CN104884597A - Laundry compositions - Google Patents
Laundry compositions Download PDFInfo
- Publication number
- CN104884597A CN104884597A CN201380060285.1A CN201380060285A CN104884597A CN 104884597 A CN104884597 A CN 104884597A CN 201380060285 A CN201380060285 A CN 201380060285A CN 104884597 A CN104884597 A CN 104884597A
- Authority
- CN
- China
- Prior art keywords
- composition
- silicone
- cationic
- acid
- preferred
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 76
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 37
- 239000003599 detergent Substances 0.000 claims abstract description 28
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 16
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229920006317 cationic polymer Polymers 0.000 claims description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 10
- 239000002736 nonionic surfactant Substances 0.000 abstract description 4
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 abstract 1
- 229960003237 betaine Drugs 0.000 abstract 1
- -1 polydimethylsiloxane Polymers 0.000 description 33
- 229920000642 polymer Polymers 0.000 description 31
- 239000000126 substance Substances 0.000 description 23
- 239000000975 dye Substances 0.000 description 20
- 125000002091 cationic group Chemical group 0.000 description 15
- 238000005406 washing Methods 0.000 description 14
- 150000001875 compounds Chemical class 0.000 description 13
- 239000000463 material Substances 0.000 description 13
- 229920001282 polysaccharide Polymers 0.000 description 13
- 239000005017 polysaccharide Substances 0.000 description 13
- 239000001913 cellulose Substances 0.000 description 12
- 229920002678 cellulose Polymers 0.000 description 12
- 239000004205 dimethyl polysiloxane Substances 0.000 description 12
- 239000000047 product Substances 0.000 description 12
- 150000002500 ions Chemical class 0.000 description 10
- 238000002360 preparation method Methods 0.000 description 10
- 150000004676 glycans Chemical class 0.000 description 9
- 239000000178 monomer Substances 0.000 description 9
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 8
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 8
- 108090000790 Enzymes Proteins 0.000 description 7
- 102000004190 Enzymes Human genes 0.000 description 7
- 229920000289 Polyquaternium Chemical group 0.000 description 7
- 239000013543 active substance Substances 0.000 description 7
- 125000000217 alkyl group Chemical group 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 7
- 229940088598 enzyme Drugs 0.000 description 7
- 239000004744 fabric Substances 0.000 description 7
- 238000009472 formulation Methods 0.000 description 7
- 239000002304 perfume Substances 0.000 description 7
- 239000002689 soil Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 229920002125 Sokalan® Polymers 0.000 description 6
- 150000001412 amines Chemical group 0.000 description 6
- 239000002585 base Substances 0.000 description 6
- 229920001519 homopolymer Polymers 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 238000012546 transfer Methods 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
- 229920002907 Guar gum Polymers 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 239000000665 guar gum Substances 0.000 description 5
- 235000010417 guar gum Nutrition 0.000 description 5
- 229960002154 guar gum Drugs 0.000 description 5
- 239000011159 matrix material Substances 0.000 description 5
- 150000004804 polysaccharides Polymers 0.000 description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- 239000002537 cosmetic Substances 0.000 description 4
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- 229920000550 glycopolymer Polymers 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 238000004987 plasma desorption mass spectroscopy Methods 0.000 description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 4
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 3
- PLFJWWUZKJKIPZ-UHFFFAOYSA-N 2-[2-[2-(2,6,8-trimethylnonan-4-yloxy)ethoxy]ethoxy]ethanol Chemical compound CC(C)CC(C)CC(CC(C)C)OCCOCCOCCO PLFJWWUZKJKIPZ-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 244000007835 Cyamopsis tetragonoloba Species 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 239000001856 Ethyl cellulose Substances 0.000 description 3
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 229940008099 dimethicone Drugs 0.000 description 3
- 238000004945 emulsification Methods 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 235000019325 ethyl cellulose Nutrition 0.000 description 3
- 229920001249 ethyl cellulose Polymers 0.000 description 3
- 239000007850 fluorescent dye Substances 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 239000003352 sequestering agent Substances 0.000 description 3
- 235000013599 spices Nutrition 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- QCYOIFVBYZNUNW-UHFFFAOYSA-N 2-(dimethylazaniumyl)propanoate Chemical group CN(C)C(C)C(O)=O QCYOIFVBYZNUNW-UHFFFAOYSA-N 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- UWKAYLJWKGQEPM-UHFFFAOYSA-N 3,7-dimethylocta-1,6-dien-3-yl acetate Chemical compound CC(C)=CCCC(C)(C=C)OC(C)=O UWKAYLJWKGQEPM-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical group COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical group [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- ZZXDRXVIRVJQBT-UHFFFAOYSA-M Xylenesulfonate Chemical compound CC1=CC=CC(S([O-])(=O)=O)=C1C ZZXDRXVIRVJQBT-UHFFFAOYSA-M 0.000 description 2
- 229920006243 acrylic copolymer Polymers 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 125000000746 allylic group Chemical group 0.000 description 2
- 125000003368 amide group Chemical group 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 2
- 150000004056 anthraquinones Chemical class 0.000 description 2
- 229940077388 benzenesulfonate Drugs 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 235000014121 butter Nutrition 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical class CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- UWKAYLJWKGQEPM-LBPRGKRZSA-N linalyl acetate Chemical compound CC(C)=CCC[C@](C)(C=C)OC(C)=O UWKAYLJWKGQEPM-LBPRGKRZSA-N 0.000 description 2
- 150000002632 lipids Chemical class 0.000 description 2
- YDSWCNNOKPMOTP-UHFFFAOYSA-N mellitic acid Chemical compound OC(=O)C1=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C(C(O)=O)=C1C(O)=O YDSWCNNOKPMOTP-UHFFFAOYSA-N 0.000 description 2
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 description 2
- 125000005395 methacrylic acid group Chemical group 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 125000004355 nitrogen functional group Chemical group 0.000 description 2
- 150000002924 oxiranes Chemical class 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 2
- 229920000768 polyamine Polymers 0.000 description 2
- 229920005646 polycarboxylate Polymers 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000001453 quaternary ammonium group Chemical group 0.000 description 2
- CZCBTSFUTPZVKJ-UHFFFAOYSA-N rose oxide Chemical compound CC1CCOC(C=C(C)C)C1 CZCBTSFUTPZVKJ-UHFFFAOYSA-N 0.000 description 2
