CN104893768A - Environment-friendly synthetic gasoline and preparation method thereof - Google Patents
Environment-friendly synthetic gasoline and preparation method thereof Download PDFInfo
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- CN104893768A CN104893768A CN201510292138.8A CN201510292138A CN104893768A CN 104893768 A CN104893768 A CN 104893768A CN 201510292138 A CN201510292138 A CN 201510292138A CN 104893768 A CN104893768 A CN 104893768A
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- parts
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- tween
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- 238000002360 preparation method Methods 0.000 title abstract description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 61
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000000654 additive Substances 0.000 claims abstract description 25
- 230000000996 additive effect Effects 0.000 claims abstract description 25
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims abstract description 25
- 229920000053 polysorbate 80 Polymers 0.000 claims abstract description 25
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract description 23
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 21
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 21
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000005642 Oleic acid Substances 0.000 claims abstract description 21
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 21
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 21
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000012964 benzotriazole Substances 0.000 claims abstract description 21
- JBTHDAVBDKKSRW-UHFFFAOYSA-N chembl1552233 Chemical compound CC1=CC(C)=CC=C1N=NC1=C(O)C=CC2=CC=CC=C12 JBTHDAVBDKKSRW-UHFFFAOYSA-N 0.000 claims abstract description 21
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 21
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 21
- 229940073450 sudan red Drugs 0.000 claims abstract description 21
- 238000006243 chemical reaction Methods 0.000 claims abstract description 13
- 238000003756 stirring Methods 0.000 claims description 36
- 229960004418 trolamine Drugs 0.000 claims description 20
- 239000000463 material Substances 0.000 claims description 11
- 229940093476 ethylene glycol Drugs 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- 229960002969 oleic acid Drugs 0.000 claims description 10
- 239000003208 petroleum Substances 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 claims description 2
- CRSOQBOWXPBRES-UHFFFAOYSA-N neopentane Chemical compound CC(C)(C)C CRSOQBOWXPBRES-UHFFFAOYSA-N 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 2
- 239000000446 fuel Substances 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 2
- ABDKAPXRBAPSQN-UHFFFAOYSA-N veratrole Chemical compound COC1=CC=CC=C1OC ABDKAPXRBAPSQN-UHFFFAOYSA-N 0.000 description 2
- 208000019901 Anxiety disease Diseases 0.000 description 1
- 230000036506 anxiety Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000003137 locomotive effect Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
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- Liquid Carbonaceous Fuels (AREA)
Abstract
The invention discloses environment-friendly synthetic gasoline and a preparation method thereof. The synthetic gasoline is synthesized from gasoline, pentane, naphtha and an additive. The formula of the synthetic gasoline comprises 15 parts of gasoline, 5 part of pentane, 3 parts of naphtha and 113 parts of the additive in proportion, wherein the additive is a product of a reaction among n-butyl alcohol, benzotriazole, Tween 80, oleic acid, triethanolamine, ethanediol and Sudan red. The emission of the environment-friendly synthetic gasoline is 3% lower than the emission of national standard gasoline and the effects of energy saving and emission reduction can be reached; raw materials used in the preparation method disclosed by the invention are low in price and therefore the cost of the environment-friendly gasoline is reduced greatly.
Description
Technical field
The invention belongs to synthol field, be specifically related to a kind of environment-friendly type synthetic gasoline and preparation method thereof.
Background technology
At present, along with the anxiety of petroleum resources, many synthols are produced one after another, but current synthol, as biogasoline there is complicated process of preparation, productive expense is high, fuel performance is unstable, atomizing effect is poor, thermo-efficiency is low, incomplete combustion, contaminate environment; Have corrosion to fuel passage, direct use can reduce the work-ing life of oil fuel pipe, increases use and maintenance cost.Need a kind of synthetic gasoline of environment-friendly type to meet the needs in market in the market.
Summary of the invention
The object of this invention is to provide a kind of environment-friendly type synthetic gasoline and preparation method thereof, this invention raw materials cost is low, and preparation method is simple, security good, and sufficient combustion efficiency is high, reduces the topsoil used.
