961244B CN201510380652.7A CN201510380652A CN104961244B CN 104961244 B CN104961244 B CN 104961244B CN 201510380652 A CN201510380652 A CN 201510380652A CN 104961244 B CN104961244 B CN 104961244B
- Authority
- CN
- China
- Prior art keywords
- liquid
- arginine
- waste fluid
- chitin
- microorganism formulation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
- Micro-Organisms Or Cultivation Processes Thereof (AREA)
- Immobilizing And Processing Of Enzymes And Microorganisms (AREA)
Abstract
The invention belongs to Amino Acid Fermentation Wastewater processing technology field, disclose a kind of processing method of L arginine fermented waste fluid, it comprises the steps：Step 1）Prepare microbe carrier, step 2）Prepare microorganism formulation, step 3）Microbial treatments.The method simple possible that the present invention disposes waste liquid, effect is good, with low cost, is easily accepted by enterprise.
Description
Technical field
The invention belongs to Amino Acid Fermentation Wastewater processing technology field is and in particular to a kind of place of L-Arginine fermented waste fluid
Reason method.
Background technology
Arginine（Arginine, Arg）Chemical scientific name：(S)-2-Amino-5-guanidinopentanoic acid, is a kind of aliphatic alkalescence
Polarity alpha amino acid containing guanidine radicals, positively charged in physiological conditions；L-Arginine is the coding amino in protein synthesis
Acid.For mammal, arginine is classified as the half necessary or necessary aminoacid of conditionality, depend on biology stage of development and
Depending on health status, natural product are present in protamine in a large number, also for the basic composition of various protein.
L-Arginine is described as " magical molecule " by scientist, and it is one of basic amino acid, for healthy adult,
For nonessential amino acid, but arginine is to maintain the requisite aminoacid of infant growth；In ornithine cycle
Between metabolite, ammonia can be promoted to be transformed into carbamide, thus reducing Blood Ammonia Concentration, when body development is not yet ripe or body stress bar
Under part, such as lack arginine, body just can not complete physiological function；Patient lacks arginine and blood ammonia can be caused too high or even confused
Fan, baby lacks arginine and is then unable to normal development and growth.Admit the doctor of L-Arginine from Nobel Prize in medicine in 1998
After learning effect, L-Arginine causes the mad interest in medical drug field, and Columbia Univ USA was once likened to the heart
" the magical bullet " of vascular system；The discovery of L-Arginine makes heart disease, immunologic function, obesity, gene growth shortage, high blood
The treatment of symptom that pressure, sexuality go down and the mankind are aging etc. obtains very big improvement.
With the fast development of aminoacid industry in recent years, the demand of aminoacid is surged, it is maximum that China has become the whole world
Amino acids production state.In amino acids production, contain higher ammonia nitrogen due in the high-concentration waste water of flushing membrane worry equipment, such as
What denitrogenation is its key problem, to the process of this waste water currently without preferable method.Chinese patent CN104222704A and
CN104261947A is prepared for feedstuff and fertilizer etc. with fermentation waste water respectively, and said method design is unique, is suitable for possessing fertilizer
Or the enterprise of Feed Manufacturing qualification and ability.
Traditional denitrification process usually by anoxic zone and aerobic distinguish, such as Prepositive denitrification, rear-mounted denitrification, A/O method,
A2O method, SBR etc., but because nitrobacteria growth speed is slower, limit the raising of nitric efficiency, bacteria adhension poor reliability
And carbon source fails the shortcomings of not enough to promote during denitrification.Meanwhile, the process of nitrification and denitrification also more difficult control, and traditional
Technique also exist that capital expenditure is big, operating cost is high, a series of drawback such as energy dissipation and emission greenhouse gas.But good
The progress of oxygen denitrifying bacterium, the discovery of nitrification bacteria and aerobic denitrification, heterotrophic nitrification and autotrophic denitrification is simultaneously
Nitrification and denitrification has established theoretical basiss.Orientation structure can carry out biochemistry/nitrification/denitrification in same reaction unit simultaneously
The high effective microbial community of effect, adapts to fermentation high concentration including screening and enrichment and produces waste water, has the spy of degraded advantage
Effect aerobic denitrifying bacteria, reaches the microcirculation of forming material mutually utilization between whole microorganism fungus kind, allows COD as life
In change/nitrification/anti-nitration reaction must being utilized of carbon source, improve the biological efficiency of sewage disposal comprehensively.Therefore in aerobic bar
Carry out simultaneous nitrification-denitrification under part（SND）Technology become current biological denitrificaion and open new technology.