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- 229960004418 trolamine Drugs 0.000 description 2
- 229920001567 vinyl ester resin Polymers 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 229940071104 xylenesulfonate Drugs 0.000 description 2
- JSYPRLVDJYQMAI-ODZAUARKSA-N (z)-but-2-enedioic acid;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)\C=C/C(O)=O JSYPRLVDJYQMAI-ODZAUARKSA-N 0.000 description 1
- WLWHLUQQCLCFNE-UHFFFAOYSA-N 1-ethenyl-3-methyl-2h-imidazole Chemical class CN1CN(C=C)C=C1 WLWHLUQQCLCFNE-UHFFFAOYSA-N 0.000 description 1
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 1
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- JBVOQKNLGSOPNZ-UHFFFAOYSA-N 2-propan-2-ylbenzenesulfonic acid Chemical compound CC(C)C1=CC=CC=C1S(O)(=O)=O JBVOQKNLGSOPNZ-UHFFFAOYSA-N 0.000 description 1
- MXMWUQAFMKOTIQ-UHFFFAOYSA-N 4-(carboxymethoxy)-4-oxobutanoic acid Chemical class OC(=O)CCC(=O)OCC(O)=O MXMWUQAFMKOTIQ-UHFFFAOYSA-N 0.000 description 1
- YGUMVDWOQQJBGA-VAWYXSNFSA-N 5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S(O)(=O)=O)C(S(=O)(=O)O)=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 YGUMVDWOQQJBGA-VAWYXSNFSA-N 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000004382 Amylase Substances 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- 102100032487 Beta-mannosidase Human genes 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical class OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- ONYKNTRMIOQQBJ-UHFFFAOYSA-N C(CCC(=O)O)(=O)O.C(CCC(=O)O)(=O)O.[O] Chemical compound C(CCC(=O)O)(=O)O.C(CCC(=O)O)(=O)O.[O] ONYKNTRMIOQQBJ-UHFFFAOYSA-N 0.000 description 1
- AYTZNKWXFCELCN-UHFFFAOYSA-N CNC.OCCC[O+] Chemical compound CNC.OCCC[O+] AYTZNKWXFCELCN-UHFFFAOYSA-N 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 108010059892 Cellulase Proteins 0.000 description 1
- 241000370738 Chlorion Species 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- 241000675108 Citrus tangerina Species 0.000 description 1
- 125000003535 D-glucopyranosyl group Chemical group [H]OC([H])([H])[C@@]1([H])OC([H])(*)[C@]([H])(O[H])[C@@]([H])(O[H])[C@]1([H])O[H] 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 244000178870 Lavandula angustifolia Species 0.000 description 1
- 235000010663 Lavandula angustifolia Nutrition 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- 108090001060 Lipase Proteins 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-L Malonate Chemical compound [O-]C(=O)CC([O-])=O OFOBLEOULBTSOW-UHFFFAOYSA-L 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 1
- 150000001204 N-oxides Chemical class 0.000 description 1
- DLKHENMIHBZMSE-UHFFFAOYSA-N OCCC[O].[Cl-].[NH4+] Chemical compound OCCC[O].[Cl-].[NH4+] DLKHENMIHBZMSE-UHFFFAOYSA-N 0.000 description 1
- 241000282372 Panthera onca Species 0.000 description 1
- 108010029182 Pectin lyase Proteins 0.000 description 1
- 102000035195 Peptidases Human genes 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- 102000003992 Peroxidases Human genes 0.000 description 1
- 229920000688 Poly[(2-ethyldimethylammonioethyl methacrylate ethyl sulfate)-co-(1-vinylpyrrolidone)] Polymers 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- LCTONWCANYUPML-UHFFFAOYSA-N Pyruvic acid Chemical class CC(=O)C(O)=O LCTONWCANYUPML-UHFFFAOYSA-N 0.000 description 1
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 229920004482 WACKER® Polymers 0.000 description 1
- AHWXCYJGJOLNFA-UHFFFAOYSA-N [1,4]benzoxazino[2,3-b]phenoxazine Chemical compound O1C2=CC=CC=C2N=C2C1=CC1=NC3=CC=CC=C3OC1=C2 AHWXCYJGJOLNFA-UHFFFAOYSA-N 0.000 description 1
- 150000003926 acrylamides Chemical class 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000005466 alkylenyl group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052728 basic metal Inorganic materials 0.000 description 1
- 150000003818 basic metals Chemical class 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 1
- 108010055059 beta-Mannosidase Proteins 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 229940106157 cellulase Drugs 0.000 description 1
- 125000003636 chemical group Chemical group 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229940071118 cumenesulfonate Drugs 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- XSNQECSCDATQEL-UHFFFAOYSA-N dihydromyrcenol Chemical compound C=CC(C)CCCC(C)(C)O XSNQECSCDATQEL-UHFFFAOYSA-N 0.000 description 1
- 229930008394 dihydromyrcenol Natural products 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- PPSZHCXTGRHULJ-UHFFFAOYSA-N dioxazine Chemical compound O1ON=CC=C1 PPSZHCXTGRHULJ-UHFFFAOYSA-N 0.000 description 1
- PMPJQLCPEQFEJW-UHFFFAOYSA-L disodium;2-[2-[4-[4-[2-(2-sulfonatophenyl)ethenyl]phenyl]phenyl]ethenyl]benzenesulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC=CC=C1C=CC1=CC=C(C=2C=CC(C=CC=3C(=CC=CC=3)S([O-])(=O)=O)=CC=2)C=C1 PMPJQLCPEQFEJW-UHFFFAOYSA-L 0.000 description 1
- VUJGKADZTYCLIL-YHPRVSEPSA-L disodium;5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfonatophenyl]ethenyl]benzenesulfonate Chemical compound [Na+].[Na+].C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S([O-])(=O)=O)C(S(=O)(=O)[O-])=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 VUJGKADZTYCLIL-YHPRVSEPSA-L 0.000 description 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- XEKOWRVHYACXOJ-UHFFFAOYSA-N ethyl acetate Substances CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 1
- KIWBPDUYBMNFTB-UHFFFAOYSA-M ethyl sulfate Chemical compound CCOS([O-])(=O)=O KIWBPDUYBMNFTB-UHFFFAOYSA-M 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 description 1
- 229940006461 iodide ion Drugs 0.000 description 1
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 125000000311 mannosyl group Chemical group C1([C@@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 150000002772 monosaccharides Chemical class 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000004028 organic sulfates Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 108040007629 peroxidase activity proteins Proteins 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 235000020030 perry Nutrition 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001444 polymaleic acid Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 150000003219 pyrazolines Chemical class 0.000 description 1
- 229930007790 rose oxide Natural products 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- RRLOOYQHUHGIRJ-UHFFFAOYSA-M sodium;ethyl sulfate Chemical compound [Na+].CCOS([O-])(=O)=O RRLOOYQHUHGIRJ-UHFFFAOYSA-M 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 235000020354 squash Nutrition 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 230000019635 sulfation Effects 0.000 description 1
- 238000005670 sulfation reaction Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical group CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- ABDKAPXRBAPSQN-UHFFFAOYSA-N veratrole Chemical compound COC1=CC=CC=C1OC ABDKAPXRBAPSQN-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3796—Amphoteric polymers or zwitterionic polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to a laundry detergent composition comprising (a) nonionic surfactant;(b) anionic surfactant; and, (c) a betaine functionalised silicone.