A kind of environment-friendly type synthetic gasoline, it is characterized in that, described synthetic gasoline is synthesized by gasoline, pentane, petroleum naphtha and additive, proportioning in described formula is 15 parts, gasoline, pentane 5 parts, petroleum naphtha 3 parts, additive 113 parts, and described additive is reacted by propyl carbinol, benzotriazole, tween 80, oleic acid, trolamine, ethylene glycol and Sudan red and forms.
Wherein, the formula of described additive is propyl carbinol 53 parts, benzotriazole 13 parts, tween 80 15 parts, oleic acid 10 parts, trolamine 12 parts and ethylene glycol 10 parts, and described Sudan red is trace, and addition is that additive per ton only needs 1g.
Wherein, described pentane comprises
skellysolve A,
iso-pentanewith
neopentanein one or more.
A making method for environment-friendly type synthetic gasoline, is characterized in that, its making step is as follows:
1) proportionally require to take propyl carbinol, benzotriazole, tween 80, oleic acid, trolamine, ethylene glycol and Sudan red, and the material precision that propyl carbinol, benzotriazole, tween 80, oleic acid, trolamine, ethylene glycol and Sudan red adopt reaches 99.9%;
2) tween 80 of propyl carbinol, benzotriazole, oleic acid, ethylene glycol and half is put into irony reactor stirring reaction 10min;
3) tween 80 and the trolamine of remaining half will be added in the reactor in step 2, continue to stir 10min;
4) again add Sudan red in the reactor in step 3), stir 40min, material is fully mixed;
5) improve stirring velocity, stir 6 hours, after question response is complete, obtain additive;
6) in additive reaction still, add pentane and gasoline, fully stir 30-40min;
7) to be mixed fully after, add naphtha, stirring reaction 30-60min;
8) react after in 120min and add water, form water sample state, namely obtain environment-friendly type synthetic gasoline.
Wherein, 15 parts, described gasoline, pentane 5 parts, petroleum naphtha 3 parts, propyl carbinol 53 parts, benzotriazole 13 parts, tween 80 15 parts, oleic acid 10 parts, trolamine 12 parts and ethylene glycol 10 parts, described Sudan red is trace, and addition is that additive per ton only needs 1g.
Wherein, the stirring velocity in described step 6) is that 5000-7000 turns/min.
Wherein, the described stirring velocity except step 6) is that 2000-4000 turns/min.
Compared with prior art, the present invention has following beneficial effect:
(1) environment protection gasoline provided by the invention, flash-point is-50--20 degrees Celsius, and burning-point improves 4-7 DEG C than flash-point, so enhance the power of locomotive.
(2) environment protection gasoline discharge of the present invention is lower than 3 percentage points, GB gasoline, can reach the effect of energy-saving and emission-reduction.
(3) making method provided by the invention is simply effective, quick and convenient, pollution-free.
(4) prices of raw and semifnished materials of making method provided by the invention are cheap, the cost of this environment protection gasoline is obtained and significantly reduces.
Embodiment
Below in conjunction with embodiment, the present invention is described further:
Embodiment 1
A making method for environment-friendly type synthetic gasoline, is characterized in that, its making step is as follows:
1) proportionally require to take propyl carbinol, benzotriazole, tween 80, oleic acid, trolamine, ethylene glycol and Sudan red, and the material precision that propyl carbinol, benzotriazole, tween 80, oleic acid, trolamine, ethylene glycol and Sudan red adopt reaches 99.9%;
2) tween 80 of propyl carbinol, benzotriazole, oleic acid, ethylene glycol and half is put into irony reactor stirring reaction 10min;
3) tween 80 and the trolamine of remaining half will be added in the reactor in step 2, continue to stir 10min;
4) again add Sudan red in the reactor in step 3), stir 40min, material is fully mixed;
5) improve stirring velocity, stir 6 hours, after question response is complete, obtain additive;
6) in additive reaction still, add pentane and gasoline, fully stir 30;
7) to be mixed fully after, add naphtha, stirring reaction 30;
8) react after in 120min and add water, form water sample state, namely obtain environment-friendly type synthetic gasoline.