Biotechnology processes fermentation waste water, and it possesses with low cost, the advantages of do not result in secondary pollution, but exists micro-
Biocompatibility is unreasonable, and treatment effeciency is low, and microbe carrier to there is internal mass transfer poor, be difficult printing opacity, specific surface area is little,
The defect such as service life is short；Biological preparation needs to throw in often, increased cost, and injected volume is big, the mud of generation
Amount is greatly it is not easy to process.
Content of the invention
The purpose of the present invention is the deficiency for traditional handicraft, there is provided a kind of process side of L-Arginine fermented waste fluid
Method, the method treatment effect is good, and long service life is with low cost, alleviates business burden, bring huge economic benefit and
Environmental benefit.In order to realize the object of the invention, adopt the following technical scheme that：
In order to realize the object of the invention, the present invention is achieved by the following technical solutions：
A kind of processing method of L-Arginine fermented waste fluid, it comprises the steps：
Step 1）Prepare microbe carrier, step 2）Prepare microorganism formulation, step 3）Microbial treatments.
Specifically, comprise the steps：
Step 1）Prepare microbe carrier：
（1）Weigh following each raw material for standby according to weight portion, wherein, water 20-30 part, brown coal 10-12 part, Kaolin 8-10
Part, zeolite powder 3-5 part, chitin 2-3 part, silica white 1-2 part；Preferably, the particle diameter of zeolite powder and silica white is 200 mesh,
The particle diameter of chitin is 50 mesh；
（2）Brown coal are crushed with disintegrating machine, then add Kaolin, mix homogeneously, be ground to the powder of 100 mesh,
It is material 1；
（3）Add the 1M calcium chloride solution of identical weight in zeolite powder, stir, then 350 DEG C of roastings 3 hours,
Obtain material 2；
（4）By water, material 1, material 2, chitin and silica white are added in stirred reactor successively, 500 turns/min
Stirring 10min, stands 30min, then 200 turns/min stirring 3min, and being finally placed in 60 DEG C and drying to moisture is 5%（Weight
Amount number）, obtain final product microbe carrier；
Step 2）Prepare microorganism formulation：
By bacillus subtilises, it is 1 × 10 that Acinetobacter bauamnnii and Sphingomonas are cultivated respectively to concentration7Individual/
The bacterium solution of ml, it is 1 × 10 that scenedesmus obliquus is cultivated to concentration5The algae solution of individual/ml, by the bacillus subtilis bacterium solution of above-mentioned culture,
Acinetobacter bauamnnii liquid, Sphingomonas liquid and scenedesmus obliquus liquid are according to 5：3：2：1 volume ratio mixing, stands 6 hours,
Obtain mixing liquid；By mixing liquid and step 1）The microbe carrier of preparation is according to 1：2 quality is than mixing and stirring, room
Temperature fermentation 24-36h, being dried to water content is 10%（Parts by weight）, obtain final product.
Step 3）Microbial treatments：
The pH adjusting L-Arginine fermented waste fluid is 7-7.5, then according to 5g microorganism formulation：The adding of 1 cubic metre of waste liquid
Dosage adds microorganism formulation, then stands six days, discharges.
Strain of the present invention and algae all can be commercially available from commercial sources such as collections.
Strain of the present invention and algae all can obtain bacterium solution or the algae solution of desired concn by conventional cultural method,
The innovative point of this and non-invention, as space is limited, does not repeat one by one.