Description
Invention field
The present invention relates to laundry composition.More particularly, the present invention relates to the laundry composition carrying out in washing softening.
background of invention
Textile fabric, comprises clothing, cleans with cloth-washing detergent traditionally.After clean, fabric may often sense of touch be coarse.For prevent clean after particularly repeatedly wash and shortcoming that the fabric touch that experiences after wearing the cycle is coarse, Development Technology increases the pliability of fabric, the conditioner composition added when comprising rinsing and the softening system joined in detergent composition.These preparations are categorized as the cloth-washing detergent carrying out in washing softening sometimes.
Silicone material such as polydimethylsiloxane (PDMS) is called softener material in laundry.
Need to improve and carrying out the product stability of the cloth-washing detergent softened based on being in the suds of silicone softener material.
We have found that the problems referred to above can by means of the preparation customer service comprising the functionalized silicone of trimethyl-glycine.These preparations provide the product of the stability showing improvement compared to aforementioned prior art.
summary of the invention
First aspect, the present invention relates to a kind of laundry detergent composition, it comprises :-
(a) 1 to 40 nonionogenic tenside of wt.%;
(b) 1 to 40 anion surfactant of wt.%; With,
C silicone that () 0.1 to 10 trimethyl-glycine of wt.% is functionalized
Preferably, the functionalized silicone of described trimethyl-glycine is with the content of 0.25 to 10 wt.%, and the more preferably content of 0.25 to 7.5 wt.%, the content more preferably causing 5 wt.% with 0.5 exists.
Preferably, described nonionogenic tenside and anion surfactant are separately with 4 to 40 wt.%, and more preferably the content of 4 to 20 wt.% exists.
Preferably, described nonionogenic tenside comprises alcohol ethoxylate.
Preferably, cationic polymers exists with the content of 0.1 to 2.5 wt.%.
Preferably, described detergent composition is liquid laundry detergent compositions.
If described composition is liquid, then its pH is preferably 6.2 to 9, is more preferably pH 6.5 to 8.5.
detailed Description Of The Invention
As used herein, term " comprises " expression and comprises (including), by ... form (made up of), by ... form (composed of), by ... composition (consisting of) and/or substantially by ... composition (consisting essentially of).
All per-cents of citation are wt%, based on the total amount in laundry composition, except as otherwise noted.
The present invention relates to the laundry composition comprising the functionalized silicone of nonionogenic tenside, anion surfactant and trimethyl-glycine.Said composition shows the stability of improvement for silicone material compared to other silicone.
form of the present invention
The present invention can adopt any one as many forms of laundry composition.Example comprises powder, particle, bar, gel and liquid.Preferred said composition is the form of liquid laundry product.Preferably they are main cleaning product (main wash products).It can adopt and can dilute or the not dilutable laundry composition form for main washing.This laundry composition can be such as isotropic liquid, or surfactant-structured liquid.Particularly preferred form of the present invention comprises composition, detergent/tenderizer product, to provide " be in the suds and soften ".
Preferably, described detergent composition is liquid laundry detergent compositions.Preferably, the pH of described liquid composition is 6.2 to 9, more preferably pH 6.5 to 8.5.
the silicone that trimethyl-glycine is functionalized
The functionalized silicone of described trimethyl-glycine exists with the content of 0.1 to 10 wt.%.The functionalized silicone of described trimethyl-glycine, preferably with the content of 0.25 to 10 wt.%, more preferably with the content of 0.25 to 7.5 wt.%, even more preferably with the content of 0.5 to 5 wt.%, most preferably exists with the content of 0.5 to 2.5 wt.%.
Described silicone has trimethyl-glycine functional group.Described silicone can be any silicone, but preferred silicone backbone is based on polydimethylsiloxane (PDMS), also referred to as dimethicone.
Preferred trimethyl-glycine functional group has the silicone backbone be connected with following preferred betaine structure:
Preferred silicone is dimethicone propyl group PG-trimethyl-glycine, can trade(brand)name TEGOPREN 6950 and REWOCARE 6950 available from Evonik.
tensio-active agent
This detergent composition comprises nonionogenic tenside and anion surfactant.
Non-ionic surfactant component preferably comprises alcohol ethoxylate.
Described alcohol ethoxylate is formed by uncle or secondary alcohol and reacting ethylene oxide.Usually, aliphatic C
8to C
18uncle or secondary straight or branched alcohol are to produce molar weight needed for alcohol ethoxylate and reacting ethylene oxide.Preferred alcohol ethoxylate has 2 to 40, and preferably 3 to 30, more preferably 5 to 20 are connected to the ethylene oxide unit of aliphatic chain.