Wherein, 15 parts, described gasoline, pentane 5 parts, petroleum naphtha 3 parts, propyl carbinol 53 parts, benzotriazole 13 parts, tween 80 15 parts, oleic acid 10 parts, trolamine 12 parts and ethylene glycol 10 parts, described Sudan red is trace, and addition is that additive per ton only needs 1g.
Wherein, the stirring velocity in described step 6) is 50000 turns/min.
Wherein, the described stirring velocity except step 6) is 2000 turns/min.
Preparation method's material price of the present invention is low, the environment protection gasoline of preparation is relative to regular gasoline, cheap, discharge is lower than 2.5 percentage points, GB gasoline, reach certain environment protecting, meanwhile, flash-point is subzero 50 DEG C, burning-point is higher than flash-point 4 DEG C, and the power of motor vehicle obtains raising to a certain extent.
Embodiment 2
A making method for environment-friendly type synthetic gasoline, is characterized in that, its making step is as follows:
1) proportionally require to take propyl carbinol, benzotriazole, tween 80, oleic acid, trolamine, ethylene glycol and Sudan red, and the material precision that propyl carbinol, benzotriazole, tween 80, oleic acid, trolamine, ethylene glycol and Sudan red adopt reaches 99.9%;
2) tween 80 of propyl carbinol, benzotriazole, oleic acid, ethylene glycol and half is put into irony reactor stirring reaction 10min;
3) tween 80 and the trolamine of remaining half will be added in the reactor in step 2, continue to stir 10min;
4) again add Sudan red in the reactor in step 3), stir 40min, material is fully mixed;
5) improve stirring velocity, stir 6 hours, after question response is complete, obtain additive;
6) in additive reaction still, add pentane and gasoline, fully stir 40min;
7) to be mixed fully after, add naphtha, stirring reaction 60min;
8) react after in 120min and add water, form water sample state, namely obtain environment-friendly type synthetic gasoline.
Wherein, 15 parts, described gasoline, pentane 5 parts, petroleum naphtha 3 parts, propyl carbinol 53 parts, benzotriazole 13 parts, tween 80 15 parts, oleic acid 10 parts, trolamine 12 parts and ethylene glycol 10 parts, described Sudan red is trace, and addition is that additive per ton only needs 1g.
Wherein, the stirring velocity in described step 6) is 7000 turns/min.
Wherein, the described stirring velocity except step 6) is 4000 turns/min.
Preparation method's material price of the present invention is low, the environment protection gasoline of preparation is relative to regular gasoline, cheap, discharge is lower than 3 percentage points, GB gasoline, reach certain environment protecting, meanwhile, flash-point is subzero 20 DEG C, burning-point is higher than flash-point 7 DEG C, and the power of motor vehicle obtains raising to a certain extent.
The foregoing is only one embodiment of the invention, do not limit the present invention, the technical scheme that the mode that all employings are equal to replacement or equivalent transformation obtains, all drop in protection scope of the present invention.
Claims (7)
1. an environment-friendly type synthetic gasoline, it is characterized in that, described synthetic gasoline is synthesized by gasoline, pentane, petroleum naphtha and additive, proportioning in described formula is 15 parts, gasoline, pentane 5 parts, petroleum naphtha 3 parts, additive 113 parts, and described additive is reacted by propyl carbinol, benzotriazole, tween 80, oleic acid, trolamine, ethylene glycol and Sudan red and forms.
2. a kind of environment-friendly type synthetic gasoline according to claims 1, it is characterized in that, the formula of described additive is propyl carbinol 53 parts, benzotriazole 13 parts, tween 80 15 parts, oleic acid 10 parts, trolamine 12 parts and ethylene glycol 10 parts, described Sudan red is trace, and addition is that additive per ton only needs 1g.
3. a kind of environment-friendly type synthetic gasoline according to claims 1, it is characterized in that, described pentane comprises
skellysolve A,
iso-pentanewith
neopentanein one or more.