The beneficial effect that the present invention obtains mainly includes：
The present invention processes the method simple possible of fermentation waste water, with low cost, high treating effect；
The carrier that the present invention provides, using the raw material of different-grain diameter, can not only expand the specific surface area of carrier, and have
Have that tensile strength is big, be evenly distributed, specific surface area big, the features such as long service life；
The carrier that the present invention provides can greatly improve the adhesion amount of microorganism, increases the biofilm biomass of overall attachment, instead
Answer the microorganism concn in groove to be improved, and mud yield can be reduced；
The presence of anaerobism, anoxia and aerobic various environment that the carrier that the present invention provides provides can promote to nitrify anti-nitre
Change effect, simultaneously facilitate the minimizing of mud, be conducive to the removal of the pollutant such as ammonia nitrogen in waste liquid；
The biological preparation of the present invention, by the various strains that can form dominant microflora and algae, is configured to high-performance bio preparation,
Reasonable compatibility between each microorganism, symbiosis is coordinated, mutually not antagonism, and Biomass is big, and breeding is fast.
Biological preparation of the present invention is suitable to Wastewater treating, is readily transported and preserves, and is easier to activate, runs into during use
This is cheap.
Specific embodiment
In order that those skilled in the art more fully understand the technical scheme in the application, below in conjunction with the application tool
Body embodiment, is clearly and completely described to the technical scheme of the application it is clear that described embodiment is only this Shen
Please a part of embodiment, rather than whole embodiment.Based on the embodiment in the application, those of ordinary skill in the art are not having
There is the every other embodiment being obtained under the premise of making creative work, all should belong to the scope of protection of the invention.
Embodiment 1
A kind of processing method of L-Arginine fermented waste fluid, it comprises the steps：
Step 1）Prepare microbe carrier, step 2）Prepare microorganism formulation, step 3）Microbial treatments.
Specifically, comprise the steps：
Step 1）Prepare microbe carrier：
（1）Weigh following each raw material for standby according to weight portion, wherein, 20 parts of water, 10 parts of brown coal, 8 parts of Kaolin, zeolite powder
3 parts, 2 parts of chitin, 1 part of silica white；Wherein, the particle diameter of zeolite powder and silica white is 200 mesh, and the particle diameter of chitin is 50
Mesh；
（2）Brown coal are crushed with disintegrating machine, then add Kaolin, mix homogeneously, be ground to the powder of 100 mesh,
It is material 1；
（3）Add the 1M calcium chloride solution of identical weight in zeolite powder, stir, then 350 DEG C of roastings 3 hours,
Obtain material 2；
（4）By water, material 1, material 2, chitin and silica white are added in stirred reactor successively, 500 turns/min
Stirring 10min, stands 30min, then 200 turns/min stirring 3min, and being finally placed in 60 DEG C and drying to moisture is 5%（Weight
Amount number）, obtain final product microbe carrier；
Step 2）Prepare microorganism formulation：
By bacillus subtilises, it is 1 × 10 that Acinetobacter bauamnnii and Sphingomonas are cultivated respectively to concentration7Individual/
The bacterium solution of ml, it is 1 × 10 that scenedesmus obliquus is cultivated to concentration5The algae solution of individual/ml, by the bacillus subtilis bacterium solution of above-mentioned culture,
Acinetobacter bauamnnii liquid, Sphingomonas liquid and scenedesmus obliquus liquid are according to 5：3：2：1 volume ratio mixing, stands 6 hours,
Obtain mixing liquid；By mixing liquid and step 1）The microbe carrier of preparation is according to 1：2 quality is than mixing and stirring, room
Temperature fermentation 36h, being dried to water content is 10%（Parts by weight）, obtain final product.
Step 3）Microbial treatments：
The pH adjusting L-Arginine fermented waste fluid is 7.5, then according to 5g microorganism formulation：The interpolation of 1 cubic metre of waste liquid
Amount adds microorganism formulation, then stands six days, discharges.
Embodiment 2
A kind of processing method of L-Arginine fermented waste fluid, it comprises the steps：
Step 1）Prepare microbe carrier, step 2）Prepare microorganism formulation, step 3）Microbial treatments.