Tensio-active agent can be selected from " Surface Active Agents ", volume 1, Schwartz & Perry, Interscience 1949, volume 2, Schwartz, Perry & Berch, Interscience 1958, " the McCutcheon's Emulsifiers and Detergents " latest edition published by Manufacturing Confectioners Company or " Tenside-Taschenbuch ", H. Stache, the second edition, Carl Hauser Verlag, the tensio-active agent described in 1981.The tensio-active agent of preferred use is saturated.
Operable suitable nonionic detergent compounds is particularly including having the reaction product of the compound of hydrophobic group with hydrogen atoms (such as fatty alcohol, acid, acid amides or alkylphenol) with oxirane (particularly independent oxyethane or oxyethane are together with propylene oxide).Specific nonionic detergent compounds is C
6to C
22alkylphenol-ethylene oxide condensate, is generally 5 to 25 EO, i.e. each molecule 5 to 25 ethylene oxide units, and aliphatic C
8to C
18the condensation product of uncle or secondary straight or branched alcohol and oxyethane, is generally 5 to 40 EO.
Operable suitable anionic detergent compounds can for having containing the organo-sulfate of alkyl of about 8 to about 22 carbon atoms and the water-soluble alkali metal salts of sulfonic acid, and term alkyl is used for comprising the moieties of higher acyl.The example of suitable synthetic anionic detergent compound is sodium and the sylvite of alkyl sulfuric ester, particularly passes through the senior C that sulfation is such as produced by butter or Oleum Cocois
8to C
18alcohol obtain those, alkyl C
9to C
20benzene sulfonic acid sodium salt and potassium, particularly linear secondary alkyl C
10to C
15benzene sulfonic acid sodium salt; With alkyl glycerol base ether sodium sulfovinate, those ethers of the higher alcohols being particularly derived from butter or Oleum Cocois and the synthol that is derived from oil.Anion surfactant also can comprise C
6-C
22the soap of lipid acid.Preferred anionic detergent compounds is C
11to C
15sodium alkyl benzene sulfonate and C
12to C
18alkyl sulfuric ester sodium.The sulfonate comprised as hydrotrote (hydrotrobe) can be considered to anion surfactant as defined herein in addition.Also useful surface-active agents such as shows those of the middle description of the resistance to EP-A-328 177 (Unilever) saltoutd, the alkyl polyglucoside surfactant described in EP-A-070 074, and alkyl monoglycosides.
Nonionic detergent with 1 to 40 wt%, preferably 2 to 35 wt%, more preferably 4 to 20 wt%, or even 6 to 20 wt% amount exist.
Anion surfactant with 1 to 40 wt%, preferably 2 to 35 wt%, more preferably 4 to 20 wt%, or even 6 to 20 wt% amount exist.
The total amount of the tensio-active agent existed in composition is preferably at least 5 wt%, is more preferably at least 10 wt%.More preferably the total amount of tensio-active agent is 15 to 65 wt%, is preferably 10 to 50 wt%.
Except above-mentioned nonionic and anion surfactant, also can there is other tensio-active agent, such as cats product, and both sexes/zwitterionics such as betaines.
optional member
cationic polymers
Described composition can comprise cationic polymers in addition.
This term represents the polymkeric substance with overall positive charge.
Preferred cationic polymkeric substance is selected from: Cationic polysaccharide polymer, there is the non-glycopolymers of positively charged ion of cationic protonated amine or quaternary ammonium functional group, the non-glycopolymers of this positively charged ion is homopolymer or multipolymer, it is derived from the monomer containing amino or quaternary nitrogen functional group, be polymerized by the following monomer classification of at least one: acrylate, methacrylic ester, acrylamide, Methacrylamide; Allylic (comprising diallyl and methacrylic); Ethyleneimine; And/or vinyl monomer classification, and composition thereof.
More preferably cationic polymers is selected from cationic cellulose polymer, cationic guar polymer, the polymkeric substance of cation quaternary diallyl ammonium and (methyl) acrylate, (methyl) vinylformic acid diethylamino ethyl ester or (methyl) tbutylaminoethylacrylate with the homopolymer of its quaternary amine or protonated amines form or multipolymer, and composition thereof.
Most preferably cationic polymers is Cationic polysaccharide polymer.
More preferably this Cationic polysaccharide polymer is cation guar gum or cationic cellulose polymer.Most preferably cationic polymers is cationic cellulose polymer, such as quaternary Natvosol.
Said composition can comprise single cationic polymers, or the mixture of cationic polymers from identical or different kind, and namely said composition can contain Cationic polysaccharide polymer and the non-polysaccharide polymer of positively charged ion.
Cationic polysaccharide polymer
Term " Cationic polysaccharide polymer " represents the polymkeric substance with polysaccharide skeleton and overall positive charge.Polysaccharide is the polymkeric substance be made up of the monosaccharide monomers linked together by glycosidic link.
The cationic polysaccharide based polyalcohol existed in the present composition has the polysaccharide skeleton of modification, and modification and extra chemical group react with some free hydroxyl groups of polysaccharide skeleton, to provide overall positive charge to the cellulose monomer units of modification.
Being applicable to preferred Cationic polysaccharide polymer kind of the present invention is have through modification to introduce those of the polysaccharide skeleton of quaternary ammonium salt.Preferred quaternary ammonium salt is connected to polysaccharide skeleton by hydroxyethyl or hydroxypropyl.The charged nitrogen of preferred quaternary ammonium salt has one or more alkyl substituent.
Preferred cationic polysaccharide based polyalcohol has based on guar gum or based on cellulosic skeleton.Most preferred based on cellulosic cationic polymers.Guar gum is the polygalactomannan with the mannose backbone that β-Isosorbide-5-Nitrae connects, and it has the branch point of the galactose units to α-1,6 connection.
Suitable cationic guar derivative, such as guar hydroxypropyltrimonium ammonium chloride, its particular instance comprises by the commercially available Jaguar series of Rhone-Poulenc Incorporated, and serial by the N-Hance that Aqualon Division of Hercules, Inc are commercially available.