4. a making method for environment-friendly type synthetic gasoline, is characterized in that, its making step is as follows:
1) proportionally require to take propyl carbinol, benzotriazole, tween 80, oleic acid, trolamine, ethylene glycol and Sudan red, and the material precision that propyl carbinol, benzotriazole, tween 80, oleic acid, trolamine, ethylene glycol and Sudan red adopt reaches 99.9%;
2) tween 80 of propyl carbinol, benzotriazole, oleic acid, ethylene glycol and half is put into irony reactor stirring reaction 10min;
3) tween 80 and the trolamine of remaining half will be added in the reactor in step 2, continue to stir 10min;
4) again add Sudan red in the reactor in step 3), stir 40min, material is fully mixed;
5) improve stirring velocity, stir 6 hours, after question response is complete, obtain additive;
6) in additive reaction still, add pentane and gasoline, fully stir 30-40min;
7) to be mixed fully after, add naphtha, stirring reaction 30-60min;
8) react after in 120min and add water, form water sample state, namely obtain environment-friendly type synthetic gasoline.
5. the making method of a kind of environment-friendly type synthetic gasoline according to claims 4, it is characterized in that, 15 parts, described gasoline, pentane 5 parts, petroleum naphtha 3 parts, propyl carbinol 53 parts, benzotriazole 13 parts, tween 80 15 parts, oleic acid 10 parts, trolamine 12 parts and ethylene glycol 10 parts, described Sudan red is trace, and addition is that additive per ton only needs 1g.
6. the making method of a kind of environment-friendly type synthetic gasoline according to claims 4, is characterized in that, the stirring velocity in described step 6) is that 5000-7000 turns/min.
7. the making method of a kind of environment-friendly type synthetic gasoline according to claims 4, is characterized in that, the described stirring velocity except step 6) is that 2000-4000 turns/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510292138.8A CN104893768A (en) | 2015-06-02 | 2015-06-02 | Environment-friendly synthetic gasoline and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510292138.8A CN104893768A (en) | 2015-06-02 | 2015-06-02 | Environment-friendly synthetic gasoline and preparation method thereof |
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| CN104893768A true CN104893768A (en) | 2015-09-09 |
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| CN201510292138.8A Pending CN104893768A (en) | 2015-06-02 | 2015-06-02 | Environment-friendly synthetic gasoline and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108384591A (en) * | 2018-03-28 | 2018-08-10 | 何杰 | A kind of alcohol-ether fuel synthetic additive and preparation method thereof |
| EP3768807A1 (en) * | 2018-03-23 | 2021-01-27 | Chevron Oronite Company LLC | Composition and method for preventing or reducing low speed pre-ignition in spark-ignited internal combustion engines |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1789388A (en) * | 2004-12-14 | 2006-06-21 | 上海中油企业集团有限公司 | Gasoline addictive composition |
| CN101671584A (en) * | 2009-09-21 | 2010-03-17 | 皮洪波 | Fuel oil additive and preparation method thereof |
| CN103987817A (en) * | 2011-09-23 | 2014-08-13 | 布特马斯先进生物燃料有限责任公司 | Isobutanol compositions for fuel blending and methods for the production thereof |
-
2015
- 2015-06-02 CN CN201510292138.8A patent/CN104893768A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1789388A (en) * | 2004-12-14 | 2006-06-21 | 上海中油企业集团有限公司 | Gasoline addictive composition |
| CN101671584A (en) * | 2009-09-21 | 2010-03-17 | 皮洪波 | Fuel oil additive and preparation method thereof |
| CN103987817A (en) * | 2011-09-23 | 2014-08-13 | 布特马斯先进生物燃料有限责任公司 | Isobutanol compositions for fuel blending and methods for the production thereof |
Non-Patent Citations (1)
| Title |
|---|
| 柳茂斌等: "正丁醇-汽油HCCI发动机燃烧特性", 《内燃机学报》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3768807A1 (en) * | 2018-03-23 | 2021-01-27 | Chevron Oronite Company LLC | Composition and method for preventing or reducing low speed pre-ignition in spark-ignited internal combustion engines |
| CN108384591A (en) * | 2018-03-28 | 2018-08-10 | 何杰 | A kind of alcohol-ether fuel synthetic additive and preparation method thereof |
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Application publication date: 20150909 |