Specifically, comprise the steps：
Step 1）Prepare microbe carrier：
（1）Weigh following each raw material for standby according to weight portion, wherein, 30 parts of water, 12 parts of brown coal, 10 parts of Kaolin, zeolite
5 parts of powder, 3 parts of chitin, 2 parts of silica white；Wherein, the particle diameter of zeolite powder and silica white is 200 mesh, and the particle diameter of chitin is 50
Mesh；
（2）Brown coal are crushed with disintegrating machine, then add Kaolin, mix homogeneously, be ground to the powder of 100 mesh,
It is material 1；
（3）Add the 1M calcium chloride solution of identical weight in zeolite powder, stir, then 350 DEG C of roastings 3 hours,
Obtain material 2；
（4）By water, material 1, material 2, chitin and silica white are added in stirred reactor successively, 500 turns/min
Stirring 10min, stands 30min, then 200 turns/min stirring 3min, and being finally placed in 60 DEG C and drying to moisture is 5%（Weight
Amount number）, obtain final product microbe carrier；
Step 2）Prepare microorganism formulation：
By bacillus subtilises, it is 1 × 10 that Acinetobacter bauamnnii and Sphingomonas are cultivated respectively to concentration7Individual/
The bacterium solution of ml, it is 1 × 10 that scenedesmus obliquus is cultivated to concentration5The algae solution of individual/ml, by the bacillus subtilis bacterium solution of above-mentioned culture,
Acinetobacter bauamnnii liquid, Sphingomonas liquid and scenedesmus obliquus liquid are according to 5：3：2：1 volume ratio mixing, stands 6 hours,
Obtain mixing liquid；By mixing liquid and step 1）The microbe carrier of preparation is according to 1：2 quality is than mixing and stirring, room
Temperature fermentation 24h, being dried to water content is 10%（Parts by weight）, obtain final product.
Step 3）Microbial treatments：
The pH adjusting L-Arginine fermented waste fluid is 7, then according to 5g microorganism formulation：The addition of 1 cubic metre of waste liquid
Add microorganism formulation, then stand six days, discharge.
Wherein, bacillus subtilises are（Bacillus subtilis）CGMCC NO：2947 (can be found in
CN101838621A), Acinetobacter bauamnnii is ATCC 19606 for (Acinetobacter baumanii)（Can be found in
Infect Immun. 2012 Mar;80(3):1015-24）, Sphingomonas are（Sphingomonas sp.）CGMCC
NO.4589（Can be found in CN102168054A）, scenedesmus obliquus is（Scenedesmus obliquus）CGMCC No.8015（Can
Referring to CN103484374A）.
Embodiment 3
Effect test of the present invention：
Tested with the fermented waste fluid removing the materials such as fermentation thalli, albumen and polysaccharide for processing sample.
Matched group 1：Using diatomite support；Microorganism type is identical with test group；Processing mode：Continuously add three days
Afterwards, daily 5g/ cubic meter, then stand six days, detection process the results are shown in Table 1.
Matched group 2：Carrier is same as Example 2, is a difference in that, only adds three kinds of bacterium, without scenedesmus obliquus；Process
Mode：Add 5g/ cubic meter within first day, then stand six days, detection process the results are shown in Table 1.
Test group：The microorganism formulation of the embodiment of the present invention 2 preparation；Processing mode：After adding one day, 5g/ cubic meter, then
Standing six days, detection process the results are shown in Table 1.
Table 1
| Before processing（mg/L） | After process（Matched group 1）（mg/L） | After process（Matched group 2）（mg/L） | After process（Test group）（mg/L） | |
| COD | 1517 | 17.9 | 52.2 | 5.9 |
| NH3-N | 223 | 15.4 | 17.3 | 2.1 |
| Sulfide | 27.4 | 5.9 | 3.1 | 1.3 |
| P2O5 | 12.8 | 2.3 | 3.7 | 0.6 |
| Chloride ion | 26.9 | 4.3 | 5.6 | 0.4 |
Conclusion：The microbe carrier rough surface of present invention preparation, specific surface area is big, and microorganism adhesion effect is good, and
Put into number of times and weight all reduces, long service life, need not repeatedly throw in, save cost, reduce the yield of mud.This
Mushroom and algae reasonable compatibility in invention microorganism formulation, can remove each pollutant in fermented waste fluid, completely effectively
Reach discharge standard.The method simple possible that the present invention disposes waste liquid, effect is good, with low cost, is easily accepted by enterprise.