Example preferably based on the cationic polymers of guar gum is guar gum 2-hydroxyl-3-(trimethyl ammonium) propyl ether salt.
Mierocrystalline cellulose is have the polysaccharide of glucose as monomer whose, and especially, it is the straight-chain polymer of the D-glucopyranose units by β-Isosorbide-5-Nitrae glycosidic link connection, and is linear unbranched polymer.
Example cationic cellulose polymer is the salt of the epoxide reactive Natvosol replaced with trimethyl ammonium, polyquaternium 10(Polyquatemium 10 is called in the art) in the international nomenclature of cosmetic composition, and department Amerchol Corporation can be divided purchased from the son of Dow Chemical Company, commercially available with Polymer LR, JR and KG series of polymers.Other suitable cationic cellulose type comprises the polymeric quaternary ammonium salts with the epoxide reactive Natvosol of lauryl dimethyl ammonium-replacement, is called polyquaternium 24 in the art in the international nomenclature of cosmetic composition.These materials purchased from Amerchol Corporation, can be sold with Polymer LM-200.
The representative instance of preferred cationic cellulose polymer comprises coco dimethyl ammonium hydroxypropyl oxygen ethyl cellulose, Lauryldimonium Hydroxypropyl base oxygen ethyl cellulose, ammonium chloride hydroxypropyl oxygen ethyl cellulose, and ammonium chloride Natvosol; Mierocrystalline cellulose 2-hydroxyethyl 2-hydroxyl 3-(trimethyl ammonium) propyl ether salt (cellulose 2-hydroxyethyl 2-hydroxy 3-(trimethyl ammonio) propyl ether salt), polyquaternium-4, Polyquaternium-10, polyquaternium-24 and Polyquaternium-67 or its mixture.
More preferably cationic cellulose polymer is quaternized hydroxyether cellulosic cationic polymers.These are commonly called Polyquaternium-10.Sold with trade(brand)name UCARE by Amerchol Corporation for suitable commercial cationic cellulose polymer compound product of the present invention.
Other cationoid polymerisation species
Also the cationic polymers based on non-polysaccharide can be used.The non-glycopolymers of suitable positively charged ion comprises those with cationic protonated amine or quaternary ammonium functional group, it is the homopolymer or the multipolymer that are derived from the monomer containing amino or quaternary nitrogen functional group, be polymerized by the following monomeric species of at least one: acrylate, methacrylic ester, acrylamide, Methacrylamide; Allylic (comprising diallyl and methacrylic); Ethyleneimine; And/or vinyl monomer kind and composition thereof.
The non-glycopolymers of preferred positively charged ion comprises the polymkeric substance containing positively charged ion quaternary diallyl ammonium, (methyl) acrylate, (methyl) vinylformic acid diethylamino ethyl ester or (methyl) tbutylaminoethylacrylate with the homopolymer of its quaternary amine or protonated amines form or multipolymer, and composition thereof.
Other suitable cationic polymers for said composition comprises the multipolymer (being called as polyquaternium-16) of l-vinyl-2-pyrrolidone and 1-vinyl-3-methylimidazole salt; The multipolymer (being called as polyquaternium-11) of l-vinyl-2-pyrrolidone and dimethylaminoethyl methacrylate; Polymkeric substance containing positively charged ion quaternary diallyl ammonium, comprises such as dimethyl diallyl ammonium chloride homopolymer, the multipolymer (being called as polyquaternium 6 and polyquaternium 7 respectively) of acrylamide and dimethyl diallyl ammonium chloride; Acrylic acid ampholyte copolymer, comprise the multipolymer (being called as polyquaternium 22) of vinylformic acid and dimethyl diallyl ammonium chloride, the terpolymer (being called as polyquaternium 39) of vinylformic acid and dimethyl diallyl ammonium chloride and acrylamide, the terpolymer (being called as polyquaternium 47) of vinylformic acid and methacryiamidopropyl trimethyl ammonium chloride and methacrylic ester.The monomer that preferred positively charged ion replaces is the dialkyl amido allyl group acrylamide (dialkylaminoallcyl acrylamides) that positively charged ion replaces, dialkyl amido allyl methacrylamide, and combination.
The counter ion of cationic polymers are freely selected from halogen ion: chlorion, bromide anion and iodide ion; Or hydroxide radical, phosphate radical, sulfate radical, bisulfate ion, ethyl sulphate, methylsulfate, formate, and acetate moiety.
Cationic polymers is with 0.1 to 2.5 wt%, and preferably 0.1 to 2 wt%, more preferably the content of 0.2 to 1 wt% exists.
Many above-mentioned cationic polymerss can with many different molecular weight synthesis and commercially available.The molecular weight of preferred cationic polymkeric substance is 10,000 to 2,000, and 000 dalton, is more preferably 100,000 to 1000,000 dalton.
Detergent composition optionally can comprise one or more following optional compositions: cover dyestuff, enzyme, antiredeposition polymkeric substance, dye transfer inhibiting polymers, washing assistant, sequestering agent, opalizer and/or soil release polymer.
washing assistant and sequestering agent
This detergent composition also optionally can contain organic detergent washing assistant or the sequester agent material of relatively low content.Example comprises basic metal, Citrate trianion, succinate, malonate, carboxymethyl succinates, carboxylate salt, multi-carboxylate and many ethanoyl carboxylate salt (polyacetyl carboxylates).Particular instance comprises oxygen disuccinic acid, mellitic acid, benzene polycarboxylic acid, ethylenediamine tetraacetic acid (EDTA), DTPA, alkyl-or alkenyl succinic acid, the sodium of nitrilotriacetic acid(NTA) and citric acid, potassium and lithium salts.Other example is DEQUEST, the organic phospho acid salt form sequestering agent sold by Monsanto, and alkane hydroxyethylidene diphosphonic acid salt.
Other suitable organic washing-assisting detergent comprises known high-molecular weight polymer and the multipolymer with washing assistant performance.Such as, this material comprises suitable polyacrylic acid, polymaleic acid, and poly propenoic acid maleic acid and their salt, such as sold with title SOKALAN by BASF those.Another kind of suitable washing assistant is sodium carbonate.
If used, builder material can form about 0.5% to 20 wt% of composition, preferably 1 wt% to 10 wt%.Preferred washing assistant content is lower than 10 wt% of composition and preferably lower than 5 wt%.
Preferred laundry detergent agent formulation is that phosphate free helps laundry detergent agent formulation, namely containing the phosphoric acid salt lower than 1 wt%.
cover dyestuff
Cover dyestuff deposits on fabric during the washing or rinse step of washing process, for fabric provides visible colourity.Covering of white garments according to consumer preference, can realize by any color.Blue and purple is particularly preferred tone, and therefore preferred dyestuff or dye mixture for providing those of blueness or violet hue in white fabrics.The dyestuff that covers used is preferably blue or purple.
Cover dye chromophore and be preferably selected from monoazo, tetrazo, triphenyl methane, San Ben Bing dioxazine (triphenodioxazine), phthalocyanine, naphthalene lactan, azine and anthraquinone.Most preferably monoazo, tetrazo, azine and anthraquinone.
Most preferably dyestuff is with at least one sulfonated group.
Preferably cover dyestuff and be selected from substantive dyestuff, matching stain, hydrophobic dye, cationic dyestuff and reactive dyestuffs.
If comprised, cover dyestuff and be present in composition with 0.0001 to 0.01 wt%.
fluorescent agent
Said composition preferably includes fluorescent agent (white dyes).Fluorescent agent is well-known, and many this fluorescent agents are commercially available.Usually, these fluorescent agents with its an alkali metal salt, the form supply of such as sodium salt and use.The total amount of one or more fluorescent agents used in composition is generally 0.005 to 2 wt%, is more preferably 0.01 to 0.1 wt%.Preferred fluorescent agent classification is: two-styrylbiphenyl compounds, such as Tinopal (trade mark) CBS-X, two-amine stilbene, two-sulfoacid compound, such as pure Xtra and Blankophor of Tinopal DMS (trade mark) HRH, and pyrazoline compounds, such as Blankophor SN.Preferred fluorescent agent is: 2-(4-styryl-3-sulfo group phenyl)-2H-naphtho-[1, 2-d] 1-Sodium-1,2,4-Triazole (sodium 2-(4-styryl-3-sulfophenyl)-2H-napthol [1, 2-d] trazole), 4, 4'-bis-{ [(4-anilino-6-(N-methyl-N-2-hydroxyethyl) amino-1, 3, 5-triazine-2-base)] amino stilbene-2-2' disulfonate, 4, 4'-bis-{ [(4-anilino-6-morpholino-1, 3, 5-triazine-2-base)] amino stilbene-2-2' disulfonate, with 4, 4'-bis-(2-sulfostyryl) biphenyl disodium.
perfume compound
Preferred said composition comprises perfume compound.Perfume compound is preferably 0.001 to 3 wt%, most preferably is 0.1 to 1 wt% scope.CTFA (the Cosmetic that many suitable example of perfume compound are being published by CFTA Publications, Toiletry and Fragrance Association), 1992 International Buyers Guide, and provide in OPD 1993 Chemicals Buyers Directory the 80th annual version published by Schnell Publishing Co..
There is multiple fragrance components in preparation is universal phenomenon.In the present compositions, estimate to have four kinds or more, preferably five kinds or more, more preferably six kinds or more or the even distinct fragrance agent component of seven kinds or more.
In fragrance blend, preferably 15 to 25 wt% are head perfume (or spice) (top note).Head perfume (or spice) is defined (Journal of the Society of Cosmetic Chemists 6 (2): 80 [1955]) by Poucher.Preferred head perfume (or spice) is selected from tangerine oil, phantol, phanteine (linalyl acetate), lavandula angustifolia, dihydromyrcenol, rose oxide and cis 3-alcohol.
Preferably laundry treatment compositions is not such as, containing peroxygen bleach, SPC-D, Sodium peroxoborate and peracid.
polymkeric substance
Said composition can comprise one or more polymkeric substance.By promoting that dirt becomes scrappy (retail) and/or prevents dye transfer in solution or suspension, polymkeric substance can contribute to cleaning process.Polymkeric substance also can contribute to decontamination process.Dye transfer, antiredeposition and soil release polymer describe in further detail following.
Said composition can comprise one or more polymkeric substance.Example is carboxymethyl cellulose, Natvosol, hydroxypropylcellulose, PEG, poly-(vinyl alcohol), ethoxylated polyamine, polycarboxylate, such as polyacrylic ester, toxilic acid/acrylic copolymer and lauryl methacrylate(LMA)/acrylic copolymer.
dye transfer inhibitor
Modern detergent compositions uses polymkeric substance as so-called ' dyestuff-transfer inhibitor ' usually.These polymkeric substance prevent dye migration, particularly during long soak time.Usually; this dye transfer inhibitor comprises polyvinylpyrrolidonepolymers polymers; polyamines N-oxide polymer; the multipolymer of NVP and N-vinyl imidazole; manganese phthalocyanine; peroxidase and composition thereof, and usually exist with the content of 0.01 to 10 wt% based on the total amount in laundry composition.
antiredeposition polymkeric substance
Design antiredeposition polymkeric substance suspends or disperses dirt.Typically, antiredeposition polymkeric substance is ethoxylation and/or propoxylation is polyethylene imine based or polycarboxylate/salt material, such as with trade mark ACUSOL purchased from Dow Chemical, with Alcosperse purchased from Akzonobel or with Sokolan purchased from BASF based on acrylic acid homopolymer or multipolymer.
soil release polymer
The example of suitable soil release polymer comprises poly-(vinyl ester), such as C
1-C
6the graft copolymer of vinyl ester, is preferably grafted to poly-(vinyl-acetic ester) on polyalkylene oxide backbones.This type of commercially available stain remover comprises SOKALAN shaped material, such as SOKALAN HP-22, purchased from BASF (West Germany).Other dissimilar suitable soil release polymer comprises commercially available material ZELCON 5126 (purchased from DuPont) and MILEASE T (purchased from ICI).When it is present, soil release polymer can be comprised based on the total amount in laundry composition with the content of 0.01 to 10 wt%.Other example of soil release polymer is the terephthalic acid/diol multipolymer sold with trade(brand)name Texcare, Repel-o-tex, Gerol, Marloquest, Cirrasol.