Although, above with general explanation and specific embodiment, this case has been made with detailed explanation, at this
On the basis of invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art.Therefore,
The modification made without departing from theon the basis of the spirit of the present invention or improvement, belong to the scope of protection of present invention.
Claims (3)
1. a kind of processing method of L-Arginine fermented waste fluid is it is characterised in that methods described comprises the steps：
Step 1）Prepare microbe carrier：
（1）Weigh following each raw material for standby according to weight portion, wherein, water 20-30 part, brown coal 10-12 part, Kaolin 8-10 part,
Zeolite powder 3-5 part, chitin 2-3 part, silica white 1-2 part；
（2）Brown coal are crushed with disintegrating machine, then adds Kaolin, mix homogeneously, be ground to the powder of 100 mesh, as
Material 1；
（3）Add the 1M calcium chloride solution of identical weight in zeolite powder, stir, then 350 DEG C of roastings 3 hours, obtain
Material 2；
（4）By water, material 1, material 2, chitin and silica white are added in stirred reactor successively, and 500 turns/min stirs
10min, stands 30min, then 200 turns/min stirring 3min, and being finally placed in 60 DEG C and drying to moisture is 5%, obtains final product micro-
Bio-carrier；
Step 2）Prepare microorganism formulation：
By bacillus subtilises, it is 1 × 10 that Acinetobacter bauamnnii and Sphingomonas are cultivated respectively to concentration7The bacterium of individual/ml
Liquid, it is 1 × 10 that scenedesmus obliquus is cultivated to concentration5The algae solution of individual/ml, by the bacillus subtilis bacterium solution of above-mentioned culture, Bao Man not
Lever bacterium solution, Sphingomonas liquid and scenedesmus obliquus liquid are according to 5：3：2：1 volume ratio mixing, stands 6 hours, is mixed
Close liquid；By mixing liquid and step 1）The microbe carrier of preparation is according to 1：2 quality is fermented than mixing and stirring, room temperature
24-36h, being dried to water content is 10%, obtains final product；
Step 3）Microbial treatments：
The pH adjusting L-Arginine fermented waste fluid is 7-7.5, then according to 5g microorganism formulation：The addition of 1 cubic metre of waste liquid
Add microorganism formulation, then stand six days, discharge.
2. method according to claim 1 is it is characterised in that the particle diameter of described zeolite powder and silica white is 200 mesh, institute
The particle diameter stating chitin is 50 mesh.
3. method according to claim 1 is it is characterised in that described bacillus subtilises（Bacillus subtilis）
For CGMCC NO：2947, described Acinetobacter bauamnnii (Acinetobacter baumanii) is ATCC 19606, described sheath
Ammonia alcohol sporangium（Sphingomonas sp.）For CGMCC NO.4589, described scenedesmus obliquus（Scenedesmus
obliquus）For CGMCC No.8015.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510380652.7A CN104961244B (en) | 2015-07-02 | 2015-07-02 | A kind of processing method of L arginine fermented waste fluid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510380652.7A CN104961244B (en) | 2015-07-02 | 2015-07-02 | A kind of processing method of L arginine fermented waste fluid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104961244A CN104961244A (en) | 2015-10-07 |
| CN104961244B true CN104961244B (en) | 2017-03-01 |
Family
ID=54215374
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510380652.7A Active CN104961244B (en) | 2015-07-02 | 2015-07-02 | A kind of processing method of L arginine fermented waste fluid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104961244B (en) |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004028982A1 (en) * | 2002-09-27 | 2004-04-08 | Shanghai Gi Biotechnology Engineering Co., Ltd. | A method for treating wastewater |
| JP4516025B2 (en) * | 2003-11-21 | 2010-08-04 | 荏原エンジニアリングサービス株式会社 | Method and apparatus for producing / recovering magnesium ammonium phosphate |
| CN101428930B (en) * | 2008-12-09 | 2010-08-25 | 中南大学 | Treatment process for hydrargyrum-containing flue gas washing wastewater from nonferrous metal smelting with biological agent |
| CN102703420A (en) * | 2010-11-29 | 2012-10-03 | 王祥红 | Microbial degradation preparation for municipal garbage and sewage and preparation method thereof |
| CN104230004B (en) * | 2014-10-16 | 2015-10-14 | 内蒙古阜丰生物科技有限公司 | A kind of biotechnological formulation processing glutamic acid fermentation waste water |
-
2015
- 2015-07-02 CN CN201510380652.7A patent/CN104961244B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN104961244A (en) | 2015-10-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110655198B (en) | Method for treating nitrogen-containing wastewater by using heterotrophic nitrification-aerobic denitrification paracoccus strain | |
| CN102616941A (en) | Sea cucumber micro-ecological water quality regulator and preparation method thereof | |
| CN103205382A (en) | Microbial agent for purifying river wastewater and preparation method of microbial agent | |
| CN110656057B (en) | Heterotrophic nitrification-aerobic denitrification paracoccus strain, seed liquid, preparation method and application thereof | |
| CN105000674B (en) | Method used for processing environmental geology industrial wastewater via biotechnology | |
| CN106986454B (en) | Method for treating low-C/N-ratio micro-polluted eutrophic water body by synchronous nitrification and denitrification | |
| CN104891678B (en) | For administering the biologic product of the high-concentration waste water that amino acid fermentation produces | |
| CN110157639A (en) | Preparation method and application of a kind of high-salt-tolerant denitrifying bacteria and its bacterial agent | |
| CN105130013A (en) | Method of treating piggery methane fluid by utilizing composite photosynthetic bacteria | |
| CN106277366A (en) | A kind of pig-breeding wastewater treatment microbial microbial inoculum and preparation method and application | |
| CN110129224B (en) | A kind of salt-tolerant denitrifying bacteria and its preparation method and application | |
| CN1266269C (en) | Acinetobacter for denitrification and decomposing ammonia in wastewater | |
| CN107879774A (en) | A kind of preparation method of biological decomposing agent | |
| CN107164265A (en) | A kind of probiotics and preparation method thereof | |
| CN101701197B (en) | Novel microorganism flora mixture and mixed nutrient medium thereof | |
| CN104496031B (en) | Preparation method and application of a sewage treatment and aquatic plant planting matrix filler | |
| CN108342338B (en) | Method for treating pharmaceutical wastewater containing antibiotics | |
| CN101880645B (en) | Verdigris pseudomonas aeruginosa strain denitrified under different dissolved oxygen conditions and application thereof | |
| CN110511894A (en) | A kind of composite bacteria agent and its preparation and application | |
| CN110004075A (en) | A kind of denitrifying bacteria nutritional agents and its preparation method and application | |
| CN109942091A (en) | Bacteria and algae attached biofiber bed and preparation method thereof and method for strengthening denitrification and phosphorus removal of swine wastewater | |
| CN101029298A (en) | Production of efficient microbe bacteria combing agent | |
| CN105036330B (en) | Preparation method of crystalline L-arginine alpha-ketoglutarate (AAKG) | |
| CN104911132A (en) | Preparation method of composite biological agent for restoring threonine fermentation waste liquid | |
| CN112574921A (en) | Method for preparing aerobic denitrification composite microbial inoculum by utilizing kitchen waste and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A treatment method of L-arginine fermentation waste liquid Effective date of registration: 20211018 Granted publication date: 20170301 Pledgee: China Construction Bank Corporation Junan sub branch Pledgor: SHANDONG FUFENG FERMENTATION Co.,Ltd. Registration number: Y2021370000120 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20230414 Granted publication date: 20170301 Pledgee: China Construction Bank Corporation Junan sub branch Pledgor: SHANDONG FUFENG FERMENTATION CO.,LTD. Registration number: Y2021370000120 |