help water solvent
Detergent composition, particularly liquid composition optionally can comprise and help water solvent, and it can prevent Formation of liquid crystals.Add and help water solvent therefore to help the clarification of composition/transparent.The suitable water solvent that helps includes but not limited to propylene glycol, ethanol, glycerine, urea, benzene sulfonate, tosylate, xylenesulfonate or cumene sulfonate.Suitable salt includes but not limited to sodium, potassium, ammonium, monoethanolamine, trolamine.Sulfonate also can be considered to anion surfactant as defined herein.Preferably, water solvent is helped to be selected from propylene glycol, xylene sulfonate/salt, ethanol and urea, to provide optimum performance.Help the amount of water solvent to be generally 0 to 30%, be preferably 0.5 to 30%, be more preferably 0.5 to 30%, most preferably be 1 to 15%.
enzyme
Enzyme also may reside in preparation.Preferred enzyme comprises proteolytic enzyme, lipase, pectin lyase, amylase, at, cellulase, mannase.If existed, enzyme can use known enzyme stablizer, such as boric acid stabilization.The impact of the cationic polymers that the selection of enzyme may be existed.
Embodiment
Test the consistency of various silicone and two kinds of anionic/nonionic surfactant laundry pharmaceutical bases ' Y ' and ' Z ' (respectively corresponding to high and low surfactant concentration).
Base preparation components | Y (Wt.%) | Z (wt.%) |
LAS (anion surfactant) (97%) | 5.15 | 14.5 |
SLES (anion surfactant) | 3.5 | 4 |
NEODOL 25-7E (nonionogenic tenside) | 7.5 | 17 |
PRIFAC 5908 (lipid acid) | 1 | 2.25 |
MPG | 15 | 17 |
Trolamine | 2 | 4.55 |
NaOH (47%) | 0.15 | 3 |
Water | 65.7 | 37.7 |
20g matrix formulations is weighed in bottle, adds emulsified silicone wherein.Stir said preparation, then make it at room temperature leave standstill.Preparation described in Visual Observations Observations detects stability.Said preparation is transparent, muddy or is separated.2 days (for matrix formulations ' Y '), or 1 week (for matrix formulations ' Z ') repeated observation afterwards.If after twice observation, preparation is limpid, then product is considered as stablizing.
The silicone used in embodiment A-G is softening silicone known in the prior art.The silicone that embodiment 1 uses trimethyl-glycine functionalized.This experiment uses emulsified silicone.' ortho states ' uses the silicone of emulsification.Use the silicone of the non-emulsification of Tergitol TMN-6 emulsification.
Use following test silicone :-
Embodiment | Title material |
A | 1, 2PDMS 1k cSt* |
B | 1, 2PDMS 1k cSt* + DPE |
C | 1, 2PDMS 60k cSt* |
D | 2Arristan 64 |
E | 2Finish WR1100 |
F | 2Finish WR1100 + DPE |
G | 1, 2PDMS 100nm emulsion |
1 | 3Rewocare 6950 (dimethicone propyl group PG-trimethyl-glycine) |
1pDMS refers to polydimethylsiloxane;
* 1kcSt refers to viscosity of material (1k cSt=1,000 centistoke etc..);
2pDMS, Arristan and Finish are the examples of softening silicone, and are derived from Dow Chemical respectively, CHT-Beitlich and Wacker;
3rewocare 6950 is derived from Evonik.
The silicone C of supply emulsion form, D, G and 1, use Tergitol TMN-6 emulsified silicone A, and E, or use combination emulsified silicone B and F of dipropylene glycol and Tergitol TMN-6 to reflect the product feature of the Rewocare 6950 (it is to comprise the emulsion form supply of dipropylene glycol) of supply.
The result introducing silicone in matrix formulations ' Y ' is :-
Embodiment | Initial inspection result | 2 days observationss |
A | Muddy | Be separated |
B | Muddy | Be separated |
C | Muddy | Be separated |
D | Muddy | Be separated |
E | Muddy | Be separated |
F | Muddy | Be separated |
G | Muddy | Be separated |
1 | Limpid | Limpid |
The silicone only having trimethyl-glycine functionalized provides acceptable limpid product.This test is unstable due to muddy and final being separated.
The result introducing silicone in matrix formulations ' Z ' is :-
Embodiment | Initial inspection result | 1 week observations |
A | Muddy | Be separated |
B | Muddy | Be separated |
C | Muddy | Be separated |
D | Muddy | Be separated |
E | Muddy | Be separated |
G | Muddy | Be separated |
1 | Limpid | Limpid |
Again, the silicone only having trimethyl-glycine functionalized provides acceptable limpid product.This test is unstable due to muddy and final being separated.
Claims (7)
1. a laundry detergent composition, it comprises :-
(a) 1 to 40 nonionogenic tenside of wt.%,
(b) 1 to 40 wt.% anion surfactant; With,
C silicone that () 0.1 to 10 wt.% trimethyl-glycine is functionalized.
2. composition according to claim 1, the functionalized silicone of wherein said trimethyl-glycine, with the content of 0.25 to 10 wt.%, preferably with the content of 0.25 to 7.5 wt.%, more preferably exists with the content of 0.5 to 5 wt.%.
3. according to the composition of claim 1 or claim 2, wherein said nonionogenic tenside is with 4 to 40 wt.%, and preferably the content of 4 to 20 wt.% exists, and described anion surfactant is with 4 to 40 wt.%, and preferably the content of 4 to 20 wt.% exists.
4., according to the composition of aforementioned any one of claim, wherein nonionogenic tenside comprises alcohol ethoxylate.
5., according to the composition of aforementioned any one of claim, it comprises the cationic polymers of 0.1 to 2.5 wt.% in addition.
6., according to the composition of aforementioned any one of claim, it is liquid composition.
7. composition according to claim 6, its pH is 6.2 to 9, preferred pH 6.5 to 8.5.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP12193353 | 2012-11-20 | ||
EP12193353.5 | 2012-11-20 | ||
PCT/EP2013/070525 WO2014079620A1 (en) | 2012-11-20 | 2013-10-02 | Laundry compositions |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104884597A true CN104884597A (en) | 2015-09-02 |
CN104884597B CN104884597B (en) | 2018-03-16 |
Family
ID=47221195
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201380060285.1A Expired - Fee Related CN104884597B (en) | 2012-11-20 | 2013-10-02 | Laundry composition |
Country Status (8)
Country | Link |
---|---|
EP (1) | EP2922938B1 (en) |
CN (1) | CN104884597B (en) |
AR (1) | AR093523A1 (en) |
BR (1) | BR112015009471B1 (en) |
CL (1) | CL2015001053A1 (en) |
TR (1) | TR201802447T4 (en) |
WO (1) | WO2014079620A1 (en) |
ZA (1) | ZA201502941B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104797696A (en) * | 2012-11-20 | 2015-07-22 | 荷兰联合利华有限公司 | Ingredient for use in a laundry composition |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB202203182D0 (en) | 2022-03-08 | 2022-04-20 | Rarity Bioscience Ab | Method of detection of a target nucleic acid sequence in a single reaction vessel |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5514302A (en) * | 1992-09-25 | 1996-05-07 | S.C. Johnson & Son, Inc. | Fabric cleaning shampoo compositions |
US5725736A (en) * | 1996-10-25 | 1998-03-10 | Kimberly-Clark Worldwide, Inc. | Tissue containing silicone betaines |
WO2000024853A2 (en) * | 1998-10-27 | 2000-05-04 | Unilever Plc | Wrinkle reduction laundry product compositions |
US20040033924A1 (en) * | 2002-08-14 | 2004-02-19 | Murphy Dennis Stephen | Methods for conferring fabric care benefits during laundering |
CN1942572A (en) * | 2004-04-16 | 2007-04-04 | 宝洁公司 | Liquid laundry detergent compositions with silicone fabric care agents |
CN104797696A (en) * | 2012-11-20 | 2015-07-22 | 荷兰联合利华有限公司 | Ingredient for use in a laundry composition |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3278670D1 (en) | 1981-07-13 | 1988-07-21 | Procter & Gamble | Foaming surfactant compositions |
GB8803036D0 (en) | 1988-02-10 | 1988-03-09 | Unilever Plc | Liquid detergents |
GB9220339D0 (en) * | 1992-09-25 | 1992-11-11 | Johnson & Son Inc S C | Improved fabric cleaning shampoo composition |
US6403548B1 (en) * | 1998-10-27 | 2002-06-11 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Wrinkle reduction laundry product compositions |
-
2013
- 2013-10-02 TR TR2018/02447T patent/TR201802447T4/en unknown
- 2013-10-02 CN CN201380060285.1A patent/CN104884597B/en not_active Expired - Fee Related
- 2013-10-02 EP EP13773698.9A patent/EP2922938B1/en not_active Not-in-force
- 2013-10-02 BR BR112015009471-6A patent/BR112015009471B1/en not_active IP Right Cessation
- 2013-10-02 WO PCT/EP2013/070525 patent/WO2014079620A1/en active Application Filing
- 2013-11-18 AR ARP130104238A patent/AR093523A1/en active IP Right Grant
-
2015
- 2015-04-23 CL CL2015001053A patent/CL2015001053A1/en unknown
- 2015-04-29 ZA ZA2015/02941A patent/ZA201502941B/en unknown
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5514302A (en) * | 1992-09-25 | 1996-05-07 | S.C. Johnson & Son, Inc. | Fabric cleaning shampoo compositions |
US5725736A (en) * | 1996-10-25 | 1998-03-10 | Kimberly-Clark Worldwide, Inc. | Tissue containing silicone betaines |
WO2000024853A2 (en) * | 1998-10-27 | 2000-05-04 | Unilever Plc | Wrinkle reduction laundry product compositions |
US20040033924A1 (en) * | 2002-08-14 | 2004-02-19 | Murphy Dennis Stephen | Methods for conferring fabric care benefits during laundering |
CN1942572A (en) * | 2004-04-16 | 2007-04-04 | 宝洁公司 | Liquid laundry detergent compositions with silicone fabric care agents |
CN104797696A (en) * | 2012-11-20 | 2015-07-22 | 荷兰联合利华有限公司 | Ingredient for use in a laundry composition |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104797696A (en) * | 2012-11-20 | 2015-07-22 | 荷兰联合利华有限公司 | Ingredient for use in a laundry composition |
CN104797696B (en) * | 2012-11-20 | 2017-09-08 | 荷兰联合利华有限公司 | Composition for laundry composition |
Also Published As
Publication number | Publication date |
---|---|
BR112015009471B1 (en) | 2021-06-15 |
EP2922938B1 (en) | 2018-02-07 |
AR093523A1 (en) | 2015-06-10 |
CN104884597B (en) | 2018-03-16 |
BR112015009471A2 (en) | 2017-07-04 |
ZA201502941B (en) | 2016-11-30 |
TR201802447T4 (en) | 2018-03-21 |
EP2922938A1 (en) | 2015-09-30 |
CL2015001053A1 (en) | 2015-08-28 |
WO2014079620A1 (en) | 2014-05-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN105745314B (en) | Laundry composition | |
CN104704101B (en) | Laundry composition | |
CN103975050B (en) | Laundry compositions | |
EP2922936B1 (en) | Laundry compositions | |
EP2791308B1 (en) | Laundry compositions | |
CN105874048B (en) | Laundry composition | |
EP3074497B1 (en) | Laundry compositions | |
WO2013087285A1 (en) | Laundry compositions and uses | |
CN104884597B (en) | Laundry composition | |
CN107075422B (en) | Laundry composition ingredients | |
CN104797696B (en) | Composition for laundry composition |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20210811 Address after: Rotterdam Patentee after: Unilever Intellectual Property Holdings Ltd. Address before: Rotterdam Patentee before: Unilever Nederland B.V. |
|
TR01 | Transfer of patent right | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20180316 |
|
CF01 | Termination of patent right due to non-payment of annual fee |